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Structural Spectroscopic And Kinetic Investigation Of Modified Photochromic Ruthenium Sulfoxide Complexes
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Book Synopsis Structural, Spectroscopic, and Kinetic Investigation of Modified Photochromic Ruthenium Sulfoxide Complexes by : Jason Patrick Malizia
Download or read book Structural, Spectroscopic, and Kinetic Investigation of Modified Photochromic Ruthenium Sulfoxide Complexes written by Jason Patrick Malizia and published by . This book was released on 2014 with total page 267 pages. Available in PDF, EPUB and Kindle. Book excerpt: The complexes [Ru(bpy)2(bpSOp)](PF6)2 (bpSOp = 1,3-bis(phenylsulfinyl)propane), [Ru(bpy)2(bpSOb)](PF6)2 (bpSOb = 1,4-bis(phenylsulfinyl)butane), [Ru(bpy)2(PhSOEtSPh)](PF6)2 (PhSOEtSPh = 2-(phenylsulfinyl)ethylsulfanylbenzene), and [Ru(bpy)2(PhSOEtSePh)](PF6)2 (PhSOEtSePh = 2-(phenylsulfinyl)ethylselenobenzene) were synthesized and investigated by a number of techniques. The structure of these complexes were characterized by 1D and 2D NMR along with X-ray crystallography. Electrochemical measurements were performed on monosulfoxide metal complexes and S to O linkage isomerization was found to occur after oxidation of ruthenium(II) to ruthenium(III). MLCT irradiation of the complexes in solution in conjunction with electronic absorption measurements have shown that the monosulfoxide complexes undergo S to O linkage isomerization and the bissulfoxide complexes undergo SS to SO and SS to OO isomerization upon absorption of a single photon. It has been shown that small or simple modifications to the sulfoxide chelate in polypyridyl ruthenium sulfoxides lead to dramatic changes in the ground and excited state dynamics and kinetics of these complexes. Specifically, increasing the size of the chelating ring of a bidentate sulfoxide ligand through the insertion of a methylene group has been shown to increase the efficacy and speed of isomerization while the chemical nature of the 2nd donor atom in a bidentate sulfoxide ligand plays a pivotal role in the observed photophysics and photochemistry of these complexes.
Book Synopsis Structural Characterization and Spectroscopic Investigation of Isomerization Dynamics in Photochromic Polypyridyl Ruthenium(II) Chelating Mono- and Bis-sulfoxide Complexes by :
Download or read book Structural Characterization and Spectroscopic Investigation of Isomerization Dynamics in Photochromic Polypyridyl Ruthenium(II) Chelating Mono- and Bis-sulfoxide Complexes written by and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Spectroscopic and Kinetic Characterization of Photochromic Ruthenium Chelating Sulfoxide Complexes by : Beth Anne McClure
Download or read book Spectroscopic and Kinetic Characterization of Photochromic Ruthenium Chelating Sulfoxide Complexes written by Beth Anne McClure and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Spectroscopic Characterization of Photochromic Ruthenium and Osmium Chelating Sulfoxide Complexes by : Komal Garg
Download or read book Synthesis and Spectroscopic Characterization of Photochromic Ruthenium and Osmium Chelating Sulfoxide Complexes written by Komal Garg and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chromic Phenomena 3rd Edition by : Peter Bamfield
Download or read book Chromic Phenomena 3rd Edition written by Peter Bamfield and published by Royal Society of Chemistry. This book was released on 2018-08-24 with total page 812 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chromic or colour related phenomena are produced in response to a chemical or physical stimulus. This new edition will update the information on all those areas where chemicals or materials interact with light to produce colour, a colour change, or luminescence especially in the imaging, analysis, lighting and display areas. The book has been restructured to show greater emphasis on applications where 'coloured' compounds are used to transfer energy or manipulate light in some way therefore reducing the details on classical dyes and pigments. In the past eight years, since the previous edition, there has been a remarkable increase in the number of papers and reviews being produced reflecting the growth of interest in this area. This ongoing research interest is matched by a large number of new technological applications gaining commercial value covering e.g. biomedical areas, energy, data storage, physical colour, bio-inspired materials and photonics. This book appeals to industrial chemists, professionals, postgraduates and as high level recommended reading for colour technology courses.
Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty
Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Book Synopsis Molecular Materials by : Duncan W. Bruce
Download or read book Molecular Materials written by Duncan W. Bruce and published by John Wiley & Sons. This book was released on 2011-04-04 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: “... the book does an excellent job of putting together several different classes of materials. Many common points emerge, and the book may facilitate the development of hybrids in which the qualities of the “parents” are enhanced.” –Angew. Chem. Int. Ed. 2011 With applications in optoelectronics and photonics, quantum information processing, nanotechnology and data storage, molecular materials enrich our daily lives in countless ways. These materials have properties that depend on their exact structure, the degree of order in the way the molecules are aligned and their crystalline nature. Small, delicate changes in molecular structure can totally alter the properties of the material in bulk. There has been increasing emphasis on functional metal complexes that demonstrate a wide range of physical phenomena. Molecular Materials represents the diversity of the area, encapsulating magnetic, optical and electrical properties, with chapters on: Metal-Based Quadratic Nonlinear Optical Materials Physical Properties of Metallomesogens Molecular Magnetic Materials Molecular Inorganic Conductors and Superconductors Molecular Nanomagnets Structured to include a clear introduction, a discussion of the basic concepts and up-to-date coverage of key aspects, each chapter provides a detailed review which conveys the excitement of work in that field. Additional volumes in the Inorganic Materials Series: Low-Dimensional Solids | Molecular Materials | Porous Materials | Energy Materials
Book Synopsis Bioinorganic Photochemistry by : Grazyna Stochel
Download or read book Bioinorganic Photochemistry written by Grazyna Stochel and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.
Book Synopsis New Frontiers in Photochromism by : Masahiro Irie
Download or read book New Frontiers in Photochromism written by Masahiro Irie and published by Springer Science & Business Media. This book was released on 2013-05-27 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photochromism is the reversible phototransformation of a chemical species between two forms having different absorption spectra. During the phototransformation not only the absorption spectra but also various physicochemical properties change, such as the refractive index, dielectric constant, oxidation/reduction potential, and geometrical structure. The property changes can be applied to photonic equipment such as erasable memory media, photo-optical switch components, and display devices. This book compiles the accomplishments of the research project titled “New Frontiers in Photochromism” supported by the Ministry of Education, Culture, Sports, Science and Technology of Japan. The project focused not only on the above-mentioned classical subjects in photochromism, such as color changes, optical memory, and optical switches, but also on fundamental physicochemical studies and unprecedented application fields that have not yet been explored in photochromism. The latter topics include light-driven mechanical motion, photocontrol of surface wettability, metal deposition on solid materials, photocontrol of chiral properties, ultrafast decoloration dyes, and femtosecond laser experiments, among others.
Download or read book Polymer Synthesis written by and published by Springer Science & Business Media. This book was released on 2004-10-08 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. T. Takata, N. Kihara, Y. Furusho: Polyrotaxanes and Polycatenanes: Recent Advances in Syntheses and Applications of Polymers Comprising of Interlocked Structures.- 2. M. Suginome, Y. Ito: Transition Metal-Mediated Polymerization of Isocyanides.- 3. K. Osakada, D. Takeuchi: Coordination Polymerization of Dienes, Allenes and Methylenecycloalkanes.
Book Synopsis Recent Advances in Density Functional Methods by : Delano Pun Chong
Download or read book Recent Advances in Density Functional Methods written by Delano Pun Chong and published by World Scientific. This book was released on 1995 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Of all the different areas in computational chemistry, density functional theory (DFT) enjoys the most rapid development. Even at the level of the local density approximation (LDA), which is computationally less demanding, DFT can usually provide better answers than Hartree-Fock formalism for large systems such as clusters and solids. For atoms and molecules, the results from DFT often rival those obtained by ab initio quantum chemistry, partly because larger basis sets can be used. Such encouraging results have in turn stimulated workers to further investigate the formal theory as well as the computational methodology of DFT.This Part II expands on the methodology and applications of DFT. Some of the chapters report on the latest developments (since the publication of Part I in 1995), while others extend the applications to wider range of molecules and their environments. Together, this and other recent review volumes on DFT show that DFT provides an efficient and accurate alternative to traditional quantum chemical methods. Such demonstration should hopefully stimulate frutiful developments in formal theory, better exchange-correlation functionals, and linear scaling methodology.
Book Synopsis Photochemistry and Photophysics of Coordination Compounds I by : Vincenzo Balzani
Download or read book Photochemistry and Photophysics of Coordination Compounds I written by Vincenzo Balzani and published by Springer. This book was released on 2007-07-31 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents critical reviews of the current position and future trends in modern chemical research. It offers short and concise reports on chemistry, each written by world renowned experts.
Book Synopsis Micro and Nanomanufacturing Volume II by : Mark J. Jackson
Download or read book Micro and Nanomanufacturing Volume II written by Mark J. Jackson and published by Springer. This book was released on 2017-10-28 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a comprehensive treatment of micro and nanofabrication techniques, and applies established and research laboratory manufacturing techniques to a wide variety of materials. It is a companion volume to “Micro and Nanomanufacturing” (2007) and covers new topics such as aligned nanowire growth, molecular dynamics simulation of nanomaterials, atomic force microscopy for microbial cell surfaces, 3D printing of pharmaceuticals, microvascular coaptation methods, and more. The chapters also cover a wide variety of applications in areas such as surgery, auto components, living cell detection, dentistry, nanoparticles in medicine, and aerospace components. This is an ideal text for professionals working in the field, and for graduate students in micro and nanomanufacturing courses.
Book Synopsis Molecular Machines and Motors by : J.-P. Sauvage
Download or read book Molecular Machines and Motors written by J.-P. Sauvage and published by Springer Science & Business Media. This book was released on 2001-07-03 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series presents critical reviews of the present position and future trends in modern chemical research. It consists of short and concise reports on chemistry, each written by the world’s renowned experts, and still valid and useful after 5 or 10 years.
Book Synopsis Handbook of Photochemistry by : Marco Montalti
Download or read book Handbook of Photochemistry written by Marco Montalti and published by CRC Press. This book was released on 2006-02-21 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fie
Book Synopsis Electroanalytical Chemistry by : Gary A. Mabbott
Download or read book Electroanalytical Chemistry written by Gary A. Mabbott and published by John Wiley & Sons. This book was released on 2020-03-04 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a strong foundation in electrochemical principles and best practices Written for undergraduate majors in chemistry and chemical engineering, this book teaches the basic principles of electroanalytical chemistry and illustrates best practices through the use of case studies of organic reactions and catalysis using voltammetric methods and of the measurement of clinical and environmental analytes by potentiometric techniques. It provides insight beyond the field of analysis as students address problems arising in many areas of science and technology. The book also emphasizes electrochemical phenomena and conceptual models to help readers understand the influence of experimental conditions and the interpretation of results for common potentiometric and voltammetric methods. Electroanalytical Chemistry: Principles, Best Practices, and Case Studies begins by introducing some basic concepts in electrical phenomena. It then moves on to a chapter that examines the potentiometry of oxidation-reduction processes, followed by another on the potentiometry of ion selective electrodes. Other sections look at: applications of ion selective electrodes; controlled potential methods; case studies in controlled potential methods; and instrumentation. The book also features several appendixes covering: Ionic Strength, Activity and Activity Coefficients; The Nicolsky-Eisenman Equation; The Henderson Equation for Liquid Junction Potentials; Selected Standard Electrode Potentials; and The Nernst Equation Derivation. Introduces the principles of modern electrochemical sensors and instrumental chemical analysis using potentiometric and voltammetric methods Develops conceptual models underlying electrochemical phenomena and useful equations Illustrates best practice with short case studies of organic reaction mechanisms using voltammetry and quantitative analysis with ion selective electrodes Offers instructors the opportunity to select focus areas and tailor the book to their course by providing a collection of shorter texts, each dedicated to a single field Intended as one of a series of modules for teaching undergraduate courses in instrumental chemical analysis Electroanalytical Chemistry: Principles, Best Practices, and Case Studies is an ideal textbook for undergraduate majors in chemistry and chemical engineering taking instrumental analysis courses. It would also benefit professional chemists who need an introduction to potentiometry or voltammetry.
Book Synopsis Macromolecular Syntheses by : Charles Gilbert Overberger
Download or read book Macromolecular Syntheses written by Charles Gilbert Overberger and published by . This book was released on 2002 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an up-to-date collection of presentations and posters given at a tutorial and workshop sponsored by the Polymer Division of the American Chemical Society. The material included encompasses recent research results, overviews of critical areas and short presentations in the form of posters and preprints. The book is targeted at established workers in the field of fluoropolymers as well as those wishing to develop a quick understanding of current knowledge and trends in this important field.
