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Ring Opening Metathesis Polymerisation And Related Chemistry
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Book Synopsis Ring Opening Metathesis Polymerisation and Related Chemistry by : Ezat Khosravi
Download or read book Ring Opening Metathesis Polymerisation and Related Chemistry written by Ezat Khosravi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.
Book Synopsis Organometallic Polymers by : Charles E. Jr. Carraher
Download or read book Organometallic Polymers written by Charles E. Jr. Carraher and published by Elsevier. This book was released on 2012-12-02 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.
Book Synopsis Olefin Metathesis and Metathesis Polymerization by : K. J. Ivin
Download or read book Olefin Metathesis and Metathesis Polymerization written by K. J. Ivin and published by Elsevier. This book was released on 1997-01-07 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis. Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering. - Discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst - Considers commercial processes with examples from existing and new technologies - Provides a complete overview of the subject from its beginning to the present day
Book Synopsis Handbook of Ring-Opening Polymerization by : Philippe Dubois
Download or read book Handbook of Ring-Opening Polymerization written by Philippe Dubois and published by John Wiley & Sons. This book was released on 2009-03-02 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes. Of much interest to chemists in academia and industry.
Book Synopsis Catalytic Polymerization of Cycloolefins by : V. Dragutan
Download or read book Catalytic Polymerization of Cycloolefins written by V. Dragutan and published by Elsevier. This book was released on 2000-06-26 with total page 1293 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.
Book Synopsis Metathesis Polymerization of Olefins and Polymerization of Alkynes by : Yavuz Imamogammalu
Download or read book Metathesis Polymerization of Olefins and Polymerization of Alkynes written by Yavuz Imamogammalu and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 443 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts was held on September 10-22, 1989 in Akcay, Turkey. Based on the fundamental research of RRSchrock, RGrubbs and K.B.Wagener in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within the last years. Therefore the second NATO-ASI held on metathesis reactions was on Ring Opening Metathesis Po lymerization of Olefins and Polymerization of Alkynes on September 3-16, 1995 in Akcay, Turkey. The course joined inorganic, organic and polymer chemists to exchange their knowledge in this field. This volume contains the main and short lectures held in Akcay. To include ADMET reactions better into the title of this volume we changed it into: Metathesis Polymerization of Olefins and Alkyne Polymerization. This volume is addressed to research scientists, but also to those who start to work in the area of olefin metathesis and alkyne polymerization. The topics of the course were: mechanism of ROMP reactions/ new catalysts for ROMP/ new products by ROMP/ new catalysts for ADMET/ new products by ADMETI degradation of polymer by metathesis reactions/ alkyne polymerization and metathesis/ industrial application of metathesis reactions. The Advanced Study Institute was generously sponsored by the Scientific Affairs Division of NATO and the editor gratefully acknowledges this sponsorship. We also thank the Members of the Local Organizing Committee for their engagement on a successful NATO-AS!.
Book Synopsis Handbook of Transition Metal Polymerization Catalysts by : Ray Hoff
Download or read book Handbook of Transition Metal Polymerization Catalysts written by Ray Hoff and published by John Wiley & Sons. This book was released on 2018-04-20 with total page 895 pages. Available in PDF, EPUB and Kindle. Book excerpt: Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Book Synopsis Handbook of Metathesis, 3 Volume Set by : Robert H. Grubbs
Download or read book Handbook of Metathesis, 3 Volume Set written by Robert H. Grubbs and published by John Wiley & Sons. This book was released on 2015-05-26 with total page 1639 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering the complete breadth of the olefin metathesis reaction. The second edition of the ultimate reference in this field is completely updated and features more than 80% new content, with the focus on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality, and this new edition retains the three-volume format: Catalyst Development, Applications in Organic Synthesis and Polymer Synthesis. Edited by a Nobel laureate in the field, and with a list of contributors that reads like a "Who's-Who" of metathesis, this is an indispensable one-stop reference for organic, polymer and industrial chemists, as well as chemists working with organometallics. Individual volumes also available separately to purchase Volume 1: Catalyst Development - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339485.html Volume 2: Applications in Organic Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339493.html Volume 3: Polymer Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339507.html
Book Synopsis Fundamentals of Polymerization by : Broja Mohan Mandal
Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Book Synopsis Ring Opening Metathesis Polymerization by : Alexey Lyapkov
Download or read book Ring Opening Metathesis Polymerization written by Alexey Lyapkov and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years, the olefins metathesis has established itself as a powerful tool for carbon-carbon bonds forming and has found numerous applications in polymer chemistry. One of the important directions of metathesis is the polymerization with cycle opening. A study of new ruthenium catalysts, resistant to the many functional groups effects, has showed the possibility of synthesizing functionalized polymers with unique properties. In this chapter, reactivity and activation parameters of eight different norbornene dicarboxylic acid alkyl esters in the presence of a Hoveyda-Grubbs II catalyst for the ring opening metathesis polymerization were determined by 1H NMR analysis in-situ. The molecules of esters differ in the aliphatic radical structure and the location of the substituent groups. Kinetic studies have shown that effective polymerization constants and activation parameters strongly depend on the monomer structure. It is shown that the elongation of the aliphatic radical does not significantly affect the reactivity, but significantly changes the activation parameters. The branching of the aliphatic radical significantly affects both the reactivity of the corresponding ester and the activation parameters of the polymerization. The position of the substituents in the norbornene ring of the ester also has a significant effect on the activation parameters of metathesis polymerization.
Book Synopsis Handbook of Maleic Anhydride Based Materials by : Osama M. Musa
Download or read book Handbook of Maleic Anhydride Based Materials written by Osama M. Musa and published by Springer. This book was released on 2016-09-22 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: A handbook on syntheses and properties, production processes, and applications of maleic anhydride and maleic anhydride derived products – all in one text. This handbook provides a comprehensive overview of maleic anhydride chemistry and applications from the professional perspective. With chapters written by leading R&D scientists from the chemical industry, and edited by the Vice President and ASI Technology Chief at Ashland Specialty Ingredients (ASI), Dr. Osama M. Musa, readers will find a unique perspective and summary of the latest advancements in the field of maleic anhydride science. Maleic anhydride is produced industrially on large scale (10E3 kt/annum). Its rich chemistry makes it an important raw material for numerous products and processes (e.g. for applications in polymers and coatings), many of which are covered in this handbook for the first time in a comprehensive manner. The broad scope spans topics ranging from production techniques (including topics such as processes, catalysis, trouble-shooting), synthesis and properties of small and polymeric maleic anhydride based compounds (focusing on industrially relevant compounds as well as emerging areas of importance) and in-depth and broad discussions of commercial maleic anhydride based applications.
Book Synopsis Advances in Ring Opening (Metathesis) Polymerization by :
Download or read book Advances in Ring Opening (Metathesis) Polymerization written by and published by Wiley-VCH. This book was released on 2000-09-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of Macromolecular Symposia contains contributions presented at the RO(M)P'99 International Symposium in Mons, Belgium. At this meeting, over one hundred chemists, physico-chemists, chemical engineers from the world of academia and industry, as well as students, discussed recent developments in mechanisms and kinetics in RO(M)P, synthesis and characterization of new macromolecular architectures, and new materials and applications via RO(M)P.
Book Synopsis Applied Polymer Science: 21st Century by : C. Craver
Download or read book Applied Polymer Science: 21st Century written by C. Craver and published by Elsevier. This book was released on 2000-12-19 with total page 1087 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 75th Anniversary Celebration of the Division of Polymeric Materials: Science and Engineering of the American Chemical Society, in 1999 sparked this third edition of Applied Polymer Science with emphasis on the developments of the last few years and a serious look at the challenges and expectations of the 21st Century.This book is divided into six sections, each with an Associate Editor responsible for the contents with the group of Associate Editors acting as a board to interweave and interconnect various topics and to insure complete coverage. These areas represent both traditional areas and emerging areas, but always with coverage that is timely. The areas and associated chapters represent vistas where PMSE and its members have made and are continuing to make vital contributions. The authors are leaders in their fields and have graciously donated their efforts to encourage the scientists of the next 75 years to further contribute to the well being of the society in which we all live.Synthesis, characterization, and application are three of the legs that hold up a steady table. The fourth is creativity. Each of the three strong legs are present in this book with creativity present as the authors were asked to look forward in predicting areas in need of work and potential applications. The book begins with an introductory history chapter introducing readers to PMSE. The second chapter introduces the very basic science, terms and concepts critical to polymer science and technology. Sections two, three and four focus on application areas emphasizing emerging trends and applications. Section five emphasizes the essential areas of characterization. Section six contains chapters focusing of the synthesis of the materials.
Book Synopsis The Chemistry of Polymers by : John W. Nicholson
Download or read book The Chemistry of Polymers written by John W. Nicholson and published by Royal Society of Chemistry. This book was released on 1997-12-31 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introductory text written from an applied angle, primarily for recent graduates now working in industry who haven't previously studied polymer chemistry. Available in the US from CRC Press. Annotation copyrighted by Book News, Inc., Portland, OR
Book Synopsis Synthesis of Catalysts for Ring Opening Metathesis Polymerization by : Martha Dolan Morton
Download or read book Synthesis of Catalysts for Ring Opening Metathesis Polymerization written by Martha Dolan Morton and published by . This book was released on 1993 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Controlled and Living Polymerizations by : Krzysztof Matyjaszewski
Download or read book Controlled and Living Polymerizations written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.
Book Synopsis Metal-Catalyzed Polymerization by : Samir Chikkali
Download or read book Metal-Catalyzed Polymerization written by Samir Chikkali and published by CRC Press. This book was released on 2017-08-03 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: The proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.
