Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes

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Publisher :
ISBN 13 :
Total Pages : 132 pages
Book Rating : 4.:/5 (811 download)

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Book Synopsis Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes by : Eric Vanover

Download or read book Photochemical Oxidation Studies of Porphyrin Ruthenium Complexes written by Eric Vanover and published by . This book was released on 2008 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ruthenium Complexes

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Publisher : John Wiley & Sons
ISBN 13 : 3527339574
Total Pages : 344 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Ruthenium Complexes by : Alvin A. Holder

Download or read book Ruthenium Complexes written by Alvin A. Holder and published by John Wiley & Sons. This book was released on 2018-02-27 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by a team of highly respected researchers combining their expertise in chemistry, physics, and medicine, this book focuses on the use of rutheniumcontaining complexes in artificial photosynthesis and medicine. Following a brief introduction to the basic coordination chemistry of ruthenium complexes and their synthesis in section one, as well as their photophysical and photochemical properties, the authors discuss in detail the major concepts of artificial photosynthesis and mechanisms of hydrogen production and water oxidation with ruthenium in section two. The third section of the text covers biological properties and important medical applications of ruthenium complexes as therapeutic agents or in diagnostic imaging. Aimed at stimulating research in this active field, this is an invaluable information source for researchers in academia, health research institutes and governmental departments working in the field of organometallic chemistry, green and sustainable chemistry as well as medicine/drug discovery, while equally serving as a useful reference also for scientists in industry.

Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-ruthenium-oxo Complexes

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ISBN 13 :
Total Pages : 160 pages
Book Rating : 4.:/5 (671 download)

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Book Synopsis Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-ruthenium-oxo Complexes by : Yan Huang

Download or read book Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-ruthenium-oxo Complexes written by Yan Huang and published by . This book was released on 2008 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in Nature, namely the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of the research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes. This study focuses on kinetic and photocatalytic studies of oxidation reactions with wellcharacterized high-valent ruthenium-oxo porphyrin complexes. The trans-dioxoruthenium(VI) porphyrins have been among the best characterized metal-oxo intermediates and their involvement as the active oxidant in the hydrocarbon oxidation have been extensively studied. Following the literature known methods, a series of trans-dioxoruthenium(VI) porphyrin complexes (3a-b) were synthesized and spectroscopically characterized by UV-vis, IR and lH-NMR. In addition to the well-known chemical methods, we developed a novel photochemical approach for generation of trans-dioxoruthenium(VI) porphyrins with visible light. The fast kinetic study of two-electron oxidations of para-substituted phenyl methyl sulfides by these dioxoruthenium(VI) species was conducted by using stopped-flow spectroscopy. Results showed that the decay of trans--dioxoruthenium(VI) porphyrins in the presence of reactive sulfides follows a biexponential process. The reactivity order in the series of dioxoruthenium complexes follows TPFPP> TPP> TMP, consistent with expectations based on the electrophilic nature of high-valent metal-oxo species. Moreover, the sulfoxidation reactions are 3 to 4 orders of magnitude faster than the well-known epoxidation reactions. In addition, several ruthenium porphyrins were used as the catalysts in the competitive oxidation reactions to identify the kinetically competent oxidants during catalytic turnover conditions.

Photochemistry and Photophysics of Coordination Compounds

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Publisher : Springer Science & Business Media
ISBN 13 : 3642726666
Total Pages : 334 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Photochemistry and Photophysics of Coordination Compounds by : Hartmut Yersin

Download or read book Photochemistry and Photophysics of Coordination Compounds written by Hartmut Yersin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Seventh International Symposium on the Photochemistry and Photophysics of Coordination Compounds Elmau/FRG, March 29-April 2, 1987

Photochemical Oxidation and Photoreactivity of Porphyrin Compounds

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Publisher :
ISBN 13 :
Total Pages : 174 pages
Book Rating : 4.:/5 (78 download)

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Book Synopsis Photochemical Oxidation and Photoreactivity of Porphyrin Compounds by : Wade Russell Potter

Download or read book Photochemical Oxidation and Photoreactivity of Porphyrin Compounds written by Wade Russell Potter and published by . This book was released on 1979 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 6-10)

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Publisher : World Scientific
ISBN 13 : 9814464910
Total Pages : 2807 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 6-10) by : Karl M Kadish

Download or read book Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 6-10) written by Karl M Kadish and published by World Scientific. This book was released on 2010-06-29 with total page 2807 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives, demonstrating new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique Handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors.This Handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.

Redox Studies of Ruthenium Porphyrin Nitrosyl Complexes

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Publisher :
ISBN 13 :
Total Pages : 128 pages
Book Rating : 4.:/5 (798 download)

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Book Synopsis Redox Studies of Ruthenium Porphyrin Nitrosyl Complexes by : Krishna P. Sharmah Gautam

Download or read book Redox Studies of Ruthenium Porphyrin Nitrosyl Complexes written by Krishna P. Sharmah Gautam and published by . This book was released on 2011 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Research in Progress

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Publisher :
ISBN 13 :
Total Pages : 644 pages
Book Rating : 4.:/5 (39 download)

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Book Synopsis Research in Progress by :

Download or read book Research in Progress written by and published by . This book was released on 1983 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Research in Progress

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Publisher :
ISBN 13 :
Total Pages : 316 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Research in Progress by : United States. Army Research Office

Download or read book Research in Progress written by United States. Army Research Office and published by . This book was released on 1983 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vols. for 1977- consist of two parts: Chemistry, biological sciences, engineering sciences, metallurgy and materials science (issued in the spring); and Physics, electronics, mathematics, geosciences (issued in the fall).

Synthetic and Photochemical Studies of Porphyrins and Their Metal Complexes

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Publisher :
ISBN 13 :
Total Pages : 266 pages
Book Rating : 4.:/5 (164 download)

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Book Synopsis Synthetic and Photochemical Studies of Porphyrins and Their Metal Complexes by : Frederick Robert Hopf

Download or read book Synthetic and Photochemical Studies of Porphyrins and Their Metal Complexes written by Frederick Robert Hopf and published by . This book was released on 1975 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 36-40)

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Publisher : World Scientific
ISBN 13 : 981314078X
Total Pages : 1975 pages
Book Rating : 4.8/5 (131 download)

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Book Synopsis Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 36-40) by : Karl M Kadish

Download or read book Handbook Of Porphyrin Science: With Applications To Chemistry, Physics, Materials Science, Engineering, Biology And Medicine (Volumes 36-40) written by Karl M Kadish and published by World Scientific. This book was released on 2016-07-01 with total page 1975 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porphyrins, phthalocyanines and their numerous analogs and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives, demonstrating new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors.This handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.

Photochemical and Photophysical Studies of Ruthenium (II) and Rhenium (I) Complexes with Phenanthrolinopyrrole and 2,6-dimethylphenylisocyanide Ligands

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ISBN 13 :
Total Pages : 450 pages
Book Rating : 4.:/5 (575 download)

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Book Synopsis Photochemical and Photophysical Studies of Ruthenium (II) and Rhenium (I) Complexes with Phenanthrolinopyrrole and 2,6-dimethylphenylisocyanide Ligands by : John Martin Villegas Abadia

Download or read book Photochemical and Photophysical Studies of Ruthenium (II) and Rhenium (I) Complexes with Phenanthrolinopyrrole and 2,6-dimethylphenylisocyanide Ligands written by John Martin Villegas Abadia and published by . This book was released on 2004 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemistry of Rhenium and Tungsten Porphyrin Complexes in Low Oxidation States ; Synthesis and Characterization of Rhenium and Tungsten Porphyrin Dimers Containing Metal-metal Multiple Bonds

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Publisher :
ISBN 13 :
Total Pages : 374 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis The Chemistry of Rhenium and Tungsten Porphyrin Complexes in Low Oxidation States ; Synthesis and Characterization of Rhenium and Tungsten Porphyrin Dimers Containing Metal-metal Multiple Bonds by : James Michael Garner

Download or read book The Chemistry of Rhenium and Tungsten Porphyrin Complexes in Low Oxidation States ; Synthesis and Characterization of Rhenium and Tungsten Porphyrin Dimers Containing Metal-metal Multiple Bonds written by James Michael Garner and published by . This book was released on 1989 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Photochemistry Vol 5

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Publisher : Royal Society of Chemistry
ISBN 13 : 0851860451
Total Pages : 804 pages
Book Rating : 4.8/5 (518 download)

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Book Synopsis Photochemistry Vol 5 by : D.. Bryce-Smith

Download or read book Photochemistry Vol 5 written by D.. Bryce-Smith and published by Royal Society of Chemistry. This book was released on 1974 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents

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Publisher : Springer
ISBN 13 : 3662467186
Total Pages : 266 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents by : Kenneth Kam-Wing Lo

Download or read book Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents written by Kenneth Kam-Wing Lo and published by Springer. This book was released on 2015-06-30 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

Bioinorganic Photochemistry

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Publisher : John Wiley & Sons
ISBN 13 : 9781405193276
Total Pages : 398 pages
Book Rating : 4.1/5 (932 download)

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Book Synopsis Bioinorganic Photochemistry by : Grazyna Stochel

Download or read book Bioinorganic Photochemistry written by Grazyna Stochel and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.

Photosensitization of Porphyrins and Phthalocyanines

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Publisher : CRC Press
ISBN 13 : 1351590553
Total Pages : 252 pages
Book Rating : 4.3/5 (515 download)

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Book Synopsis Photosensitization of Porphyrins and Phthalocyanines by : Ichiro Okura

Download or read book Photosensitization of Porphyrins and Phthalocyanines written by Ichiro Okura and published by CRC Press. This book was released on 2017-05-12 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photosensitization of Porphyrins and Phthalocyanines covers the scentific background to porphyrins and phthalocyanines, and applications of the compounds, especially for the application for photosensitization. It also has a review of advances in research and applications in this field.