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Oxidation In Organic Synthesis
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Book Synopsis Oxidation in Organic Synthesis by : V. K. Ahluwalia
Download or read book Oxidation in Organic Synthesis written by V. K. Ahluwalia and published by CRC Press. This book was released on 2012-02-13 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions.
Book Synopsis Chromium Oxidations in Organic Chemistry by : G. Cainelli
Download or read book Chromium Oxidations in Organic Chemistry written by G. Cainelli and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chromium oxidation, well known and widely explored in organic chemistry since the very beginning of this science, is a topic of current interest for the organic chemist as evidenced by the continuous development of new techni ques and procedures reported in the literature. Chromium oxidation is a simple process which can be easily performed in the laboratory and scaled up in industry as well. Although almost every oxidizable organic functional group may undergo chromium oxidation, the most important fields of appli cation are the oxidation of alcohols, allylic and benzylic oxidation, oxidative degradation and oxidation of some organometallic compounds. A high degree of selectivity is often possible by choosing the most suitable reagent among those several ones now available. This book takes account of the various functional groups that undergo oxidation and the entire literature up to 1982. It has been written in the hope to help the synthetic organic chemist in his experimental work. For this purpose a number of tables comprising yields and references have been included; detailed descriptions of typical procedures are meant to show the experimental conditions and the scope of the reactions. We wish to thank Dr. Mario Orena for his valuable scientific and technical assistence and Prof. Bruno Camerino, who read the entire manuscript and corrected many of the errors. Bologna, February 1984 Gianfranco Cainelli Giuliana Cardillo Table of Contents I. Introduction . . . . . . . . . . .
Book Synopsis Oxidizing and Reducing Agents by : Steven D. Burke
Download or read book Oxidizing and Reducing Agents written by Steven D. Burke and published by Handbook of Reagents for Organ. This book was released on 1999-07-09 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidizing and Reducing Agents S. D. Burke University of Wisconsin at Madison, USA R. L. Danheiser Massachusetts Institute of Technology, Cambridge, USA Recognising the critical need for bringing a handy reference work that deals with the most popular reagents in synthesis to the laboratory of practising organic chemists, the Editors of the acclaimed Encyclopedia of Reagents for Organic Synthesis (EROS) have selected the most important and useful reagents employed in contemporary organic synthesis. Handbook of Reagents for Organic Synthesis: Oxidizing and Reducing Agents, provides the synthetic chemist with a convenient compendium of information concentrating on the most important and frequently employed reagents for the oxidation and reduction of organic compounds, extracted and updated from EROS. The inclusion of a bibliography of reviews and monographs, a compilation of Organic Syntheses procedures with tested experimental details and references to oxidizing and reducing agents will ensure that this handbook is both comprehensive and convenient.
Book Synopsis Green Oxidation in Organic Synthesis by : Ning Jiao
Download or read book Green Oxidation in Organic Synthesis written by Ning Jiao and published by John Wiley & Sons. This book was released on 2019-07-12 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: A valuable introduction to green oxidation for organic chemists interested in discovering new strategies and new reactions for oxidative synthesis Green Oxidation in Organic Synthesis provides a comprehensive introduction and overview of chemical preparation by green oxidative processes, an entry point to the growing journal literature on green oxidation in organic synthesis. It discusses both experimental and theoretical approaches for the study of new catalysts and methods for catalytic oxidation and selective oxidation. The book highlights the discovery of new reactions and catalysts in recent years, discussing mechanistic insights into the green oxidative processes, as well as applications in organic synthesis with significant potential to have a major impact in academia and industry. Chapters are organized according to the functional groups generated in the reactions, presenting interesting achievements for functional group formation by green oxidative processes with O2, H2O2, photocatalytic oxidation, electrochemical oxidation, and enzymatic oxidation. The mechanisms of these novel transformations clearly illustrated. Green Oxidation in Organic Synthesis will serve as an excellent reference for organic chemists interested in discovering new strategies for oxidative synthesis which address the priorities of green and sustainable chemistry.
Download or read book Oxidation written by Barry M. Trost and published by Elsevier. This book was released on 1992-09-08 with total page 1039 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers all methods of oxidation for use in organic synthesis. Emphasis has been placed on selectivity and functional group compatibility together with practical utility and applications. The volume is broadly divided to cover oxidation of unactivated carbon-hydrogen bonds, oxidation of activated carbon-hydrogen bonds, that is to say those adjacent to activating substituents and adjacent to heteroatoms, and oxidation of carbon-carbon double bonds. The volume also covers oxidation of C-X bonds, carbon-carbon single bonds, heteroatom oxidation and a number of special topics such as electrochemical methods, oxidative rearrangements, solid supported reagents, electron transfer oxidation, and biological methods.
Book Synopsis Science of Synthesis: Catalytic Oxidation in Organic Synthesis by : Kilian Muñiz
Download or read book Science of Synthesis: Catalytic Oxidation in Organic Synthesis written by Kilian Muñiz and published by Thieme. This book was released on 2018-03-23 with total page 1425 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of catalytic systems for the oxidation of organic compounds continues to be of great importance. There is an ongoing and increasing demand for methods that are selective, proceed under mild conditions, and adhere to green chemistry principles. "Science of Synthesis: Catalytic Oxidation in Organic Synthesis" includes the latest developments in the field, as well as selective coverage of more well-established methods. Systems based on metal catalysts, organocatalysts, and biomimetic oxidation are covered, and there is a particular focus on asymmetric processes. Scope, limitations, and mechanism of the reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.
Book Synopsis Organic Synthesis by : Michael Smith
Download or read book Organic Synthesis written by Michael Smith and published by Academic Press. This book was released on 2016-11-22 with total page 1108 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Synthesis, Fourth Edition, provides a reaction-based approach to this important branch of organic chemistry. Updated and accessible, this eagerly-awaited revision offers a comprehensive foundation for graduate students coming from disparate backgrounds and knowledge levels, to provide them with critical working knowledge of basic reactions, stereochemistry and conformational principles. This reliable resource uniquely incorporates molecular modeling content, problems, and visualizations, and includes reaction examples and homework problems drawn from the latest in the current literature. In the Fourth Edition, the organization of the book has been improved to better serve students and professors and accommodate important updates in the field. The first chapter reviews basic retrosynthesis, conformations and stereochemistry. The next three chapters provide an introduction to and a review of functional group exchange reactions; these are followed by chapters reviewing protecting groups, oxidation and reduction reactions and reagents, hydroboration, selectivity in reactions. A separate chapter discusses strategies of organic synthesis, and he book then delves deeper in teaching the reactions required to actually complete a synthesis. Carbon-carbon bond formation reactions using both nucleophilic carbon reactions are presented, and then electrophilic carbon reactions, followed by pericyclic reactions and radical and carbene reactions. The important organometallic reactions have been consolidated into a single chapter. Finally, the chapter on combinatorial chemistry has been removed from the strategies chapter and placed in a separate chapter, along with valuable and forward-looking content on green organic chemistry, process chemistry and continuous flow chemistry. Throughout the text, Organic Synthesis, Fourth Edition utilizes Spartan-generated molecular models, class tested content, and useful pedagogical features to aid student study and retention, including Chapter Review Questions, and Homework Problems. A full Solutions Manual is also available online for qualified instructors, to support teaching. Winner, 2018 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association Fully revised and updated throughout, and organized into 19 chapters for a more cogent and versatile presentation of concepts Includes reaction examples taken from literature research reported between 2010-2015 Features new full-color art and new chapter content on process chemistry and green organic chemistry Offers valuable study and teaching tools, including Chapter Review Questions and Homework Problems for students; Solutions Manual for qualified course instructors
Book Synopsis Methods for the Oxidation of Organic Compounds by : Alan H. Haines
Download or read book Methods for the Oxidation of Organic Compounds written by Alan H. Haines and published by . This book was released on 1988 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for Oxidation of Organic Compounds V2 ...
Book Synopsis Catalytic Oxidation Reagents by : Philip L. Fuchs
Download or read book Catalytic Oxidation Reagents written by Philip L. Fuchs and published by John Wiley & Sons. This book was released on 2013-07-29 with total page 2037 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Handbook is part of the Handbook of Reagents for Organic Chemistry series, aiming at collecting articles on a particular theme that individual researchers in academia or industry can use on a daily basis. The Handbook starts with a section discussing the most important aspects of heteroarene functionalization. The introduction is followed by the alphabetical listing of the most relevant reagents drawn from the EROS database. The Editor, André Charette from the University of Montreal, has selected 120 reagent descriptions, many of them updated with heteroarene-specific reactions for this Handbook. Following the standard format for EROS, each article contains an overview of the synthesis and physical properties of the reagents or catalyst, conditions for its storage, and purification methods. Given the importance of heteroarenes in biology and especially in medicinal chemistry, a Handbook that focuses exclusively on heteroarene functionalization has been long overdue. This Handbook will have a broad appeal to many individuals engaged in the area of medicinal chemistry, fine chemical synthesis and industrial-scale chemistry. Key features: Builds on the success of the previously published Handbooks of Reagents for Organic Synthesis Compares the numerous new C-H functionalization reactions that have been developed in the past decade Heteroarene functionalization is widely used in the development of pharmaceuticals and other bioactive compounds Contains listings of secondary reagents for which more information is available in the online edition
Book Synopsis Electrochemical Reactions and Mechanisms in Organic Chemistry by : J. Grimshaw
Download or read book Electrochemical Reactions and Mechanisms in Organic Chemistry written by J. Grimshaw and published by Elsevier. This book was released on 2000-12-01 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook.As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.
Book Synopsis Oxidation and Reduction in Organic Synthesis by : Timothy J. Donohoe
Download or read book Oxidation and Reduction in Organic Synthesis written by Timothy J. Donohoe and published by . This book was released on 2003 with total page 91 pages. Available in PDF, EPUB and Kindle. Book excerpt: The manipulation of functional groups by oxidative or reductive processes is central to organic chemistry. Despite the importance of these reactions, no existing text has attempted to summarize them simply for students. Together with a later volume in the series, this book provides a clear and comprehensive summary of oxidative and reductive processes, emphasizing general principles and common factors, and showing the applications of these compounds in organic synthesis.
Book Synopsis Oxidation of Alcohols to Aldehydes and Ketones by : Gabriel Tojo
Download or read book Oxidation of Alcohols to Aldehydes and Ketones written by Gabriel Tojo and published by Springer Science & Business Media. This book was released on 2006-06-15 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.
Book Synopsis Organic Syntheses by Oxidation with Metal Compounds by : W.J. Mijs
Download or read book Organic Syntheses by Oxidation with Metal Compounds written by W.J. Mijs and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is concerned with the synthetic aspects of oxidation reactions involving metal compounds. which are readily available or easy to prepare. The sequence followed in the chapters is as follows: a general introduction. a limited treatment of reaction mechanisms to serve as a basis for synthesis. and scope and limitations of the oxidant system. mostly in terms of substrate and product classes. Finally, at the end of each chapter. representative synthetic procedures are given together with relevant experimental considerations. A general table is included as an appendix. This contains substrate classes and resulting product classes, referring to the oxidative procedures in the chapters. The table provides the synthetic organic chemist with a quick overview of oxidation possibilities with metal-contain ing oxidants, enabling him to select the right method for his purpose. The editors hope that not only organic research chemists in industry and at universities, but also advanced undergraduate and graduate students in organic chemistry, will find this book a useful guide in the design, understanding, and practical performance of oxidative organic syntheses. The editors are grateful to the authors not only for their contributions. containing interesting new developments in oxidation chemistry, but also for the way they fitted the text into the general framework given for the book. Their suggestions and comments are gratefully acknowledged. Thanks are also due to Mrs. A. I. Rohnstrom-Ouwejan, secretary to the editors, for her administrative support.
Book Synopsis Metal-Catalyzed Oxidations of Organic Compounds by : Roger Sheldon
Download or read book Metal-Catalyzed Oxidations of Organic Compounds written by Roger Sheldon and published by Elsevier. This book was released on 2012-12-02 with total page 447 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Catalyzed Oxidations of Organic Compounds: Mechanistic Principles and Synthetic focuses on the oxidative transformations of functional groups. This book explores oxidation as being extensively used in the laboratory synthesis of fine organic chemicals and in the manufacture of large-volume petrochemicals. Organized into two parts encompassing 13 chapters, this book starts with an overview of the mechanistic principles of oxidation–reduction in biochemical, organic, and inorganic systems. This text then proceeds with a discussion of the use of molecular oxygen, hydrogen peroxide, and alkyl hydroperoxides as primary oxidants. Other chapters explore stoichiometric oxidations with metal oxidants, which include permanganate and chromic acid. This book discusses as well the synthetic applications of catalytic oxidations as well as the technology of petrochemical oxidation. The final chapter deals with the autoxidations of sulfur, phosphorus, and nitrogen compounds. This book is intended for chemists involved in organic synthesis, catalysis, and organometallic chemistry, both in academic institutions and in industrial laboratories.
Book Synopsis Organic Synthesis with Palladium Compounds by : Jiro Tsuji
Download or read book Organic Synthesis with Palladium Compounds written by Jiro Tsuji and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-
Book Synopsis Oxidation of Primary Alcohols to Carboxylic Acids by : Gabriel Tojo
Download or read book Oxidation of Primary Alcohols to Carboxylic Acids written by Gabriel Tojo and published by Springer Science & Business Media. This book was released on 2007-05-31 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the second volume in a comprehensive encyclopedia of organic reactions, this work provides an elaborated description of the experimental methods used for the oxidation of alcohols to acids. It supplies important data on possible interferences from protecting groups and functional groups, as well as on potential side-reactions. This book is a must for anyone involved in the preparation of organic compounds.
Book Synopsis Science of Synthesis: Catalytic Oxidation in Organic Synthesis by :
Download or read book Science of Synthesis: Catalytic Oxidation in Organic Synthesis written by and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
