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Silicon Chemistry I
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Download or read book Silicon Chemistry written by Peter Jutzi and published by John Wiley & Sons. This book was released on 2007-09-24 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: The combined results from an international research project involving 40 interdisciplinary groups, providing the latest knowledge from the past few years. Adopting an application-oriented approach, this handy reference is a must-have for every silicon chemist, whether working in inorganic, organic, physical or polymer chemistry, materials science or physics.
Book Synopsis Coordination Chemistry of Silicon by : Prof. Dr. Shigeyoshi Inoue
Download or read book Coordination Chemistry of Silicon written by Prof. Dr. Shigeyoshi Inoue and published by MDPI. This book was released on 2019-03-04 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.
Book Synopsis Silicon in Organic Synthesis by : Ernest W. Colvin
Download or read book Silicon in Organic Synthesis written by Ernest W. Colvin and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a "ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of a-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.
Book Synopsis Efficient Methods for Preparing Silicon Compounds by : Herbert W Roesky
Download or read book Efficient Methods for Preparing Silicon Compounds written by Herbert W Roesky and published by Academic Press. This book was released on 2016-05-12 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
Book Synopsis Silicon in Organic, Organometallic, and Polymer Chemistry by : Michael A. Brook
Download or read book Silicon in Organic, Organometallic, and Polymer Chemistry written by Michael A. Brook and published by Wiley-Interscience. This book was released on 1999-12-28 with total page 704 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive, up-to-date reference to synthetic applications of organosilicon chemistry Organic, organometallic, and polymer chemistry as well as materials science all utilize silicon in various forms, yet there is little cross-fertilization of ideas and applications among the disciplines. This book presents a much-needed overview of silicon chemistry, allowing fundamental and applied scientists to take full advantage of progress made within and outside their primary fields of expertise. With an emphasis on the preparation and reactivity of silicon compounds in organic, organometallic, and polymer chemistry, the author examines a broad range of useful topics-from mechanisms to syntheses of and syntheses using different organofunctional silanes. Numerous schemes as well as up-to-date examples from academia and industry will help readers to solve current synthetic problems and explore ideas for future research. Clear, concise coverage includes: * The mechanistic basis for the development of new silicon-based reactions * Formation and cleavage of silane reagents and functional siliconheteroatom compounds * Silicones, silica, polysilanes, and other silicon-containing polymers * Properties of molecules containing silicon, including bioactivity * Methods for the preparation of Si-C compounds * Silicon in organic synthesis * An extensive functional group index for easy access to functional group transformations
Book Synopsis Electrochemistry of Silicon and Its Oxide by : Xiaoge Gregory Zhang
Download or read book Electrochemistry of Silicon and Its Oxide written by Xiaoge Gregory Zhang and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: It may be argued that silicon, carbon, hydrogen, oxygen, and iron are among the most important elements on our planet, because of their involvement in geological, biol- ical, and technological processes and phenomena. All of these elements have been studied exhaustively, and voluminous material is available on their properties. Included in this material are numerous accounts of their electrochemical properties, ranging from reviews to extensive monographs to encyclopedic discourses. This is certainly true for C, H, O, and Fe, but it is true to a much lesser extent for Si, except for the specific topic of semiconductor electrochemistry. Indeed, given the importance of the elect- chemical processing of silicon and the use of silicon in electrochemical devices (e. g. , sensors and photoelectrochemical cells), the lack of a comprehensive account of the electrochemistry of silicon in aqueous solution at the fundamental level is surprising and somewhat troubling. It is troubling in the sense that the non-photoelectrochemistry of silicon seems “to have fallen through the cracks,” with the result that some of the electrochemical properties of this element are not as well known as might be warranted by its importance in a modern technological society. Dr. Zhang’s book, Electrochemical Properties of Silicon and Its Oxide, will go a long way toward addressing this shortcoming. As with his earlier book on the elect- chemistry of zinc, the present book provides a comprehensive account of the elect- chemistry of silicon in aqueous solution.
Book Synopsis The Chemistry of Silicon by : Eugene George Rochow
Download or read book The Chemistry of Silicon written by Eugene George Rochow and published by . This book was released on 1973 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemistry and Technology of Silicones by : Walter Noll
Download or read book Chemistry and Technology of Silicones written by Walter Noll and published by Elsevier. This book was released on 2012-12-02 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and Technology of Silicones retains the nature of a monograph despite its expanded scope, giving the reader in condensed form not only a wide-ranging but also a thorough review of this rapidly growing field. In contrast to some other monographs on organosilicon compounds that have appeared in the interim, the silicones occupy in this edition the central position, and the technological part of the work is entirely devoted to them. This book comprises 12 chapters, and begins with a general discussion of the chemistry and molecular structure of the silicones. The following chapters then discuss preparation of silanes with nonfunctional organic substituents; monomeric organosilicon compounds RnSiX4-n; and organosilanes with organofunctional groups. Other chapters cover preparation of polyorganosiloxanes; the polymeric organosiloxanes; other organosilicon polymers; production of technical silicone products from polyorganosiloxanes; properties of technical products; applications of technical silicone products in various branches of industry; esters of silicic acid; and analytical methods. This book will be of interest to practitioners in the fields of molecular chemistry.
Book Synopsis Chemistry of Silica and Zeolite-Based Materials by : Abderrazzak Douhal
Download or read book Chemistry of Silica and Zeolite-Based Materials written by Abderrazzak Douhal and published by Elsevier. This book was released on 2019-07-04 with total page 465 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry of Silica and Zeolite-Based Materials covers a wide range of topics related to silica-based materials from design and synthesis to applications in different fields of science and technology. Since silica is transparent and inert to the light, it is a very attractive host material for constructing artificial photosynthesis systems. As an earth-abundant oxide, silica is an ideal and basic material for application of various oxides, and the science and technology of silica-based materials are fundamentally important for understanding other oxide-based materials. The book examines nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, photonics, photosensors, photovoltaics, energy, environmental sciences, drug delivery, and health. Written by a highly experienced and internationally renowned team from around the world, Chemistry of Silica and Zeolite-Based Materials is ideal for chemists, materials scientists, chemical engineers, physicists, biologists, biomedical sciences, environmental scientists, toxicologists, and pharma scientists. --- "The enormous versatility of silica for building a large variety of materials with unique properties has been very well illustrated in this book.... The reader will be exposed to numerous potential applications of these materials – from photocatalytic, optical and electronic applications, to chemical reactivity in confined spaces and biological applications. This book is of clear interest not only to PhD students and postdocs, but also to researchers in this field seeking an understanding of the possible applications of meso and microporous silica-derived materials." - Professor Avelino Corma, Institute of Chemical Technology (ITQ-CSIC) and Polytechnical University of Valencia, Spain - Discusses the most important advances in various fields using silica materials, including nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, and other topics - Written by a global team of experts from a variety of science and technology disciplines - Ideal resource for chemists, materials scientists, and chemical engineers working with oxide-based materials
Book Synopsis Electrochemistry of Silicon by : Volker Lehmann
Download or read book Electrochemistry of Silicon written by Volker Lehmann and published by Wiley-VCH. This book was released on 2002-04-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon has been and will most probably continue to be the dominant material in semiconductor technology. Although the defect-free silicon single crystal is one of the best understood systems in materails science, its electrochemistry to many people is still a kind of "alchemy". This view is partly due to the interdisciplinary aspects of the topic: Physics meets chemistry at the silicon-electrolyte interface. This book gives a comprehensive overview of this important aspect of silicon technology as well as examples of applications ranging from photonic crystals to biochips. It will serve materials scientists as well as engineers involved in silicon technology as a quick reference with its more than 150 technical tables and diagrams and ca. 1000 references cited for easy access of the original literature.
Book Synopsis Silicon Chemistry by : Ulrich Schubert
Download or read book Silicon Chemistry written by Ulrich Schubert and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon and silicon compounds have contributed decisively to the technical progress. Technical applications range from mass commodities to highly sophisticated special materials, from ceramics to polymers, from medicine to microelectronics. To keep pace with scientific and technical developments Germany and Austria have established national priority programs, strongly linked to each other as well as to some Swiss groups. At mid-term of the German program and the end of the first funding period of the Austrian program the results are summarized in this special edition of the journal Monatshefte für Chemie/Chemical Monthly, giving an excellent overview of the current chemical (and partly physical) acitivites in the joint Austrian/German/Swiss program. The contributions cover topical and interdisciplinary developments in the following areas: • new phenomena in compounds with Si-Si bonds: transitions between molecular compounds and solids, cyclosilanes, polysilanes, silicides, amorphous hydrogenated silicon, • novel silicon-oxygen systems: functionalized sol-gel compounds, spherosiloxanes, siloxene, • compounds with low- and high-coordinated silicon, • new spectroscopic and analytical techniques for the characterization of molecular and polymeric silicon compounds.
Book Synopsis Porous Silicon in Practice by : M. J. Sailor
Download or read book Porous Silicon in Practice written by M. J. Sailor and published by John Wiley & Sons. This book was released on 2012-01-09 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: By means of electrochemical treatment, crystalline silicon can be permeated with tiny, nanostructured pores that entirely change the characteristics and properties of the material. One prominent example of this can be seen in the interaction of porous silicon with living cells, which can be totally unwilling to settle on smooth silicon surfaces but readily adhere to porous silicon, giving rise to great hopes for such future applications as programmable drug delivery or advanced, braincontrolled prosthetics. Porous silicon research is active in the fields of sensors, tissue engineering, medical therapeutics and diagnostics, photovoltaics, rechargeable batteries, energetic materials, photonics, and MEMS (Micro Electro Mechanical Systems). Written by an outstanding, well-recognized expert in the field, this book provides detailed, step-by-step instructions to prepare and characterize the major types of porous silicon. It is intended for those new to the fi eld. Sampling of topics covered: * Principles of Etching Porous Silicon * Etch Cell Construction and Considerations * Photonic Crystals, Microcavities, and Bragg Stacks Etched in Silicon * Preparation of Free-standing Films and Particles of Porous Silicon * Preparation of Photoluminescent Nanoparticles from Porous Silicon * Preparation of Silicon Nanowires by Electrochemical Etch of Silicon * Surface Modifi cation Chemistry and Biochemistry * Measurement of Optical Properties * Measurement of Pore Size, Porosity, Thickness, Surface Area The whole is backed by a generous use of color photographs to illustrate the described procedures in detail, plus a bibliography of further literature pertinent to a wide range of application fi elds. For materials scientists, chemists, physicists, optical physicists, biomaterials scientists, neurobiologists, bioengineers, and graduate students in those fields, as well as those working in the semiconductor industry.
Book Synopsis D-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur by : H. Kwart
Download or read book D-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur written by H. Kwart and published by Springer. This book was released on 1977-12 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book was undertaken for the purpose of bringing together the widely diverse lines of experimental work and thinking which has been expressed but has often been unheard on the title question. It will be clear to the reader that a critical viewpoint has been maintained in assembling the material of this rapidly expanding area of concern to organic chemists. It should be clear, too, that the authors are not purvey ing a singular viewpoint and do not regard the discussions presented as the ultimate word on the subject. In fact, it should be anticipated that many ofthe viewpoints pre sented may have to be altered in the light of new developments. In recognition of this and to show the wayan appendix of recent results and interpretation has been included where an alteration in viewpoint on some of the material treated in the text has been necessitated by developments in the most recent literature. This ap pendix should be regarded as the reader's opportunity to maintain currency in all aspects of this subject ifit is kept abreast of the literature. The bibliography, from which most of the material of discussion has been drawn, is organized in a somewhat unusual manner which deserves some explana tion here. A reference citation can consist of (as much as) a six space combination of letters and numerals.
Book Synopsis Silicon Based Polymers by : François Ganachaud
Download or read book Silicon Based Polymers written by François Ganachaud and published by Springer Science & Business Media. This book was released on 2008-08-09 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon Based Polymers presents highlights in advanced research and technological innovations using macromolecular organosilicon compounds and systems, as presented in the 2007 ISPO congress. Silicon-containing materials and polymers are used all over the world and in a variety of industries, domestic products and high technology applications. Among them, silicones are certainly the most well–known, however there are still new properties discovered and preparative processes developed all the time, therefore adding to their potential. Less known, but in preparation for the future, are other silicon containing-polymers which are now close to maturity and in fact some are already available like polysilsesquioxanes and polysilanes. All these silicon based materials can adopt very different structures like chains, dendrimers, hyperbranched and networks, physical and chemical gels. The result is a vast array of materials with applications in various areas such as optics, electronics, ionic electrolytes, liquid crystals, biomaterials, ceramics and concrete, paints and coatings ... all needed to face the environmental, energetical and technological issues of today. Some industrial aspects of the applications of these materials will also be presented.
Book Synopsis Silicon-Based Polymers and Materials by : Jerzy J. Chruściel
Download or read book Silicon-Based Polymers and Materials written by Jerzy J. Chruściel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-03-07 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Silicon based materials and polymers are made of silicon containing polymers, mainly macromolecular siloxanes (silicones). This book covers the different kinds of siliconbased polymers: silicones, silsesquioxanes (POSS), and silicon-based copolymers. Other silicon containig polymers: polycarbosilanes, polysilazanes, siloxane-organic copolymers, silicon derived high-tech ceramics: silicon carbide and oxycarbide, silicon nitride, etc. have also a very important practical meaning and a hudge number of practical applications. These materials make up products in a variety of industries and products, including technical and medical applicatons. Polycrystalline silicon is the basic material for large scale photovoltaic (PV) applications as solar cells. Technical applications of crystalline (c-Si) and amorphous (a-Si) silicon (fully inorganic materials), silicon nanowires are still quickly growing, especially in the fi eld of microelectronics, optoelectronics, photonics. and photovoltaics, catalysts, and different electronic devices (e.g. sensors, thermoelectric devices). This book is ideal for researchers and as such covers the industrial perspective of using each class of silicon based materials. Discusses silanes, silane coupling agents (SCA), silica, silicates, silane modified fillers, silsesquioxanes, silicones, and other silicon polymers and copolymers for practical applications as polymeric materials and very useful ingredients in materials science.
Book Synopsis Bio-Inspired Silicon-Based Materials by : Paul M. Zelisko
Download or read book Bio-Inspired Silicon-Based Materials written by Paul M. Zelisko and published by Springer. This book was released on 2014-11-14 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contributed volume addresses a wide range of topics including, but not limited to, biotechnology, synthetic chemistry, polymer chemistry and materials chemistry. The book will serve as a specialized review of the field of biologically inspired silicon-based structures. Researchers studying biologically inspired silicon materials chemistry will find this volume invaluable.
Book Synopsis The Physics and Chemistry of SiO2 and the Si-SiO2 Interface 2 by : B.E. Deal
Download or read book The Physics and Chemistry of SiO2 and the Si-SiO2 Interface 2 written by B.E. Deal and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first international symposium on the subject "The Physics and Chemistry of Si02 and the Si-Si02 Interface," organized in association with the Electrochemical Society, Inc. , was held in Atlanta, Georgia on May 15- 20, 1988. This symposium contained sixty papers and was so successful that the sponsoring divisions decided to schedule it on a regular basis every four years. Thus, the second symposium on "The Physics and Chemistry of Si02 and the Si02 Interface was held May 18-21, 1992 in St. Louis, Missouri, again sponsored by the Electronics and Dielectrics Science and Technology Divisions of The Electrochemical Society. This volume contains manuscripts of most of the fifty nine papers presented at the 1992 symposium, and is divided into eight chapters - approximating the organization of the symposium. Each chapter is preceded with an introduction by the session organizers. It is appropriate to provide a general assessment of the current status and understanding of the physics and chemistry of Si02 and the Si02 interface before proceeding with a brief overview of the individual chapters. Semiconductor devices have continued to scale down in both horizontal and vertical dimensions. This has resulted in thinner gate and field oxides as well as much closer spacing of individual device features. As a result, surface condition, native oxide composition, and cleaning and impurity effects now provide a much more significant contribution to the properties of oxides and their interfaces.
