Spin State

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Spin State

Author : Chris Moriarty
Publisher : Spectra
ISBN 13 : 0553586246
Total Pages : 642 pages
Book Rating : 4.5/5 (535 download)

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Book Synopsis Spin State by : Chris Moriarty

Download or read book Spin State written by Chris Moriarty and published by Spectra. This book was released on 2004-11-23 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: From a stunning new voice in hard science fiction comes the thrilling story of one woman’s quest to wrest truth from chaos, love from violence, and reality from illusion in a post-human universe of emergent AIs, genetic constructs, and illegal wetware. . . . UN Peacekeeper Major Catherine Li has made thirty-seven faster-than-light jumps in her lifetime—and has probably forgotten more than most people remember. But that’s what backup hard drives are for. And Li should know; she’s been hacking her memory for fifteen years in order to pass as human. But no memory upgrade can prepare Li for what she finds on Compson’s World: a mining colony she once called home and to which she is sent after a botched raid puts her on the bad side of the powers that be. A dead physicist who just happens to be her cloned twin. A missing dataset that could change the interstellar balance of power and turn a cold war hot. And a mining “accident” that is starting to look more and more like murder. . . . Suddenly Li is chasing a killer in an alien world miles underground where everyone has a secret. And one wrong turn in streamspace, one misstep in the dark alleys of blackmarket tech and interstellar espionage, one risky hookup with an AI could literally blow her mind.

Spin States in Biochemistry and Inorganic Chemistry

Author : Marcel Swart
Publisher : John Wiley & Sons
ISBN 13 : 1118898281
Total Pages : 500 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Spin States in Biochemistry and Inorganic Chemistry by : Marcel Swart

Download or read book Spin States in Biochemistry and Inorganic Chemistry written by Marcel Swart and published by John Wiley & Sons. This book was released on 2015-09-22 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.

Spin States in Biochemistry and Inorganic Chemistry

Author : Marcel Swart
Publisher : John Wiley & Sons
ISBN 13 : 1118898311
Total Pages : 500 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Spin States in Biochemistry and Inorganic Chemistry by : Marcel Swart

Download or read book Spin States in Biochemistry and Inorganic Chemistry written by Marcel Swart and published by John Wiley & Sons. This book was released on 2015-12-14 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.

Spin Control

Author : Chris Moriarty
Publisher : Spectra
ISBN 13 : 0553586254
Total Pages : 610 pages
Book Rating : 4.5/5 (535 download)

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Book Synopsis Spin Control by : Chris Moriarty

Download or read book Spin Control written by Chris Moriarty and published by Spectra. This book was released on 2007-06-26 with total page 610 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this stunning follow-up to the critically acclaimed novel Spin State, Chris Moriarty depicts a grim future in which the final frontier may well be extinction. For as far-flung planets are terraformed and Earth’s age-old conflicts are contracted out to AIs, humanity is losing the only war that counts: the war for survival. Call Arkady a clone with a conscience. Or call him a traitor. A member of the space-faring Syndicates, Arkady has defected to Israel with a hot commodity: a genetic weapon powerful enough to wipe out humanity. But Israel’s not buying it. They’re selling it—and Arkady—to the highest bidder. As the auction heats up, the Artificial Life Emancipation Front sends in Major Catherine Li. Already drummed out of the Peacekeepers for “war crimes,” Li has now literally hooked up with an AI who has lived many lifetimes and shunted through many bodies. And while they each have their own definition of victory, together they have only one chance at survival. . . .

Spin Physics in Semiconductors

Author : Mikhail I. Dyakonov
Publisher : Springer
ISBN 13 : 9783642097621
Total Pages : 0 pages
Book Rating : 4.0/5 (976 download)

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Book Synopsis Spin Physics in Semiconductors by : Mikhail I. Dyakonov

Download or read book Spin Physics in Semiconductors written by Mikhail I. Dyakonov and published by Springer. This book was released on 2010-11-17 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this collective book is to present a non-exhaustive survey of sp- related phenomena in semiconductors with a focus on recent research. In some sense it may be regarded as an updated version of theOpticalOrientation book, which was entirely devoted to spin physics in bulk semiconductors. During the 24 years that have elapsed, we have witnessed, on the one hand, an extraordinary development in the wonderful semiconductor physics in two dim- sions with the accompanying revolutionary applications. On the other hand, during the last maybe 15 years there was a strong revival in the interest in spin phen- ena, in particular in low-dimensional semiconductor structures. While in the 1970s and 1980s the entire world population of researchers in the ?eld never exceeded 20 persons, now it can be counted by the hundreds and the number of publications by the thousands. This explosive growth is stimulated, to a large extent, by the hopes that the electron and/or nuclear spins in a semiconductor will help to accomplish the dream of factorizing large numbers by quantum computing and eventually to develop a new spin-based electronics, or “spintronics”. Whether any of this will happen or not, still remains to be seen. Anyway, these ideas have resulted in a large body of interesting and exciting research, which is a good thing by itself. The ?eld of spin physics in semiconductors is extremely rich and interesting with many spectacular effects in optics and transport.

Spin-Crossover Materials

Author : Malcolm A. Halcrow
Publisher : John Wiley & Sons
ISBN 13 : 1118519310
Total Pages : 729 pages
Book Rating : 4.1/5 (185 download)

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Book Synopsis Spin-Crossover Materials by : Malcolm A. Halcrow

Download or read book Spin-Crossover Materials written by Malcolm A. Halcrow and published by John Wiley & Sons. This book was released on 2013-01-07 with total page 729 pages. Available in PDF, EPUB and Kindle. Book excerpt: The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved. Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including Spin-crossover in mononuclear, polynuclear and polymeric complexes Structure: function relationships in molecular spin-crossover materials Charge-transfer-induced spin-transitions Reversible spin-pairing in crystalline organic radicals Spin-state switching in solution Spin-crossover compounds in multifunctional switchable materials and nanotechnology Physical and theoretical methods for studying spin-crossover materials Spin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.

University Physics

Author : OpenStax
Publisher :
ISBN 13 : 9781680920451
Total Pages : 622 pages
Book Rating : 4.9/5 (24 download)

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Book Synopsis University Physics by : OpenStax

Download or read book University Physics written by OpenStax and published by . This book was released on 2016-11-04 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: University Physics is a three-volume collection that meets the scope and sequence requirements for two- and three-semester calculus-based physics courses. Volume 1 covers mechanics, sound, oscillations, and waves. Volume 2 covers thermodynamics, electricity and magnetism, and Volume 3 covers optics and modern physics. This textbook emphasizes connections between between theory and application, making physics concepts interesting and accessible to students while maintaining the mathematical rigor inherent in the subject. Frequent, strong examples focus on how to approach a problem, how to work with the equations, and how to check and generalize the result. The text and images in this textbook are grayscale.

Spin Dynamics

Author : Malcolm H. Levitt
Publisher : Wiley
ISBN 13 : 0470517123
Total Pages : 744 pages
Book Rating : 4.4/5 (75 download)

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Book Synopsis Spin Dynamics by : Malcolm H. Levitt

Download or read book Spin Dynamics written by Malcolm H. Levitt and published by Wiley. This book was released on 2008-07-31 with total page 744 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spin Dynamics: Basics of Nuclear Magnetic Resonance, Second Edition is a comprehensive and modern introduction which focuses on those essential principles and concepts needed for a thorough understanding of the subject, rather than the practical aspects. The quantum theory of nuclear magnets is presented within a strong physical framework, supported by figures. The book assumes only a basic knowledge of complex numbers and matrices, and provides the reader with numerous worked examples and exercises to encourage understanding. With the explicit aim of carefully developing the subject from the beginning, the text starts with coverage of quarks and nucleons and progresses through to a detailed explanation of several important NMR experiments, including NMR imaging, COSY, NOESY and TROSY. Completely revised and updated, the Second Edition features new material on the properties and distributions of isotopes, chemical shift anisotropy and quadrupolar interactions, Pake patterns, spin echoes, slice selection in NMR imaging, and a complete new chapter on the NMR spectroscopy of quadrupolar nuclei. New appendices have been included on Euler angles, and coherence selection by field gradients. As in the first edition, all material is heavily supported by graphics, much of which is new to this edition. Written for undergraduates and postgraduate students taking a first course in NMR spectroscopy and for those needing an up-to-date account of the subject, this multi-disciplinary book will appeal to chemical, physical, material, life, medical, earth and environmental scientists. The detailed physical insights will also make the book of interest for experienced spectroscopists and NMR researchers. • An accessible and carefully written introduction, designed to help students to fully understand this complex and dynamic subject • Takes a multi-disciplinary approach, focusing on basic principles and concepts rather than the more practical aspects • Presents a strong pedagogical approach throughout, with emphasis placed on individual spins to aid understanding • Includes numerous worked examples, problems, further reading and additional notes Praise from the reviews of the First Edition: "This is an excellent book... that many teachers of NMR spectroscopy will cherish... It deserves to be a ‘classic’ among NMR spectroscopy texts." NMR IN BIOMEDICINE "I strongly recommend this book to everyone…it is probably the best modern comprehensive description of the subject." ANGEWANDTE CHEMIE, INTERNATIONAL EDITION

Ghost Spin

Author : Chris Moriarty
Publisher : Spectra
ISBN 13 : 0553384945
Total Pages : 578 pages
Book Rating : 4.5/5 (533 download)

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Book Synopsis Ghost Spin by : Chris Moriarty

Download or read book Ghost Spin written by Chris Moriarty and published by Spectra. This book was released on 2013-05-28 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sometimes a ghost of a chance is all you get. Award-winning author Chris Moriarty returns to a dazzling cyber-noir far future in this gritty, high-stakes thriller where the only rule is “Evolve . . . or die.” The Age of Man is ending. The UN’s sprawling interstellar empire is failing as its quantum teleportation network collapses, turning once-viable colonies into doomed island outposts. Humanity’s only hope of survival is the Drift: a mysterious region of space where faster-than-light travel—or something far stranger—seems possible. As mercenaries and pirates flock to the Drift, the cold war between the human-led UN and the clone-dominated Syndicates heats up. Whoever controls the Drift will chart the future course of human evolution—and no one wants to be left behind in a universe where the price of failure is extinction. When the AI called Cohen ventures into the Drift, he dies—allegedly by his own hand—and his consciousness is scattered across the cosmos. Some of his ghosts are still self-aware. Some are insane. And one of them hides a secret worth killing for. Enter Major Catherine Li, Cohen’s human (well, partly human) lover, who embarks on a desperate search to solve the mystery of Cohen’s death—and put him back together. But Li isn’t the only one interested in Cohen’s ghosts. Astrid Avery, a by-the-book UN navy captain, is on the hunt. So is William Llewellyn, a pirate who has one of the ghosts in his head, which is slowly eating him alive. Even the ghosts have their own agendas. And lurking behind them all is a pitiless enemy who will stop at nothing to make sure the dead don’t walk again. Praise for Ghost Spin “Complexity is the watchword here, of thought, idea, narrative, character and plot. . . . Highly rewarding.”—Kirkus Reviews “Rewarding . . . The adaptations humans make to survive in the hostile environments of other worlds, a galaxy teetering on the edge of singularity . . . are genuinely visionary.”—Publishers Weekly “This stand-along ‘spin-off’ offers a compelling tale of adventure/suspense blended with cybernoir and high-tech sf.”—Library Journal “An excellent read: gripping, fast-paced, provocative and handsome.”—Tordotcom “A brilliant mix of space opera, cyberpunk, and just plain great writing, Moriarty’s work is some of the most impressive in science fiction today.”—SFRevu

Long-lived Nuclear Spin Order

Author : Giuseppe Pileio
Publisher : Royal Society of Chemistry
ISBN 13 : 1788015681
Total Pages : 462 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Long-lived Nuclear Spin Order by : Giuseppe Pileio

Download or read book Long-lived Nuclear Spin Order written by Giuseppe Pileio and published by Royal Society of Chemistry. This book was released on 2020-04-15 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: The idea that a long-lived form of spin order, namely singlet order, can be prepared from nuclear spin magnetisation first emerged in 2004. The unusual properties of singlet order–its long lifetime and the fact that it is NMR silent but interconvertible into other forms of NMR active order—make it a ‘smart tag’ that can be used to store information for a long time or through distant space points. It is not unexpected then, that since its first appearance, this idea has caught the attention of research groups interested in exploiting this form of order in different fields of research spanning from biology to materials science and from hyperpolarisation to quantum computing. This first book on the subject gives a thorough description of the various aspects that affect the development of the topic and details the interdisciplinary applications. The book starts with a section dedicated to the basic theories of long-lived spin order and then proceeds with a description of the state-of-the-art experimental techniques developed to manipulate singlet order. It then concludes by covering the generalization of the concept of singlet order by introducing and discussing other forms of long-lived spin order.

Spin Ice

Author : Masafumi Udagawa
Publisher : Springer Nature
ISBN 13 : 3030708608
Total Pages : 492 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Spin Ice by : Masafumi Udagawa

Download or read book Spin Ice written by Masafumi Udagawa and published by Springer Nature. This book was released on 2021-10-19 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with a new class of magnetic materials, spin ice. Spin ice has become the canonical example of modern frustrated magnetism where competing interactions between spins set the rules for an emergent magnetostatic gauge field theory. Excitations take the form of magnetic monopoles or can condense via a Higgs mechanism. Beyond classical spin ice, the book describes the new physics emerging when quantum coherence (spin liquids, photon-like excitations) and itinerant electrons (anomalous Hall effect) are included in artificial systems. This first book dedicated to spin ice is a review of the current understanding of the field, both on the theoretical and experimental levels, written by leading experts. The book is written in a linear way with very few prerequisites. It also contains textbook-like descriptions of theoretical methods to help advanced students and researchers to enter the field.

Spin Crossover in Transition Metal Compounds II

Author : Philipp Gütlich
Publisher : Springer
ISBN 13 : 9783642073281
Total Pages : 295 pages
Book Rating : 4.0/5 (732 download)

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Book Synopsis Spin Crossover in Transition Metal Compounds II by : Philipp Gütlich

Download or read book Spin Crossover in Transition Metal Compounds II written by Philipp Gütlich and published by Springer. This book was released on 2010-12-01 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electron Spin Resonance and Related Phenomena in Low-Dimensional Structures

Author : Marco Fanciulli
Publisher : Springer Science & Business Media
ISBN 13 : 3540793658
Total Pages : 272 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Electron Spin Resonance and Related Phenomena in Low-Dimensional Structures by : Marco Fanciulli

Download or read book Electron Spin Resonance and Related Phenomena in Low-Dimensional Structures written by Marco Fanciulli and published by Springer Science & Business Media. This book was released on 2009-08-24 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Here is a discussion of the state of the art of spin resonance in low dimensional structures, such as two-dimensional electron systems, quantum wires, and quantum dots. Leading scientists report on recent advances and discuss open issues and perspectives.

Spin Fluctuations in Itinerant Electron Magnetism

Author : Toru Moriya
Publisher : Springer Science & Business Media
ISBN 13 : 3642824994
Total Pages : 253 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Spin Fluctuations in Itinerant Electron Magnetism by : Toru Moriya

Download or read book Spin Fluctuations in Itinerant Electron Magnetism written by Toru Moriya and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ferromagnetism of metallic systems, especially those including transition metals, has been a controversial subject of modern science for a long time. This controversy sterns from the apparent dual character of the d-electrons responsible for magnetism in transition metals, i.e., they are itinerant elec trons described by band theory in their ground state, while at finite tem peratures they show various properties that have long been attributed to a system consisting of local magnetic moments. The most familiar example of these properties is the Curie-Weiss law of magnetic susceptibility obeyed by almost all ferromagnets above their Curie temperatures. At first the problem seemed to be centered around whether the d-elec trons themselves are localized or itinerant. This question was settled in the 1950s and early 1960s by various experimental investigations, in particular by observations of d-electron Fermi surfaces in ferromagnetic transition metals. These observations are generally consistent with the results of band calculations. Theoretical investigations since then have concentrated on explaining this dual character of d-electron systems, taking account of the effects of electron-electron correlations in the itinerant electron model. The problem in physical terms is to study the spin density fluctuati·ons, which are ne glected in the mean-field or one-electron theory, and their influence on the physical properties.

Spin Dynamics

Author : Malcolm H. Levitt
Publisher : John Wiley & Sons
ISBN 13 : 1118681843
Total Pages : 824 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Spin Dynamics by : Malcolm H. Levitt

Download or read book Spin Dynamics written by Malcolm H. Levitt and published by John Wiley & Sons. This book was released on 2013-05-20 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spin Dynamics: Basics of Nuclear Magnetic Resonance, Second Edition is a comprehensive and modern introduction which focuses on those essential principles and concepts needed for a thorough understanding of the subject, rather than the practical aspects. The quantum theory of nuclear magnets is presented within a strong physical framework, supported by figures. The book assumes only a basic knowledge of complex numbers and matrices, and provides the reader with numerous worked examples and exercises to encourage understanding. With the explicit aim of carefully developing the subject from the beginning, the text starts with coverage of quarks and nucleons and progresses through to a detailed explanation of several important NMR experiments, including NMR imaging, COSY, NOESY and TROSY. Completely revised and updated, the Second Edition features new material on the properties and distributions of isotopes, chemical shift anisotropy and quadrupolar interactions, Pake patterns, spin echoes, slice selection in NMR imaging, and a complete new chapter on the NMR spectroscopy of quadrupolar nuclei. New appendices have been included on Euler angles, and coherence selection by field gradients. As in the first edition, all material is heavily supported by graphics, much of which is new to this edition. Written for undergraduates and postgraduate students taking a first course in NMR spectroscopy and for those needing an up-to-date account of the subject, this multi-disciplinary book will appeal to chemical, physical, material, life, medical, earth and environmental scientists. The detailed physical insights will also make the book of interest for experienced spectroscopists and NMR researchers. • An accessible and carefully written introduction, designed to help students to fully understand this complex and dynamic subject • Takes a multi-disciplinary approach, focusing on basic principles and concepts rather than the more practical aspects • Presents a strong pedagogical approach throughout, with emphasis placed on individual spins to aid understanding • Includes numerous worked examples, problems, further reading and additional notes Praise from the reviews of the First Edition: "This is an excellent book... that many teachers of NMR spectroscopy will cherish... It deserves to be a ‘classic’ among NMR spectroscopy texts." NMR IN BIOMEDICINE "I strongly recommend this book to everyone...it is probably the best modern comprehensive description of the subject." ANGEWANDTE CHEMIE, INTERNATIONAL EDITION

Spin Crossover in Transition Metal Compounds I

Author : Philipp Gütlich
Publisher : Springer Science & Business Media
ISBN 13 : 9783540403944
Total Pages : 640 pages
Book Rating : 4.4/5 (39 download)

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Book Synopsis Spin Crossover in Transition Metal Compounds I by : Philipp Gütlich

Download or read book Spin Crossover in Transition Metal Compounds I written by Philipp Gütlich and published by Springer Science & Business Media. This book was released on 2004-05-12 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Handbook of Spin Transport and Magnetism

Author : Evgeny Y. Tsymbal
Publisher : CRC Press
ISBN 13 : 1439803781
Total Pages : 797 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Handbook of Spin Transport and Magnetism by : Evgeny Y. Tsymbal

Download or read book Handbook of Spin Transport and Magnetism written by Evgeny Y. Tsymbal and published by CRC Press. This book was released on 2016-04-19 with total page 797 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the past several decades, the research on spin transport and magnetism has led to remarkable scientific and technological breakthroughs, including Albert Fert and Peter Grunberg's Nobel Prize-winning discovery of giant magnetoresistance (GMR) in magnetic metallic multilayers. Handbook of Spin Transport and Magnetism provides a comprehensive, bal