Preparative Acetylenic Chemistry

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Publisher : Elsevier
ISBN 13 : 1483290034
Total Pages : 334 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Preparative Acetylenic Chemistry by : L. Brandsma

Download or read book Preparative Acetylenic Chemistry written by L. Brandsma and published by Elsevier. This book was released on 2013-10-22 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first edition of Preparative Acetylenic Chemistry was published in 1971 as one of a series of laboratory manuals containing experimental procedures. The book was used extensively by students during practical courses and laboratory research work and enabled procedures to be carried out by persons with relatively limited bench experience. Discussions about their results have in many cases led to modified procedures or descriptions which have now been incorporated in this considerably revised and up-dated edition.The new book contains a collection of some 250 experimental procedures on a scale of at least 0.1 molar for the preparation of a wide variety of compounds with a triple bond. A number of procedures in the old edition have been omitted and replaced by others; the subdivision and titling of the chapters and experiments have been changed; and the indexes have been replaced by a type-compound-method index. Some new and attractive methods have been included, e.g. eliminations under phase-transfer conditions and couplings under the influence of zero-valent palladium compounds. In a number of cases, additional experiments have been described in order to give a more complete picture of the scope of the concerned methods.This collection is based on almost 30 years active bench experience by the author and all the procedures have been checked at least once in the author's laboratory. It will undoubtedly provide as much useful and practical assistance as did its predecessor.

Preparative acetylenic chemistry

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Publisher :
ISBN 13 :
Total Pages : 321 pages
Book Rating : 4.:/5 (844 download)

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Book Synopsis Preparative acetylenic chemistry by : Lambert Brandsma

Download or read book Preparative acetylenic chemistry written by Lambert Brandsma and published by . This book was released on with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparative Acetylenic Chemistry

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Publisher :
ISBN 13 : 9780444417374
Total Pages : 0 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Preparative Acetylenic Chemistry by : Lambert Brandsma

Download or read book Preparative Acetylenic Chemistry written by Lambert Brandsma and published by . This book was released on 1988 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparative Acetylenic Chemistry

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (959 download)

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Book Synopsis Preparative Acetylenic Chemistry by : Bruce Wallace

Download or read book Preparative Acetylenic Chemistry written by Bruce Wallace and published by . This book was released on 1971 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparative Acetylene Chemistry

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (989 download)

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Book Synopsis Preparative Acetylene Chemistry by : L. Brandsma

Download or read book Preparative Acetylene Chemistry written by L. Brandsma and published by . This book was released on 1971 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparative acetylenic chemistry

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Publisher :
ISBN 13 :
Total Pages : 207 pages
Book Rating : 4.:/5 (872 download)

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Book Synopsis Preparative acetylenic chemistry by : L. Brandsma

Download or read book Preparative acetylenic chemistry written by L. Brandsma and published by . This book was released on 1971 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Modern Acetylene Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527615261
Total Pages : 527 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Acetylene Chemistry by : Peter J. Stang

Download or read book Modern Acetylene Chemistry written by Peter J. Stang and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 527 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook presents the full potential of modern acetylene chemistry, from organic synthesis through materials science to bioorganic chemistry. K. Houk, H. Hopf, P. Stang, K. M. Nicholas, N. Schore, M. Regitz, K. C. Nicolaou, R. Gleiter, L. Scott, R. Grubbs, H. Iwamura, J. Moore, and F. Diederich - internationally renowned authors introduce the reader, in a didactically skilful manner, to the state-of-the-art in alkyne chemistry. Emphasis is placed on presenting carefully selected and instructive examples as well as essential references to the original literature. Special benefits: Each chapter is rounded off by useful experimental procedures.

Acetylene Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527604707
Total Pages : 528 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Acetylene Chemistry by : François Diederich

Download or read book Acetylene Chemistry written by François Diederich and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Acetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental procedures, this book is a practical aid for both organic and organometallic chemists, as well as for materials scientists, biochemists, and industrial chemists.

Acetylene Chemistry

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Publisher :
ISBN 13 :
Total Pages : 426 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Acetylene Chemistry by : Walter Reppe

Download or read book Acetylene Chemistry written by Walter Reppe and published by . This book was released on 1949 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Preparative Polar Organometallic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642879217
Total Pages : 250 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Preparative Polar Organometallic Chemistry by : Lambert Brandsma

Download or read book Preparative Polar Organometallic Chemistry written by Lambert Brandsma and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polar organometallic compounds are indispensable for the synthetic chemist. As this book shows, these almost ideal reagents are easy to prepare with high specificity under mild conditions and yet react quite readily with a great variety of substrates. Many compounds can be metallated directly at positions which would otherwise be difficult to substitute. Functional groups and heteroatoms already present in a molecule direct metallation to sites in their vicinity. The rules which govern polar organometallic chemistry often are not dominated by the usual n-delocalization and inductive effects; dipolar interactions, chelation, polarization, etc. often can be much more important. This affords novel synthetic opportunities. A good example is the development of a basically new type of aromatic substitution chemistry not based on positively charged intermediates. Seebach's injunction, "Thinking of polar organometallic compounds as carbanions is an impoverishment rather than a simplification" (International Symposium, Chemistry of Carbanions, Durham 1984), stresses the need to consider the metal not only as an integral, but perhaps also as the key component of these reagents. Rather than wandering off as solvated cations and acting as uninvolved spectators, the metals, rather than the anion moieties, can initiate and govern the subsequent reactions. To the founders of this field, e. g. Grignard, Ziegler, Gilman, Wittig, and their followers, the metal was critical. The title of Schlosser's book, "Polare Organometalle", certainly was apt.

Aliphatic Compounds

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Publisher : Elsevier
ISBN 13 : 008088072X
Total Pages : 285 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Aliphatic Compounds by : M. F. Ansell

Download or read book Aliphatic Compounds written by M. F. Ansell and published by Elsevier. This book was released on 1975-01-01 with total page 285 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aliphatic Compounds

Organomagnesium Methods in Organic Chemistry

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Publisher : Academic Press
ISBN 13 : 0080538177
Total Pages : 269 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Organomagnesium Methods in Organic Chemistry by : Basil J. Wakefield

Download or read book Organomagnesium Methods in Organic Chemistry written by Basil J. Wakefield and published by Academic Press. This book was released on 1995-03-16 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. - Presents a general overview of the constitution and reactivity of organomagnesium compounds - Provides coverage on the detection and estimation of organomagnesium compounds - Emphasizes practical aspects as well as principles - Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes - Includes preparations by metallation and metal-halogen exchanges - Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes - Outlines information on synthetically useful reactions of organomagnesium compounds - Describes the formation of carbon-heteroatom bonds in organic compounds - Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds - Includes representative procedures and tables with references to well-described examples

Classics in Hydrocarbon Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527296069
Total Pages : 578 pages
Book Rating : 4.5/5 (272 download)

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Book Synopsis Classics in Hydrocarbon Chemistry by : Henning Hopf

Download or read book Classics in Hydrocarbon Chemistry written by Henning Hopf and published by John Wiley & Sons. This book was released on 2000-06-15 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kohlenstoff und Wasserstoff - jedem Chemiestudenten sind sie wohlbekannt als Grundbausteine der Organischen Chemie. Welch ungeahnte Vielfalt von Verbindungen sich aus diesen Elementen aufbauen läßt, zeigt dieses einzigartige Buch. Dabei beschränkt es sich nicht nur auf die bloße Darstellung von Struktur und Eigenschaften von Kohlenwasserstoffen, sondern verdeutlicht überdies die Herausforderung, die Moleküle wie Tetrahedran, Superphan oder Dodecahedran an das synthetische Geschick eines jeden Organikers stellen. In seinem Konzept folgt das Werk - retrosynthetische Analyse der Reaktionssequenzen, ausführliche Erläuterung der Synthesemethoden, umfassende Verweise auf die Originalliteratur - dem Bestseller von K. C. Nicolaou und E. J. Sorensen "Classics in Total Synthesis". Es vermittelt so eine Fülle von generellen Prinzipien und Methoden der organischen Synthese und empfiehlt sich auf Jahre hinaus als Standardwerk, das jedem Studenten und Organiker in Forschung und Lehre geläufig sein sollte.

Acetylene Chemistry

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Publisher :
ISBN 13 :
Total Pages : 209 pages
Book Rating : 4.:/5 (86 download)

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Book Synopsis Acetylene Chemistry by : Walter Julius Reppe

Download or read book Acetylene Chemistry written by Walter Julius Reppe and published by . This book was released on 1981 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Praparative Acetylenic Chemistry

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (473 download)

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Book Synopsis Praparative Acetylenic Chemistry by : L. Brandsma

Download or read book Praparative Acetylenic Chemistry written by L. Brandsma and published by . This book was released on 1971 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Iodine Chemistry and Applications

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Publisher : John Wiley & Sons
ISBN 13 : 1118466292
Total Pages : 668 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Iodine Chemistry and Applications by : Tatsuo Kaiho

Download or read book Iodine Chemistry and Applications written by Tatsuo Kaiho and published by John Wiley & Sons. This book was released on 2014-11-24 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book comprehensively covers iodine, its chemistry, and its role in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodine chemistry with discussion on elemental aspects: characteristics, properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how to synthesize complex compounds using iodine reagents or intermediates • Describes traditional and modern processing techniques, such as starch, cupper, blowing out, and ion exchange resin methods • Includes seven detailed sections devoted to the applications of iodine: Characteristics, Production, Synthesis, Biological Applications, Industrial Applications, Bioorganic Chemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalent iodine-mediated cross coupling reactions, agrochemicals, dye sensitized solar cells, and therapeutic agents

Best Synthetic Methods: Acetylenes, Allenes and Cumulenes

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Publisher : Elsevier
ISBN 13 : 0080542204
Total Pages : 503 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Best Synthetic Methods: Acetylenes, Allenes and Cumulenes by : Lambert Brandsma

Download or read book Best Synthetic Methods: Acetylenes, Allenes and Cumulenes written by Lambert Brandsma and published by Elsevier. This book was released on 2003-12-16 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The Best Synthetic Methods series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real advantages and limitations. With the emphasis on laboratory use, these volumes represent a comprehensive and practical guide to modern synthetic organic chemistry. Best Synthetic Methods: Acetylenes, Allenes and Cumulenes is the product of the author's many years practical experience and reading of the original literature. It contains a valuable distillation and critical evaluation of the Best Synthetic Methods for the formation and reaction of molecules containing carbon-carbon triple bonds or cumulative carbon-carbon double bonds. A brief review of each area is provided, but the emphasis in all cases is on describing efficient practical methods to effect the transformations described. The reader can therefore use this book to rapidly review and select the best methods of performing a synthetic conversion to create or modify a molecule containing an acetylene, allene or cumulene functionality. In addition, the documentation of a large number of experimental recipes enables the user to synthesise an unsaturated molecule without the need to access to the original literature. - Reviews and evaluates the various methods for the formation and reaction of acetylenes, cumulenes and allenes - Provides detailed practical experimental for many important reactions - General tips and analytical data are provided from the author's own extensive research in this area