Synthesis and Catalytic Performance of Metal-zeolite Composite Catalysts

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (113 download)

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Book Synopsis Synthesis and Catalytic Performance of Metal-zeolite Composite Catalysts by : Camila Gomes Flores

Download or read book Synthesis and Catalytic Performance of Metal-zeolite Composite Catalysts written by Camila Gomes Flores and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites are microporous crystalline solids with a regular pore system, which have found numerous applications in industrial processes such as oil refining, organic synthesis, adsorption and separation. Very small pore size of zeolites (~1 nm) imposes diffusional limitations for many catalytic reactions. The catalytic performance of metal zeolite bifunctional catalysts can be improved by creating hierarchical zeolites and by controlling localization of metal species within the zeolite crystals. Impregnation is an efficient method for the preparation of bi-functional cobalt-zeolite catalysts for the direct production of liquid fuels from syngas. In the catalysts prepared via impregnation, cobalt occupies the cation exchange positions in the zeolite micropores decreasing the number of acid sites available for hydrocarbon isomerization and cracking. Isolation of cobalt ions in cationic positions reduces catalyst reducibility, makes it difficult to achieve metallic state and decreases the amount available metal active sites for Fischer Tropsch synthesis. We found that the presence of Na+ instead of H+ ions in the exchange positions of the large pore Beta zeolite favored deposition of cobalt on the external surface of the zeolite, while the acid sites in the zeolite micropores were not much affected. The large pore cobalt Beta zeolite catalyst with cobalt species localized on the external surface and high concentration of acid sites in the zeolite crystals has showed enhanced catalytic performance in Fischer-Tropsch synthesis combined with hydrocarbon isomerization. Another approach of this thesis has addressed creating hierarchical zeolites with several levels of meso- and microporosity using sacrificial templates. Hierarchical zeolites synthesized using cobalt containing carbon nanotubes, as sacrificial hard templates exhibited higher catalytic activity, lower methane selectivity and higher selectivity to isomerized hydrocarbons in Fischer-Tropsch synthesis. The synthesis strategy based on metal carbon nanotubes as sacrificial templates has been extended to other metals such as nickel and magnesium. This new approach to the synthesis of metal-zeolite composite increases the mesoporosity and improves the catalytic performance in hydrogenation of aromatics and anisole acylation.

Zeolites and Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 9783527630301
Total Pages : 918 pages
Book Rating : 4.6/5 (33 download)

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Book Synopsis Zeolites and Catalysis by : Jiri Cejka

Download or read book Zeolites and Catalysis written by Jiri Cejka and published by John Wiley & Sons. This book was released on 2010-05-27 with total page 918 pages. Available in PDF, EPUB and Kindle. Book excerpt: This indispensable two-volume handbook covers everything on this hot research field. The first part deals with the synthesis, modification, characterization and application of catalytic active zeolites, while the second focuses on such reaction types as cracking, hydrocracking, isomerization, reforming and other industrially important topics. Edited by a highly experienced and internationally renowned team with chapters written by the "Who's Who" of zeolite research.

Mesoporous Zeolites

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Publisher : John Wiley & Sons
ISBN 13 : 3527335749
Total Pages : 608 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Mesoporous Zeolites by : Javier García-Martínez

Download or read book Mesoporous Zeolites written by Javier García-Martínez and published by John Wiley & Sons. This book was released on 2015-05-26 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Authored by a top-level team of both academic and industrial researchers in the field, this is an up-to-date review of mesoporous zeolites. The leading experts cover novel preparation methods that allow for a purpose-oriented fine-tuning of zeolite properties, as well as the related materials, discussing the specific characterization methods and the applications in close relation to each individual preparation approach. The result is a self-contained treatment of the different classes of mesoporous zeolites. With its academic insights and practical relevance this is a comprehensive handbook for researchers in the field and related areas, as well as for developers from the chemical industry.

Structure and Reactivity of Metals in Zeolite Materials

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Publisher : Springer
ISBN 13 : 9783319989044
Total Pages : 0 pages
Book Rating : 4.9/5 (89 download)

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Book Synopsis Structure and Reactivity of Metals in Zeolite Materials by : Joaquín Pérez Pariente

Download or read book Structure and Reactivity of Metals in Zeolite Materials written by Joaquín Pérez Pariente and published by Springer. This book was released on 2018-09-22 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides the reader with the most up-to-date and relevant knowledge on the reactivity of metals located in zeolite materials, either in framework or extra-framework positions, and the way it is connected with the nature of the chemical environment provided by the host. Since the first report of the isomorphous substitution of titanium in the framework of zeolites giving rise to materials with unusual catalytic properties, the incorporation of many other metals have been investigated with the aim for developing catalysts with improved performance in different reactions. The continuous expansion of the field, both in the variety of metals and zeolite structures, has been accompanied by an increasing focus on the relationship between the reactivity of metal centers and their unique chemical environment. The concepts covered in this volume are of interest to people working in the field of inorganic and physical chemistry, catalysis and chemical engineering, but also for those more interested in theoretical approaches to chemical reactivity. In particular the volume is useful to postgraduate students conducting research in the design, synthesis and catalytic performance of metal-containing zeolites in both academic and application contexts.

Zeolite Catalysts

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Publisher : CRC Press
ISBN 13 : 100009863X
Total Pages : 302 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Zeolite Catalysts by : Subhash Bhatia

Download or read book Zeolite Catalysts written by Subhash Bhatia and published by CRC Press. This book was released on 2020-07-24 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presented in an easy-to-read form, this book on zeolite catalysis cover all aspects of the subject. It focuses on synthesis, structure, diffusion, deactivation, and industrial applications. This book is an ideal text for courses on catalysis or as a supplementary text for those studying applied or industrial chemistry. It is also a useful resource for anyone who works with zeolites as catalysts in the laboratory, pilot plants, or commercial installations.

Zeolites in Sustainable Chemistry

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Publisher : Springer
ISBN 13 : 366247395X
Total Pages : 490 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Zeolites in Sustainable Chemistry by : Feng-Shou Xiao

Download or read book Zeolites in Sustainable Chemistry written by Feng-Shou Xiao and published by Springer. This book was released on 2015-09-28 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the new development of zeolitic catalysts with an emphasis on new strategies for the preparation of zeolites, novel techniques for their characterization and emerging applications of zeolites as catalysts for sustainable chemistry, especially in the fields of energy, biomass conversion and environmental protection. Over the years, energy and the environment have become the most important global issues, while zeolitic catalysts play important roles in addressing them. With individual chapters written by leading experts, this book offers an essential reference work for researchers and professionals in both academia and industry. Feng-Shou Xiao is a Professor at the Department of Chemistry, Zhejiang University, China. Xiangju Meng is an Associate Professor at the Department of Chemistry, Zhejiang University, China.

Ceramic Catalysts

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Publisher : Elsevier
ISBN 13 : 0323856330
Total Pages : 352 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Ceramic Catalysts by : Manju Kurian

Download or read book Ceramic Catalysts written by Manju Kurian and published by Elsevier. This book was released on 2023-04-27 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ceramic Catalysts: Materials, Strategies and Applications focuses on synthesis techniques and applications of ceramic materials in heterogenous catalysis. In order to enable an affordable, sustainable, low-carbon economy, research activities have been intensified in this area over recent years. The rapid accumulation of results has been evaluated and summarized by recognized experts working in their respective fields in the form of separate and complementary chapters. The first part of the book is dedicated to synthesis and catalytic applications of different categories of ceramics that include both porous ceramics and ceramic composites. Catalytic applications of ceramics mainly involving waste-water treatment, combustion reactions, and fine chemical synthesis are also discussed. Use of ceramics as catalyst supports is also given importance in the book. The book is intended to act as a valuable reference resource for both researchers and postgraduate students with key emphasis on the following areas of research: Recent techniques for the synthesis of different ceramics; specific characteristics of each type of ceramics for catalytic applications; different types of catalyzed reactions based on inherent chemical characteristics and sustainable technologies based on ceramic catalysts.The book will be an essential reference resource for industrial and academic researchers, materials scientists, chemists, and environmental scientists. Provides an extensive overview of ceramic materials involved in catalysis Presents the current state of art as tremendous progress has been achieved over recent years Contributors are at the forefront of research Provides an evaluation and comparison of the different types of ceramic materials available, including structure, properties and performance

Recent advances in shape selectivity of MFI zeolite and its effect on the catalytic performance

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Author :
Publisher : OAE Publishing Inc.
ISBN 13 :
Total Pages : 26 pages
Book Rating : 4./5 ( download)

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Book Synopsis Recent advances in shape selectivity of MFI zeolite and its effect on the catalytic performance by : Lan Zhang

Download or read book Recent advances in shape selectivity of MFI zeolite and its effect on the catalytic performance written by Lan Zhang and published by OAE Publishing Inc.. This book was released on 2023-01-01 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt: MFI zeolite characterized by uniform pore size, adjustable acidity, and high-temperature resistance has a broad application prospect in catalytic reactions. However, controlling the product distribution of zeolite as a catalyst is still confronting great challenges and applications. It is considered as an effective way to control the product distribution by developing and improving new zeolites to modulate their shape selective effect. In recent years, researchers have achieved remarkable successes in investigating the shape selective modulation of zeolites on catalytic reaction and molecular diffusion. The microporous channels of MFI zeolite are the main places for the entry and exit of reactants or product molecules. This review provides the research progress of the shape-selective modulation of MFI zeolite channels and its influence on a series of catalytic performances in recent years. The shape-selective modulation of microporous channels of zeolite, encapsulation of micropores to metals, catalysis of mesoporous zeolite, and the distribution of framework Al were all systematically discussed. The development of advanced catalysts still faces great challenges and potential applications. Finally, we discussed the problems to be addressed urgently in the field of zeolite catalysts in the future.

Catalysis and Zeolites

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Publisher : Springer Science & Business Media
ISBN 13 : 3662037645
Total Pages : 582 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Catalysis and Zeolites by : Jens Weitkamp

Download or read book Catalysis and Zeolites written by Jens Weitkamp and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites occur in nature and have been known for almost 250 years as alumino silicate minerals. Examples are clinoptilolite, mordenite, offretite, ferrierite, erionite and chabazite. Today, most of these and many other zeolites are of great interest in heterogeneous catalysis, yet their naturally occurring forms are of limited value as catalysts because nature has not optimized their properties for catalytic applications and the naturally occurring zeolites almost always contain undesired impurity phases. It was only with the advent of synthetic zeolites in the period from about 1948 to 1959 (thanks to the pioneering work of R. M. Barrer and R. M. Milton) that this class of porous materials began to playa role in catalysis. A landmark event was the introduction of synthetic faujasites (zeolite X at first, zeolite Y slightly later) as catalysts in fluid catalytic cracking (FCC) of heavy petroleum distillates in 1962, one of the most important chemical processes with a worldwide capacity of the order of 500 million t/a. Compared to the previously used amorphous silica-alumina catalysts, the zeolites were not only orders of magnitude more active, which enabled drastic process engineering improvements to be made, but they also brought about a significant increase in the yield of the target product, viz. motor gasoline. With the huge FCC capacity worldwide, the added value of this yield enhancement is of the order of 10 billion US $ per year.

Characterization and Design of Zeolite Catalysts

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Publisher : Springer Science & Business Media
ISBN 13 : 3642126200
Total Pages : 189 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Characterization and Design of Zeolite Catalysts by : Miki Niwa

Download or read book Characterization and Design of Zeolite Catalysts written by Miki Niwa and published by Springer Science & Business Media. This book was released on 2010-08-17 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysis and catalyst is a key technology to solve the problems in energy and environment issues to sustain our human society. We believe that comprehensive understanding of the catalysis and catalyst provides us a chance to develop a new catalyst and contributes greatly to our society. However, the ?eld of heterogeneous catalyst is dif?cultto study andstill stays behindmoredeveloped?elds ofchemistry such as organic and physical chemistries. This is a dilemma to the chemists who study the catalysis and catalyst. While we can accomplish the progress in the - dustrial application, the scienti?c understandingis not complete yet. A gap between the useful application and incomplete scienti?c understanding, however, becomes smaller and smaller in recent years. Because zeolites are ?ne crystals, and the structure is clearly known, the study on the catalysis using the zeolites is easier than those encountered in other catalysts such as metals and metal oxides. Very fortunately, zeolites provide us the strong acidity with the ?ne distribution which enables various useful catalytic reactions. When some metals and cations are loaded in close to the acid sites, these loadede- ments show extraordinarycharacters, and many catalytic reactions proceed thereon.

Zeolites in Catalysis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782627847
Total Pages : 547 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Zeolites in Catalysis by : Jiří Čejka

Download or read book Zeolites in Catalysis written by Jiří Čejka and published by Royal Society of Chemistry. This book was released on 2017-06-07 with total page 547 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.

Zeolite Characterization and Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 140209678X
Total Pages : 372 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Zeolite Characterization and Catalysis by : Arthur W. Chester

Download or read book Zeolite Characterization and Catalysis written by Arthur W. Chester and published by Springer Science & Business Media. This book was released on 2009-10-03 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The idea for putting together a tutorial on zeolites came originally from my co-editor, Eric Derouane, about 5 years ago. I ?rst met Eric in the mid-1980s when he spent 2 years working for Mobil R&D at our then Corporate lab at Princeton, NJ. He was on the senior technical staff with projects in the synthesis and characterization of new materials. At that time, I managed a group at our Paulsboro lab that was responsible for catalyst characterization in support of our catalyst and process development efforts, and also had a substantial group working on new material synthesis. Hence, our interests overlapped considerably and we met regularly. After Eric moved back to Namur (initially), we maintained contact, and in the 1990s, we met a number of times in Europe on projects of joint interest. It was after I retired from ExxonMobil in 2002 that we began to discuss the tutorial concept seriously. Eric had (semi-)retired and lived on the Algarve, the southern coast of Portugal. In January 2003, my wife and I spent 3 weeks outside of Lagos, and I worked parts of most days with Eric on the proposed content of the book. We decided on a comprehensive approach that ultimately amounted to some 20+ chapters covering all of zeolite chemistry and catalysis and gave it the title Zeolite Chemistry and Catalysis: An integrated Approach and Tutorial.

Synthesis, Modification, Characterization and Catalytic Studies of Zeolite Based Bifunctional Catalysts for Hydroisomerization Reactions

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (53 download)

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Book Synopsis Synthesis, Modification, Characterization and Catalytic Studies of Zeolite Based Bifunctional Catalysts for Hydroisomerization Reactions by :

Download or read book Synthesis, Modification, Characterization and Catalytic Studies of Zeolite Based Bifunctional Catalysts for Hydroisomerization Reactions written by and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolite ZSM-12 was identified as a promising candidate for hydroisomerization of n-alkanes and a large part of the work was focused on the preparation of ZSM-12 and studying its catalytic performance. Reliable and efficient methods for synthesis of ZSM-12 with high levels of acidity were not available in the literature. Through systematic studies, the synthesis was greatly simplified and ZSM-12 was successfully crystallized at a relatively low Si/Al ratio of 30 using tetraethylammonium cations as the template. In the hydroisomerization of n-heptane as well as mixtures of n-alkanes, ZSM-12 catalysts provided a significantly higher selectivity to both monobranched and dibranched isomers, compared to other large pore zeolites. Kinetic studies carried out using individual octane isomers showed that the formation of certain dibranched and tribranched isomers was mildly hindered by the shape selective effect of the ZSM-12 pore, which resulted in the higher isomer yield. It was found that the cracking activity of ZSM-12 could be increased by three to four times by carrying out the calcination to remove the template at temperatures higher than what is normally used. The variation of the cracking activity with respect to the calcination temperature was very unusual, only the samples calcined in two separate narrow temperature ranges showed substantially enhanced activity. Extensive FTIR characterizations, with pyridine adsorbed on the acidic zeolite, indicated that the enhancement in the cracking activity was due to a synergistic interaction between the framework Brn̲sted acid sites and a Lewis acidic extra framework aluminum (possibly cationic) species present in the zeolite. Hydroisomerization of n-heptane was studied over large pore zeolites with different acidity properties and wide range of Si/Al ratios. The performance of zeolite catalysts with enhanced activity were very sensitive to the platinum precursor used and the pretreatment conditions. The results suggested that zeolite acidity characteristics do not affect the isomer yield, provided the catalyst is carefully prepared to ensure good metal/acidity balance. Therefore, it appears that the only way to obtain isomer yields higher than that of Y zeolite is by employing shape selective zeolites.

Advances in Heterocatalysis by Nanomaterials

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Publisher : MDPI
ISBN 13 : 3039288350
Total Pages : 166 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Advances in Heterocatalysis by Nanomaterials by : Ioannis V. Yentekakis

Download or read book Advances in Heterocatalysis by Nanomaterials written by Ioannis V. Yentekakis and published by MDPI. This book was released on 2020-05-13 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneous catalysis played, plays, and will continue to play, a major key role in industrial processes for large-scale synthesis of commodity chemicals of global importance, and in catalytic systems that possess a critical role in energy generation and environmental protection approaches. As a result of the ongoing progress in materials science, nanotechnology, and characterizations, great advances have been achieved in heterogeneous catalysis by nanomaterials. Efficient approaches and advanced methods for the design of nano-structured composite materials (up to atomic level), subject to specific nano-morphologies with enhanced metal–metal and metal–support interactions favorable for catalysis (that enable fine-tuning of the critical properties of the designed catalysts), provide optimized catalysts with outstanding performances in numerous eco-friendly and cost-effective applications. Accordingly, great progress has been achieved involving, for example, emissions control, waste treatment, photocatalytic, bio-refinery, CO2 utilization, and fuel cells applications, as well as hydrocarbon processing for H2, added-value chemicals, and liquid fuels production. The themed Special Issue has succeeded in collecting 10 high-quality contributions that cover recent research progress in the field for a variety of applications (e.g., environment, energy, added-value chemicals/organics synthesis, and bio-transformation) declaring the prospect and importance of nanomaterials in all the directions of heterogeneous catalysis.

Zeolites and Zeolite-like Materials

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Publisher : Elsevier
ISBN 13 : 0444635149
Total Pages : 475 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Zeolites and Zeolite-like Materials by : Bert Sels

Download or read book Zeolites and Zeolite-like Materials written by Bert Sels and published by Elsevier. This book was released on 2016-07-29 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and Zeolite-like Materials offers a comprehensive and up-to-date review of the important areas of zeolite synthesis, characterization, and applications. Its chapters are written in an educational, easy-to-understand format for a generation of young zeolite chemists, especially those who are just starting research on the topic and need a reference that not only reflects the current state of zeolite research, but also identifies gaps and opportunities. The book demonstrates various applications of zeolites in heterogeneous catalysis and biomass conversion and identifies the endless possibilities that exist for this class of materials, their structures, functions, and future applications. In addition, it demonstrates that zeolite-like materials should be regarded as a living body developing towards new modern applications, thereby responding to the needs of modern technology challenges, including biomass conversion, medicine, laser techniques, and nanomaterial design, etc. The book will be of interest not only to zeolite-focused researchers, but also to a broad scientific and non-scientific audience. Provides a comprehensive review of the literature pertaining to zeolites and zeolite-like materials since 2000 Covers the chemistry of novel zeolite-like materials such as Metal-Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), hierarchical zeolite materials, new mesoporous and composite zeolite-like micro/mesoporous materials Presents essential information of the new zeolite-like structures, with a balanced coverage of the most important areas of the zeolite research (synthesis, characterization, adsorption, catalysis, new applications of zeolites and zeolite-like materials) Contains chapters prepared by known specialists who are members of the International Zeolite Association

Chemistry of Zeolites and Related Porous Materials

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Publisher : John Wiley & Sons
ISBN 13 : 0470822368
Total Pages : 616 pages
Book Rating : 4.4/5 (78 download)

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Book Synopsis Chemistry of Zeolites and Related Porous Materials by : Ruren Xu

Download or read book Chemistry of Zeolites and Related Porous Materials written by Ruren Xu and published by John Wiley & Sons. This book was released on 2009-05-29 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Advanced Zeolite Science and Applications

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Publisher : Elsevier
ISBN 13 : 0080886957
Total Pages : 715 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Advanced Zeolite Science and Applications by : Michael Stöcker

Download or read book Advanced Zeolite Science and Applications written by Michael Stöcker and published by Elsevier. This book was released on 1994-07-19 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: Zeolites and related microporous materials are used in oil processing and in the fine and petrochemical industries on a large scale. New applications of zeolites contribute to environmentally friendly processes and refined zeolites such as catalytic zeolite membranes and zeolites containing exhaust-pipe reactors are being introduced. Recent diversity in zeolite research has been fueled by the increase in number of microporous materials and the combination with interfacing science areas. The possibility to accommodate ions, large molecules or nanostructures in the crystalline matrix has been explored and the performance of electronic, acoustic and photonic modified response of the materials has been tested. This volume provides up-to-date information on new zeolite and related materials and composites, their applications, testing of new processes and techniques, and promising laboratory results as well. A vast amount of work from a fundamental aspect is incorporated. In particular, the combination of science and application offers useful information for readers interested in molecular sieves.