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Morphology Control Of Noble Metal Nanoparticle Catalysts Using Strategic Organic Capping Agents In Colloidal Phase Synthesis
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Book Synopsis Morphology Control of Noble Metal Nanoparticle Catalysts Using Strategic Organic Capping Agents in Colloidal Phase Synthesis by : Kayla Mae Roeser
Download or read book Morphology Control of Noble Metal Nanoparticle Catalysts Using Strategic Organic Capping Agents in Colloidal Phase Synthesis written by Kayla Mae Roeser and published by . This book was released on 2014 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: Noble metals are the most sought after elements for catalysis because of their versatility, activity, and recyclability for a variety of applications; however they are limited as a resource and expensive. Noble metal nanoparticles offer a solution for use in catalysis because their high surface area to volume ratio maximizes their available surface sites while minimizing the amount of metal used. Additionally, particularly exposed facets of nanoparticles can increase surface energies for superior catalytic activity and induce novel electronic/physical properties. In the first chapter of my thesis, I synthesized palladium, platinum, and semiconductor titania nanoparticles through a biomimetic approach by using peptides to preferentially bind to and expose particular crystal facets of nanoparticles. Using a combinatorial approach called biopanning to find highly selective surface energy modifiers for particular facets of materials gave insight to unique binding motifs for materials as well as induced morphology controlled nanoparticles at ambient conditions. There are limitless combinations of solvents, capping agents, and inorganic precursors for inorganic nanoparticle synthesis. Understanding these systems in terms of more global trends would circumvent the current colossal approach of empirically screening systems. To do this, considering the inorganic-organic interfacial relationship is key. In the second chapter, I report unique aryl small molecules which preferentially bind to palladium surfaces through electrostatic potentials and epitaxial binding in nanoparticle synthesis. These results offer an understanding to the dynamic binding relationship between capping agents and nanoparticle surfaces. Lastly, I report on the synthesis of gold-palladium nanoparticles and their activity for the benzyl alcohol oxidation reaction. It was found that the (100) facets of gold-palladium were more catalytically active than the (111) surface. Details of the nanoparticle shape, size, and activity add to the understanding how this material behaves at the atomic level and will help to impact future advances in this field of catalysis. The syntheses described here are important because they are environmentally friendly, they offer information about the binding mechanisms at the organic-inorganic interface of the systems, and give insight to catalytic behavior. All of this work is necessary to further exploit nanoparticle synthesis, assembly and provide the precise engineering of nanostructured materials.
Book Synopsis Morphology Control in Colloidal Metal Nanoparticle Synthesis and Their Application to Catalysis by : Romen Padilla
Download or read book Morphology Control in Colloidal Metal Nanoparticle Synthesis and Their Application to Catalysis written by Romen Padilla and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanoparticles in Catalysis by : Karine Philippot
Download or read book Nanoparticles in Catalysis written by Karine Philippot and published by John Wiley & Sons. This book was released on 2021-04-29 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.
Book Synopsis Plant Mediated Synthesis of Metal Nanoparticles by : Anita Rani
Download or read book Plant Mediated Synthesis of Metal Nanoparticles written by Anita Rani and published by Bentham Science Publishers. This book was released on 2024-05-30 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides valuable knowledge about environmentally friendly methods of nanoparticle synthesis. The contents present information about the subject from synthesis, characterization, advantages, disadvantages, route of administrations up to effects of drug combinations. Starting with an introduction to the concept of green nanoparticles, the book summarizes different types of plant extracts and their components. Green methods for preparing nanotherapeutic agents utilizing algae and marine plants to synthesize metal based nanoparticles are also explained. The book also places an emphasis on the improvement of metal nanoparticle formulations with polymers for antibacterial applications. A detailed review of the interaction of nanoparticles with or without drugs rounds the contents, with a guide to easily understand their site of action along with suitable reactions in the body. This book is a primer on nanoparticle synthesis for pharmacology or nanomedicine programs that focus on sustainable and environmentally friendly methodologies for synthesizing therapeutics.
Book Synopsis Application of Transition Metal Catalysts in Organic Synthesis by : L. Brandsma
Download or read book Application of Transition Metal Catalysts in Organic Synthesis written by L. Brandsma and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.
Book Synopsis Nanotechnology in Catalysis 3 by : Bing Zhou
Download or read book Nanotechnology in Catalysis 3 written by Bing Zhou and published by Springer Science & Business Media. This book was released on 2007-09-05 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume continues the tradition formed in Nanotechnology in Catalysis 1 and 2. As with those books, this one is based upon an ACS symposium. Some of the most illustrious names in heterogeneous catalysis are among the contributors. The book covers: Design, synthesis, and control of catalysts at nanoscale; understanding of catalytic reaction at nanometer scale; characterization of nanomaterials as catalysts; nanoparticle metal or metal oxides catalysts; nanomaterials as catalyst supports; new catalytic applications of nanomaterials.
Book Synopsis Directed Synthesis by : David J. Fisher
Download or read book Directed Synthesis written by David J. Fisher and published by Materials Research Forum LLC. This book was released on 2023-11-05 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure-directed synthesis aims at the design and preparation of novel solid-state structures; using the structure-directing capability of some molecular additive, the so-called structure-directing agent. This general train of thought has led to the development of many weird and wonderful strategies. The book presents an in-depth review of the field and discusses the potential for further developments. Some of the topics are listed under ‘Keywords’. The book references 343 original resources with their direct web links for in-depth reading. Keywords: Directed Synthesis, Multicomponent Colloidal Nanostructures, Nanoparticle-Seed Surfaces, Photocatalytic and Photo-Electrochemical Applications, Synthesis of Nanostructured Metal Oxides and Metal Oxalates, Wide-Bandgap Semiconductors and Metals with Surface Plasmon-Resonance Active Bands, Mesoporous Materials Possessing Multilevel Architectures, Spatially Distinct Nanostructured Organic and Inorganic Arrays, 2- and 3-Dimensional Periodic Composite Structures, Protein-Protein Interaction and DNA Hybridization, Polynuclear Complexes and Coordination Polymers of 3d Metals, Ultra-Small Metal Nanoclusters, Biomolecule-Nanocluster Composites, Nanostructured Sulphur-Carbon Nanotube Cathode.
Book Synopsis Nanoparticles for Catalysis by : Hermenegildo García
Download or read book Nanoparticles for Catalysis written by Hermenegildo García and published by MDPI. This book was released on 2018-07-04 with total page 165 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Nanoparticles for Catalysis" that was published in Nanomaterials
Book Synopsis Contextualizing Noble Metal Nanoparticle Morphology and Sustainable Catalysis Through Plasmon-mediated Closed-loop Reconfiguration and in Situ DRIFTS Experimentation by : Dylan Robert Judd
Download or read book Contextualizing Noble Metal Nanoparticle Morphology and Sustainable Catalysis Through Plasmon-mediated Closed-loop Reconfiguration and in Situ DRIFTS Experimentation written by Dylan Robert Judd and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanoparticles in Catalysis by : Shū Kobayashi
Download or read book Nanoparticles in Catalysis written by Shū Kobayashi and published by Springer Nature. This book was released on 2020-11-06 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume discusses the great potential of metal nanoparticle catalysts for complicated molecular synthesis and reviews the current progress of this field. The development of highly active and stable heterogeneous catalysts is a crucial subject in modern science. However, development of heterogeneous catalysts for fine chemical synthesis has lagged far behind those for bulk chemical process. In recent years metal nanoparticle catalysts have been of great interest in this area due to their unique activity, ease of heterogenization, and robustness. Therefore, metal nanoparticle catalysts are an excellent candidate for the above-mentioned active and robust heterogeneous catalysts and this book provides an overview of this area. The present volume summarizes recent progress on nanoparticle catalysis for various organic transformations from simple redox reactions to complex asymmetric C–C bond forming reactions and also presents seminal studies on new technologies. It comprehensively summarizes advances in metal nanoparticle catalysis across several aspects including reaction manners, mechanistic investigations and new synthetic methodologies to encourage the use of metal nanoparticle catalysts for future organic synthesis. This volume will be of interest to students, researchers and professionals focused on the next-generation of fine chemical synthesis.
Book Synopsis Recent Advances in Nanoparticle Catalysis by : Piet W.N.M. van Leeuwen
Download or read book Recent Advances in Nanoparticle Catalysis written by Piet W.N.M. van Leeuwen and published by Springer Nature. This book was released on 2020-07-01 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the latest developments in the field of nanoparticle catalysis. It not only discusses established topics in detail, but also explores several emerging topics. Catalysis with nanoparticles is expanding exponentially and is attracting significant interest due to the many exciting findings being reported. Mastering the synthesis, characterization, stabilization and use of these catalysts offers numerous possibilities that far exceed those of classic heterogeneous and homogeneous catalysis.
Book Synopsis Nanocatalysts in Environmental Applications by : Samira Bagheri
Download or read book Nanocatalysts in Environmental Applications written by Samira Bagheri and published by Springer. This book was released on 2018-02-09 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a range of nanocatalysts, together with their primary environmental applications and use in chemical production processes. In addition, it describes the nanomaterials used for catalysts and details their performance. The book introduces readers to the fundamentals and applications of nanocatalysis, synthesis, characterization, modification and application. Further topics include: landfill organic pollutant photodegradation; magnetic photocatalysis; synergistic effects on hydrogenated TiO2; and photoinduced fusion of gold-semiconductor nanoparticles. A detailed explanation of the chemistry of nanostructures and the ability to control materials at the nano-scale rounds out the coverage. Given the central importance of research in nanotechnology and nanoscience for the development of new catalysts, the book offers a valuable source of information for researchers and academics alike. It will also benefit industrial engineers and production managers who wish to understand the environmental impact of nanocatalysts.
Book Synopsis Synthesis and Characterization of Transition-metal Nanocrystals and Their Application in Catalysis by : Guangjun Cheng
Download or read book Synthesis and Characterization of Transition-metal Nanocrystals and Their Application in Catalysis written by Guangjun Cheng and published by . This book was released on 2003 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanocatalysis by : Vivek Polshettiwar
Download or read book Nanocatalysis written by Vivek Polshettiwar and published by John Wiley & Sons. This book was released on 2013-09-06 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors’ first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book’s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.
Book Synopsis Colloidal Nanoparticles for Heterogeneous Catalysis by : Priscila Destro
Download or read book Colloidal Nanoparticles for Heterogeneous Catalysis written by Priscila Destro and published by Springer. This book was released on 2018-12-13 with total page 89 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explores the formation of colloidal gold–copper (AuCu) alloy nanoparticles and evaluate their application in heterogeneous catalysis. Metal alloys are extremely versatile materials that have been used since the Antiquity to improve the properties of commonly used metals, therefore the understanding of their properties has fostered the applications in areas such as photonics, sensors, clinical diagnostics, and especially in heterogeneous catalysis, which allows catalyst active sites to be modulated. In this book, readers will appreciate the fundamental aspects involved in the synthesis of AuCu nanoalloys, including real-time information about their atomic organization, electronic properties, as well a deeper understand about the behavior of AuCu supported nanoalloys under real catalytic conditions, providing interesting insights about the effect of the support on the nanoalloy stability. The results presented here open new horizons for using metal alloys in catalysis and also other areas where the metal–support interface may play a crucial role.
Book Synopsis Nanotechnology in Catalysis by : Bert Sels
Download or read book Nanotechnology in Catalysis written by Bert Sels and published by John Wiley & Sons. This book was released on 2017-06-20 with total page 1500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reflecting the R&D efforts in the field that have resulted in a plethora of novel applications over the past decade, this handbook gives a comprehensive overview of the tangible benefits of nanotechnology in catalysis. By bridging fundamental research and industrial development, it provides a unique perspective on this scientifically and economically important field. While the first three parts are devoted to preparation and characterization of nanocatalysts, the final three provide in-depth insights into their applications in the fine chemicals industry, the energy industry, and for environmental protection, with expert authors reporting on real-life applications that are on the brink of commercialization. Timely reading for catalytic chemists, materials scientists, chemists in industry, and process engineers.
Book Synopsis Metal Oxide Nanoparticles in Organic Solvents by : Markus Niederberger
Download or read book Metal Oxide Nanoparticles in Organic Solvents written by Markus Niederberger and published by Springer Science & Business Media. This book was released on 2009-09-17 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanoparticles in Organic Solvents discusses recent advances in the chemistry involved for the controlled synthesis and assembly of metal oxide nanoparticles, the characterizations required by such nanoobjects, and their size and shape depending properties. In the last few years, a valuable alternative to the well-known aqueous sol-gel processes was developed in the form of nonaqueous solution routes. Metal Oxide Nanoparticles in Organic Solvents reviews and compares surfactant- and solvent-controlled routes, as well as providing an overview of techniques for the characterization of metal oxide nanoparticles, crystallization pathways, the physical properties of metal oxide nanoparticles, their applications in diverse fields of technology, and their assembly into larger nano- and mesostructures. Researchers and postgraduates in the fields of nanomaterials and sol-gel chemistry will appreciate this book’s informative approach to chemical formation mechanisms in relation to metal oxides.
