A Textbook of Inorganic Chemistry – Volume 1

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Author :
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 482 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Transition Metal Carbonyl Cluster Chemistry

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Publisher : CRC Press
ISBN 13 : 9789056992897
Total Pages : 190 pages
Book Rating : 4.9/5 (928 download)

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Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2000-11-17 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Modern Perspectives in Inorganic Crystal Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 9401127263
Total Pages : 283 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Modern Perspectives in Inorganic Crystal Chemistry by : Erwin Parthé

Download or read book Modern Perspectives in Inorganic Crystal Chemistry written by Erwin Parthé and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of crystal structures has had an ever increasing impact on many fields of science such as physics, chemistry, biology, materials science, medicine, pharmacy, metallurgy, mineralogy and geology. Particularly, with the advent of direct methods of structure determination, the data on crystal structures are accumulating at an unbelievable pace and it becomes more and more difficult to oversee this wealth of data. A crude rationalization of the structures of organic compounds and the atom coordinations can be made with the well-known Kekule model, however, no such generally applicable model exists for the structures of inorganiC and particularly intermetallic compounds. There is a need to rationalize the inorganic crystal structures, to find better ways of describing them, of denoting the geometrical relationships between them, of elucidating the electronic factors and of explaining the bonding between the atoms with the aim of not only having a better understanding of the known structures, but also of predicting structural features of new compounds.

Cluster Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 3642859267
Total Pages : 310 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Cluster Chemistry by : Guillermo Gonzalez-Moraga

Download or read book Cluster Chemistry written by Guillermo Gonzalez-Moraga and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cluster chemistry is one of the recent, exciting areas of Inorganic Chemistry. The occurence of molecular clusters, like fullerene C60, constitutes a fundamental feature midway between the chemistry of isolated chemical compounds and that of the elements. Main features of the Cluster Chemistry of both main group and transition metal elements are treated in this book. The author highlights aspects releated to the synthesis, the structure, the special bonding and the reactivity of these species. The book is written as a textbook for senior undergraduate and postgraduate students. References in tables andillustrations permit the reader to reach relevant original information. Professor Gonzalez-Moraga fills a demand for a publication appropriate for dissemination and specially for teaching this exciting subject. From the Contents: Current Concepts in Modern Chemistry - Transition Metal Cluster Chemistry - Main Group-Transition Metal Mixed Clusters - Cluster Compounds of the Main Group Elements - Synthetic Analogues of the Active Sites of Iron-Sulfur Proteins.

Introduction to Cluster Chemistry

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Author :
Publisher :
ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Introduction to Cluster Chemistry by : D. M. P. Mingos

Download or read book Introduction to Cluster Chemistry written by D. M. P. Mingos and published by . This book was released on 1990 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Multiple Bonds between Metal Atoms

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Publisher : Springer Science & Business Media
ISBN 13 : 9780387250847
Total Pages : 856 pages
Book Rating : 4.2/5 (58 download)

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Book Synopsis Multiple Bonds between Metal Atoms by : F. Albert Cotton

Download or read book Multiple Bonds between Metal Atoms written by F. Albert Cotton and published by Springer Science & Business Media. This book was released on 2005-06-28 with total page 856 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included

Structure and Properties of Atomic Nanoclusters

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Publisher : World Scientific
ISBN 13 : 1848167334
Total Pages : 492 pages
Book Rating : 4.8/5 (481 download)

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Book Synopsis Structure and Properties of Atomic Nanoclusters by : Julio A. Alonso

Download or read book Structure and Properties of Atomic Nanoclusters written by Julio A. Alonso and published by World Scientific. This book was released on 2012 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic clusters are aggregates of atoms containing a few to several thousand atoms. Due to the small size of these pieces of matter, the properties of atomic clusters in general are different from those of the corresponding material in the macroscopic bulk phase. This monograph presents the main developments of atomic clusters and the current status of the field. The book treats different types of clusters with very different properties: clusters in which the atoms or molecules are tied by weak van der Waals interactions, metallic clusters, clusters of ionic materials, and network clusters made of typical covalent elements. It includes methods of experimental cluster synthesis as well as the structural, electronic, thermodynamic and magnetic properties of clusters, covering both experiments and the theoretical work that has led to our present understanding of the different properties of clusters. The question of assembling nanoclusters to form solids with new properties is also considered. Having an adequate knowledge of the properties of clusters can be of great help to any scientist working with objects of nanometric size. On the other hand, nanoclusters are themselves potentially important in fields like catalysis and nanomedicine.

Molecular Clusters

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Publisher : Cambridge University Press
ISBN 13 : 1107320836
Total Pages : 388 pages
Book Rating : 4.1/5 (73 download)

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Book Synopsis Molecular Clusters by : Thomas Fehlner

Download or read book Molecular Clusters written by Thomas Fehlner and published by Cambridge University Press. This book was released on 2007-07-05 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.

Chemistry, Structure, and Bonding of Zintl Phases and Ions

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Publisher : VCH Publishers
ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemistry, Structure, and Bonding of Zintl Phases and Ions by : Susan Mary Kauzlarich

Download or read book Chemistry, Structure, and Bonding of Zintl Phases and Ions written by Susan Mary Kauzlarich and published by VCH Publishers. This book was released on 1996 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Seven chapters report current research into the phases and ions of a class of compounds that are electronically positioned between the intermetallic compounds and insulating valence compounds. They cover structure and bonding at the Zintl border, structural patterns of homo- and hetero-nuclear anions and related intermetallic compounds and concepts for interpreting them, the early p-block elements, polyanions in liquid ionic alloys, molecular transition metal complexes, transition metal compounds, and synthesizing and characterizing intermetallic materials using Zintl phases as precursors. An introduction surveys the life and work of German chemist Eduard Zintl (1898-1941). Annotation copyright by Book News, Inc., Portland, OR

Aromaticity and Metal Clusters

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Publisher : CRC Press
ISBN 13 : 9781439813355
Total Pages : 466 pages
Book Rating : 4.8/5 (133 download)

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Book Synopsis Aromaticity and Metal Clusters by : Pratim Kumar Chattaraj

Download or read book Aromaticity and Metal Clusters written by Pratim Kumar Chattaraj and published by CRC Press. This book was released on 2010-10-15 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal clusters, an intermediate state between molecules and the extended solid, show peculiar bonding and reactivity patterns. Their significance is critical to many areas, including air pollution, interstellar matter, clay minerals, photography, catalysis, quantum dots, and virus crystals. In Aromaticity and Metal Clusters, dozens of international experts explore not only the basic aspects of aromaticity, but also the structures, properties, reactivity, stability, and other consequences of the aromaticity of a variety of metal clusters. Although the concept of aromaticity has been known for nearly two centuries, there is no way to measure it experimentally and no theoretical formula to calculate it. In order to gain insight into its exact nature, the authors of this volume examine various indirect characteristics such as geometrical, electronic, magnetic, thermodynamic, and reactivity considerations. The book begins by discussing the evolution of aromaticity from benzene to atomic clusters. Next, more specialized chapters focus on areas of significant interest. Topics discussed include: Computational studies on molecules with unusual aromaticity Electronic shells and magnetism in small metal clusters A density functional investigation on the structures, energetics, and properties of sodium clusters through electrostatic guidelines and molecular tailoring The correlation between electron delocalization and ring currents in all metallic aromatic compounds Phenomenological shell model and aromaticity in metal clusters Rationalizing the aromaticity indexes used to describe the aromatic behavior of metal clusters 5f orbital successive aromatic and antiaromatic zones in triangular uranium cluster chemistry This collection of diverse contributions, composed of the work of scientists worldwide, is destined to not only answer puzzling questions about the nature of aromaticity, but also to provoke further inquiry in the minds of researchers.

Modern Inorganic Synthetic Chemistry

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Publisher : Elsevier
ISBN 13 : 0444535993
Total Pages : 612 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Modern Inorganic Synthetic Chemistry by : Ruren Xu

Download or read book Modern Inorganic Synthetic Chemistry written by Ruren Xu and published by Elsevier. This book was released on 2011-01-13 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: The contributors to this book discuss inorganic synthesis reactions, dealing with inorganic synthesis and preparative chemistry under specific conditions. They go on to describe the synthesis, preparation and assembly of six important categories of compounds with wide coverage of distinct synthetic chemistry systems

Atomic Clusters with Unusual Structure, Bonding and Reactivity

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Publisher : Elsevier
ISBN 13 : 0128231017
Total Pages : 446 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Atomic Clusters with Unusual Structure, Bonding and Reactivity by : Pratim Kumar Chattaraj

Download or read book Atomic Clusters with Unusual Structure, Bonding and Reactivity written by Pratim Kumar Chattaraj and published by Elsevier. This book was released on 2022-10-06 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic Clusters with Unusual Structure, Bonding and Reactivity: Theoretical Approaches, Computational Assessment and Applications reviews the latest computational tools and approaches available for accurately assessing the properties of a cluster, while also highlighting how such clusters can be adapted and utilized for the development of novel materials and applications. Sections provide an introduction to the computational methods used to obtain global minima for clusters and effectively analyze bonds, outline experimental approaches to produce clusters, discuss specific applications, and explore cluster reactivity and usage across a number of fields.Drawing on the knowledge of its expert editors and contributors, this book provides a detailed guide to ascertaining the stability, bonding and properties of atomic clusters. Atomic clusters, which exhibit unusual properties, offer huge potential as building blocks for new materials and novel applications, but understanding their properties, stability and bonding is essential in order to accurately understand, characterize and manipulate them for further use. Searching for the most stable geometry of a given cluster is difficult and becomes even more so for clusters of medium and large sizes, where the number of possible isomers sharply increase, hence this book provides a unique and comprehensive approach to the topic and available techniques and applications. - Introduces readers to the vast structural and bonding diversity that clusters show and reflects on their potential for novel application and material development - Highlights the latest computational methods and theoretical tools available for identification of the most stable isomers and accurate analysis of bonding in the clusters - Focuses on clusters which violate the rules established in traditional chemistry and exhibit unusual structure, bonding and reactivity

Fundamentals of Structural Chemistry

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Publisher : World Scientific
ISBN 13 : 9789810213350
Total Pages : 500 pages
Book Rating : 4.2/5 (133 download)

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Book Synopsis Fundamentals of Structural Chemistry by : Gong-du Zhou

Download or read book Fundamentals of Structural Chemistry written by Gong-du Zhou and published by World Scientific. This book was released on 1993 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on two main topics in fundamental structural chemistry: the properties of chemical bonding derived from the behavior of the microscopic particles and their wave functions, and the three-dimensional molecular and crystal structures. The principle that ?structure determines properties and properties reflect structures? is clearly demonstrated. This book emphasizes practical examples linking structure with properties and applications which provide invaluable insight for students, thus stimulating their mind to deal with problems in the topics concerned.

Applications of Density Functional Theory to Biological and Bioinorganic Chemistry

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Publisher : Springer
ISBN 13 : 3642327508
Total Pages : 245 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Applications of Density Functional Theory to Biological and Bioinorganic Chemistry by : Mihai V. Putz

Download or read book Applications of Density Functional Theory to Biological and Bioinorganic Chemistry written by Mihai V. Putz and published by Springer. This book was released on 2013-02-01 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.

Cloud Computing in Ocean and Atmospheric Sciences

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Publisher : Elsevier
ISBN 13 : 012803193X
Total Pages : 456 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Cloud Computing in Ocean and Atmospheric Sciences by : Tiffany C Vance

Download or read book Cloud Computing in Ocean and Atmospheric Sciences written by Tiffany C Vance and published by Elsevier. This book was released on 2016-03-24 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Cloud Computing in Ocean and Atmospheric Sciences provides the latest information on this relatively new platform for scientific computing, which has great possibilities and challenges, including pricing and deployments costs and applications that are often presented as primarily business oriented. In addition, scientific users may be very familiar with these types of models and applications, but relatively unfamiliar with the intricacies of the hardware platforms they use. The book provides a range of practical examples of cloud applications that are written to be accessible to practitioners, researchers, and students in affiliated fields. By providing general information on the use of the cloud for oceanographic and atmospheric computing, as well as examples of specific applications, this book encourages and educates potential users of the cloud. The chapters provide an introduction to the practical aspects of deploying in the cloud, also providing examples of workflows and techniques that can be reused in new projects. - Provides real examples that help new users quickly understand the cloud and provide guidance for new projects - Presents proof of the usability of the techniques and a clear path to adoption of the techniques by other researchers - Includes real research and development examples - that are ideal for cloud computing adopters in ocean and atmospheric domains

Structure and Bonding in Crystalline Materials

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Publisher : Cambridge University Press
ISBN 13 : 9780521663793
Total Pages : 554 pages
Book Rating : 4.6/5 (637 download)

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Book Synopsis Structure and Bonding in Crystalline Materials by : Gregory S. Rohrer

Download or read book Structure and Bonding in Crystalline Materials written by Gregory S. Rohrer and published by Cambridge University Press. This book was released on 2001-07-19 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the motivating questions in materials research today is, how can elements be combined to produce a solid with specified properties? This book is intended to acquaint the reader with established principles of crystallography and cohesive forces that are needed to address the fundamental relationship between the composition, structure and bonding. Starting with an introduction to periodic trends, the book discusses crystal structures and the various primary and secondary bonding types, and finishes by describing a number of models for predicting phase stability and structure. Containing a large number of worked examples, exercises, and detailed descriptions of numerous crystal structures, this book is primarily intended as an advanced undergraduate or graduate level textbook for students of materials science. It will also be useful to scientists and engineers who work with solid materials.

The Chemistry of Metal Cluster Complexes

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Publisher :
ISBN 13 :
Total Pages : 464 pages
Book Rating : 4.:/5 (5 download)

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Book Synopsis The Chemistry of Metal Cluster Complexes by : Duward F. Shriver

Download or read book The Chemistry of Metal Cluster Complexes written by Duward F. Shriver and published by . This book was released on 1990 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt: