Phase Equilibria Of Binary Mixtures

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Liquids Under Negative Pressure

Author : A.R. Imre
Publisher : Springer Science & Business Media
ISBN 13 : 9401004986
Total Pages : 347 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Liquids Under Negative Pressure by : A.R. Imre

Download or read book Liquids Under Negative Pressure written by A.R. Imre and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is possible to "stretch" a liquid and, when suitably prepared, liquids are capable of sustaining substantial levels of tension, often for significant periods of time. These negative pressure states are metastable but can last for days - long enough for substantial experimental investigation. This volume is a review of recent and current research into the behaviour of liquids under negative pressure. Part I deals with the thermodynamics of stretched liquids. Part II discusses the physical and chemical behaviour of liquids under negative pressure. Part III contains papers on the effect of negative pressure on the solidification of a liquid. Part IV is devoted to stretched helium and Part V discusses cavitation in various stretched liquids. Part VI deals with the effect of foreign substances on cavitation.

Equations of State

Author : Kwang-chu Chao
Publisher :
ISBN 13 :
Total Pages : 616 pages
Book Rating : 4.:/5 (42 download)

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Book Synopsis Equations of State by : Kwang-chu Chao

Download or read book Equations of State written by Kwang-chu Chao and published by . This book was released on 1986 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Vapor-Liquid Equilibria Using Unifac

Author : Aage Fredenslund
Publisher : Elsevier
ISBN 13 : 0444601503
Total Pages : 393 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Vapor-Liquid Equilibria Using Unifac by : Aage Fredenslund

Download or read book Vapor-Liquid Equilibria Using Unifac written by Aage Fredenslund and published by Elsevier. This book was released on 2012-12-02 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vapor-Liquid Equilibria Using UNIFAC: A Group-Contribution Method focuses on the UNIFAC group-contribution method used in predicting quantitative information on the phase equilibria during separation by estimating activity coefficients. Drawing on tested vapor-liquid equilibrium data on which UNIFAC is based, it demonstrates through examples how the method may be used in practical engineering design calculations. Divided into nine chapters, this volume begins with a discussion of vapor and liquid phase nonidealities and how they are calculated in terms of fugacity and activity coefficients, respectively. It then introduces the reader to the UNIFAC method and how it works, the procedure used in establishing the parameters needed for the model, prediction of binary and multicomponent vapor-liquid equilibria for a large number of systems, the potential of UNIFAC for predicting liquid-liquid equilibria, and how UNIFAC can be used to solve practical distillation design problems. This book will benefit process design engineers who want to reliably predict phase equilibria for designing distillation columns and other separation processes.

Vapor-liquid Equilibrium Data Collection: Aqueous-organic systems

Author : Jürgen Gmehling
Publisher :
ISBN 13 :
Total Pages : 570 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Vapor-liquid Equilibrium Data Collection: Aqueous-organic systems by : Jürgen Gmehling

Download or read book Vapor-liquid Equilibrium Data Collection: Aqueous-organic systems written by Jürgen Gmehling and published by . This book was released on 2004 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:

High-Pressure Fluid Phase Equilibria

Author : Ulrich K Deiters
Publisher : Elsevier
ISBN 13 : 0444563547
Total Pages : 363 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis High-Pressure Fluid Phase Equilibria by : Ulrich K Deiters

Download or read book High-Pressure Fluid Phase Equilibria written by Ulrich K Deiters and published by Elsevier. This book was released on 2012-04-26 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. - introduces phase diagram classes, how to recognize them and identify their characteristic features - presents rational nomenclature of binary fluid phase diagrams - includes problems and solutions for self-testing, exercises or seminars

Phase Equilibrium Engineering

Author : Esteban Alberto Brignole
Publisher : Newnes
ISBN 13 : 044459471X
Total Pages : 347 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Phase Equilibrium Engineering by : Esteban Alberto Brignole

Download or read book Phase Equilibrium Engineering written by Esteban Alberto Brignole and published by Newnes. This book was released on 2013-04-02 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. - Methodologies are discussed using relevant industrial examples - The molecular nature and composition of the process mixture is given a key role in process decisions - Phase equilibrium diagrams are used as a drawing board for process implementation

Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys

Author : Felicitas Predel
Publisher : Springer
ISBN 13 : 9783642249761
Total Pages : 254 pages
Book Rating : 4.2/5 (497 download)

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Book Synopsis Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys by : Felicitas Predel

Download or read book Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys written by Felicitas Predel and published by Springer. This book was released on 2016-11-03 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamics determines the properties and region of existence of any alloy. Pressure, temperature and composition are the key parameters that dictate its crystal structure, crystallographic data, physical and mechanical properties. Phase diagrams are of utmost importance as overviews of the particularities of any alloying mixture. The present volume presents phase equilibria, thermodynamic and crystallographic data of the binary alloys K-O ... Y-Zr.

Modeling Vapor-Liquid Equilibria

Author : Hasan Orbey
Publisher : Cambridge University Press
ISBN 13 : 9780521620277
Total Pages : 230 pages
Book Rating : 4.6/5 (22 download)

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Book Synopsis Modeling Vapor-Liquid Equilibria by : Hasan Orbey

Download or read book Modeling Vapor-Liquid Equilibria written by Hasan Orbey and published by Cambridge University Press. This book was released on 1998-05-28 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews the latest developments in a subject relevant to professionals involved in the simulation and design of chemical processes - includes disk of computer programs.

Phase Equilibria, Phase Diagrams and Phase Transformations

Author : Mats Hillert
Publisher : Cambridge University Press
ISBN 13 : 1139465864
Total Pages : 525 pages
Book Rating : 4.1/5 (394 download)

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Book Synopsis Phase Equilibria, Phase Diagrams and Phase Transformations by : Mats Hillert

Download or read book Phase Equilibria, Phase Diagrams and Phase Transformations written by Mats Hillert and published by Cambridge University Press. This book was released on 2007-11-22 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.

Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set

Author : Pascal Richet
Publisher : John Wiley & Sons
ISBN 13 : 1118799399
Total Pages : 1568 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set by : Pascal Richet

Download or read book Encyclopedia of Glass Science, Technology, History, and Culture Two Volume Set written by Pascal Richet and published by John Wiley & Sons. This book was released on 2021-02-05 with total page 1568 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Encyclopedia begins with an introduction summarizing itsscope and content. Glassmaking; Structure of Glass, GlassPhysics,Transport Properties, Chemistry of Glass, Glass and Light,Inorganic Glass Families, Organic Glasses, Glass and theEnvironment, Historical and Economical Aspect of Glassmaking,History of Glass, Glass and Art, and outlinepossible newdevelopments and uses as presented by the best known people in thefield (C.A. Angell, for example). Sections and chapters arearranged in a logical order to ensure overall consistency and avoiduseless repetitions. All sections are introduced by a briefintroduction and attractive illustration. Newly investigatedtopics will be addresses, with the goal of ensuring that thisEncyclopedia remains a reference work for years to come.

Classical Thermodynamics of Non-Electrolyte Solutions

Author : H. C. Van Ness
Publisher : Elsevier
ISBN 13 : 148322547X
Total Pages : 176 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Classical Thermodynamics of Non-Electrolyte Solutions by : H. C. Van Ness

Download or read book Classical Thermodynamics of Non-Electrolyte Solutions written by H. C. Van Ness and published by Elsevier. This book was released on 2013-10-22 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.

Molecular Simulation Studies on Thermophysical Properties

Author : Gabriele Raabe
Publisher : Springer
ISBN 13 : 9811035458
Total Pages : 324 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Molecular Simulation Studies on Thermophysical Properties by : Gabriele Raabe

Download or read book Molecular Simulation Studies on Thermophysical Properties written by Gabriele Raabe and published by Springer. This book was released on 2017-02-17 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses the fundamentals of molecular simulation, starting with the basics of statistical mechanics and providing introductions to Monte Carlo and molecular dynamics simulation techniques. It also offers an overview of force-field models for molecular simulations and their parameterization, with a discussion of specific aspects. The book then summarizes the available know-how for analyzing molecular simulation outputs to derive information on thermophysical and structural properties. Both the force-field modeling and the analysis of simulation outputs are illustrated by various examples. Simulation studies on recently introduced HFO compounds as working fluids for different technical applications demonstrate the value of molecular simulations in providing predictions for poorly understood compounds and gaining a molecular-level understanding of their properties. This book will prove a valuable resource to researchers and students alike.

Molecular Thermodynamics of Fluid-Phase Equilibria

Author : John M. Prausnitz
Publisher : Pearson Education
ISBN 13 : 0132440504
Total Pages : 1150 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Molecular Thermodynamics of Fluid-Phase Equilibria by : John M. Prausnitz

Download or read book Molecular Thermodynamics of Fluid-Phase Equilibria written by John M. Prausnitz and published by Pearson Education. This book was released on 1998-10-22 with total page 1150 pages. Available in PDF, EPUB and Kindle. Book excerpt: The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

Alloy Phase Equilibria

Author : Alan Prince
Publisher :
ISBN 13 :
Total Pages : 308 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Alloy Phase Equilibria by : Alan Prince

Download or read book Alloy Phase Equilibria written by Alan Prince and published by . This book was released on 1966 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Gas Hydrates 1

Author : Daniel Broseta
Publisher : John Wiley & Sons
ISBN 13 : 1119427436
Total Pages : 279 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Gas Hydrates 1 by : Daniel Broseta

Download or read book Gas Hydrates 1 written by Daniel Broseta and published by John Wiley & Sons. This book was released on 2017-06-29 with total page 279 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gas hydrates, or clathrate hydrates, are crystalline solids resembling ice, in which small (guest) molecules, typically gases, are trapped inside cavities formed by hydrogen-bonded water (host) molecules. They form and remain stable under low temperatures – often well below ambient conditions – and high pressures ranging from a few bar to hundreds of bar, depending on the guest molecule. Their presence is ubiquitous on Earth, in deep-marine sediments and in permafrost regions, as well as in outer space, on planets or comets. In addition to water, they can be synthesized with organic species as host molecules, resulting in milder stability conditions: these are referred to as semi-clathrate hydrates. Clathrate and semi-clathrate hydrates are being considered for applications as diverse as gas storage and separation, cold storage and transport and water treatment. This book is the first of two edited volumes, with chapters on the experimental and modeling tools used for characterizing and predicting the unique molecular, thermodynamic and kinetic properties of gas hydrates (Volume 1) and on gas hydrates in their natural environment and for potential industrial applications (Volume 2).

Phase Theory

Author : H.A.J. Oonk
Publisher : Elsevier
ISBN 13 : 0444599339
Total Pages : 284 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Phase Theory by : H.A.J. Oonk

Download or read book Phase Theory written by H.A.J. Oonk and published by Elsevier. This book was released on 2012-12-02 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Studies in Modern Thermodynamics, 3: Phase Theory: The Thermodynamics of Heterogeneous Equilibria focuses on the processes, methodologies, principles, and approaches employed in the determination of the thermodynamics of heterogeneous equilibria. The publication first elaborates on thermodynamic background, phase rule, and general relations for binary equilibria. Discussions focus on linear contributions, G-curves and phase diagram, function changes, Clapeyron's equation, derivation of phase rule, pressure and temperature, heat capacity, enthalpy, and Gibbs energy. The manuscript then examines demixing, isothermal liquid-vapor equilibria, isobaric equilibria between two mixed states, and isobaric equilibria between unmixed solid and mixed liquid state. Topics include phase diagrams, pure solid component with liquid mixture, equilibrium between two ideal states, calculation of phase diagrams, and types of phase diagram. The text ponders on the interpretation of TX phase diagrams and retrograde equilibrium curves, including retrograde solubility, regions of demixing, excess parameters, and eutectic systems. The publication is a valuable reference for researchers wanting to dig deeper into the thermodynamics of heterogeneous equilibria.

Distillation

Author : Johann G. Stichlmair
Publisher : John Wiley & Sons
ISBN 13 : 1119414687
Total Pages : 688 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Distillation by : Johann G. Stichlmair

Download or read book Distillation written by Johann G. Stichlmair and published by John Wiley & Sons. This book was released on 2021-05-19 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: Distillation Principles and Practice Second Edition covers all the main aspects of distillation including the thermodynamics of vapor/liquid equilibrium, the principles of distillation, the synthesis of distillation processes, the design of the equipment, and the control of process operation. Most textbooks deal in detail with the principles and laws of distilling binary mixtures. When it comes to multi-component mixtures, they refer to computer software nowadays available. One of the special features of the second edition is a clear and easy understandable presentation of the principles and laws of ternary distillation. The right understanding of ternary distillation is the link to a better understanding of multi-component distillation. Ternary distillation is the basis for a conceptual process design, for separating azeotropic mixtures by using an entrainer, and for reactive distillation, which is a rapidly developing field of distillation. Another special feature of the book is the design of distillation equipment, i.e. tray columns and packed columns. In practice, empirical know-how is preferably used in many companies, often in form of empirical equations, which are not even dimensionally correct. The objective of the proposed book is the derivation of the relevant equations for column design based on first principles. The field of column design is permanently developing with respect to the type of equipment used and the know-how of two-phase flow and interfacial mass transfer.