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Reactions Of Vinyl Platinum Complexes
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Book Synopsis Mechanisms of Inorganic and Organometallic Reactions Volume 7 by : M.V. Twigg
Download or read book Mechanisms of Inorganic and Organometallic Reactions Volume 7 written by M.V. Twigg and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.
Book Synopsis Synthesis, Reactions and Mechanistic Studies of Rhenium-platinum Complexes by : Yan Wang
Download or read book Synthesis, Reactions and Mechanistic Studies of Rhenium-platinum Complexes written by Yan Wang and published by . This book was released on 1993 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organic Functional Group Transformations by : Alan R. Katritzky
Download or read book Comprehensive Organic Functional Group Transformations written by Alan R. Katritzky and published by Elsevier. This book was released on 1995 with total page 1452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Volume covers the formation of carbon-carbon single-, double- and triple bonds by substitution and addition reactions as well as by various rearrangements. The formation of carbon-carbon multiple bonds by elimination and condensation procedures is fully documented. In addition the synthesis of carbon-hydrogen bonds principally by substitution and addition reactions is featured as is the preparation of a wide variety of carbon-centred anions, cations and radicals.
Book Synopsis Perspectives of Hydrosilylation Reactions by : Bogdan Marciniec
Download or read book Perspectives of Hydrosilylation Reactions written by Bogdan Marciniec and published by Springer Nature. This book was released on 2023-12-01 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume describes the latest advances and perspectives in hydrosilylation, with a focus on new organometallic catalysts and their mechanistic aspects. Hydrosilylation is the reaction of ≡SiH with carbon-carbon, carbon-heteroatom or heteroatom-heteroatom bonds and is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon molecular and macromolecular compounds. Yet these reactions do require a catalyst, for which initially homogeneous noble metal catalyst, mainly platinum, rhodium, iridium or ruthenium were used. However the high prices, metallic residues of these valuable catalysts as well as issues with product purification, did increase the interest in developing new catalysts. Noteworthy in this regard are the recently developed hydrosilylation reactions using catalysts based on earth-abundant transition metals (for example Mn, Fe, Co, Ni) and heterogeneous catalysts presented here. This volume of Topics in Organometallic Chemistry is written for scientists interested in silicon chemistry and its catalytic aspects, but can also be used as valuable handbook for postgraduate and advanced undergraduate students working with organometallic chemistry, catalysis as well as synthesis of fine chemicals.
Book Synopsis Reactive Polymers: Fundamentals and Applications by : Johannes Karl Fink
Download or read book Reactive Polymers: Fundamentals and Applications written by Johannes Karl Fink and published by William Andrew. This book was released on 2017-10-24 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. - Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones - Offers an indispensable guide for engineers and advanced students alike - Provides extensive literature and patent review - Reflects a thorough review of all literature published in this area since 2014 - Features revised and updated chapters to reflect the latest research in reactive polymers
Author :Florian P. Pruchnik Publisher :Springer Science & Business Media ISBN 13 :9780306431920 Total Pages :784 pages Book Rating :4.4/5 (319 download)
Book Synopsis Organometallic Chemistry of the Transition Elements by : Florian P. Pruchnik
Download or read book Organometallic Chemistry of the Transition Elements written by Florian P. Pruchnik and published by Springer Science & Business Media. This book was released on 1990-09-30 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry belongs to the most rapidly developing area of chemistry today. This is due to the fact that research dealing with the structure of compounds and chemical bonding has been greatly intensified in recent years. Additionally, organometallic compounds have been widely utilized in catalysis, organic synthesis, electronics, etc. This book is based on my lectures concerning basic organometallic chemistry for fourth and fifth year chemistry students and on my lectures concerning advanced organometallic chemistry and homogeneous catalysis for Ph.D. graduate students. Many recent developments in the area of organometallic chemistry as weIl as homogeneous catalysis are presented. Essential research results dealing with a given class of organometallic compounds are discussed briefly. Results of physicochemical research methods of various organometallic compounds as weIl as their synthesis, properties, structures, reactivities, and applications are discussed more thoroughly. The selection of tabulated data is arbitrary because, often, it has been impossible to avoid omissions. Nevertheless, these data can be very helpful in understanding properties of organometaIlic compounds and their reactivities. All physical data are given in SI units; the interatomic distances are given in pm units in figures and tables. I am indebted to Professor S. A. Duraj for translating and editing this book. His remarks, discussions, and suggestions are greatly appreciated. I also express gratitude to Virginia E. Duraj for editing and proofreading.
Book Synopsis The Mizoroki-Heck Reaction by : Martin Oestreich
Download or read book The Mizoroki-Heck Reaction written by Martin Oestreich and published by John Wiley & Sons. This book was released on 2009-02-11 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the importance of Richard F. Heck’s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium-catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck. The Mizoroki-Heck reaction is a palladium-catalyzed carbon–carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on: mechanisms of the Mizoroki-Heck reaction intermolecular Mizoroki-Heck reactions focus on regioselectivity and product outcome in organic synthesis waste-minimized Mizoroki-Heck reactions intramolecular Mizoroki-Heck reactions formation of heterocycles chelation-controlled Mizoroki-Heck reactions the Mizoroki-Heck reaction in domino processes oxidative heck-type reactions (Fujiwara-Moritani reactions) Mizoroki-Heck reactions with metals other than palladium ligand design for intermolecular asymmetric Mizoroki-Heck reactions intramolecular enantioselective Mizoroki-Heck reactions desymmetrizing Mizoroki-Heck reactions applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist. “I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the “’Mizoroki–Heck reaction’.” (Synthesis, March 2010)
Book Synopsis Organometallic Chemistry by : M Green
Download or read book Organometallic Chemistry written by M Green and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Book Synopsis Comprehensive Organic Synthesis by :
Download or read book Comprehensive Organic Synthesis written by and published by Newnes. This book was released on 2014-02-14 with total page 9815 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
Book Synopsis Theoretical Aspects of Transition Metal Catalysis by : Gernot Frenking
Download or read book Theoretical Aspects of Transition Metal Catalysis written by Gernot Frenking and published by Springer Science & Business Media. This book was released on 2005-06-23 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.
Book Synopsis The Physical Basis for Heterogeneous Catalysis by : Edmund Drauglis
Download or read book The Physical Basis for Heterogeneous Catalysis written by Edmund Drauglis and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 604 pages. Available in PDF, EPUB and Kindle. Book excerpt: THE PHYSICAL BASIS FOR HETEROGENEOUS CATALYSIS is the proceedings of the ninth Battelle Colloquium in the Materials Sciences, held in Gstaad, Switzerland, September 2-6, 1974. It took as its theme the application of modern theoretical and experimental surface physics to heterogeneous catalysis. Progress in the field by classical chemical methods seemed to have slowed down, at a time when the need for better catalysts was particularly great. The Organizing Committee thought it might be possible to accelerate progress by the application of the powerful techniques evolved in recent years for studying atomically clean surfaces. However, the translation of ideas derived from clean single crystal surfaces with well characterized chemisorbed layers to real catalysts with high ratios of surface to mass on which reactions were taking place and requiring transport of mass and energy is a giant step, raising many questions and requiring thorough discussion by surface physicists on the one hand and catalytic chemists on the other. The 1974 Battelle Colloquium provided a forum for this exchange. As its usual custom, the Colloquium started the first day of introduc tory lectures by three distinguished scientists who have contributed impor tantly over many years to this field.
Book Synopsis Perspectives in Organometallic Chemistry by : Barry R Steele
Download or read book Perspectives in Organometallic Chemistry written by Barry R Steele and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an area which touches on, and plays an active role in, all of the traditional divisions of chemistry: inorganic, organic, physical and theoretical. This timely book provides overviews of recent original developments in these areas, including: the synthesis of main group, transition metal and lanthanide organometallics; applications to homogeneous catalysis; structural and theoretical studies; and enantioselective processes. As these topics are currently part of a stream of exciting research with potentially important industrial applications, this title presents informed accounts of state-of-the-art research which will be of great interest to readers. Written by some of the foremost groups in the field and handsomely illustrated throughout, each chapter also provides an extensive bibliography. By introducing areas that are likely to play a prominent role in organometallic chemistry in the near future, Perspectives in Organometallic Chemistry provides an authoritative source of ideas, particularly for all those engaged in research.
Book Synopsis Methods and Applications of Cycloaddition Reactions in Organic Syntheses by : Nagatoshi Nishiwaki
Download or read book Methods and Applications of Cycloaddition Reactions in Organic Syntheses written by Nagatoshi Nishiwaki and published by John Wiley & Sons. This book was released on 2013-12-17 with total page 996 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced tools for developing new functional materials and applications in chemical research, pharmaceuticals, and materials science Cycloadditions are among the most useful tools for organic chemists, enabling them to build carbocyclic and heterocyclic structures. These structures can then be used to develop a broad range of functional materials, including pharmaceuticals, agrochemicals, dyes, and optics. With contributions from an international team of leading experts and pioneers in cycloaddition chemistry, this book brings together and reviews recent advances, trends, and emerging research in the field. Methods and Applications of Cycloaddition Reactions in Organic Syntheses focuses on two component cycloadditions, with chapters covering such topics as: N1 unit transfer reaction to C–C double bonds [3+2] Cycloaddition of α, β-unsaturated metal-carbene complexes Formal [3+3] cycloaddition approach to natural product synthesis Development of new methods for the construction of heterocycles based on cycloaddition reaction of 1,3-dipoles Cycloreversion approach for preparation of large π-conjugated compounds Transition metal-catalyzed or mediated [5+1] cycloadditions Readers will learn methods for seamlessly executing important reactions such as Diels-Alder and stereoselective dipolar reactions in order to fabricate heterocyclic compounds, natural products, and functional molecules. The book not only features cutting-edge topics, but also important background information, such as the contributors’ process for developing new methodologies, to help novices become fully adept in the field. References at the end of each chapter lead to original research papers and reviews for facilitating further investigation of individual topics. Covering the state of the science and technology, Methods and Applications of Cycloaddition Reactions in Organic Syntheses enables synthetic organic chemists to advance their research and develop new functional materials and applications in chemical research, pharmaceuticals, and materials science.
Book Synopsis Additions to and Substitutions at C-C ?-Bonds by : M.F. Semmelhack
Download or read book Additions to and Substitutions at C-C ?-Bonds written by M.F. Semmelhack and published by Elsevier. This book was released on 1992-09-08 with total page 1322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Book Synopsis Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds by : Barry M. Trost
Download or read book Comprehensive Organic Synthesis: Additions to and substitutions at C-C[pi]-Bonds written by Barry M. Trost and published by Elsevier. This book was released on 1991 with total page 1328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 4 focuses on additions and the resulting substitutions at carbon-carbon &pgr;-bonds. Part 1 includes processes generally considered as simple polar reactions, reactive electrophiles and nucleophiles adding to alkenes and alkynes. A major topic is Michael-type addition to electron deficient &pgr;-bonds, featured in the first six chapters. In part 2 are collected the four general processes leading to nucleophilic aromatic substitution, including radical chain processes and transition metal activation through to &pgr;-complexation. Metal-activated addition (generally by nucleophiles) to alkenes and polyenes is presented in part 3, including allylic alkylation catalyzed by palladium. The coverage of nonpolar additions in part 4 includes radical additions, organometal addition (Heck reaction), carbene addition, and 1,3-dipolar cycloadditions.
Book Synopsis The Chemistry of Peroxides, Volume 3 by :
Download or read book The Chemistry of Peroxides, Volume 3 written by and published by John Wiley & Sons. This book was released on 2015-04-20 with total page 957 pages. Available in PDF, EPUB and Kindle. Book excerpt: The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.
Book Synopsis Organic Reaction Mechanisms 2014 by : A. C. Knipe
Download or read book Organic Reaction Mechanisms 2014 written by A. C. Knipe and published by John Wiley & Sons. This book was released on 2018-04-10 with total page 1023 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Reaction Mechanisms 2014, the 50th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2014. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.
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