Multi-dimensional Ultrafast Spectroscopy of Vibrational Coherence Dynamics in Excited Electronic States of Polyenes

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ISBN 13 :
Total Pages : 232 pages
Book Rating : 4.:/5 (881 download)

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Book Synopsis Multi-dimensional Ultrafast Spectroscopy of Vibrational Coherence Dynamics in Excited Electronic States of Polyenes by : Jan Philip Kraack

Download or read book Multi-dimensional Ultrafast Spectroscopy of Vibrational Coherence Dynamics in Excited Electronic States of Polyenes written by Jan Philip Kraack and published by . This book was released on 2013 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Coherent Vibrational Dynamics

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Publisher : CRC Press
ISBN 13 : 1420017519
Total Pages : 286 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Coherent Vibrational Dynamics by : Guglielmo Lanzani

Download or read book Coherent Vibrational Dynamics written by Guglielmo Lanzani and published by CRC Press. This book was released on 2007-11-29 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Remarkable developments in the spectroscopy field regarding ultrashort pulse generation have led to the possibility of producing light pulses ranging from 50 to5 fs and frequency tunable from the near infrared to the ultraviolet range. Such pulses enable us to follow the coupling of vibrational motion to the electronic transitions in molecules and

Multidimensional Time-Resolved Spectroscopy

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Publisher : Springer
ISBN 13 : 3030024784
Total Pages : 320 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Multidimensional Time-Resolved Spectroscopy by : Tiago Buckup

Download or read book Multidimensional Time-Resolved Spectroscopy written by Tiago Buckup and published by Springer. This book was released on 2018-12-07 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Research in Political Economy

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Publisher : Emerald Group Pub Limited
ISBN 13 : 9780892323500
Total Pages : 303 pages
Book Rating : 4.3/5 (235 download)

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Book Synopsis Research in Political Economy by : Paul Zarembka

Download or read book Research in Political Economy written by Paul Zarembka and published by Emerald Group Pub Limited. This book was released on 1983 with total page 303 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analyzing society in a manner consistent with classical Marxism, this title deals primarily with economic and political issues and the unity between them. It includes both theoretical and empirical works.

Extreme Photonics & Applications

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Publisher : Springer Science & Business Media
ISBN 13 : 9048136334
Total Pages : 259 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Extreme Photonics & Applications by : Trevor Hall

Download or read book Extreme Photonics & Applications written by Trevor Hall and published by Springer Science & Business Media. This book was released on 2009-12-11 with total page 259 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Extreme Photonics & Applications" arises from the 2008 NATO Advanced Study Institute in Laser Control & Monitoring in New Materials, Biomedicine, Environment, Security and Defense. Leading experts in the manipulation of light offered by recent advances in laser physics and nanoscience were invited to give lectures in their fields of expertise and participate in discussions on current research, applications and new directions. The sum of their contributions to this book is a primer for the state of scientific knowledge and the issues within the subject of photonics taken to the extreme frontiers: molding light at the ultra-finest scales, which represents the beginning of the end to limitations in optical science for the benefit of 21st Century technological societies. Laser light is an exquisite tool for physical and chemical research. Physicists have recently developed pulsed lasers with such short durations that one laser shot takes the time of one molecular vibration or one electron rotation in an atom, which makes it possible to observe their internal electronic structure, thereby enabling the study of physical processes and new chemical reactions. In parallel, advances in micro- and nano-structured photonic materials allow the precise manipulation of light on its natural scale of a wavelength. Photonic crystals, plasmons and related metamaterials - composed of subwavelength nanostructures - permit the manipulation of their dispersive properties and have allowed the experimental confirmation of bizarre new effects such as slow light and negative refraction. These advances open a vista on a new era in which it is possible to build lasers and engineer materials to control and use photons as precisely as it is already possible to do with electrons. http://www.photonics.uottawa.ca/nato-asi-2008/

Ultrafast Multidimensional Vibrational Spectroscopy

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Publisher :
ISBN 13 :
Total Pages : 348 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Ultrafast Multidimensional Vibrational Spectroscopy by : Kusai Abid Merchant

Download or read book Ultrafast Multidimensional Vibrational Spectroscopy written by Kusai Abid Merchant and published by . This book was released on 2003 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Picosecond and Femtosecond Coherent Multidimensional Spectroscopy of Colloidal PbSe Quantum Dot Structure and Dynamics

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Publisher :
ISBN 13 :
Total Pages : 494 pages
Book Rating : 4.:/5 (817 download)

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Book Synopsis Picosecond and Femtosecond Coherent Multidimensional Spectroscopy of Colloidal PbSe Quantum Dot Structure and Dynamics by :

Download or read book Picosecond and Femtosecond Coherent Multidimensional Spectroscopy of Colloidal PbSe Quantum Dot Structure and Dynamics written by and published by . This book was released on 2012 with total page 494 pages. Available in PDF, EPUB and Kindle. Book excerpt: Multiresonant coherent multidimensional spectroscopy (MR-CMDS) is a fully coherent mixed frequency/time domain technique that selectively characterizes vibrational and electronic energetic structure and dynamics. The work reported here describes technique development with 1-picosecond pulses on model vibrational systems, application of this technique to PbSe quantum dots, and recent adaptation to include use of 50-femtosecond pulses. An overview of the quantum mechanical theory behind experimental design and interpretation, with an emphasis on the perturbative limit, is included. A record of the instrumentation and optical component selection associated with both laser systems is provided, which is particularly important for the development of the femtosecond laser table. Initial experiments on the femtosecond system revealed environmental artifacts that have now been identified and characterized. Picosecond pulses are not a good match for studying PbSe quantum dots with MR-CMDS because the pulses are too long to isolate coherence lifetimes and fully coherent processes. Frequency domain results previously acquired on the picosecond system revealed coherence lifetimes near 50fs, which directed the selection of a more appropriate laser system. Experiments with femtosecond pulses are now confirmed to directly measure coherence lifetimes and selectively emphasize spectral signatures from fully coherent processes that were not visible with longer pulses. These confirmations reveal that the flexibility of MR-CMDS techniques, as developed on the model vibrational systems, is available for quantum-confined semiconductor structures. Future directions include laser system improvements and suggestions of samples that may better inform dye-sensitized solar cell core charge transfer events.

Ultrafast Dynamics and Interfacial Structural Orientation Investigated with Multidimensional Vibrational Spectroscopy

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Publisher :
ISBN 13 :
Total Pages : 156 pages
Book Rating : 4.:/5 (111 download)

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Book Synopsis Ultrafast Dynamics and Interfacial Structural Orientation Investigated with Multidimensional Vibrational Spectroscopy by : Jiaxi Wang

Download or read book Ultrafast Dynamics and Interfacial Structural Orientation Investigated with Multidimensional Vibrational Spectroscopy written by Jiaxi Wang and published by . This book was released on 2019 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, two multidimensional spectroscopic methods--two-dimensional infrared (2D IR) spectroscopy and heterodyne 2D sum frequency generation (HD 2D SFG) spectroscopy--are applied to investigate ultrafast chemical exchange of organometallics in bulk solution and structural orientation of surface catalysts at interface, respectively. 2D IR spectroscopy is used to study the ultrafast chemical exchange of two organometallics compound ( Ru(S2C2(CF3)2)(CO)(PPh3)2 and Co(CNArMes2)4 ) occurring on the picosecond time scale. Combined with DFT simulation results, 2D IR provides direct evidence of the existence of various isomers. For the five-coordinate Ru complex, one isomers that serves as the intermediate of the axial-equatorial exchange was observed for the first time. Furthermore, our 2D IR works find the kinetic barriers of dynamic exchange between multiple isomers surprisingly low, consider both of the transition metal complexes under study have relatively large ligands. The low kinetic barriers are attributed to the small core-angle movement involved in the chemical exchange. 2D IR is also applied to W(CO)6/dual cavity system to observe ultrafast intercavity nonlinear polariton interactions. Combined with a newly developed theory model, we show that the nonlinear interaction is realized by shared molecular anharmonicities among cavity modes, e.g. through mode delocalization, some molecules (with anharmonicity) are coupled by cavity modes adjacent to each other. HD 2D SFG spectroscopy is used to study a model CO2 reduction catalyst, Re(diCNbpy)(CO)3Cl, as a monolayer on a gold surface. We show that short-range interactions with the surface can cause substantial line-shape differences between vibrational bands from the same molecules. This interaction can be explained as the result of couplings between CO vibrational modes of the catalyst molecules and the image dipoles on gold surface, which are sensitive to the relative distance between the molecule and the surface. Thus, by analysis of HD 2D SFG lineshape differences and polarization dependences of IR spectra, the ensemble-averaged orientation of the molecules on the surface can be determined unambiguously. The high sensitivity of HD 2D SFG spectra to short-range interactions can be applied to many other adsorbate-substrate interactions and therefore serve as a unique tool to determine adsorbate orientations on surfaces. Meanwhile, surface molecules of the monolayers can adopt conformations with many different orientations. Thus, it is necessary to describe the orientations of surface molecular monolayers using both mean tilt angle and orientational distribution, which together we refer to as orientation heterogeneity. Orientation heterogeneity is difficult to measure. In most cases, in order to calculate the mean tilt angle, it is assumed that the orientational distribution is narrow. This assumption causes ambiguities in determining the mean tilt angle and loss of orientational distribution information, which is known as the "magic angle" challenge. Using HD 2D SFG spectroscopy, we report a novel method to solve the "magic angle" challenge, by simultaneously measuring mean tilt angle and orientational distribution of molecular monolayers. Although applied to a specific system, this method is a general way to determine the orientation heterogeneity of an ensemble-averaged molecular interface.

Chemical Abstracts

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ISBN 13 :
Total Pages : 2710 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Abstracts by :

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2710 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ultrafast Phenomena in Molecular Sciences

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Publisher : Springer Science & Business Media
ISBN 13 : 331902051X
Total Pages : 298 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Ultrafast Phenomena in Molecular Sciences by : Rebeca de Nalda

Download or read book Ultrafast Phenomena in Molecular Sciences written by Rebeca de Nalda and published by Springer Science & Business Media. This book was released on 2013-10-22 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the latest developments in Femtosecond Chemistry and Physics for the study of ultrafast photo-induced molecular processes. Molecular systems, from the simplest H2 molecule to polymers or biological macromolecules, constitute central objects of interest for Physics, Chemistry and Biology, and despite the broad range of phenomena that they exhibit, they share some common behaviors. One of the most significant of those is that many of the processes involving chemical transformation (nuclear reorganization, bond breaking, bond making) take place in an extraordinarily short time, in or around the femtosecond temporal scale (1 fs = 10-15 s). A number of experimental approaches - very particularly the developments in the generation and manipulation of ultrashort laser pulses - coupled with theoretical progress, provide the ultrafast scientist with powerful tools to understand matter and its interaction with light, at this spatial and temporal scale. This book is an attempt to reunite some of the state-of-the-art research that is being carried out in the field of ultrafast molecular science, from theoretical developments, through new phenomena induced by intense laser fields, to the latest techniques applied to the study of molecular dynamics.

Multidimensional Time-Resolved Spectroscopy

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Publisher : Springer
ISBN 13 : 9783030024772
Total Pages : 0 pages
Book Rating : 4.0/5 (247 download)

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Book Synopsis Multidimensional Time-Resolved Spectroscopy by : Tiago Buckup

Download or read book Multidimensional Time-Resolved Spectroscopy written by Tiago Buckup and published by Springer. This book was released on 2019-01-21 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Directory of Graduate Research

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Publisher :
ISBN 13 :
Total Pages : 1932 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Directory of Graduate Research by : American Chemical Society. Committee on Professional Training

Download or read book Directory of Graduate Research written by American Chemical Society. Committee on Professional Training and published by . This book was released on 2005 with total page 1932 pages. Available in PDF, EPUB and Kindle. Book excerpt: Faculties, publications and doctoral theses in departments or divisions of chemistry, chemical engineering, biochemistry and pharmaceutical and/or medicinal chemistry at universities in the United States and Canada.

Physics Briefs

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Publisher :
ISBN 13 :
Total Pages : 1156 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Physics Briefs by :

Download or read book Physics Briefs written by and published by . This book was released on 1992 with total page 1156 pages. Available in PDF, EPUB and Kindle. Book excerpt:

J-aggregates

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Publisher : World Scientific
ISBN 13 : 9814365742
Total Pages : 529 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis J-aggregates by : Takayoshi Kobayashi

Download or read book J-aggregates written by Takayoshi Kobayashi and published by World Scientific. This book was released on 2012 with total page 529 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work deals with J-aggregates, which have a long history of research. The volume covers electronic states, linear and nonlinear optical properties. Various properties and processes of J-aggregates, such as super-radiance, excitons, photon echo, geometrical structure, electron transfer and femtosecond spectroscopy, are discussed.

Principles of Nonlinear Optical Spectroscopy

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Publisher : Oxford University Press on Demand
ISBN 13 : 9780195132915
Total Pages : 543 pages
Book Rating : 4.1/5 (329 download)

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Book Synopsis Principles of Nonlinear Optical Spectroscopy by : Shaul Mukamel

Download or read book Principles of Nonlinear Optical Spectroscopy written by Shaul Mukamel and published by Oxford University Press on Demand. This book was released on 1999 with total page 543 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook presents a systematic and unifying viewpoint for a wide class of nonlinear spectroscopic techniques in time domain and frequency domain. It is directed towards active researchers in physics, optics, chemistry, and materials science, as well as graduate students who enter this complex and rapidly developing field. Nonlinear optical interactions of laser fields with matter provide powerful spectroscopic tools for the understanding of microscopic interactions and dynamic processes. One of the major obstacles facing researchers in this field, however, is the flood of experimental techniques and terminologies, which create a serious language barrier. The general microscopic correlation function approach to the nonlinear optical response developed in this book is essential for understanding the relationships among different techniques and a comparison of their information content, the design of new measurements, and for a systematic comparison of the optical response of different systems such as dyes in solutions, atoms and molecules in the gas phase, liquids, molecular aggregates and superlatives, and semiconductor nanostructures. The approach is based on formulating the nonlinear response by representing the state of matter by the density matrix and following its evolution on Liouville space. Current active research areas such as femtosecond time-domain techniques, semi-classical and wave-packet dynamics, pulse shaping, pulse locking, exciton confinement, and the interplay of electronic, nuclear and field coherence are emphasized. The material has been developed from the author's highly successful interdisciplinary course at the University of Rochester attended by science and engineering graduate students.

Non-Photochemical Quenching and Energy Dissipation in Plants, Algae and Cyanobacteria

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Publisher : Springer
ISBN 13 : 9401790329
Total Pages : 672 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Non-Photochemical Quenching and Energy Dissipation in Plants, Algae and Cyanobacteria by : Barbara Demmig-Adams

Download or read book Non-Photochemical Quenching and Energy Dissipation in Plants, Algae and Cyanobacteria written by Barbara Demmig-Adams and published by Springer. This book was released on 2014-11-22 with total page 672 pages. Available in PDF, EPUB and Kindle. Book excerpt: Harnessing the sun’s energy via photosynthesis is at the core of sustainable production of food, fuel, and materials by plants, algae, and cyanobacteria. Photosynthesis depends on photoprotection against intense sunlight, starting with the safe removal of excess excitation energy from the light-harvesting system, which can be quickly and non-destructively assessed via non-photochemical quenching of chlorophyll fluorescence (NPQ). By placing NPQ into the context of whole-organism function, this book aims to contribute towards identification of plant and algal lines with superior stress resistance and productivity. By addressing agreements and open questions concerning photoprotection’s molecular mechanisms, this book contributes towards development of artificial photosynthetic systems. A comprehensive picture –from single molecules to organisms in ecosystems, and from leading expert’s views to practical information for non-specialists on NPQ measurement and terminology – is presented.

Annual Review

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Publisher :
ISBN 13 :
Total Pages : 274 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Annual Review by : 岡崎国立共同研究機構分子科学研究所

Download or read book Annual Review written by 岡崎国立共同研究機構分子科学研究所 and published by . This book was released on 1996 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: