Selective Hydrogenation Of Benzene On A Rhodium Catalyst

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Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene

Author : Ruijun Hou
Publisher : Springer
ISBN 13 : 981100773X
Total Pages : 151 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene by : Ruijun Hou

Download or read book Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene written by Ruijun Hou and published by Springer. This book was released on 2017-01-05 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.“/p>

Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis

Author : Shigeo Nishimura
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 728 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis by : Shigeo Nishimura

Download or read book Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis written by Shigeo Nishimura and published by Wiley-Interscience. This book was released on 2001-04-17 with total page 728 pages. Available in PDF, EPUB and Kindle. Book excerpt: A complete guide to the most important reduction method in organic synthesis The most comprehensive reference in the field, Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis provides synthetic chemists and chemical engineers in fine chemicals and pharmaceuticals with detailed experimental guidelines for heterogeneous catalytic hydrogenation. Organized by functional groups for ready reference and featuring detailed examples of hundreds of reactions, this handbook covers hydrogenations of alkenes, alkynes, aldehydes and ketones, nitriles, imines, nitro and nitroso compounds, carboxylic acids and esters, and aromatic and heterocyclic compounds. In addition, coverage includes the preparation of amines by reductive alkylation and the hydrogenolysis of a variety of compounds. Examples of hydrogenation of functional groups and reaction pathways are illustrated with numerous equations and schemes. Practitioners will appreciate the plenitude of experimental details given for most of the reactions selected, including amounts of reagents and catalysts, reaction temperatures, hydrogen pressures, and reaction times. They will also find helpful the more than one hundred tables included throughout the book detailing the effects of key factors governing rate and selectivity, such as compound structure, the nature of catalysts and supports, and the nature of solvents. Researchers will benefit from the introductory chapters covering an array of hydrogenation catalysts, including nickel, cobalt, copper, iron, platinum group metals, rhenium, and other oxide and sulfide catalysts, as well as reactors and reaction conditions.

Heterogeneous Catalysis for the Synthetic Chemist

Author : Robert L. Augustine
Publisher : CRC Press
ISBN 13 : 1000148211
Total Pages : 674 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Heterogeneous Catalysis for the Synthetic Chemist by : Robert L. Augustine

Download or read book Heterogeneous Catalysis for the Synthetic Chemist written by Robert L. Augustine and published by CRC Press. This book was released on 2020-08-11 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work delineates the effect of different reaction variables on the outcome of heterogeneously catalyzed reactions, and explains how to optimize the product yield of specific compounds. Metal catalysis, simple and complex oxides, zeolites and clays are discussed, both as catalysts and as potential supports for catalytically active metals.

N-Heterocyclic Carbenes

Author : Silvia Diez-Gonzalez
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626816
Total Pages : 637 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis N-Heterocyclic Carbenes by : Silvia Diez-Gonzalez

Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Asymmetric Dearomatization Reactions

Author : Shu-Li You
Publisher : John Wiley & Sons
ISBN 13 : 3527338519
Total Pages : 422 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Asymmetric Dearomatization Reactions by : Shu-Li You

Download or read book Asymmetric Dearomatization Reactions written by Shu-Li You and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive account of the rapidly growing field of asymmetric dearomatization reactions with a focus on catalytic methods. It introduces the concept of dearomatization and describes recent progress in asymmetric reaction procedures with different catalyst systems, such as organocatalysts, transition metal catalysts, and enzymes. Chapters on dearomatizations of electron-deficient aromatic rings, dearomatization reactions via transition metal-catalyzed cross-couplings as well as dearomatization strategies in the synthesis of complex natural products are also included. Written by pioneers in the field, this is a highly valuable source of information not only for professional synthetic chemists in academia and industry but also for all those are interested in asymmetric methodologies and organic synthesis in general.

Spillover and Mobility of Species on Solid Surfaces

Author : A. Guerrero-Ruiz
Publisher : Elsevier
ISBN 13 : 0080539742
Total Pages : 501 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Spillover and Mobility of Species on Solid Surfaces by : A. Guerrero-Ruiz

Download or read book Spillover and Mobility of Species on Solid Surfaces written by A. Guerrero-Ruiz and published by Elsevier. This book was released on 2001-08-02 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.Among the 70 contributions received, the 56 accepted papers were selected on the basis of the reports of at least two international reviewers, according to standards comparable to those applied for other specialised journals. These papers are from 21 different countries.

Rhodium Catalysis

Author : Carmen Claver
Publisher : Springer
ISBN 13 : 3319666657
Total Pages : 291 pages
Book Rating : 4.3/5 (196 download)

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Book Synopsis Rhodium Catalysis by : Carmen Claver

Download or read book Rhodium Catalysis written by Carmen Claver and published by Springer. This book was released on 2017-12-15 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbrev iated as Top Organomet Chem and cited as a journal.

Inorganic Reactions and Methods, Reactions Catalyzed by Inorganic Compounds

Author : A. P. Hagen
Publisher : John Wiley & Sons
ISBN 13 : 0470145528
Total Pages : 686 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Inorganic Reactions and Methods, Reactions Catalyzed by Inorganic Compounds by : A. P. Hagen

Download or read book Inorganic Reactions and Methods, Reactions Catalyzed by Inorganic Compounds written by A. P. Hagen and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.

Catalytic Hydrogenation

Author : L. Cervený
Publisher : Elsevier
ISBN 13 : 0080960618
Total Pages : 705 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Catalytic Hydrogenation by : L. Cervený

Download or read book Catalytic Hydrogenation written by L. Cervený and published by Elsevier. This book was released on 1986-08-01 with total page 705 pages. Available in PDF, EPUB and Kindle. Book excerpt: The collection of contributions in this volume presents the most up-to-date findings in catalytic hydrogenation. The individual chapters have been written by 36 top specialists each of whom has achieved a remarkable depth of coverage when dealing with his particular topic. In addition to detailed treatment of the most recent problems connected with catalytic hydrogenations, the book also contains a number of previously unpublished results obtained either by the authors themselves or within the organizations to which they are affiliated.Because of its topical and original character, the book provides a wealth of information which will be invaluable not only to researchers and technicians dealing with hydrogenation, but also to all those concerned with homogeneous and heterogeneous catalysis, organic technology, petrochemistry and chemical engineering.

Homogeneous Hydrogenation

Author : P.A. Chaloner
Publisher : Springer Science & Business Media
ISBN 13 : 9401717915
Total Pages : 293 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Homogeneous Hydrogenation by : P.A. Chaloner

Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.

Basic Principles in Applied Catalysis

Author : Manfred Baerns
Publisher : Springer Science & Business Media
ISBN 13 : 3662059819
Total Pages : 540 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Basic Principles in Applied Catalysis by : Manfred Baerns

Download or read book Basic Principles in Applied Catalysis written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.

Natural Gas Conversion VI

Author : T.H. Fleisch
Publisher : Elsevier
ISBN 13 : 0080537316
Total Pages : 577 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Natural Gas Conversion VI by : T.H. Fleisch

Download or read book Natural Gas Conversion VI written by T.H. Fleisch and published by Elsevier. This book was released on 2001-06-01 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings.The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.

Catalytic Hydrogenation over Platinum Metals

Author : Paul Rylander
Publisher : Elsevier
ISBN 13 : 0323145868
Total Pages : 565 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Catalytic Hydrogenation over Platinum Metals by : Paul Rylander

Download or read book Catalytic Hydrogenation over Platinum Metals written by Paul Rylander and published by Elsevier. This book was released on 2012-12-02 with total page 565 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalytic Hydrogenation over Platinum Metals focuses on catalytic hydrogenation as an effective process in attaining controlled transformations of organic compounds. Composed of contributions of various authors, the book first provides information on catalysts, equipment, and conditions. Catalyst stability and reuse; types of catalyst; platinum metals; and synergism are covered. The text proceeds with discussions on hydrogenation reactors. Topics include atmospheric pressure reactors; low pressure reactors; microreactors; and high pressure reactors. The book also covers hydrogenation of carbon-carbon unsaturation. Catalytic metal; modified catalyst systems; stereochemistry; diacetylenes; and hydrogenolysis are discussed. The text also looks at the hydrogenation of aromatics, nitrogen and carbonyl compounds, and hydrogenolysis. Numerical representations and analysis, diagrams, and reactions of compounds when exposed to different laboratory conditions are considered. The selection is a great source of data for readers interested in studying the process of catalytic hydrogenation.

Catalysis by Polymer-Immobilized Metal Complexes

Author : Anatoly D. Pomogailo
Publisher : CRC Press
ISBN 13 : 1000124711
Total Pages : 424 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Catalysis by Polymer-Immobilized Metal Complexes by : Anatoly D. Pomogailo

Download or read book Catalysis by Polymer-Immobilized Metal Complexes written by Anatoly D. Pomogailo and published by CRC Press. This book was released on 2020-08-18 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the activity of these catalytic systems and methods of optimizing their control; and specific problems of catalysis by fixed complexes (e.g., ligand exchange and electron transfer in metal polymer systems, macromolecular effects and polyfunctional catalysis).

Industrial Arene Chemistry

Author : Jacques Mortier
Publisher : John Wiley & Sons
ISBN 13 : 3527827986
Total Pages : 2751 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Industrial Arene Chemistry by : Jacques Mortier

Download or read book Industrial Arene Chemistry written by Jacques Mortier and published by John Wiley & Sons. This book was released on 2023-03-17 with total page 2751 pages. Available in PDF, EPUB and Kindle. Book excerpt: Industrial Arene Chemistry Explore the wide array of uses for aromatic hydrocarbons in this comprehensive reference Aromatics are a class of compounds—normally but not exclusively organic—which tend to be produced as by-products of various industrial processes. Their importance as petrochemical materials in themselves, along with the range of inter-relations between different aromatic chemicals, creates a complex and opportunity-filled market for aromatics. Industrial Arene Chemistry provides a thorough look at the conventional techniques required to use and produce these aromatic hydrocarbons. Beginning with an overview of the global aromatic market—including, but not limited to, manufacturers, markets of BTX, and downstream functional aromatics, aromatics derived from renewable sources, and economic forecasts—the book will also explore the impact shifting environmental factors will have on the future of aromatic chemistry. The text further explores BTX production processes differentiated according to the raw materials used. Importantly, this will establish the importance and growth of the biobased chemical industry. Industrial Arene Chemistry readers will also find: Case studies that describe major elements of specific technologies prototyped by contributors/companies as part of ongoing market development efforts Process chapters that include summaries of the conventional techniques and a more detailed discussion of recent high-impact studies Recent advances in conventional aromatic reactions, including alkylation, acylation and carboxylation, hydrogenation/reduction, oxidation, nitration/amination, sulfonation, and halogenation Industrial Arene Chemistry is a useful reference for chemists and chemical engineers who work with aromatics.

Nitroarenes

Author : Paul C. Howard
Publisher : Springer Science & Business Media
ISBN 13 : 1461538009
Total Pages : 324 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Nitroarenes by : Paul C. Howard

Download or read book Nitroarenes written by Paul C. Howard and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Prior to 1979, consideration of the problem of the carcinogenicity of the aromatic amine class of chemicals took place primarily in poster sessions and symposia of annual meetings of the American Association for Cancer Research and analogous international associations. In November 1979 the first meeting concerned with the aromatic amines was held in Rockville, Haryland under primary sponsorship of the National Cancer Institute. The proceedings from this meeting were published as Monograph 58 of the Journal of the National Cancel' Institute in 1981. The second meeting in this series, the Second International Conference on N-Substituted Aryl Compounds, was held in March/April of 1982 in Hot Springs, Arkansas. The National Cancer Institute and The National Center for Toxicological Research were the primary sponsors of this meeting. The proceedings were published as Volume 49 of the journal En-vil'onmental Health Perspectives in 1983. The third meeting in this series was held in April of 1987 at the Dearborn Hyatt in Dearborn, Michigan. The principal sponsor of this meeting was the Heyer L. Pre ntis Comprehensive Cancer Center of Metropolitan Detroit. The proceedings, Carcinogenic and Mutagenic Responses to Aromatic Amines and Nitroal'enes, were published in 1987 by Elsevier Press. The fourth meeting was held in Cleveland, Ohio, on July 15-19, 1989.

Nanostructured Carbon Materials for Catalysis

Author : Philippe Serp
Publisher : Royal Society of Chemistry
ISBN 13 : 1849739099
Total Pages : 570 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Nanostructured Carbon Materials for Catalysis by : Philippe Serp

Download or read book Nanostructured Carbon Materials for Catalysis written by Philippe Serp and published by Royal Society of Chemistry. This book was released on 2015 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt: Looking at the structure, properties and synthesis of nanocarbons as catalysts, this is the first book to provide a comprehensive view of the subject.