Specific Interactions And The Miscibility Of Polymer Blends

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Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher : Routledge
ISBN 13 : 1351415158
Total Pages : 435 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by Routledge. This book was released on 2017-11-13 with total page 435 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor

Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (141 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by . This book was released on 1991 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer-Polymer Miscibility

Author : Olagoke Olabis
Publisher : Elsevier
ISBN 13 : 0323153070
Total Pages : 383 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Polymer-Polymer Miscibility by : Olagoke Olabis

Download or read book Polymer-Polymer Miscibility written by Olagoke Olabis and published by Elsevier. This book was released on 2012-12-02 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer–Polymer Miscibility discusses miscibility of polymeric mixtures. This book explains the theoretical and practical aspects of polymer miscibility, which has become a considerable area of research in many academic and industrial laboratories. Comprised of seven chapters, this book starts with an overview of the physical nature of the variations of the basic polymer structure. This monograph then discusses the two cases of miscible polymer blends, namely, poly(vinyl chloride) (PVC)–butadiene/acrylonitrile copolymer (NBR) and polystyrene–poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) blends. This text explores the useful and unique properties of blends of poly(vinyl chloride) and butadiene/acrylonitrile copolymer rubber. Other chapters discuss the thermodynamic theories for the phase separation of block copolymers. The reader is also introduced to other variations of chemical structure, which can result in the permanent attachment of polymers to each other through block and graft copolymers. This text also explores the feasibility of covalent bonding of polymer components. This book is intended for chemical engineers and materials scientists.

Specific Interactions and the Miscibility of Polymer Blends

Author : Michael M. Coleman
Publisher : CRC Press
ISBN 13 : 1351415166
Total Pages : 516 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Specific Interactions and the Miscibility of Polymer Blends by : Michael M. Coleman

Download or read book Specific Interactions and the Miscibility of Polymer Blends written by Michael M. Coleman and published by CRC Press. This book was released on 2017-11-13 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book with software provides powerful tools for the analysis, prediction and creation of new polymer blends, an area of significant commercial potential. The R&D approaches and methods described in the book have attracted the interest of polymer R&D leaders in industry, and have been put into use in several major chemical companies. The companion set of computer programs speeds and facilitates work in this area. FROM THE AUTHORS' PREFACE: During the 1980's a steadily increasing number of compatible systems [polymer blends] have been reported. We believe that miscible mixtures will prove to be fairly common and the purpose of this book is to explore the circumstances in which single phase materials can be obtained. We will also describe a model for the phase behavior of these mixtures which we believe to have a predictive value, or be used as a practical guide to polymer miscibility. Our approach is based on the use of association models which have until recently been largely ignored in treating hydrogen bonding in polymer mixtures. They have most frequently been applied to mixtures of alcohols with simple hydrocarbons, where the equilibrium constants used to describe association have most frequently been determined by a fit to thermodynamic data (e.g., vapor pressures, heat of mixing). In our work we have sought to, first, adapt this approach to a description of the phase behavior of polymer mixtures; second, develop spectroscopic methods that provide an independent measurement of the equilibrium constants. Our purpose in this book is to explore and describe this approach and illustrate its broad utility. We address two overlapping yet different audiences. One would be primarily interested in the broad nature of this approach and the practical applications of a simple model. The second would be more interested in the derivations of the equations and some of the fundamental aspects of the spectroscopy of these systems. Accor

Characterization of Polymer Blends

Author : Sabu Thomas
Publisher : John Wiley & Sons
ISBN 13 : 3527331530
Total Pages : 972 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Characterization of Polymer Blends by : Sabu Thomas

Download or read book Characterization of Polymer Blends written by Sabu Thomas and published by John Wiley & Sons. This book was released on 2015-02-09 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap for a reference dedicated to the characterization of polymer blends and their micro and nano morphologies, this book provides comprehensive, systematic coverage in a one-stop, two-volume resource for all those working in the field. Leading researchers from industry and academia, as well as from government and private research institutions around the world summarize recent technical advances in chapters devoted to their individual contributions. In so doing, they examine a wide range of modern characterization techniques, from microscopy and spectroscopy to diffraction, thermal analysis, rheology, mechanical measurements and chromatography. These methods are compared with each other to assist in determining the best solution for both fundamental and applied problems, paying attention to the characterization of nanoscale miscibility and interfaces, both in blends involving copolymers and in immiscible blends. The thermodynamics, miscibility, phase separation, morphology and interfaces in polymer blends are also discussed in light of new insights involving the nanoscopic scale. Finally, the authors detail the processing-morphology-property relationships of polymer blends, as well as the influence of processing on the generation of micro and nano morphologies, and the dependence of these morphologies on the properties of blends. Hot topics such as compatibilization through nanoparticles, miscibility of new biopolymers and nanoscale investigations of interfaces in blends are also addressed. With its application-oriented approach, handpicked selection of topics and expert contributors, this is an outstanding survey for anyone involved in the field of polymer blends for advanced technologies.

Miscible Polymer Blends

Author : Michael M. Coleman
Publisher : DEStech Publications, Inc
ISBN 13 : 193207855X
Total Pages : 40 pages
Book Rating : 4.9/5 (32 download)

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Book Synopsis Miscible Polymer Blends by : Michael M. Coleman

Download or read book Miscible Polymer Blends written by Michael M. Coleman and published by DEStech Publications, Inc. This book was released on 2006-12 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: The accompanying CD-ROM contains a set of original programs that allow one to calculate solubility parameters, provide a guide to polymer miscibility, and allow the calculation of the phase behavior of hydrogen-bonded polymer systems. The book is divided into two parts. In the first part, the authors describe the principles underlying the simple guide to polymer blend miscibility, which are the basis of the programs Miscibility Checker and Miscibility Guide. The second part is more rigorous and pertains to hydrogen bonded polymer blends and forms the basis of the program Phase Calculator.

Polymer Blends Handbook

Author : L. A. Utracki
Publisher :
ISBN 13 : 9789400760653
Total Pages : 1800 pages
Book Rating : 4.7/5 (66 download)

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Book Synopsis Polymer Blends Handbook by : L. A. Utracki

Download or read book Polymer Blends Handbook written by L. A. Utracki and published by . This book was released on 2014-01-31 with total page 1800 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an international group of highly respected contributors, this fundamental reference work covers all aspects of polymer blends: science, engineering, technology and applications.

Nanostructured Polymer Blends

Author : Chandran C. Sarath
Publisher : Elsevier Inc. Chapters
ISBN 13 : 0128090782
Total Pages : 28 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Nanostructured Polymer Blends by : Chandran C. Sarath

Download or read book Nanostructured Polymer Blends written by Chandran C. Sarath and published by Elsevier Inc. Chapters. This book was released on 2013-11-28 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt: Miscibility and compatibility in polymer blends is a topic of great academic and industrial importance. This is because miscibility and compatibility contribute to morphology, properties, and performance. Miscibility results in one phase; compatibility creates a disperse phase with size and stability determined by interfacial interactions. Miscible polymer properties are averaged similar to a plasticizer polymer, and compatible polymers retain properties of each component, such as toughening or reinforcement. With miscible polymer blends the continuous phase dominates properties; the disperse phase contributes via stress transfer. This chapter revisits the criteria for miscibility or compatibility in polymer blends and the contributors of compatibility compared with miscibility and incompatibility. Development of copolymers and their blending with thermosets and thermoplastics result in complex two-phase morphologies. The dynamics of phase separation observed in polymer blends leading to different morphologies and the criteria for phase separation is explained. A nanometer-dispersed phase requires strong interfacial interactions to stabilize the large interfacial area, and this is favored by rapid spinodal phase separation compared with size diminution by high shear. Nanoblends open up a new arena for polymer blends, and research shows that nanoblends have outstanding optical and mechanical properties.

Polymer Blends Volume 1

Author : Donald R Paul
Publisher : Elsevier
ISBN 13 : 0323138896
Total Pages : 520 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Polymer Blends Volume 1 by : Donald R Paul

Download or read book Polymer Blends Volume 1 written by Donald R Paul and published by Elsevier. This book was released on 2012-12-02 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Blends, Volume 1 highlights the importance of polymer blends as a major new branch of macromolecular science. Topics range from polymer-polymer compatibility and the statistical thermodynamics of polymer blends to the phase separation behavior of polymer-polymer mixtures, transport phenomena in polymer blends, and mechanical properties of multiphase polymer blends. The optical behavior, solid state transition behavior, and rheology of polymer blends are also discussed. This book is organized into 10 chapters and begins with an overview of polymer blends, with emphasis on terminology and the effect of molecular weight on the thermodynamics of polymer blends as well as phase equilibria and transitions. The discussion then turns to the miscibility of homopolymers and copolymers, in bulk and in solution, from the experimental and theoretical viewpoints. The chapters that follow explore the statistical thermodynamics of polymer blends, paying particular attention to the Flory and lattice fluid theories, along with the phase relationship in polymer mixtures. The interfacial energy, structure, and adhesion between polymers in relation to the properties of polymer blends are considered. The final chapter examines the phenomena of low molecular weight penetrant transport. Currently accepted models for unsteady-state and steady-state permeation of polymeric materials are presented. A discussion of unsteady-state absorption and desorption behavior observed in a variety of polymer blends complements the treatment of permeation behavior. This book is intended to provide academic and industrial research scientists and technologists with a broad background in current principles and practice concerning mixed polymer systems.

Compatibilization of Polymer Blends

Author : Ajitha A. R
Publisher : Elsevier
ISBN 13 : 0128162880
Total Pages : 640 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Compatibilization of Polymer Blends by : Ajitha A. R

Download or read book Compatibilization of Polymer Blends written by Ajitha A. R and published by Elsevier. This book was released on 2019-10-10 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends Draws on novel studies and state-of-the-art research, discussing the latest issues and developments

Polymer Thermodynamics

Author : Kal Renganathan Sharma
Publisher : CRC Press
ISBN 13 : 1439826404
Total Pages : 371 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Polymer Thermodynamics by : Kal Renganathan Sharma

Download or read book Polymer Thermodynamics written by Kal Renganathan Sharma and published by CRC Press. This book was released on 2011-10-10 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Thermodynamics: Blends, Copolymers and Reversible Polymerization describes the thermodynamic basis for miscibility as well as the mathematical models used to predict the compositional window of miscibility and construct temperature versus volume-fraction phase diagrams. The book covers the binary interaction model, the solubility parameter

Nanostructured Immiscible Polymer Blends

Author : Suprakas Sinha Ray
Publisher : Elsevier
ISBN 13 : 0128168781
Total Pages : 240 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Nanostructured Immiscible Polymer Blends by : Suprakas Sinha Ray

Download or read book Nanostructured Immiscible Polymer Blends written by Suprakas Sinha Ray and published by Elsevier. This book was released on 2019-09-17 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Immiscible Polymer Blends: Migration and Interface covers a wide range of nanoparticle types, emphasizing the mechanisms and parameters involved in the migration of nanofillers inside immiscible polymer blends. This book explores the influence of nanoparticle migration on the localization, and hence, morphology development, electrical conductivity, and met-rheological properties of blended composite materials. As the influence of solid particles, ranging in size from several hundred nanometers to a few microns in immiscible polymer blends has been extensively studied for use as compatibilizers, morphology stabilizers, and reinforcement agents, this book is a timely resource. Outlines techniques used to prepare nanoparticles-modified immiscible polymer blend composites Explains the structural and morphological development, and melt-state rheological behaviors of nanoparticles-modified immiscible polymer blend composites Discusses major industrial applications

Polymer Blends and Alloys

Author : George P. Simon
Publisher : Routledge
ISBN 13 : 1351423622
Total Pages : 766 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Polymer Blends and Alloys by : George P. Simon

Download or read book Polymer Blends and Alloys written by George P. Simon and published by Routledge. This book was released on 2019-07-16 with total page 766 pages. Available in PDF, EPUB and Kindle. Book excerpt: Distinguishing among blends, alloys and other types of combinations, clarifying terminology and presenting data on new processes and materials, this work present up-to-date and effective compounding techniques for polymers. It offers extensive analyses on the challenging questions that surround miscibility, compatibility, dynamic processing, interaction/phase behaviour, and computer simulations for predicting behaviours of polymer mixture and interaction.

Encyclopedia of Polymer Blends, Volume 3

Author : Avraam I. Isayev
Publisher : John Wiley & Sons
ISBN 13 : 3527653996
Total Pages : 528 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Encyclopedia of Polymer Blends, Volume 3 by : Avraam I. Isayev

Download or read book Encyclopedia of Polymer Blends, Volume 3 written by Avraam I. Isayev and published by John Wiley & Sons. This book was released on 2016-06-07 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete and timely overview of the topic, this Encyclopedia imparts knowledge of fundamental principles and their applications for academicians, scientists and researchers, while informing engineers, industrialists and entrepreneurs of the current state of the technology and its utilization. The most comprehensive source on polymer blends available on the market Offers a complete and timely overview of the topic Each article presents up to date research & development on a topic and its basic principles and applications, integrates case studies, laboratory and pilot plant experiments, and gives due reference to published and patented literature Equips academics, scientists and researchers with knowledge of fundamentals principles and their applications, and informs the engineers, industrialists and entrepreneurs about the state of the art technology and its applications

Functional Polymer Blends

Author : Vikas Mittal
Publisher : CRC Press
ISBN 13 : 1439856702
Total Pages : 345 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Functional Polymer Blends by : Vikas Mittal

Download or read book Functional Polymer Blends written by Vikas Mittal and published by CRC Press. This book was released on 2016-04-19 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: With their broad range of properties, polymer blends are widely used in adhesion, colloidal stability, the design of composite and biocompatible materials, and other areas. As the science and technology of polymer blends advances, an increasing number of polymer blend systems and applications continue to be developed. Functional Polymer Blends: Syn

Polymer Blends

Author : Lloyd M. Robeson
Publisher : Hanser Gardner Publications
ISBN 13 : 9781569904084
Total Pages : 459 pages
Book Rating : 4.9/5 (4 download)

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Book Synopsis Polymer Blends by : Lloyd M. Robeson

Download or read book Polymer Blends written by Lloyd M. Robeson and published by Hanser Gardner Publications. This book was released on 2007 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been well-recognized that polymer blends offer a key option in solving emerging application requirements. The ability to combine existing polymers into new compositions with commercializable properties offers the advantage of reduced research and development expense compared to the development of new monomers and polymers to yield a similar property profile. An additional advantage is the much lower capital expense involved with scale-up and commercialization. Another specific advantage of polymer blends versus new monomer/polymer compositions is that blends often offer property profile combinations not easily obtained with new polymeric structures. In the rapidly emerging technology landscape, polymer blend technology can quickly respond to developing needs.

Spectroscopic Techniques for Polymer Characterization

Author : Yukihiro Ozaki
Publisher : John Wiley & Sons
ISBN 13 : 3527348336
Total Pages : 500 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Spectroscopic Techniques for Polymer Characterization by : Yukihiro Ozaki

Download or read book Spectroscopic Techniques for Polymer Characterization written by Yukihiro Ozaki and published by John Wiley & Sons. This book was released on 2022-03-14 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: An insightful exploration of cutting-edge spectroscopic techniques in polymer characterization In Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications, a team of distinguished chemists delivers a comprehensive exploration of the vast potential of spectroscopic characterization techniques in polymer research. The book offers a concise outline of the principles, advantages, instrumentation, experimental techniques, and noteworthy applications of cutting-edge spectroscopy. Covering a wide range of polymers, from nylon to complex polymeric nanocomposites, the author presents recent developments in polymer science to polymer, analytical, and material chemists, assisting them in keeping track of the progress in modern spectroscopy. Spectroscopic Techniques for Polymer Characterization contains contributions from pioneers in modern spectroscopic techniques from around the world. The included materials bridge the gap between spectroscopists, polymer scientists, and engineers in academia and industry. The book also offers: A thorough introduction to the progress in spectroscopic techniques, including polymer spectroscopy and near-infrared spectroscopy Comprehensive explorations of topical polymers studied by spectroscopy, including polymer thin films, fluoropolymers, polymer solutions, conductive polymers Practical discussions of infrared imaging, near-infrared imaging, two-dimensional correlation spectroscopy, and far-ultraviolet spectroscopy In-depth examinations of spectroscopic studies of weak hydrogen bonding in polymers Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications is a must-read reference for polymer, analytical, and physical chemists, as well as materials scientists and spectroscopists seeking a one-stop resource for polymer characterization using spectroscopic analyses.