Statistical Thermodynamics Of Liquids And Liquid Mixtures

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Liquids and Liquid Mixtures

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Author : J S Rowlinson
Publisher : Butterworth-Heinemann
ISBN 13 : 1483140679
Total Pages : 337 pages
Book Rating : 4.4/5 (831 download)

Book Synopsis Liquids and Liquid Mixtures by : J S Rowlinson

Download or read book Liquids and Liquid Mixtures written by J S Rowlinson and published by Butterworth-Heinemann. This book was released on 2013-09-03 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.

Molecular Thermodynamics of Fluid-Phase Equilibria

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Author : John M. Prausnitz
Publisher : Pearson Education
ISBN 13 : 0132440504
Total Pages : 1150 pages
Book Rating : 4.1/5 (324 download)

Book Synopsis Molecular Thermodynamics of Fluid-Phase Equilibria by : John M. Prausnitz

Download or read book Molecular Thermodynamics of Fluid-Phase Equilibria written by John M. Prausnitz and published by Pearson Education. This book was released on 1998-10-22 with total page 1150 pages. Available in PDF, EPUB and Kindle. Book excerpt: The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

Applied Thermodynamics of Fluids

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Author : Anthony R. Goodwin
Publisher : Royal Society of Chemistry
ISBN 13 : 1849730989
Total Pages : 535 pages
Book Rating : 4.8/5 (497 download)

Book Synopsis Applied Thermodynamics of Fluids by : Anthony R. Goodwin

Download or read book Applied Thermodynamics of Fluids written by Anthony R. Goodwin and published by Royal Society of Chemistry. This book was released on 2010-11-01 with total page 535 pages. Available in PDF, EPUB and Kindle. Book excerpt: Published under the auspices of both IUPAC and its affiliated body, the International Association of Chemical Thermodynamics (IACT), this book will serve as a guide to scientists or technicians who use equations of state for fluids. Concentrating on the application of theory, the practical use of each type of equation is discussed and the strengths and weaknesses of each are addressed. It includes material on the equations of state for chemically reacting and non-equilibrium fluids which have undergone significant developments and brings up to date the equations of state for fluids and fluid mixtures. Applied Thermodynamics of Fluids addresses the needs of practitioners within academia, government and industry by assembling an international team of distinguished experts to provide each chapter. The topics presented in the book are important to the energy business, particularly the hydrocarbon economy and the development of new power sources and are also significant for the application of liquid crystals and ionic liquids to commercial products. This reference will be useful for post graduate researchers in the fields of chemical engineering, mechanical engineering, chemistry and physics.

Metastable Liquids

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Author : Pablo G. Debenedetti
Publisher : Princeton University Press
ISBN 13 : 9780691085951
Total Pages : 432 pages
Book Rating : 4.0/5 (859 download)

Book Synopsis Metastable Liquids by : Pablo G. Debenedetti

Download or read book Metastable Liquids written by Pablo G. Debenedetti and published by Princeton University Press. This book was released on 1996 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Building on the interplay of kinetics and thermodynamics that determines the thermophysical properties and structural relaxation of metastable liquids, it offers an in-depth treatment of thermodynamic stability theory, the statistical mechanics of metastability, nucleation, spinodal decomposition, supercooled liquids, and the glass transition.

Statistical Mechanics of Liquids and Solutions

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Author : Roland Kjellander
Publisher : CRC Press
ISBN 13 : 1482244047
Total Pages : 557 pages
Book Rating : 4.4/5 (822 download)

Book Synopsis Statistical Mechanics of Liquids and Solutions by : Roland Kjellander

Download or read book Statistical Mechanics of Liquids and Solutions written by Roland Kjellander and published by CRC Press. This book was released on 2019-07-30 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications for many industrial applications. This book shows how you can start from basic laws for the interactions and motions of microscopic particles and calculate how macroscopic systems of these particles behave, thereby explaining properties of matter at the scale that we perceive. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author’s treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book also provides an expanded, in-depth treatment of polar liquids and electrolytes.

Theory of Simple Liquids

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Author : Jean-Pierre Hansen
Publisher : Elsevier
ISBN 13 : 0080571018
Total Pages : 569 pages
Book Rating : 4.0/5 (85 download)

Book Synopsis Theory of Simple Liquids by : Jean-Pierre Hansen

Download or read book Theory of Simple Liquids written by Jean-Pierre Hansen and published by Elsevier. This book was released on 1990-09-24 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. - Compares theoretical deductions with experimental results - Molecular dynamics - Monte Carlo computations - Covers ionic, metallic, and molecular liquids

Thermodynamics of Fluids Under Flow

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Author : David Jou
Publisher : Springer Science & Business Media
ISBN 13 : 9400701993
Total Pages : 304 pages
Book Rating : 4.4/5 (7 download)

Book Synopsis Thermodynamics of Fluids Under Flow by : David Jou

Download or read book Thermodynamics of Fluids Under Flow written by David Jou and published by Springer Science & Business Media. This book was released on 2010-12-02 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second edition of the book “Thermodynamics of Fluids under Flow,” which was published in 2000 and has now been corrected, expanded and updated. This is a companion book to our other title Extended irreversible thermodynamics (D. Jou, J. Casas-Vázquez and G. Lebon, Springer, 4th edition 2010), and of the textbook Understanding non-equilibrium thermodynamics (G. Lebon, D. Jou and J. Casas-Vázquez, Springer, 2008. The present book is more specialized than its counterpart, as it focuses its attention on the non-equilibrium thermodynamics of flowing fluids, incorporating non-trivial thermodynamic contributions of the flow, going beyond local equilibrium theories, i.e., including the effects of internal variables and of external forcing due to the flow. Whereas the book's first edition was much more focused on polymer solutions, with brief glimpses into ideal and real gases, the present edition covers a much wider variety of systems, such as: diluted and concentrated polymer solutions, polymer blends, laminar and turbulent superfluids, phonon hydrodynamics and heat transport in nanosystems, nuclear collisions, far-from-equilibrium ideal gases, and molecular solutions. It also deals with a variety of situations, emphasizing the non-equilibrium flow contribution: temperature and entropy in flowing ideal gases, shear-induced effects on phase transitions in real gases and on polymer solutions, stress-induced migration and its application to flow chromatography, Taylor dispersion, anomalous diffusion in flowing systems, the influence of the flow on chemical reactions, and polymer degradation. The new edition is not only broader in scope, but more educational in character, and with more emphasis on applications, in keeping with our times. It provides many examples of how a deeper theoretical understanding may bring new and more efficient applications, forging links between theoretical progress and practical aims. This updated version expands on the trusted content of its predecessor, making it more interesting and useful for a larger audience.

NBS Technical Note

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Author :
Publisher :
ISBN 13 :
Total Pages : 204 pages
Book Rating : 4.:/5 (3 download)

Book Synopsis NBS Technical Note by :

Download or read book NBS Technical Note written by and published by . This book was released on 1970 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Selected Works of Paul J. Flory Volume I

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Author :
Publisher : Stanford University Press
ISBN 13 :
Total Pages : 736 pages
Book Rating : 4./5 ( download)

Book Synopsis Selected Works of Paul J. Flory Volume I by :

Download or read book Selected Works of Paul J. Flory Volume I written by and published by Stanford University Press. This book was released on with total page 736 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Equilibrium Critical Phenomena in Fluids and Mixtures

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Author : Stella Michaels
Publisher :
ISBN 13 :
Total Pages : 238 pages
Book Rating : 4.3/5 (91 download)

Book Synopsis Equilibrium Critical Phenomena in Fluids and Mixtures by : Stella Michaels

Download or read book Equilibrium Critical Phenomena in Fluids and Mixtures written by Stella Michaels and published by . This book was released on 1970 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Thermodynamics

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Author : Jean Vidal
Publisher : Editions OPHRYS
ISBN 13 : 9782710811183
Total Pages : 522 pages
Book Rating : 4.8/5 (111 download)

Book Synopsis Thermodynamics by : Jean Vidal

Download or read book Thermodynamics written by Jean Vidal and published by Editions OPHRYS. This book was released on 1980 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: The simulation and optimization of processes assumes that the thermodynamic properties and phase equilibria of the mixtures concerned are well known. This knowledge is still based upon experimentation, but it is also the result of calculation methods based on the principles of thermodynamics that govern them, insure their coherence, and confer upon them a wide range of application. This text is concerned primarily with the description of these methods and their evolution. It devotes extensive space to fundamental concepts and places particular emphasis on the models that, although based on simplified concepts of the subject matter at the molecular level, have predictive character. Computational examples are used to explain the application of these concepts and models. Contents: 1. Principles. Thermodynamic functions. The ideal gas. 2. Properties of pure substances. 3. Predicting thermodynamic properties of pure substances. General principles. Corresponding states. Group contributions. 4. Equations of state. 5. Characterization of mixtures. 6. Mixtures: liquid-vapor equilibria. 7. Deviations from ideality in the liquid phase. 8. Application of equations of state to mixtures. Calculation of liquid-vapor equilibria under pressure. 9. Liquid-liquid and liquid-liquid-vapor equilibria. 10. Fluid-solid equilibria. Crystallization. Hydrates. 11. Polymer solutions and alloys. 12. Multicomponent mixtures. 13. Chemical reactions. Appendixes. Index. Bibliography.

Perturbation Theories for the Thermodynamic Properties of Fluids and Solids

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Author : J. R. Solana
Publisher : CRC Press
ISBN 13 : 1439807752
Total Pages : 408 pages
Book Rating : 4.4/5 (398 download)

Book Synopsis Perturbation Theories for the Thermodynamic Properties of Fluids and Solids by : J. R. Solana

Download or read book Perturbation Theories for the Thermodynamic Properties of Fluids and Solids written by J. R. Solana and published by CRC Press. This book was released on 2013-03-22 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories—as well as integral equation theories and density functional theories—for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.

Equations of State for Fluids and Fluid Mixtures

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Author : J.V. Sengers
Publisher : Elsevier
ISBN 13 : 0080531180
Total Pages : 455 pages
Book Rating : 4.0/5 (85 download)

Book Synopsis Equations of State for Fluids and Fluid Mixtures by : J.V. Sengers

Download or read book Equations of State for Fluids and Fluid Mixtures written by J.V. Sengers and published by Elsevier. This book was released on 2000-10-30 with total page 455 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book has been prepared under the auspices of Commission I.2 on Thermodynamics of the International Union of Pure and Applied Chemistry (IUPAC). The authors of the 18 chapters are all recognized experts in the field. The book gives an up-to-date presentation of equations of state for fluids and fluid mixtures. All principal approaches for developing equations of state are covered. The theoretical basis and practical use of each type of equation is discussed and the strength and weaknesses of each is addressed. Topics addressed include the virial equation of state, cubic equations and generalized van der Waals equations, perturbation theory, integral equations, corresponding stated and mixing rules. Special attention is also devoted to associating fluids, polydisperse fluids, polymer systems, self-assembled systems, ionic fluids and fluids near critical points.

Molecular Thermodynamics of Nonideal Fluids

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Author : Lloyd L. Lee
Publisher : Butterworth-Heinemann
ISBN 13 :
Total Pages : 520 pages
Book Rating : 4.3/5 (91 download)

Book Synopsis Molecular Thermodynamics of Nonideal Fluids by : Lloyd L. Lee

Download or read book Molecular Thermodynamics of Nonideal Fluids written by Lloyd L. Lee and published by Butterworth-Heinemann. This book was released on 1988 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: The statistical ensembles - The ideal gas - The structure of liquids - Microthermodynamics - Integral equation theories - Theories for polar fluids - Hard spheres and hard-core fluids - The lennard-jones fluid - Solution thermodynamics - The perturbation theories - Electrolyte solutions - Molecular dynamics - Interaction site models for polyatomics - Adsorption : the solid-fluid interface.

Classical and Molecular Thermodynamics of Fluid Systems

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Author : Juan H. Vera
Publisher : CRC Press
ISBN 13 : 1040132774
Total Pages : 564 pages
Book Rating : 4.0/5 (41 download)

Book Synopsis Classical and Molecular Thermodynamics of Fluid Systems by : Juan H. Vera

Download or read book Classical and Molecular Thermodynamics of Fluid Systems written by Juan H. Vera and published by CRC Press. This book was released on 2024-11-14 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text explores the connections between different thermodynamic subjects related to fluid systems. In an innovative way, it covers the subject from first principles to the state of the art in fundamental and applied topics. Using simple nomenclature and algebra, it clarifies concepts by returning to the conceptual foundation of thermodynamics. The structural elements of classical and molecular thermodynamics of fluid systems presented cover, via examples and references, both the usefulness and the limitations of thermodynamics for the treatment of practical problems. This new edition explores recent advances in statistical associated fluid theories and contains creative end‐of‐chapter problems connecting the theory with real‐life situations. It includes new chapters on thermodynamics of polymer solutions and molecular thermodynamics and also presents advances in the study of the activity of individual ions. Provides a concise structure of concepts, using simple nomenclature and algebra Clarifies problems usually overlooked by standard texts Features end‐of‐chapter problems to enhance the reader’s understanding of the concepts Includes diverse topics of interest to researchers and advanced students, including elements of statistical thermodynamics, models of solutions, statistical associated fluid theory and the activity of individual ions Offers four appendices giving step‐by‐step procedures and parameters for direct use of the PRSV equation of state and the ASOG‐KT group method for fugacity and activity coefficient calculations Features a complete set of solutions to problems throughout the book, available for download on the book’s webpage under "Support Material" This textbook is written for advanced undergraduate and graduate students studying chemical engineering and chemistry as well as for practicing engineers and researchers.

Selected Works of Paul J. Flory Volume III

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Author :
Publisher : Stanford University Press
ISBN 13 :
Total Pages : 978 pages
Book Rating : 4./5 ( download)

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Download or read book Selected Works of Paul J. Flory Volume III written by and published by Stanford University Press. This book was released on with total page 978 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Publications of the National Institute of Standards and Technology ... Catalog

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Author : National Institute of Standards and Technology (U.S.)
Publisher :
ISBN 13 :
Total Pages : 392 pages
Book Rating : 4.:/5 (31 download)

Book Synopsis Publications of the National Institute of Standards and Technology ... Catalog by : National Institute of Standards and Technology (U.S.)

Download or read book Publications of the National Institute of Standards and Technology ... Catalog written by National Institute of Standards and Technology (U.S.) and published by . This book was released on 1971 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: