Stereochemical Aspects Of Organolithium Compounds

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Stereochemical Aspects of Organolithium Compounds

Author : Robert E. Gawley
Publisher : John Wiley & Sons
ISBN 13 : 3906390632
Total Pages : 305 pages
Book Rating : 4.9/5 (63 download)

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Book Synopsis Stereochemical Aspects of Organolithium Compounds by : Robert E. Gawley

Download or read book Stereochemical Aspects of Organolithium Compounds written by Robert E. Gawley and published by John Wiley & Sons. This book was released on 2010-04-16 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Topics in Stereochemistry, previously edited by "the father of stereochemistry" Ernest L. Eliel, is a longstanding, successful series covering the most important advances in the field. The much-anticipated Volume 26 on stereochemical aspects of organolithium compounds includes chapters on the following topics: * Asymmetric Deprotonations Using Chiral Lithium Amide Bases * Self-Regeneration of Stereocenters (SRS) via Stereolabile Axially Chiral Intermediates * Overview of Carbanion Dynamics and Electrophilic Substitutions in Chiral Organolithium Compounds * Oxiranyllithiums as Chiral Synthons for Asymmetric Synthesis * Test on the Configurational Stability/Lability of Organolithium Compounds * Mechanism and Stereochemical Features in Asymmetric Deprotonation Using RLi/(-)-Sparteine Bases * Dynamic Resolutions of Chiral Organolithiums Volume 26 of Topics in Stereochemistry marks the end of an era, while developing a bridge to the next generation. A new generation in publishing, parallel to a new generation in Stereochemistry mandated a new venue and modus operandi for Topics. Zurich, the home of Werner and Wislicenus, has a unique heritage in Stereochemistry. Fortunately, the Wiley family's publishing partnerships include Verlag Helvetica Chimica Acta, a house with a reputation for superior quality in publishing. Indeed, within the pages of its namesake periodical, Helvetica Chimica Acta, one finds many of the seminal research works of stereochemistry's giants. As such, a transfer of editorial operations to Zurich and a collaboration bringing Topics as a series closer to periodical status provides a growth platform for the future.

The Chemistry of Organolithium Compounds

Author : B. J. Wakefield
Publisher : Elsevier
ISBN 13 : 1483278700
Total Pages : 348 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : B. J. Wakefield

Download or read book The Chemistry of Organolithium Compounds written by B. J. Wakefield and published by Elsevier. This book was released on 2013-10-22 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Organolithium Compounds is a comprehensive review of the status of organolithium compound chemistry. This book is composed of four parts and nineteen chapters that particularly describe the reactions involving these compounds The first part highlights the constitution of organolithium compounds, specifically in the absence and presence of electron donors, as well as the configurational stability of these compounds. The second part deals with their preparation from organic halides and lithium metal involving metallation and metal-halogen exchange, while the third part focuses on their organic synthesis. The fourth part considers the synthesis of organometallic compound derivatives from main group and transition metals. This book will prove useful to organic chemists and organic chemistry researchers.

The Chemistry of Organolithium Compounds

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 0470023228
Total Pages : 768 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2006-06-14 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Patai Series: The Chemistry of Functional Groups A series of advanced treatises founded by Professor Saul Patai and under the general editorship of Professor Zvi Rappoport The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopical methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 100 volumes have been published in the series. Recently Published Titles * The chemistry of the Cyclopropyl Group (Volume 2) * The chemistry of the Hydrazo Azo and Azozy Groups (Volume 2, 2 parts) * The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) * The chemistry of Organophosphorus Compounds (Volume 4) * The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) * The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) * The chemistry of Dienes and Polyenes (2 volumes) * The chemistry of Organic Derivatives of Gold and Silver * The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) * The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) * The chemistry of Phenols (2 parts) * The chemistry of Organolithium Compounds (2 parts) * The chemistry of Cyclobutanes (2 parts) * Forthcoming Titles * The chemistry of Peroxides (Volume 2, 2 parts) * The chemistry of Organozinc Compounds * The chemistry of Anilines The Patai Series Online The Patai Series is available in electronic format on Wiley InterScience. All new titles will be published online and a growing list of older titles is added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format.

The Chemistry of Organolithium Compounds

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 0470021101
Total Pages : 1400 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2004-08-20 with total page 1400 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general. It deals with theoretical/physical/computational apsects, as well as major spectroscopies, such as MS, NMR, IR/UV etc and both biological and industrial applications. The core of the volume is the synthetic chapters with lots of examples for modern synthetic approaches Written by key researchers in the field An invaluable reference source to organic chemists working in academia and industry Features important reagents in organic synthesis

Synthetic and Stereochemical Aspects

Author : Philip Page
Publisher : Academic Press
ISBN 13 : 0080538207
Total Pages : 325 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Synthetic and Stereochemical Aspects by : Philip Page

Download or read book Synthetic and Stereochemical Aspects written by Philip Page and published by Academic Press. This book was released on 1997-10-17 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: The impact of organosulfur chemistry, especially in the areas of heterocyclic chemistry, stereocontrolled processes, and asymmetric synthesis, has led to a resurgence of interest in the field. This book is the secondin a series intended to provide coverage of topics of current interest throughout the whole range of organosulfur chemistry. Each volume is comprised of five or six chapters, each consisting of an in-depth, self-contained review in a well-defined area. This volume and its predecessor Organosulfur Chemistry, Synthetic Aspects will prove valuable references for researchers and practitioners in organic chemistry. - Methods of asymmetric sulfur oxidation processes - Preparation of chiral sulfoxides in nucleophilic displacement at sulfur - Conformational preferences of the sulfinyl group - Preparation and chemistry of unsaturated sulfoxides - Applications of sulfoxides as stereocontrol elements - The chemistry of sulfolenes

The Chemistry of Organolithium Compounds, 2 Volume Set

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 684 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis The Chemistry of Organolithium Compounds, 2 Volume Set by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds, 2 Volume Set written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2004-07-16 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first volume in the series to concentrate on organo-lithium compounds - the sub series "The chemistry of the metal-carbon bond" (5 vol) treated organometallics in general. It deals with theoretical/physical/computational apsects, as well as major spectroscopies, such as MS, NMR, IR/UV etc and both biological and industrial applications. * The core of the volume is the synthetic chapters with lots of examples for modern synthetic approaches * Written by key researchers in the field * An invaluable reference source to organic chemists working in academia and industry * Features important reagents in organic synthesis

Organolithiums: Selectivity for Synthesis

Author : Jonathan Clayden
Publisher : Elsevier
ISBN 13 : 0080538169
Total Pages : 401 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Organolithiums: Selectivity for Synthesis by : Jonathan Clayden

Download or read book Organolithiums: Selectivity for Synthesis written by Jonathan Clayden and published by Elsevier. This book was released on 2002-07-12 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume, number 23 in the "Tetrahedron Organic Chemistry" series, presents organolithium chemistry from the perspective of a synthetic organic chemist, drawing from the synthetic literature to present a unified overview of how organolithiums can be used to make molecules. The development of methods for the regioselective synthesis of organolithiums has replaced their image of indiscriminate high reactivity with one of controllable and subtle selectivity. Organolithium chemistry has a central role in the selective construction of C-C bonds in both simple and complex molecules, and for example has arguably overtaken aromatic electrophilic substitution as the most powerful method for regioselective functionalisation of aromatic rings. The twin themes of reactivity and selectivity run through the book, which reviews the ways by which organolithiums may be formed and the ways in which they react. Topics include advances in directed metallation, reductive lithiation and organolithium cyclisation reactions, along with a discussion of organolithium stereochemistry and the role played by ligands such as (-)-sparteine.

Organolithiums in Enantioselective Synthesis

Author : David M. Hodgson
Publisher : Springer Science & Business Media
ISBN 13 : 3540001042
Total Pages : 325 pages
Book Rating : 4.5/5 (4 download)

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Book Synopsis Organolithiums in Enantioselective Synthesis by : David M. Hodgson

Download or read book Organolithiums in Enantioselective Synthesis written by David M. Hodgson and published by Springer Science & Business Media. This book was released on 2003-04-30 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is the first dedicated to a comprehensive coverage of this rapidly developing transdisciplinary field. It provides a rich source of essential information on synthesizing molecules in an enantioselective manner using organolithiums, and serves as an inspiration for future developments.

The Chemistry of Organolithium Compounds

Author : Zvi Rappoport
Publisher :
ISBN 13 :
Total Pages : 717 pages
Book Rating : 4.:/5 (634 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds written by Zvi Rappoport and published by . This book was released on 2004 with total page 717 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Stereochemistry of Organometallic and Inorganic Compounds

Author : Bozzano G Luisa
Publisher : Elsevier
ISBN 13 : 0444597328
Total Pages : 395 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Stereochemistry of Organometallic and Inorganic Compounds by : Bozzano G Luisa

Download or read book Stereochemistry of Organometallic and Inorganic Compounds written by Bozzano G Luisa and published by Elsevier. This book was released on 2012-12-02 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies.In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N2, CO2 and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds.

Bonding and Stereochemical Studies of Unsaturated Organolithium Compounds

Author : Joseph Jordan Brooks
Publisher :
ISBN 13 :
Total Pages : 286 pages
Book Rating : 4.:/5 (462 download)

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Book Synopsis Bonding and Stereochemical Studies of Unsaturated Organolithium Compounds by : Joseph Jordan Brooks

Download or read book Bonding and Stereochemical Studies of Unsaturated Organolithium Compounds written by Joseph Jordan Brooks and published by . This book was released on 1971 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Reactions

Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119570409
Total Pages : 1136 pages
Book Rating : 4.1/5 (195 download)

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Book Synopsis Organic Reactions by :

Download or read book Organic Reactions written by and published by John Wiley & Sons. This book was released on 2019-10-17 with total page 1136 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.

Dynamic Stereochemistry of Chiral Compounds

Author : Christian Wolf
Publisher : Royal Society of Chemistry
ISBN 13 : 0854042466
Total Pages : 534 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Dynamic Stereochemistry of Chiral Compounds by : Christian Wolf

Download or read book Dynamic Stereochemistry of Chiral Compounds written by Christian Wolf and published by Royal Society of Chemistry. This book was released on 2008 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion. Recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples.

Arene Chemistry

Author : Jacques Mortier
Publisher : John Wiley & Sons
ISBN 13 : 1118754956
Total Pages : 991 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Arene Chemistry by : Jacques Mortier

Download or read book Arene Chemistry written by Jacques Mortier and published by John Wiley & Sons. This book was released on 2015-11-30 with total page 991 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organized to enable students and synthetic chemists to understand and expand on aromatic reactions covered in foundation courses, the book offers a thorough and accessible mechanistic explanation of aromatic reactions involving arene compounds. • Surveys methods used for preparing arene compounds and their transformations • Connects reactivity and methodology with mechanism • Helps readers apply aromatic reactions in a practical context by designing syntheses • Provides essential information about techniques used to determine reaction mechanisms

Lithium Compounds in Organic Synthesis

Author : Renzo Luisi
Publisher : John Wiley & Sons
ISBN 13 : 3527667539
Total Pages : 705 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Lithium Compounds in Organic Synthesis by : Renzo Luisi

Download or read book Lithium Compounds in Organic Synthesis written by Renzo Luisi and published by John Wiley & Sons. This book was released on 2014-03-11 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique book covers fundamentals of organolithium compounds and gives a comprehensive overview of the latest synthetic advances and developments in the field. Part I covers computational and spectroscopic aspects as well as structure-reactivity relationships of organolithiums, whereas Part II deals with new lithium-based synthetic methodologies as well as novel synthetic applications of functionalized lithium compounds. A useful resource for newcomers and active researchers involved in organic synthesis, whether working in academia or industry!

The Chemistry of Organolithium Compounds

Author : Zvi Rappoport
Publisher :
ISBN 13 :
Total Pages : 746 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds written by Zvi Rappoport and published by . This book was released on 2004 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Contemporary Carbene Chemistry

Author : Robert A. Moss
Publisher : John Wiley & Sons
ISBN 13 : 1118730267
Total Pages : 506 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Contemporary Carbene Chemistry by : Robert A. Moss

Download or read book Contemporary Carbene Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2013-10-17 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents the most innovative results in carbene chemistry, setting the foundation for new discoveries and applications The discovery of stable carbenes has reinvigorated carbene chemistry research, with investigators seeking to develop carbenes into new useful catalysts and ligands. Presenting the most innovative and promising areas of carbene research over the past decade, this book explores newly discovered structural, catalytic, and organometallic aspects of carbene chemistry, with an emphasis on new and emerging synthetic applications. Contemporary Carbene Chemistry features contributions from an international team of pioneering carbene chemistry researchers. Collectively, these authors have highlighted the most interesting and promising areas of investigation in the field. The book is divided into two parts: Part 1, Properties and Reactions of Carbenes, explores new findings on carbene stability, acid-base behavior, and catalysis. Carbenic structure and reactivity are examined in chapters dedicated to stable carbenes, carbodicarbenes, carbenes as guests in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited state precursors. Theoretical concerns are addressed in chapters on computational methods and dynamics applied to carbene reactions. Part 2, Metal Carbenes, is dedicated to the synthetic dimensions of carbenes, particularly the reactions and catalytic properties of metal carbenes. The authors discuss lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold. All the chapters conclude with a summary of the current situation, new challenges on the horizon, and promising new research directions. A list of key reviews and suggestions for further reading also accompanies every chapter. Each volume of the Wiley Series on Reactive Intermediates in Chemistry and Biology focuses on a specific reactive intermediate, offering a broad range of perspectives from leading experts that sets the stage for new applications and further discoveries.