Nitric Acid Dissolution of Uranium-aluminum Alloy

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Total Pages : 24 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Nitric Acid Dissolution of Uranium-aluminum Alloy by : R. E. Burns

Download or read book Nitric Acid Dissolution of Uranium-aluminum Alloy written by R. E. Burns and published by . This book was released on 1952 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Nitric Acid Dissolution of Uranium-Aluminum Alloy in a Flooded Continuous Dissolver

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Book Synopsis The Nitric Acid Dissolution of Uranium-Aluminum Alloy in a Flooded Continuous Dissolver by :

Download or read book The Nitric Acid Dissolution of Uranium-Aluminum Alloy in a Flooded Continuous Dissolver written by and published by . This book was released on 1954 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Extensive pilot plant studies of the mercury-catalyzed nitric acid dissolution of unirradiated 7.5% uranium--92.5% aluminum alloy slugs were carried out in tall-pipe, flooded, continuous dissolvers, In producing an acidic product containing 1.2M aluminum nitrate, dissolution rates as high as 15 kg of aluminum per day per square inch of cross section were achieved. Countercurrent flow of metal and acid has some advantages over concurrent flow, The large heat of reaction produced great volumes of steam in the dissolvers; the operational problems due to the resulting foam were best solved by the use of an over head reflux condenser to condense, partially or totally, the steam in the off-gas. Only minor quantities of solids were found in acidic product solutions. Extruded alloy dissolved abcut twice as fast as cast alloy, The metal dissolving rate was directly proportional to the 0.8 power of the nitric acid feed rate and tc the cube root of the mercuric ion (catalyst) concentration. The maximim dissolving rates occurred at feed acid concentrations of abcut 3M for cast slugs and 5M for extruded alloy, The system studied is inherently self-regulating in that a uniform product composition will normally be produced by feeding slugs, nitric acid, and catalyst at constant rates. The occasional minor rate adjustments are best accomplished by varying the catalyst concentration. Data and correlations developed are given. (auth).

Aqueous Processes for Dissolution of Uranium-molybdenum Alloy Reactor Fuel Elements

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Total Pages : 44 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Aqueous Processes for Dissolution of Uranium-molybdenum Alloy Reactor Fuel Elements by : L. M. Ferris

Download or read book Aqueous Processes for Dissolution of Uranium-molybdenum Alloy Reactor Fuel Elements written by L. M. Ferris and published by . This book was released on 1961 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dissolving Highly Irradiated Pu - Al Alloy

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Total Pages : 16 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Dissolving Highly Irradiated Pu - Al Alloy by : William C. Perkins

Download or read book Dissolving Highly Irradiated Pu - Al Alloy written by William C. Perkins and published by . This book was released on 1964 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Electrolytic Dissolution of Power Reactor Fuels in Nitric Acid

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Total Pages : 28 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Electrolytic Dissolution of Power Reactor Fuels in Nitric Acid by :

Download or read book Electrolytic Dissolution of Power Reactor Fuels in Nitric Acid written by and published by . This book was released on 1961 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dissolver for Natural Uranium Fuel Elements

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Total Pages : 28 pages
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Book Synopsis Dissolver for Natural Uranium Fuel Elements by : Vincent P. Caracciolo

Download or read book Dissolver for Natural Uranium Fuel Elements written by Vincent P. Caracciolo and published by . This book was released on 1958 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reprocessing Uranium-molybdenum Alloy Fuels

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Total Pages : 42 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Reprocessing Uranium-molybdenum Alloy Fuels by : W. W. Schulz

Download or read book Reprocessing Uranium-molybdenum Alloy Fuels written by W. W. Schulz and published by . This book was released on 1960 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Continuous Pilot Plant Dissolution of Aluminum-jacketed Uranium Fuel Elements in Nitric Acid

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Total Pages : 38 pages
Book Rating : 4.:/5 (549 download)

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Book Synopsis Continuous Pilot Plant Dissolution of Aluminum-jacketed Uranium Fuel Elements in Nitric Acid by : T. F. Evans

Download or read book Continuous Pilot Plant Dissolution of Aluminum-jacketed Uranium Fuel Elements in Nitric Acid written by T. F. Evans and published by . This book was released on 1958 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Analysis of UO2 Dissolution in Nitric Acid Solution

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Total Pages : 42 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Analysis of UO2 Dissolution in Nitric Acid Solution by : H. F. Johnson

Download or read book Analysis of UO2 Dissolution in Nitric Acid Solution written by H. F. Johnson and published by . This book was released on 1962 with total page 42 pages. Available in PDF, EPUB and Kindle. Book excerpt:

AQUEOUS PROCESSES FOR DISSOLUTION OF URANIUM-MOLYBDENUM ALLOY REACTOR FUEL ELEMENTS.

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Book Synopsis AQUEOUS PROCESSES FOR DISSOLUTION OF URANIUM-MOLYBDENUM ALLOY REACTOR FUEL ELEMENTS. by :

Download or read book AQUEOUS PROCESSES FOR DISSOLUTION OF URANIUM-MOLYBDENUM ALLOY REACTOR FUEL ELEMENTS. written by and published by . This book was released on 1961 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for dissolving unirradiated uranium-molybdenum alloy reactcr fuels in nitric acid, nitric acid--ferric nitrate, and nitric acid-- phosphoric acid solutions were studied on a laboratory scale. Flowsheets based on the results propose dissolution of alloys containing 3% molybdenum in boiling 6 M HNO/ sub 3/ to yield stsble solutions that are 0.6 M in uranium and 3 to 4 M in nitric acid. The uranium can then be easily decontaminated and recovered in a conventional Purex-type tributyl phosphate solvent extraction process. Alloys containing 10% molybdenum would be dissolved in boiling 11 M HNO3, allowing molybdic oxide to precipitate. The molybdic oxide, which carries 5-10% of the uranium, is removed by centrifugation and the acidity of the supernatant solution adjusted tc allow recovery of the uranium by Purex-type solvent extraction procedures. The uranium carried by the molybdic oxide is recovered after the MoO/ sub 3/ is dissolved in warm 5 M NaOH. Less than 0.1% of the uranium is solubilized during the caustic dissolution. Alternative methods investigated involve dissolution in nitric acid containing 0.5 to 1 M ferric nitrate to complex the molybdenum. These techniques lead to undesirably large volumes of high-level solvent extraction waste solutions. Phosphate ion is also effective in complexing molybdenum; however, its use in the dissolvent would be purposeless since it must be complexed with iron during solvent extraction. Rates of reaction of the various alloys and the solubility of molybdic oxide were determined in nitric acid, nitric acid-- ferric nitrate, and nitric acid-- phosphonic acid solutions. (auth).

Publications

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ISBN 13 :
Total Pages : 128 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Publications by : Savannah River Laboratory

Download or read book Publications written by Savannah River Laboratory and published by . This book was released on 1951 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reprocessing of Irradiated Fission Reactor Fuel and Breeding Materials

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ISBN 13 :
Total Pages : 212 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Reprocessing of Irradiated Fission Reactor Fuel and Breeding Materials by :

Download or read book Reprocessing of Irradiated Fission Reactor Fuel and Breeding Materials written by and published by . This book was released on 1964 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Effect of Geometrical Shape on the Continuous Dissolution of Aluminum in Mercury

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Total Pages : 28 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Effect of Geometrical Shape on the Continuous Dissolution of Aluminum in Mercury by : A. F. Boeglin

Download or read book Effect of Geometrical Shape on the Continuous Dissolution of Aluminum in Mercury written by A. F. Boeglin and published by . This book was released on 1957 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

CONTROLLED NITRIC ACID DISSOLUTION OF ALUMINUM--PLUTONIUM ALLOYS.

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Book Synopsis CONTROLLED NITRIC ACID DISSOLUTION OF ALUMINUM--PLUTONIUM ALLOYS. by :

Download or read book CONTROLLED NITRIC ACID DISSOLUTION OF ALUMINUM--PLUTONIUM ALLOYS. written by and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Determination of Uranium in Aluminum

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Total Pages : 14 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Determination of Uranium in Aluminum by : G. S. Petit

Download or read book Determination of Uranium in Aluminum written by G. S. Petit and published by . This book was released on 1964 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Undissolved Uranium Aluminide in Reprocessing of Test Reactor Ruels

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Total Pages : 58 pages
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Book Synopsis Undissolved Uranium Aluminide in Reprocessing of Test Reactor Ruels by : B. E. Paige

Download or read book Undissolved Uranium Aluminide in Reprocessing of Test Reactor Ruels written by B. E. Paige and published by . This book was released on 1970 with total page 58 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reactor Fuel Processing

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ISBN 13 :
Total Pages : 726 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Reactor Fuel Processing by :

Download or read book Reactor Fuel Processing written by and published by . This book was released on 1963 with total page 726 pages. Available in PDF, EPUB and Kindle. Book excerpt: