Production of Hydrogen by Steam Reforming of Glycerol Over Nickel Supported Catalyst

Download Production of Hydrogen by Steam Reforming of Glycerol Over Nickel Supported Catalyst PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 105 pages
Book Rating : 4.:/5 (96 download)

DOWNLOAD NOW!


Book Synopsis Production of Hydrogen by Steam Reforming of Glycerol Over Nickel Supported Catalyst by : Nurul Huda Zamzuri

Download or read book Production of Hydrogen by Steam Reforming of Glycerol Over Nickel Supported Catalyst written by Nurul Huda Zamzuri and published by . This book was released on 2012 with total page 105 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hydrogen Production Via Glycerol Dry Reforming Over Nickel Catalyst Supported on Sio2 and Al2O3 Modified by La

Download Hydrogen Production Via Glycerol Dry Reforming Over Nickel Catalyst Supported on Sio2 and Al2O3 Modified by La PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 59 pages
Book Rating : 4.:/5 (953 download)

DOWNLOAD NOW!


Book Synopsis Hydrogen Production Via Glycerol Dry Reforming Over Nickel Catalyst Supported on Sio2 and Al2O3 Modified by La by : Farahani Sarajuddin

Download or read book Hydrogen Production Via Glycerol Dry Reforming Over Nickel Catalyst Supported on Sio2 and Al2O3 Modified by La written by Farahani Sarajuddin and published by . This book was released on 2015 with total page 59 pages. Available in PDF, EPUB and Kindle. Book excerpt: Currently, energy has become the most demand for human needed. The utilization of future energy that is clean and sustainable becomes increasingly urgent because of dwindling petroleum reserves and mounting environmental concerns that are associated with fossil fuel. Hydrogen has been considered as the most suitable alternative for future energy aiming to reduce the dependence on fossil fuel and carbon based emission. Previously, non-renewable resources mainly coal, fossil fuel, petroleum coke, and petroleum residues has been widely used as the main feedstock for syngas (H2 and CO) production. However, due to the various factors such are global warming, the unstable price and availability of petroleum-based oil as well as the environmental pollution, the desirability towards biomass (glycerol) as the alternative energy feedstock has attract the world's attention. Glycerol which a by-product of biodiesel production is one of the most promising renewable sources associated environmental impacts from the usage of the fossil fuels in which it minimal carbon dioxide (CO2) emission and more preferable in fuels production. In recent years, the production of hydrogen from glycerol via steam reforming widely investigated, only a few studies on dry reforming with CO2. Therefore, this project was attempted to study the production of hydrogen via glycerol dry reforming over nickel (Ni) catalyst supported on silica oxide (SiO2) and alumina (Al2O3) modified with lanthanum (La). This works aims to synthesis, characterize, and screening Ni catalyst supported on SiO2 and Al2O3 with promoted in La solution using various techniques such are Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) analysis , Mastersizer 2000 Ver.5.60 and elemental analysis. The catalyst characterization includes their porosity, structure, crystalline behaviour, and a physiochemical property is investigated. It shows that the promoted catalyst possessed smaller metal crystalline size, hence higher metal dispersion compared than both Ni/Al2O3 and Ni/SiO2 catalyst. In addition, the particle size distribution measured by Mastersizer measurement for promoted alumina catalyst gave higher size distribution which about 0.452 m2/g compared than silica oxides support. The reaction studies for syngas production at T=973 K for 3 hour reaction time with the inlet flowrate and carbon to to glycerol ratio is 0.03 ml/min and 1 had successfully produced H2 with glycerol conversion and H2 yield that peaked at 5.8% and 28% respectively over 3% La content. The catalyst screening shows that the alumina support gave excellent catalytic performance compared than silica oxide due to the larger surface area and smaller crystallite size that ensured accessibility of active catalytic area.

18th World Hydrogen Energy Conference 2010 - WHEC 2010

Download 18th World Hydrogen Energy Conference 2010 - WHEC 2010 PDF Online Free

Author :
Publisher : Forschungszentrum Jülich
ISBN 13 : 389336658X
Total Pages : 169 pages
Book Rating : 4.8/5 (933 download)

DOWNLOAD NOW!


Book Synopsis 18th World Hydrogen Energy Conference 2010 - WHEC 2010 by : Detlef Stolten

Download or read book 18th World Hydrogen Energy Conference 2010 - WHEC 2010 written by Detlef Stolten and published by Forschungszentrum Jülich. This book was released on 2012 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Solid Base Catalysis

Download Solid Base Catalysis PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642183395
Total Pages : 431 pages
Book Rating : 4.6/5 (421 download)

DOWNLOAD NOW!


Book Synopsis Solid Base Catalysis by : Yoshio Ono

Download or read book Solid Base Catalysis written by Yoshio Ono and published by Springer Science & Business Media. This book was released on 2012-08-31 with total page 431 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of solid base catalysts has come to be recognized for their environmentally benign qualities, and much significant progress has been made over the past two decades in catalytic materials and solid base-catalyzed reactions. The book is focused on the solid base. Because of the advantages over liquid bases, the use of solid base catalysts in organic synthesis is expanding. Solid bases are easier to dispose than liquid bases, separation and recovery of products, catalysts and solvents are less difficult, and they are non-corrosive. Furthermore, base-catalyzed reactions can be performed without using solvents and even in the gas phase, opening up more possibilities for discovering novel reaction systems. Using numerous examples, the present volume describes the remarkable role solid base catalysis can play, given the ever increasing worldwide importance of "green" chemistry. The reader will obtain an overall view of solid base catalysis and gain insight into the versatility of the reactions to which solid base catalysts can be utilized. The concept and significance of solid base catalysis are discussed, followed by descriptions of various methods for the characterization of solid bases, including spectroscopic methods and test reactions. The preparation and properties of base materials are presented in detail, with the two final chapters devoted to surveying the variety of reactions catalyzed by solid bases.

Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts

Download Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (514 download)

DOWNLOAD NOW!


Book Synopsis Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts by : Sushil Adhikari

Download or read book Steam Reforming of Oxygenated Hydrocarbons for Hydrogen Production Over Metal Catalysts written by Sushil Adhikari and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: With the increase in production of biodiesel, a glut of glycerol has resulted in the world market. Glycerol, once a valuable chemical, has become a recalcitrant byproduct. It is also a potential renewable feedstock for hydrogen production. This study is focused on hydrogen production from glycerol steam reforming. During the initial stage, effect of process variables, such as system pressure (1-5 atm), temperature (327-727 °C) were calculated by the method of Gibbs free energy minimization. The study revealed that the best conditions for producing hydrogen is at temperature> 627 °C, atmospheric pressure, and water/glycerol molar ratio (WGMR) 9:1. As a part of catalysts screening, 14 catalysts were prepared on monoliths and tested for their activity. Effects of those catalysts on hydrogen selectivity and glycerol conversion in temperatures ranging from 600-900 °C were discussed. Ni/Al2O3 and Rh/CeO2/Al2O3 were found to be the best performing catalysts based on hydrogen selectivity and glycerol conversion under the conditions investigated in this study. Also, the effect of WGMR, metal loading, and feed flow rate (FFR) were analyzed for the two best performing catalysts. Subsequently, effect of CeO2, MgO, and TiO2 supported Ni catalysts on hydrogen production from glycerol was studied. Effects of reaction temperature, FFR, and WGMR on hydrogen selectivity and glycerol conversion were also analyzed. Ni/CeO2 was found to be the best performing catalyst when compared to Ni/MgO and Ni/TiO2 under the experimental conditions investigated. The activation energy of glycerol reforming reaction was found to be 103 kJ/mol, and the reaction order with respect to glycerol was 0.23 over Ni/CeO2 catalysts based on the power law.

Catalysts for Hydrogen Production by the Auto-Thermal Reforming of Glycerol

Download Catalysts for Hydrogen Production by the Auto-Thermal Reforming of Glycerol PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

DOWNLOAD NOW!


Book Synopsis Catalysts for Hydrogen Production by the Auto-Thermal Reforming of Glycerol by : Faezeh Sabri

Download or read book Catalysts for Hydrogen Production by the Auto-Thermal Reforming of Glycerol written by Faezeh Sabri and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Environmental Catalysis

Download Environmental Catalysis PDF Online Free

Author :
Publisher : World Scientific
ISBN 13 : 1783262265
Total Pages : 385 pages
Book Rating : 4.7/5 (832 download)

DOWNLOAD NOW!


Book Synopsis Environmental Catalysis by : F J J G Janssen

Download or read book Environmental Catalysis written by F J J G Janssen and published by World Scientific. This book was released on 1999-04-14 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book brings together highlights of a theme which is growing in interest: the creation of a sustainable society using catalysis as the main tool. Catalysts play key roles in the production of clean fuels, the conversion of waste and green raw materials into energy, clean combustion engines including control of NOx and soot production and reduction of greenhouse gases, production of clean water and of polymers, as well as reduction from polymers to monomers. Catalysts are also of prime importance in the developing H2 and syngas production technology, aimed at producing clean fuels for the coming decades. And catalysts can be recycled.

STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS.

Download STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS. PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (654 download)

DOWNLOAD NOW!


Book Synopsis STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS. by :

Download or read book STEAM REFORMING OF OXYGENATED HYDROCARBONS FOR HYDROGEN PRODUCTION OVER METAL CATALYSTS. written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: With the increase in production of biodiesel, a glut of glycerol has resulted in the world market. Glycerol, once a valuable chemical, has become a recalcitrant byproduct. It is also a potential renewable feedstock for hydrogen production. This study is focused on hydrogen production from glycerol steam reforming. During the initial stage, effect of process variables, such as system pressure (1-5 atm), temperature (327 727 oC), and water/glycerol molar ratio of (1:1-9:1) on hydrogen yield was investigated using a thermodynamic analysis. The equilibrium concentrations of different compounds were calculated by the method of Gibbs free energy minimization. The study revealed that the best conditions for producing hydrogen is at temperature> 627 oC, atmospheric pressure, and water/glycerol molar ratio (WGMR) 9:1. As a part of catalysts screening, 14 catalysts were prepared on monoliths and tested for their activity. Effects of those catalysts on hydrogen selectivity and glycerol conversion in temperatures ranging from 600-900 oC were discussed. Ni/Al2O3 and Rh/CeO2/Al2O3 were found to be the best performing catalysts based on hydrogen selectivity and glycerol conversion under the conditions investigated in this study. Also, the effect of WGMR, metal loading, and feed flow rate (FFR) were analyzed for the two best performing catalysts. Subsequently, effect of CeO2, MgO, and TiO2 supported Ni catalysts on hydrogen production from glycerol was studied. Effects of reaction temperature, FFR, and WGMR on hydrogen selectivity and glycerol conversion were also analyzed. Ni/CeO2 was found to be the best performing catalyst when compared to Ni/MgO and Ni/TiO2 under the experimental conditions investigated. The activation energy of glycerol reforming reaction was found to be 103 kJ/mol, and the reaction order with respect to glycerol was 0.23 over Ni.

Hydrogen Production Technologies

Download Hydrogen Production Technologies PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119283663
Total Pages : 524 pages
Book Rating : 4.1/5 (192 download)

DOWNLOAD NOW!


Book Synopsis Hydrogen Production Technologies by : Mehmet Sankir

Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.

Chemical Catalysts for Biomass Upgrading

Download Chemical Catalysts for Biomass Upgrading PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527344667
Total Pages : 634 pages
Book Rating : 4.5/5 (273 download)

DOWNLOAD NOW!


Book Synopsis Chemical Catalysts for Biomass Upgrading by : Mark Crocker

Download or read book Chemical Catalysts for Biomass Upgrading written by Mark Crocker and published by John Wiley & Sons. This book was released on 2020-03-09 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.

Synthesis Gas Production from Glycerol Steam Reforming Over Alumina Supported Bimetallic Co-Ni Catalyst

Download Synthesis Gas Production from Glycerol Steam Reforming Over Alumina Supported Bimetallic Co-Ni Catalyst PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 259 pages
Book Rating : 4.:/5 (953 download)

DOWNLOAD NOW!


Book Synopsis Synthesis Gas Production from Glycerol Steam Reforming Over Alumina Supported Bimetallic Co-Ni Catalyst by : Chin Kui Cheng

Download or read book Synthesis Gas Production from Glycerol Steam Reforming Over Alumina Supported Bimetallic Co-Ni Catalyst written by Chin Kui Cheng and published by . This book was released on 2011 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hydrogen Production by the Cataylitic Auto-Thermal Reforming of Synthetic Crude Glycerol in a Packed Bed Tubular Reactor

Download Hydrogen Production by the Cataylitic Auto-Thermal Reforming of Synthetic Crude Glycerol in a Packed Bed Tubular Reactor PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

DOWNLOAD NOW!


Book Synopsis Hydrogen Production by the Cataylitic Auto-Thermal Reforming of Synthetic Crude Glycerol in a Packed Bed Tubular Reactor by : Ahmad Mahmoud Abdul Ghani

Download or read book Hydrogen Production by the Cataylitic Auto-Thermal Reforming of Synthetic Crude Glycerol in a Packed Bed Tubular Reactor written by Ahmad Mahmoud Abdul Ghani and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Basic Principles in Applied Catalysis

Download Basic Principles in Applied Catalysis PDF Online Free

Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3662059819
Total Pages : 540 pages
Book Rating : 4.6/5 (62 download)

DOWNLOAD NOW!


Book Synopsis Basic Principles in Applied Catalysis by : Manfred Baerns

Download or read book Basic Principles in Applied Catalysis written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.

Renewable Hydrogen Technologies

Download Renewable Hydrogen Technologies PDF Online Free

Author :
Publisher : Newnes
ISBN 13 : 044456361X
Total Pages : 471 pages
Book Rating : 4.4/5 (445 download)

DOWNLOAD NOW!


Book Synopsis Renewable Hydrogen Technologies by : Luis M Gandia

Download or read book Renewable Hydrogen Technologies written by Luis M Gandia and published by Newnes. This book was released on 2013-05-03 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fields covered by the hydrogen energy topic have grown rapidly, and now it has become clearly multidisciplinary. In addition to production, hydrogen purification and especially storage are key challenges that could limit the use of hydrogen fuel. In this book, the purification of hydrogen with membrane technology and its storage in "solid" form using new hydrides and carbon materials are addressed. Other novelties of this volume include the power conditioning of water electrolyzers, the integration in the electric grid of renewable hydrogen systems and the future role of microreactors and micro-process engineering in hydrogen technology as well as the potential of computational fluid dynamics to hydrogen equipment design and the assessment of safety issues. Finally, and being aware that transportation will likely constitute the first commercial application of hydrogen fuel, two chapters are devoted to the recent advances in hydrogen fuel cells and hydrogen-fueled internal combustion engines for transport vehicles. Hydrogen from water and biomass considered Holistic approach to the topic of renewable hydrogen production Power conditioning of water electrolyzers and integration of renewable hydrogen energy systems considered Subjects not included in previous books on hydrogen energy Micro process technology considered Subject not included in previous books on hydrogen energy Applications of CFD considered Subject not included in previous books on hydrogen energy Fundamental aspects will not be discussed in detail consciously as they are suitably addressed in previous books Emphasis on technological advancements Chapters written by recognized experts Up-to date approach to the subjects and relevant bibliographic references

Catalytic Conversion of Energy Resources into High Value-Added Products

Download Catalytic Conversion of Energy Resources into High Value-Added Products PDF Online Free

Author :
Publisher : MDPI
ISBN 13 : 3036510745
Total Pages : 134 pages
Book Rating : 4.0/5 (365 download)

DOWNLOAD NOW!


Book Synopsis Catalytic Conversion of Energy Resources into High Value-Added Products by : José Luis Pinilla

Download or read book Catalytic Conversion of Energy Resources into High Value-Added Products written by José Luis Pinilla and published by MDPI. This book was released on 2021-09-02 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: Developing active, selective and energy-efficient heterogeneous catalysts is of paramount importance for the production of high value-added products from energy resources in a more sustainable manner. In this Special Issue of Energies, we provide a showcase of the latest progress in the development of cleaner, more efficient processes for the conversion of these feedstocks into valuable fuels, chemicals and energy. Most of the works collected are focused on the conversion of biomass which clearly reflects the paramount importance that the biorefinery concept will play in the years to come.

The Future of Glycerol

Download The Future of Glycerol PDF Online Free

Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 184973108X
Total Pages : 187 pages
Book Rating : 4.8/5 (497 download)

DOWNLOAD NOW!


Book Synopsis The Future of Glycerol by : Mario Pagliaro

Download or read book The Future of Glycerol written by Mario Pagliaro and published by Royal Society of Chemistry. This book was released on 2010-05-20 with total page 187 pages. Available in PDF, EPUB and Kindle. Book excerpt: By-products of global biodiesel manufacturing are a modern day global fact responsible for igniting a number of year’s worldwide intense research activity into human chemical ingenuity. This fully updated and revised 2nd edition depicts how practical limitations posed by glycerol chemistry are solved based on the understanding of the fundamental chemistry of glycerol and by application of catalysis science and technology. The authors report and comment on employable, practical avenues applicable to convert glycerol into value added products of mass consumption. This book is the best-selling reference book in the field. The highly anticipated 2nd Edition is essential reading for anyone interested in understanding whether biodiesel and glycerol refineries are convenient and economically sound.

Hydrogen and Syngas Production and Purification Technologies

Download Hydrogen and Syngas Production and Purification Technologies PDF Online Free

Author :
Publisher : John Wiley & Sons
ISBN 13 : 0471719757
Total Pages : 572 pages
Book Rating : 4.4/5 (717 download)

DOWNLOAD NOW!


Book Synopsis Hydrogen and Syngas Production and Purification Technologies by : Ke Liu

Download or read book Hydrogen and Syngas Production and Purification Technologies written by Ke Liu and published by John Wiley & Sons. This book was released on 2010-01-07 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems