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Rheology Of Monosodium Titanate Mst And Modified Mst Mmst Mixtures Relevant To The Salt Waste Processing Facility
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Book Synopsis Rheology Of MonoSodium Titanate (MST) And Modified Mst (mMST) Mixtures Relevant To The Salt Waste Processing Facility by :
Download or read book Rheology Of MonoSodium Titanate (MST) And Modified Mst (mMST) Mixtures Relevant To The Salt Waste Processing Facility written by and published by . This book was released on 2013 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Savannah River National Laboratory performed measurements of the rheology of suspensions and settled layers of treated material applicable to the Savannah River Site Salt Waste Processing Facility. Suspended solids mixtures included monosodium titanate (MST) or modified MST (mMST) at various solid concentrations and soluble ion concentrations with and without the inclusion of kaolin clay or simulated sludge. Layers of settled solids were MST/sludge or mMST/sludge mixtures, either with or without sorbed strontium, over a range of initial solids concentrations, soluble ion concentrations, and settling times.
Book Synopsis MONOSODIUM TITANATE MULTI-STRIKE TESTING. by :
Download or read book MONOSODIUM TITANATE MULTI-STRIKE TESTING. written by and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research over the past decade has studied the adsorption of plutonium and uranium onto monosodium titanate (MST) in alkaline solutions. Tests showed that MST would remove the targeted radionuclides from simulated alkaline waste. Testing also indicated that Pu removal kinetics and Np capacity of the MST material impacts the size of equipment and waste blending plans for the Salt Waste Processing Facility (SWPF). Additionally, calculations suggested the baseline MST process may not achieve the desired decontamination in wastes containing elevated concentrations of Pu and Np. In this task, the authors investigated the performance of non-baseline process parameters and their effectiveness for treating waste feed in the Salt Waste Processing Facility. The work addresses a DOE request in support of technical needs expressed, in part, by the Engineering, Procurement, and Construction Contractors for the Salt Waste Processing Facility. The work investigated the effect of increased MST addition (up to 1.2 g/L) and the benefit of extra filtration steps with multiple additions of MST to salt waste containing actinides and strontium. Both simulant and actual waste testing occurred. Actual waste tests used a Tank 39H composite waste solution. In addition, testing to determine desorption of actinides from residual MST occurred. The release of sorbed Sr and actinides from loaded MST during the washing stages in the Salt Waste Processing Facility is an unresolved process behavior. Desorption tests assessed this potential problem using loaded MST from the residue of the MST adsorption tests. Analysis of non-radioactive Sr in the tests proved difficult due to the low concentration of nonradioactive Sr and its nearness to the method detection limit for ICP-MS. Efforts to use AMP to minimize dilution of actual waste for removal from the cell did not help for this analysis since instrument dilution still proved necessary due to the salt content.
Book Synopsis Demonstration of MST Efficacy on Removal of Actinides and Strontium in ''Bounding Alpha'' Waste by : S. D. Fink
Download or read book Demonstration of MST Efficacy on Removal of Actinides and Strontium in ''Bounding Alpha'' Waste written by S. D. Fink and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Previous work at the Savannah River Site identified five microbatches of waste projected to fail to meet removal requirements for total alpha after treatment with monosodium titanate (MST) at the baseline conditions proposed for the Salt Waste Processing Facility (SWPF). This document describes an experimental demonstration that examined removal of strontium and alpha emitting radionuclides from a composite of several tanks present in the most limiting macrobatches. The work investigated the amount of MST needed to treat this ''bounding alpha'' macrobatch composite such that the separated liquid can meet the Salt Waste Processing Facility limits.
Book Synopsis THE HYDROTHERMAL REACTIONS OF MONOSODIUM TITANATE, CRYSTALLINE SILICOTITANATE AND SLUDGE IN THE MODULAR SALT PROCESS by :
Download or read book THE HYDROTHERMAL REACTIONS OF MONOSODIUM TITANATE, CRYSTALLINE SILICOTITANATE AND SLUDGE IN THE MODULAR SALT PROCESS written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of crystalline silicotitanate (CST) is proposed for an at-tank process to treat High Level Waste at the Savannah River Site. The proposed configuration includes deployment of ion exchange columns suspended in the risers of existing tanks to process salt waste without building a new facility. The CST is available in an engineered form, designated as IE-911-CW, from UOP. Prior data indicates CST has a proclivity to agglomerate from deposits of silica rich compounds present in the alkaline waste solutions. This report documents the prior literature and provides guidance for the design and operations that include CST to mitigate that risk. The proposed operation will also add monosodium titanate (MST) to the supernate of the tank prior to the ion exchange operation to remove strontium and select alpha-emitting actinides. The cesium loaded CST is ground and then passed forward to the sludge washing tank as feed to the Defense Waste Processing Facility (DWPF). Similarly, the MST will be transferred to the sludge washing tank. Sludge processing includes the potential to leach aluminum from the solids at elevated temperature (e.g., 65 C) using concentrated (3M) sodium hydroxide solutions. Prior literature indicates that both CST and MST will agglomerate and form higher yield stress slurries with exposure to elevated temperatures. This report assessed that data and provides guidance on minimizing the impact of CST and MST on sludge transfer and aluminum leaching sludge.
Book Synopsis Impact of MST on the Rheology of the Neutralized Am by :
Download or read book Impact of MST on the Rheology of the Neutralized Am written by and published by . This book was released on 2001 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The americium (Am) and curium (Cm) solution, currently stored in F-Canyon Tank 17.1 will be neutralized and diluted prior to addition to High Level Waste (HLW) sludge batch 3 to eliminate the cost and uncertainty of processing and vitrifying this solution. One of the processing alternatives involves the addition of monosodium titanate (MST) to adsorb any soluble Am, Cm or Pu present in the slurry. This paper discusses the impact of the MST on the rheology of the neutralized Am/Cm slurry.
Book Synopsis TESTING AND CHARACTERIZATION OF ENGINEERED FORMS OF MONOSODIUM TITANATE (MST). by :
Download or read book TESTING AND CHARACTERIZATION OF ENGINEERED FORMS OF MONOSODIUM TITANATE (MST). written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Engineered forms of MST and mMST were prepared at ORNL using an internal gelation process. Samples of these two materials were characterized at SRNL to examine particle size and morphology, peroxide content, tapped densities, and Na, Ti, and C content. Batch contact tests were also performed to examine the performance of the materials. The {sup E}mMST material was found to contain less than 10% of the peroxide found in a freshly prepared batch of mMST. This was also evidenced in batch contact testing with both simulated and actual waste, where little difference in performance was seen between the two engineered materials, {sup E}MST and {sup E}mMST. Based on these results, attempts were made to increase the peroxide content of the materials by post-treatment with hydrogen peroxide. The peroxide treatment resulted in a slight (≈10%) increase in peroxide content; however, the peroxide:Ti molar ratio was still much lower (≈0.1 X) than what is seen in a freshly prepared batch of mMST. Testing with simulated waste showed the performance of the peroxide treated materials was improved. Batch contact tests were also performed with an earlier (2003) prepared lot of {sup E}MST to examine the effect of ionic strength on the performance of the material. In general the results showed a decrease in removal performance with increasing ionic strength, which is consistent with previous testing with MST. A Sr loading isotherm was also determined, and the {sup E}MST material was found to reach a Sr loading as high as 13.2 wt % after 100 days of contact at a phase ratio of 20000 mL/g. At the typical MST phase ratio of 2500 mL/g (0.4 g/L), a Sr loading of 2.64 wt % was reached after 506 hours of contact. Samples of {sup E}MST and the post-peroxide treated {sup E}mMST were also tested in a column configuration using simulated waste solution. The breakthrough curves along with analysis of the sorbent beds at the conclusion of the experiments showed that the peroxide treated {sup E}mMST has a higher Sr and Np capacity, but that both materials have similar Pu capacities. The {sup E}MST removed a larger percentage of U than the peroxide treated {sup E}mMST, which is consistent with previous testing which showed that mMST has little affinity for U under these conditions.
Book Synopsis Filterability of Monosodium Titanate Supplied by Blue Grass Chemical Specialties by :
Download or read book Filterability of Monosodium Titanate Supplied by Blue Grass Chemical Specialties written by and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design specification for monosodium titanate (MST) requires that less than 1 per cent of the particles are larger than 35 micron and that less than 1 per cent of the particles are smaller than 1 micron. Blue Grass Chemical Specialties produced two batches of MST for the Defense Waste Processing Facility (DWPF) that do not meet the particle size specification. The material has more than 1 per cent of the particles smaller than 1 micron. This increase in the fraction of particles less than 1 micron could adversely affect filtration within the Actinide Removal Project (ARP). The authors conducted dead-end filtration testing with 0.45 micron polymeric filter media, 0.5 micron Mott sintered stainless steel filter media, and 0.1 micron Mott sintered stainless steel filter media. The authors make the following recommendations for MST particle size. If a 0.5 micron Mott filter is used for the ARP process, the existing particle size specification (less than 1 per cent of particles less than 1 micron and less than 1 per cent of particles greater than 35 micron) should be maintained. If a 0.1 micron Mott filter is used for the ARP process and the existing particle size specification is not met, DWPF personnel should arrange for filter tests, such as those described in this report, to be performed to evaluate the filterability of the MST. DWPF personnel should consider revising the particle size specification, because technology improvements allow better resolution of particles less than 1 micron. The limited data collected during this testing is not sufficient to change the particle size specification. Limited additional testing similar to that performed here would provide sufficient technical bases.
Book Synopsis Phase I Technical Report for the Engineering of Monosodium Titanate by : CHARLES. NASH
Download or read book Phase I Technical Report for the Engineering of Monosodium Titanate written by CHARLES. NASH and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monosodium titanate (MST) is an inorganic adsorbent that effectively removes strontium, plutonium, uranium, and other trace elements from alkaline salt supernate. Current plans use the MST in batch contact processes to treat Savannah River Site (SRS) waste solutions that require 90Sr and actinide removal to meet low level disposal criteria. More effective use of MST may be realized if the MST could be engineered into a form suitable for a continuous treatment process such as an adsorption column. The main benefits of column operation are (1) enhanced loading due to equilibration with feed adsorbate levels versus product levels, and (2) a small footprint relative to that of a batch contact tank. The current baseline MST material features particles of nominally 0.5-35 micron in size, which are much too fine for use in an adsorption column. An extensive review of the literature and consultation with technical experts identified candidate methods to produce engineered forms of MST. From this list a review team selected five candidate methods for further study. Laboratory syntheses at Savannah River National Laboratory (SRNL) and offsite produced representative samples for characterization and performance testing. Testing identified two suitable methods. The two methods include internal gelation, which is patented technology of Oak Ridge National Laboratory, and internal hydrolysis, a method in which the MST is produced within a porous substrate. A commercial sodium titanate, SrTreat(R), produced by Fortum Engineering (Finland), demonstrated good performance as well although plutonium removal kinetics appeared much slower than observed for the other engineered MST materials.
Book Synopsis RESULTS OF SUPPLEMENTAL MST STUDIES. by : T. Peters
Download or read book RESULTS OF SUPPLEMENTAL MST STUDIES. written by T. Peters and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The current design of the Salt Waste Processing Facility (SWPF) includes an auxiliary facility, the Actinide Finishing Facility, which provides a second contact of monosodium titanate (MST) to remove soluble actinides and strontium from waste if needed. This treatment will occur after cesium removal by Caustic-Side Solvent Extraction (CSSX). Although the process changes and safety basis implications have not yet been analyzed, provisions also exist to recover the MST from this operation and return to the initial actinide removal step in the SWPF for an additional (third) contact with fresh waste. A U.S. Department of Energy (DOE) request identified the need to study the following issues involving this application of MST: Determine the effect of organics from the solvent extraction (CSSX) process on radionuclide sorption by MST; Determine the efficiency of re-using MST for multiple contacts; and Examine fissile loading on MST under conditions using a waste containing significantly elevated concentrations of plutonium, uranium, neptunium, and strontium. This report describes the results of three experimental studies conducted to address these needs: (1) Addition of high concentrations of entrained CSSX solvent had no noticeable effect, over a two week period, on the sorption of the actinides and strontium by MST in a direct comparison experiment. (2) Test results show that MST still retains appreciable capacity after being used once. For instance, reused MST--in the presence of entrained solvent--continued to sorb actinides and strontium. (3) A single batch of MST was used to sequentially contact five volumes of a simulant solution containing elevated concentrations of the radionuclides of interest. After the five contacts, we measured the following solution actinide loadings on the MST: plutonium: 0.884 {+-} 0.00539 wt % or (1.02 {+-} 0.0112) E+04 {micro}g/g MST, uranium: 12.1 {+-} 0.786 wt % or (1.40 {+-} 0.104) E+05 {micro}g/g MST, and neptunium: 0.426 {+-} 0.00406 wt % or (4.92 {+-} 0.0923) E+03 {micro}g/g MST. (4) Over the duration of an experiment with the sequential strikes, the ability of MST to sorb actinides improved with additional strikes. This trend is counter-intuitive, but is confirmed by replicate experiments for plutonium, uranium, and neptunium. Conversely, over the duration of the experiment, the ability of MST to sorb strontium decreased the more it was used. This trend is confirmed by replicate experiment.
Book Synopsis Determination of Fissile Loadings Onto Monosodium Titanate (MST) Under Conditions Relevant to the Actinide Removal Process Facility by : T. Peters
Download or read book Determination of Fissile Loadings Onto Monosodium Titanate (MST) Under Conditions Relevant to the Actinide Removal Process Facility written by T. Peters and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes the results of an experimental study to measure the sorption of fissile actinides on monosodium titanate (MST) at conditions relevant to operation of the Actinide Removal Process (ARP). The study examined the effect of a single contact of a large volume of radionuclide-spiked simulant solution with a small mass of MST. The volume of simulant to MST (8.5 L to 0.2 g of MST solids) was designed to mimic the maximum phase ratio that occurs between the multiple contacts of MST and waste solution and washing of the accumulated solids cycle of ARP. This work provides the following results. (1) After a contact time of {approx}2 weeks, we measured the following actinide loadings on the MST (average of solution and solids data), Pu: 2.79 {+-} 0.197 wt %, U: 14.0 {+-} 1.04 wt %, and Np: 0.839 {+-} 0.0178 wt %. (2) The plutonium and uranium loadings reported above are considerably higher than previously reported values. The higher loading result from the very high phase ratio and the high initial mass concentrations of uranium and plutonium. A separate upcoming document details the predicted values for this system versus the results. (3) The strontium DF values measured in these tests proved much lower than those reported previously with simulants having the same bulk chemical composition. The low strontium DF values reflect the very low initial mass concentration of strontium in this simulant (100 {micro}g/L) compared to that in previous testing ( 600 {micro}g/L).
Book Synopsis DEVELOPMENT OF MONOSODIUM TITANATE (MST) PURCHASE SPECIFICATIONS. by : D. Hobbs
Download or read book DEVELOPMENT OF MONOSODIUM TITANATE (MST) PURCHASE SPECIFICATIONS. written by D. Hobbs and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Savannah River National Laboratory (SRNL) evaluated the previous monosodium titanate (MST) purchase specifications for particle size and strontium decontamination factor. Based on the measured particle size and filtration performance characteristics of several MST samples with simulated waste solutions and various filter membranes we recommend changing the particle size specification as follows. The recommended specification varies with the size and manufacturer of the filter membrane as shown below. We recommend that future batches of MST received at SRS be tested for particle size and filtration performance. This will increase the available database and provide increased confidence that particle size parameters are an accurate prediction of filtration performance. Testing demonstrated the feasibility of a non-radiochemical method for evaluating strontium removal performance of MST samples. Using this analytical methodology we recommend that the purchase specification include the requirement that the MST exhibits a strontium DF factor of>1.79 upon contact with a simulated waste solution with composition as reported for simulated waste solution SWS-7-2005-1 in Table 1 and containing 5.2 to 5.7 mg L{sup -1} strontium with 0.1 g L{sup -1} of the MST. We also recommend performing additional tests with these simulants and MST samples and, if available, new MST samples, to determine the reproducibility and increase the available database for the measurements by the ICP-ES instrument. These measurements will provide increased confidence that the non-radiological method provides a reliable method for evaluating the strontium and actinide removal performance for MST samples.
Book Synopsis Demonstration of MST and Permanganate Efficiency on Removal of Actinides and Strontium from Savannah River Site High Level Waste by : T. B. Peters
Download or read book Demonstration of MST and Permanganate Efficiency on Removal of Actinides and Strontium from Savannah River Site High Level Waste written by T. B. Peters and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: We conducted a series of four demonstrations to determine the ability of either monosodium titanate (MST) or permanganate (MnO4- ) to remove strontium and actinides from salt solutions, under a variety of conditions. Each of the demonstrations used material derived from actual tank waste. The demonstrations used volumes as large as 68 L compared to typical prior experiments at 100 mL. Also, the study used, in two experiments, hydraulically scaled mixing conditions to match those of the equipment installed in Building 512-S for the Actinide Removal Process. (Plans call for radioactive commissioning of that facility as early as December 2003.).
Book Synopsis Engineering Monosodium Titanate for Adsorption Column Processes by : CHARLES. NASH
Download or read book Engineering Monosodium Titanate for Adsorption Column Processes written by CHARLES. NASH and published by . This book was released on 2004 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monosodium titanate (MST) is an inorganic adsorbent powder that effectively removes strontium, plutonium, neptunium, and other trace elements from alkaline high-level waste (HLW) supernate. This work tested one commercial titanate and four general methods to engineer MST into particles large enough to use in adsorption columns. The most successful of the engineered products selected from batch contact and chemical stability testing succeeded in treating 2900 bed volumes (BV) of simulated salt waste containing dissolved plutonium and strontium. There was no detectable strontium breakthrough and only 6 per cent plutonium breakthrough--well within the processing goal--at the end of the demonstration which operated at 5.3 BV/hour. Additional column tests at nominally 15 BV/hr demonstrated similar removal performance. Batch testing of adsorbents used both actual Savannah River Site (SRS) tank supernate as well as simulated salt solutions spiked with strontium, neptunium, and plutonium. In tank waste tests, internal gelation beads produced by the Oak Ridge National Laboratory (ORNL) demonstrated a batch distribution coefficient of 35,000 +/- 4,000 mL/g for plutonium at a phase ratio of 1970 mL/g. In the same batch the sorbent demonstrated a batch distribution coefficient of 99,000 +/- 7,500 mL/g for strontium. These results indicate that this material should be able to process thousands of bed volumes of SRS salt waste before column breakthrough.
Book Synopsis Hydrogen Peroxide Modified Sodium Titanates with Improved Sorption Capabilities by :
Download or read book Hydrogen Peroxide Modified Sodium Titanates with Improved Sorption Capabilities written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The sorption capabilities (e.g., kinetics, selectivity, capacity) of the baseline monosodium titanate (MST) sorbent material currently being used to sequester Sr-90 and alpha-emitting radioisotopes at the Savannah River Site are significantly improved when treated with hydrogen peroxide; either during the original synthesis of MST, or, as a post-treatment step after the MST has been synthesized. It is expected that these peroxide-modified MST sorbent materials will have significantly improved sorption capabilities for non-radioactive cations found in industrial processes and waste streams.
Book Synopsis Analysis of Harrell Monosodium Titanate Lot #03031 by :
Download or read book Analysis of Harrell Monosodium Titanate Lot #03031 written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Monosodium titanate (MST) for use in the Actinide Removal Process (ARP) must be qualified and verified in advance. A single qualification sample for each batch of material is sent to SRNL for analysis, as well as a statistical sampling of verification samples. The Harrell Industries Lot 030311 qualification and 9 verification samples met all the requirements in the specification indicating the material is acceptable for use in the process. Harrell Industries is under contract with Savannah River Remediation to provide MST for use in the Actinide Removal Process (ARP). A 500-mL qualification sample for Lot 030311 was sent to the Savannah River National Laboratory (SRNL) to confirm the material meets the requirements specified in the purchase specification. The vendor is also obligated to send verification samples from ≈10% or more of the pails of MST product for each lot (distributed roughly evenly through the entire lot of pails). For the verification of this lot, Harrell Industries sent 9 samples, one each from pails 1, 5, 15, 20, 25, 30, 40, 45, and 55 of 59 total pails.
Book Synopsis Analysis of Harrell Monosodium Titanate Lot #050411 by :
Download or read book Analysis of Harrell Monosodium Titanate Lot #050411 written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Harrell Industries is under contract with Savannah River Remediation to provide Monosodium titanate (MST) for use in the Actinide Removal Process (ARP). A 500-mL qualification sample for Lot 050411 was sent to the Savannah River National Laboratory (SRNL) to confirm the material meets the requirements specified in the purchase specification. The vendor is also obligated to send verification samples from ≈10% or more of the pails of MST product for each lot (distributed roughly evenly through the entire lot of pails). For the verification of this lot, Harrell Industries sent 12 samples, one each from pails No.1, 10, 20, 30, 40, 60, 70, 80, 90, 100, 110, and 120 of 120 total pails. MST for use in the Actinide Removal Process (ARP) must be qualified and verified in advance. A single qualification sample for each batch of material is sent to SRNL for analysis, as well as a statistical sampling of verification samples. The Harrell Industries Lot 050411 qualification and 12 verification samples met all the requirements in the specification indicating the material is acceptable for use in the process.
Book Synopsis INVESTIGATING SUSPENSION OF MST SLURRIES IN A PILOT-SCALE WASTE TANK. by :
Download or read book INVESTIGATING SUSPENSION OF MST SLURRIES IN A PILOT-SCALE WASTE TANK. written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is for the pumps to suspend the MST particles so that MST can be removed from the tank. The pilot-scale tank is a 1/10.85 linear scaled model of Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations).
