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Spectroscopic Investigations Of Platinumii And Palladiumii Metal Olefin Complexes
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Book Synopsis Spectroscopic Investigations of Platinum(II) and Palladium(II) Metal-olefin Complexes by : Michael J. Grogan
Download or read book Spectroscopic Investigations of Platinum(II) and Palladium(II) Metal-olefin Complexes written by Michael J. Grogan and published by . This book was released on 1967 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Spectroscopic Investigations of Platinum and Palladium Poly-ynes by : Hermann Felix Wittmann
Download or read book Spectroscopic Investigations of Platinum and Palladium Poly-ynes written by Hermann Felix Wittmann and published by . This book was released on 1993 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Preparative and Spectroscopic Studies of Some Platinum and Palladium Complexes by : D. A. Duddell
Download or read book Preparative and Spectroscopic Studies of Some Platinum and Palladium Complexes written by D. A. Duddell and published by . This book was released on 1967 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Investigations of the Reactivity of Palladium and Platinum Complexes with Molecular Oxygen and Characterization of a Gold(III)-alkene Complex by : Margaret Louise Scheuermann
Download or read book Investigations of the Reactivity of Palladium and Platinum Complexes with Molecular Oxygen and Characterization of a Gold(III)-alkene Complex written by Margaret Louise Scheuermann and published by . This book was released on 2013 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: Understanding the reactivity of metal complexes with molecular oxygen will facilitate the development of catalysts that can enable the widespread use of molecular oxygen as an oxidant for organic synthesis. This thesis presents two new classes of reactions between metal complexes and molecular oxygen. Neutral five-coordinate Pt complexes were tested for reactivity in the presence of molecular oxygen. In arene solution, the complexes (t̳B̳u̳̳M̳e̳2̳ nacnac)PtMe3 (1, t̳̳B̳u̳M̳e̳2̳ nacnac- = [((4-tBu-2,6-Me2C6H2)NC(CH3))2CH]-), (M̳e̳3̳ Me-nacnac)PtMe3 (2, M̳e̳3̳ Me-nacnac- = [((2,4,6-Me3C6H2)NC(CH3))2CCH3]-), and (t̳B̳u̳2̳ PyPyr)PtMe3 (3, t̳B̳u̳2̳ PyPyr- = 3,5-di-tert-butyl-2-(2-pyridyl)pyrrolide) reacted immediately with oxygen to form peroxo species in which two oxygen atoms bridge between the metal center and a carbon atom in the ligand backbone. In contrast, no reaction between ( i̳P̳r̳2̳ AnIm)PtMe3 (4a, i̳P̳r̳2̳ AnIm− = [o- C66H4-{N(C6H3 i Pr2)}(CH=NC6H3 i Pr2)]−) or (M̳e̳3̳ AnIm)PtMe3 (4b, M̳e̳̳3̳ AnIm− = [o-C6H4- {N(C6H2Me3)}(CH=NC6H2Me3)]−) and oxygen was observed. As activation of oxygen by five- coordinate PtIV species was found to involve cooperation between the metal center and the ligand, the ability of the ligand to participate in the oxygen binding appears to be a vital component. Oxygen atom transfer reactions of the novel peroxo species are also presented. In a separate study, an unusual reaction involving the activation of both molecular oxygen and a C-H bond at the same metal center was investigated. Pd(P(Ar)(tBu)2)2 (15, Ar = naphthyl) was found to react with molecular oxygen at room temperature in arene solvent to form a hydroxide dimer in which one equivalent of phosphine per Pd was lost and the remaining phosphine was cyclometalated through the naphthyl ring. At low temperature, two intermediates were observed. The nature of these intermediates suggests a mechanism involving initial reaction of Pd(P(Ar) (tBu)2)2 with O2 followed by the C-H activation step. In a final chapter unrelated to oxygen reactivity, the generation and characterization of a gold III̳-alkene complex by NMR and X-ray crystallography is presented. Such species have been proposed as intermediates in catalytic reactions but until recently none had been observed.
Book Synopsis The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements by : F. R. Hartley
Download or read book The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements written by F. R. Hartley and published by . This book was released on 1973 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Spectroscopic Investigation Into the Nature of Bonding Between Some Rarer Platinum Metals and Olefins by : Martin Arthur Moseley
Download or read book A Spectroscopic Investigation Into the Nature of Bonding Between Some Rarer Platinum Metals and Olefins written by Martin Arthur Moseley and published by . This book was released on 1978 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and Redox Studies of Platinum and Palladium Complexes with Mer-coordinating Ligands by : Seher Kuyuldar Tastan
Download or read book Synthesis, Characterization and Redox Studies of Platinum and Palladium Complexes with Mer-coordinating Ligands written by Seher Kuyuldar Tastan and published by . This book was released on 2009 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic, structural, spectroscopic, and redox studies of platinum(II) and palladium(II) compounds with mer-coordinating ligands have been undertaken in an effort to better understand the role of the metal and the ligands in controlling d^6/d^8 electron-transfer reactions. A series of Pd(pip2NCN)X (pip2NCNH=1,3-bis(piperdylmethyl)benzene) and [Pd(pip2NNN)X]X (X=Cl, Br, I) (pip2NNN=2,6- bis(piperdyl-methyl)pyridine) complexes are reported. Electronic spectra are consistent with stabilization of ligand-to-metal-charge-transfer states as the ancillary ligand is varied along the ClBr
Book Synopsis Platinum Group Metals and Compounds by : Upadhyayula Veereswara Rao
Download or read book Platinum Group Metals and Compounds written by Upadhyayula Veereswara Rao and published by . This book was released on 1971 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Spectroscopic Investigations of Bis(chelated) Complexes of Platinum(II) by : Thomas A. Reynolds
Download or read book Synthesis and Spectroscopic Investigations of Bis(chelated) Complexes of Platinum(II) written by Thomas A. Reynolds and published by . This book was released on 1989 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Dissertation Abstracts written by and published by . This book was released on 1968 with total page 998 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthetic and Spectroscopic Studies of Palladium (II) and Platinum (II) Dithioacid Complexes by : Margaret C. Cornock
Download or read book Synthetic and Spectroscopic Studies of Palladium (II) and Platinum (II) Dithioacid Complexes written by Margaret C. Cornock and published by . This book was released on 1977 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum (II) and Palladium (II) by : David Gordon Cooper
Download or read book Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum (II) and Palladium (II) written by David Gordon Cooper and published by c1976.. This book was released on 1976 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 2001 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthetic, Structural and Spectroscopic Studies on Some Platinum Group Metal Complexes by : Ewan Blyth McAslan
Download or read book Synthetic, Structural and Spectroscopic Studies on Some Platinum Group Metal Complexes written by Ewan Blyth McAslan and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Spectroscopic Properties of Inorganic and Organometallic Compounds by : N N Greenwood
Download or read book Spectroscopic Properties of Inorganic and Organometallic Compounds written by N N Greenwood and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt: Spectroscopic Properties of Inorganic and Organometallic Compounds provides a unique source of information on an important area of chemistry. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in this field, researchers will find this Specialist Periodical Report an invaluable source of information on current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Book Synopsis Synthetic, Structural and Spectroscopic Studies on Some Platinum Group Metal Complexes by : Ewan Blyth McAslan
Download or read book Synthetic, Structural and Spectroscopic Studies on Some Platinum Group Metal Complexes written by Ewan Blyth McAslan and published by . This book was released on 1986 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum (II) and Palladium (II) by : David Gordon Cooper
Download or read book Spectroscopic and Kinetic Studies of Tetragonal Planar Complexes of Platinum (II) and Palladium (II) written by David Gordon Cooper and published by . This book was released on 1976 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: