Silicon in Organic Synthesis

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Author :
Publisher : Butterworth-Heinemann
ISBN 13 : 148314223X
Total Pages : 361 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Silicon in Organic Synthesis by : Ernest W. Colvin

Download or read book Silicon in Organic Synthesis written by Ernest W. Colvin and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.

Progress in Organosilicon Chemistry

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Author :
Publisher : Taylor & Francis
ISBN 13 : 9782884491228
Total Pages : 620 pages
Book Rating : 4.4/5 (912 download)

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Book Synopsis Progress in Organosilicon Chemistry by : Bogdan Marciniec

Download or read book Progress in Organosilicon Chemistry written by Bogdan Marciniec and published by Taylor & Francis. This book was released on 1995 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Organosilicon Chemistry comprises more than thirty papers presented by many of the world's most eminent organosilicon specialists at the Tenth International Symposium on Organosilicon Chemistry held in Poznan, Poland in August 1993. The conference marked the fiftieth anniversary of the discovery and exploration of "direct synthesis." As much attention today is directed beyond silicon polymers, chemists have become involved with the use of elementary silicon and its applications, including ultrapure silicon in transistors and computers, silicon precursors of polymers, and other silicon-based materials as well as fine chemicals. This book provides an overview of organosilicon chemistry, including organic and inorganic chemistry of silicon, silicon polymers and oligomers; theoretical and structural chemistry of silicon; silicon-based materials and their applications; silicon in organic synthesis; mechanistic organosilicon chemistry; and bio- and environmental organosilicon chemistry. This diverse range of topics makes the book a valuable reference for chemists working in both applied and theoretical chemistry.

Silicon Reagents for Organic Synthesis

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642686613
Total Pages : 446 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Silicon Reagents for Organic Synthesis by : William P. Weber

Download or read book Silicon Reagents for Organic Synthesis written by William P. Weber and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reagents for Silicon-Mediated Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 1118636139
Total Pages : 816 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Reagents for Silicon-Mediated Organic Synthesis by : Philip L. Fuchs

Download or read book Reagents for Silicon-Mediated Organic Synthesis written by Philip L. Fuchs and published by John Wiley & Sons. This book was released on 2013-05-30 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last three decades the importance of organosiliconchemistry has greatly increased because it has opened a number ofnew synthetic strategies. Silicon reagents are usually low-cost,versatile and allow a wide range of reactions. This is the firstHandbook to compile essential Silicon containing reagents and makesuse of the leading reagent database e-EROS. Another hotvolume in the series Handbooks of Reagents for OrganicSynthesis, this is a must-have resource for all syntheticchemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key syntheticapproaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactivepair of functional groups and taking advantage of theirtemplate-biased intramolecular cyclization. 2. The specific use of the silane functionality as a heterot-butyl group, often colloquially referred to as the use ofsilicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relaystratagem'. A new feature in this Handbook is the reagent finder, analphabetically organized lookup table arranged by organicfunctionality and specific structure of the silicon atom to whichit is bound.

Silicon Reagents in Organic Synthesis

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Publisher :
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Silicon Reagents in Organic Synthesis by : Ernest W. Colvin

Download or read book Silicon Reagents in Organic Synthesis written by Ernest W. Colvin and published by . This book was released on 1988 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work provides a full coverage of organosilicon chemistry, with pertinent references to more detailed treatment given at appropriate points in the book.

Silicon in Organic Synthesis

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Author :
Publisher :
ISBN 13 :
Total Pages : 348 pages
Book Rating : 4.:/5 (64 download)

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Book Synopsis Silicon in Organic Synthesis by : Ernest W. Colvin

Download or read book Silicon in Organic Synthesis written by Ernest W. Colvin and published by . This book was released on 1985 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Silicon in Organic, Organometallic, and Polymer Chemistry

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Author :
Publisher : Wiley-Interscience
ISBN 13 : 9780471196587
Total Pages : 704 pages
Book Rating : 4.1/5 (965 download)

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Book Synopsis Silicon in Organic, Organometallic, and Polymer Chemistry by : Michael A. Brook

Download or read book Silicon in Organic, Organometallic, and Polymer Chemistry written by Michael A. Brook and published by Wiley-Interscience. This book was released on 1999-12-28 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations

Organosilicon Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527344535
Total Pages : 566 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Organosilicon Chemistry by : Tamejiro Hiyama

Download or read book Organosilicon Chemistry written by Tamejiro Hiyama and published by John Wiley & Sons. This book was released on 2020-02-18 with total page 566 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.

Organosilicon Compounds

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Publisher : Academic Press
ISBN 13 : 0128019913
Total Pages : 758 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Organosilicon Compounds by : Vladimir Ya Lee

Download or read book Organosilicon Compounds written by Vladimir Ya Lee and published by Academic Press. This book was released on 2017-08-22 with total page 758 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

The Chemistry of Organic Silicon Compounds

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Publisher :
ISBN 13 :
Total Pages : 922 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis The Chemistry of Organic Silicon Compounds by : Saul Patai

Download or read book The Chemistry of Organic Silicon Compounds written by Saul Patai and published by . This book was released on 1989 with total page 922 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalysis with Earth-abundant Elements

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Publisher : Royal Society of Chemistry
ISBN 13 : 178801118X
Total Pages : 431 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Catalysis with Earth-abundant Elements by : Uwe Schneider

Download or read book Catalysis with Earth-abundant Elements written by Uwe Schneider and published by Royal Society of Chemistry. This book was released on 2020-10-30 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: Considering the limited resources of our planet, earth-abundant elements will have to be explored increasingly in the future. This book highlights the uses of the most earth-abundant elements in catalysis and will be of interest to graduates, academic researchers and practitioners in catalysis.

Organosilicon Chemistry

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Publisher : Walter de Gruyter
ISBN 13 : 3110862387
Total Pages : 201 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Organosilicon Chemistry by : Stephan Pawlenko

Download or read book Organosilicon Chemistry written by Stephan Pawlenko and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Synthesis, the Roles of Boron and Silicon

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (474 download)

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Book Synopsis Organic Synthesis, the Roles of Boron and Silicon by : Susan E. Thomas

Download or read book Organic Synthesis, the Roles of Boron and Silicon written by Susan E. Thomas and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Efficient Methods for Preparing Silicon Compounds

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Publisher : Academic Press
ISBN 13 : 0128035684
Total Pages : 540 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Efficient Methods for Preparing Silicon Compounds by : Herbert W Roesky

Download or read book Efficient Methods for Preparing Silicon Compounds written by Herbert W Roesky and published by Academic Press. This book was released on 2016-05-12 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. Includes contributions and edits from leading experts in the field Includes detailed chemical schemes and useful references for each preparative method Organized by the coordination numbers of the central silicon atom for each compound for easy navigation Serves as a go-to primer for researchers in novel compositions of silicon matter

An Introduction Chemistry of the Silicones

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Publisher : Read Books Ltd
ISBN 13 : 1446546101
Total Pages : 143 pages
Book Rating : 4.4/5 (465 download)

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Book Synopsis An Introduction Chemistry of the Silicones by : Eugene G. Rochow

Download or read book An Introduction Chemistry of the Silicones written by Eugene G. Rochow and published by Read Books Ltd. This book was released on 2011-03-23 with total page 143 pages. Available in PDF, EPUB and Kindle. Book excerpt: The organic compounds of silicon, which have been the subject of many scholarly researches during the past 80 years, at last show promise of emerging from the laboratory and finding a place in industry. An understanding of the behaviour of organosilicon materials is necessary to their intelligent use and, inasmuch as the chemistry of these substances ordinarily is not treated in our textbooks, it is possible that a compact yet comprehensive survey of our present knowledge in this field would be of service to chemists, engineers, and industrial designers. This volume has just such a purpose. The first few chapters review the silanes and their derivatives in some detail, in order to provide an understanding of the fundamental chemistry of the nonsilicate compounds of silicon. The later chapters emphasize the silicone polymers which have achieved commercial importance and deal with the methods for their preparation, their chemical and physical properties, and their possible uses. The processes available for large-scale production are treated separately, and a review of methods of analysis is included.

The Chemistry of Organic Silicon Compounds

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Publisher :
ISBN 13 :
Total Pages : 896 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis The Chemistry of Organic Silicon Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organic Silicon Compounds written by Zvi Rappoport and published by . This book was released on 1998 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organosilicon compounds are key organometallic compounds (R-Si) which have many uses in materials science and in metallurgy. Their applications include the synthesis of sugars and in the synthesis of organic compounds for the pharmaceutical industry. This volume will contain both updated chapters on key topics included in the original volumes as well as a number of new chapters reflecting the rapid developments made in silicon chemistry and its applications to organometallic chemistry, materials science, and semiconductors, over the last five years. As for the majority of volumes in this series, chapters will be prepared by leading scientists in the field. This volume is now available in electronic format from Books Online.

Recent Developments in the Use of Silicon in Organic Synthesis

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Publisher :
ISBN 13 :
Total Pages : 171 pages
Book Rating : 4.:/5 (476 download)

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Book Synopsis Recent Developments in the Use of Silicon in Organic Synthesis by : Hans Reich

Download or read book Recent Developments in the Use of Silicon in Organic Synthesis written by Hans Reich and published by . This book was released on 1983 with total page 171 pages. Available in PDF, EPUB and Kindle. Book excerpt: