Solvent Effects On Reaction Rates And Mechanicsms

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Solvent Effects on Reaction Rates and Mechanisms

Author : Edward Stephen Amis
Publisher :
ISBN 13 :
Total Pages : 380 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Solvent Effects on Reaction Rates and Mechanisms by : Edward Stephen Amis

Download or read book Solvent Effects on Reaction Rates and Mechanisms written by Edward Stephen Amis and published by . This book was released on 1966 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Solvent Effects on Reaction Ratyes and mechanisms" is a title that will conjure up visions of different things to different investigators in the field of reaction kinetics. The physical chemist will envision the effects on rates of reactions of dieelectric constant, viscosity, internal cohesion, and externaL pressure as these are iinfluenced by the solvent. The physical-organic chemist will perhaps call to mind acidity, basicity, hydrogen bonding, structure effects, electro-negativity, and solvating ability as related to the solvent. The stricly organic chemist may simplyt think in terms of a medium in which reactants can be made to form products merely because of solubility relations, and his choice of solvent may depend on the ease of obtaining in a reasonable length of time a relatively pure product by extraction or other procedures. And, in fact, the topic includes all these and much more. Some of the phenomena are merely recorded as experimental observations. Some factors are subject to theoretical explanation, but even when theoretically explained or mathematically formulated they may not be sufficiently dominant ti justify the applicaton of the theory. Other effects may not be subject to theoretical explanations but may be included in correlations that are widely applicable. The explanation of some effects may be purely conjectural, but at least give some satisfaction to the seekers of the answer to the question, why? The material presented in the following pages will run the gamut of all the above possibilities.

Inorganic Reaction Mechanisms

Author : J Burgess
Publisher : Royal Society of Chemistry
ISBN 13 : 1847556485
Total Pages : 356 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Inorganic Reaction Mechanisms by : J Burgess

Download or read book Inorganic Reaction Mechanisms written by J Burgess and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Solvents and Solvent Effects in Organic Chemistry

Author : Christian Reichardt
Publisher : John Wiley & Sons
ISBN 13 : 3527642137
Total Pages : 722 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Solvents and Solvent Effects in Organic Chemistry by : Christian Reichardt

Download or read book Solvents and Solvent Effects in Organic Chemistry written by Christian Reichardt and published by John Wiley & Sons. This book was released on 2011-08-04 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt: Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.

Mechanisms in Organic Reactions

Author : Richard A. Jackson
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854046423
Total Pages : 212 pages
Book Rating : 4.0/5 (464 download)

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Book Synopsis Mechanisms in Organic Reactions by : Richard A. Jackson

Download or read book Mechanisms in Organic Reactions written by Richard A. Jackson and published by Royal Society of Chemistry. This book was released on 2004 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: An increasing knowledge and understanding of organic reaction mechanisms has been a major factor in the rapid advance of organic chemistry, biochemistry and pharmacology in the last century. It therefore forms a vital part of today's chemistry courses. Mechanisms in Organic Reactions helps students to make sensible proposals for the mechanisms of particular organic reactions, and then how to distinguish between different possible mechanisms. Techniques for this include product studies, kinetics, and the identification of intermediates. Three chapters on intermediates discuss likely points of attack on molecules by anions, radicals and cations, and the important role of acid- and base-catalysed reactions and radical chain reactions. The prediction of reaction rates and the effects of structural changes on reaction rate are also covered. It concludes with a discussion of molecular reactions, both thermal and photochemical - reactions which provide deep and beautiful insights into the reasons why some reactions go and others do not, and why the majority of real-life reactions involve multi-step processes. The book provides both illuminating insights into fundamental chemistry, and also practical value for students who will go on to teach, research, or be involved in other scientific roles (administration, policy making or journalism). Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

Solvent Effects on Chemical Phenomena

Author : Edward Amis
Publisher : Elsevier
ISBN 13 : 0323148522
Total Pages : 487 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Solvent Effects on Chemical Phenomena by : Edward Amis

Download or read book Solvent Effects on Chemical Phenomena written by Edward Amis and published by Elsevier. This book was released on 2012-12-02 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvent Effects on Chemical Phenomena, Volume I discusses the developments in the understanding of solvent effects on chemical phenomena in solution. This five-chapter volume begins with a discussion on the general concepts of various solvation types, including positive and negative, inner and outer sphere, and mixed component. The subsequent chapter deals with the determination of the actual solvation number for single ions. A short list of the total effective hydration numbers of electrolytes determined from temperature dependence of proton shifts is also provided in this chapter. Another chapter presents a number of examples of the unusual properties of certain mixed aqueous systems. The solvent effects on reaction rates and mechanisms are highlighted in the concluding chapter. This chapter also covers various types of solvents, such as protic and dipolar aprotic. The enthalpy and entropy of activation in salvation and the Finkelstein reactions are also discussed. Research chemists and scientists, teachers, and students with courses in solution chemistry will greatly benefit from this volume.

Isotope Effects in Chemical Reactions

Author : Clair J. Collins
Publisher :
ISBN 13 :
Total Pages : 456 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Isotope Effects in Chemical Reactions by : Clair J. Collins

Download or read book Isotope Effects in Chemical Reactions written by Clair J. Collins and published by . This book was released on 1971 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Solvent Effects and Chemical Reactivity

Author : Orlando Tapia
Publisher : Springer Science & Business Media
ISBN 13 : 9781402004179
Total Pages : 396 pages
Book Rating : 4.0/5 (41 download)

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Book Synopsis Solvent Effects and Chemical Reactivity by : Orlando Tapia

Download or read book Solvent Effects and Chemical Reactivity written by Orlando Tapia and published by Springer Science & Business Media. This book was released on 2003-07-31 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an up-to-date view of theories, practical methods and applications of solvent effects and chemical reactivity in condensed phases. Subjects treated include continuum solvation models, the theoretical basis for the treatment of solvent effects in density functional theory, Monte Carlo simulations of chemical reactions in solution, DFT molecular dynamics simulations, crossing the transition state in solution, valence bond multi-state approach to chemical reactions in solution, quantum theory of solvent effects and chemical reactions. The approaches taken as well as the resulting findings are discussed in detail, thus covering a large part of the methodology currently used in this field. Audience: This volume will be useful to graduate students in chemistry, physical chemistry and biochemistry, to research workers with a background in quantum chemistry and quantum mechanics, to pure and applied quantum chemists, and to industrial molecular modellers.

Reaction Rate Theory and Rare Events

Author : Baron Peters
Publisher : Elsevier
ISBN 13 : 0444594701
Total Pages : 636 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Reaction Rate Theory and Rare Events by : Baron Peters

Download or read book Reaction Rate Theory and Rare Events written by Baron Peters and published by Elsevier. This book was released on 2017-03-22 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition state theory, RRKM theory, catalysis, diffusion limited kinetics, mean first passage times, Kramers theory, Grote-Hynes theory, transition path theory, non-adiabatic reactions, electron transfer, and topics from reaction network analysis. It is an essential reference for students, professors and scientists who use reaction rate theory or the theory of rare events. In addition, the book discusses transition state search algorithms, tunneling corrections, transmission coefficients, microkinetic models, kinetic Monte Carlo, transition path sampling, and importance sampling methods. The unified treatment in this book explains why chemical reactions and other rare events, while having many common theoretical foundations, often require very different computational modeling strategies. - Offers an integrated approach to all simulation theories and reaction network analysis, a unique approach not found elsewhere - Gives algorithms in pseudocode for using molecular simulation and computational chemistry methods in studies of rare events - Uses graphics and explicit examples to explain concepts - Includes problem sets developed and tested in a course range from pen-and-paper theoretical problems, to computational exercises

Solvents, Ionic Liquids and Solvent Effects

Author : Daniel Glossman-Mitnik
Publisher : BoD – Books on Demand
ISBN 13 : 1789852811
Total Pages : 260 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Solvents, Ionic Liquids and Solvent Effects by : Daniel Glossman-Mitnik

Download or read book Solvents, Ionic Liquids and Solvent Effects written by Daniel Glossman-Mitnik and published by BoD – Books on Demand. This book was released on 2020-01-15 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solvents and ionic liquids are ubiquitous within our whole life since ancient times and their effects are actually being studied through basic sciences like Chemistry, Physics and Biology as well as being researched by a large number of scientific disciplines.This book represents an attempt to present examples on the utility of old and new solvents and the effects they exercise on several fields of academic and industrial interest. The first section, Solvents, presents information on bio-solvents and their synthesis, industrial production and applications, about per and trichloroethylene air monitoring in dry cleaners in the city of Sfax (Tunsia) and on the synthesis of polyimides using molten benzoic acid as the solvent. The second section, Ionic Liquids, shows information about the synthesis, physicochemical characterization and exploration of antimicrobial activities of imidazolium ionic liquid-supported Schiff base and its transition metal complexes, the technology of heterogenization of transition metal catalysts towards the synthetic applications in an ionic liquid matrix, the progress in ionic liquids as reaction media, monomers, and additives in high-performance polymers, a pre-screening of ionic liquids as gas hydrate inhibitor via application of COSMO-RS for methane hydrate, the extraction of aromatic compounds from their mixtures with alkanes from ternary to quaternary (or higher) systems and a review on ionic liquids as environmental benign solvent for cellulose chemistry. The final section, Solvent Effects, displays interesting information on solvent effects on dye sensitizers derived from anthocyanidins for applications in photocatalysis, about the solvent effect on a model of SNAr reaction in conventional and non-conventional solvents, and on solvent effects in supramolecular systems.

Fundamentals of Reaction Mechanisms in Organic Chemistry

Author : Narain R. P.
Publisher : PHI Learning Pvt. Ltd.
ISBN 13 : 8120341791
Total Pages : 279 pages
Book Rating : 4.1/5 (23 download)

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Book Synopsis Fundamentals of Reaction Mechanisms in Organic Chemistry by : Narain R. P.

Download or read book Fundamentals of Reaction Mechanisms in Organic Chemistry written by Narain R. P. and published by PHI Learning Pvt. Ltd.. This book was released on 2011-03 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written for the undergraduate and postgraduate students of chemistry, this textbook presents comprehensive coverage of different types of reactions and their mechanisms. The need for such a book has been felt for a very long time both by students and teachers. The book discusses chemical kinetics, structure and reactivity, and reactive intermediates such as carbenes, nitrenes and benzynes. It also describes the mechanism of tautomerism and the concepts of aromaticity. In addition, the book elaborates the various reactions such as substitution, free radical, addition, elimination and alkylation reactions. Finally, the text presents a detailed discussion on molecular rearrangements, oximes and diazo compounds, as well as the concepts of photochemistry. KEY FEATURES: Presents a number of examples to explain the mechanistic concepts. Offers graphs and tables at various places to illustrate the key points. Includes latest information on the subject.

Chemical Kinetics and Inorganic Reaction Mechanisms

Author : Smiljko Asperger
Publisher : Springer Science & Business Media
ISBN 13 : 1441992766
Total Pages : 363 pages
Book Rating : 4.4/5 (419 download)

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Book Synopsis Chemical Kinetics and Inorganic Reaction Mechanisms by : Smiljko Asperger

Download or read book Chemical Kinetics and Inorganic Reaction Mechanisms written by Smiljko Asperger and published by Springer Science & Business Media. This book was released on 2011-06-27 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: The serious study of the reaction mechanisms of transition metal com plexes began some five decades ago. Work was initiated in the United States and Great Britain; the pioneers ofthat era were, inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C. S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G. Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community of research scientists then entered the field, many of them stu dents ofthose just mentioned. Interest spread elsewhere as well, principally to Asia, Canada, and Europe. Before long, the results ofindividual studies were being consolidated into models, many of which traced their origins to the better-established field of mechanistic organic chemistry. For a time this sufficed, but major revisions and new assignments of mechanism became necessary for both ligand sub stitution and oxidation-reduction reactions. Mechanistic inorganic chemistry thus took on a shape of its own. This process has brought us to the present time. Interests have expanded both to include new and more complex species (e.g., metalloproteins) and a wealth of new experimental techniques that have developed mechanisms in ever-finer detail. This is the story the author tells, and in so doing he weaves in the identities of the investigators with the story he has to tell. This makes an enjoyable as well as informative reading.

Chemical Kinetics and Reaction Dynamics

Author : Santosh K. Upadhyay
Publisher : Springer Science & Business Media
ISBN 13 : 1402045476
Total Pages : 256 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Chemical Kinetics and Reaction Dynamics by : Santosh K. Upadhyay

Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.

Chemistry 2e

Author : Paul Flowers
Publisher :
ISBN 13 : 9781947172623
Total Pages : 0 pages
Book Rating : 4.1/5 (726 download)

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Book Synopsis Chemistry 2e by : Paul Flowers

Download or read book Chemistry 2e written by Paul Flowers and published by . This book was released on 2019-02-14 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.

Organic Reaction Mechanisms 2006

Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 9780470669570
Total Pages : 602 pages
Book Rating : 4.6/5 (695 download)

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Book Synopsis Organic Reaction Mechanisms 2006 by : A. C. Knipe

Download or read book Organic Reaction Mechanisms 2006 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2010-04-20 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Reaction Mechanisms 2006 is the 42nd volume in this classical series. Every year, an experienced team of authors compiles these reviews, so that the reader can rely on a continuing quality of selection and presentation. Detailed author and subject indexes help the reader to find the information they are looking for. As a new service to the reader, all reaction mechanisms leading to stereospecific products are highlighted. This reflects the interest of synthetic organic chemists in such reactions and the pharmaceutical role of chiral molecules.

Reaction Mechanisms of Inorganic and Organometallic Systems

Author : Robert B. Jordan
Publisher : Oxford University Press
ISBN 13 : 019971973X
Total Pages : 532 pages
Book Rating : 4.1/5 (997 download)

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Book Synopsis Reaction Mechanisms of Inorganic and Organometallic Systems by : Robert B. Jordan

Download or read book Reaction Mechanisms of Inorganic and Organometallic Systems written by Robert B. Jordan and published by Oxford University Press. This book was released on 2007-06-18 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Mechanisms of Reactions of Metal Complexes

Author : Debabrata Banerjea
Publisher : Royal Society of Chemistry
ISBN 13 : 1839163607
Total Pages : 539 pages
Book Rating : 4.8/5 (391 download)

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Book Synopsis Mechanisms of Reactions of Metal Complexes by : Debabrata Banerjea

Download or read book Mechanisms of Reactions of Metal Complexes written by Debabrata Banerjea and published by Royal Society of Chemistry. This book was released on 2022-09-21 with total page 539 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Mechanisms of Metal Complexes in Solution provides a comprehensive overview of an often-overlooked research area. Despite its importance and recent reshaping of the field, many inorganic chemists have lost an appreciation for the significance of stability constants and the thermodynamic aspects of complex formation. Ideal for newcomers and established researchers in the field this book is a complete treatment of the area covering advanced topics with relevance to biomedical applications, extraction metallurgy, food chemistry and a wealth of other industrial processes and research areas. The book will be of particular interest to postgraduates with an interest in coordination chemistry, catalysis, supramolecular chemistry, metallobiology and related aspects of biochemistry.

Organic Reaction Mechanisms 2007

Author : A. C. Knipe
Publisher : John Wiley & Sons
ISBN 13 : 1119957672
Total Pages : 656 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Organic Reaction Mechanisms 2007 by : A. C. Knipe

Download or read book Organic Reaction Mechanisms 2007 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2011-07-05 with total page 656 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Reaction Mechanisms 2007, the 43rd annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2007. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.