Molybdenum(VI) Dioxo Complexes: Synthesis, Characterization and Catalytic Application in Olefin Epoxidation

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ISBN 13 : 9783868534030
Total Pages : 169 pages
Book Rating : 4.5/5 (34 download)

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Book Synopsis Molybdenum(VI) Dioxo Complexes: Synthesis, Characterization and Catalytic Application in Olefin Epoxidation by : Alev Günyar

Download or read book Molybdenum(VI) Dioxo Complexes: Synthesis, Characterization and Catalytic Application in Olefin Epoxidation written by Alev Günyar and published by . This book was released on 2010 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, Characterization and Catalytic Activity of Molybdenum(VI) Di- and Monooxo Aryloxides

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (271 download)

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Book Synopsis Synthesis, Characterization and Catalytic Activity of Molybdenum(VI) Di- and Monooxo Aryloxides by : Mauricio Quiroz-Guzmán

Download or read book Synthesis, Characterization and Catalytic Activity of Molybdenum(VI) Di- and Monooxo Aryloxides written by Mauricio Quiroz-Guzmán and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of molybdenum is immensely rich and diverse. Molybdenum is essential for life, and has many applications in industry. The first chapter offers a general perspective of the chemistry of molybdenum in high oxidation states dominated by diverse oxo species, such as the MoO22+ and MoO4+ units that are focus of my research. I describe the importance of MoO22+ complexes as models for the active sites of oxo transfer molybdoenzymes (e.g. DMSO oxidase) and for industrial heterogeneous transformation such as the SOHIO process (one of our ultimate goals). I also outline the importance of MoO4+ complexes as procatalysts for metathesis polymerization and as models of deoxygenated active sites of MoO22+ oxygen catalysts that have triggered our interest. The second chapter introduces the synthesis and full characterization of 4-, 5- and 6-coordinated MoO2(OAr)2L0-1 complexes with bulky aryloxide ligands, starting from the MoO2Cl2 or MoO2Cl2(DMF)2 precursors. Steric and electronic modifications in the aryloxide moieties were performed in order to understand their effect in the final structure and yields of the synthesized complexes. The nature and mechanism of formation of the radical species detected in their synthesis is proposed. The third chapter presents the facile synthesis of varios MoO(OAr)4-nCln complexes starting from the MoO2Cl2 precursor. Their mechanism of formation is proposed and the supporting evidence for this new reaction is provided. Steric and electronic modifications in the aryloxide moieties were used to study their structural and electronic effects in the MoO4+ complexes. The fourth chapter outlines the synthesis of Mo(VI) monooxo bisphenoxides with a characteristic cis-chloro cis-bisphoxide arrangement around the MoO4+ unit. Electronic and steric modifications in the bisphenoxide rings were done to determine their effect in the structure and reactivity of the final complexes. The fifth chapter introduces the application of the synthesized MoO(OAr)4-nCln and MoO(bisphenoxides)2Cl2 complexes as procatalysts for olefin metathesis polymerization of norbornene. The correlation between structure and reactivity of the procatalyst is discussed.

Rhenium and Molybdenum Oxo Complexes

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ISBN 13 : 9783934767225
Total Pages : 205 pages
Book Rating : 4.7/5 (672 download)

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Book Synopsis Rhenium and Molybdenum Oxo Complexes by : Ana Santos

Download or read book Rhenium and Molybdenum Oxo Complexes written by Ana Santos and published by . This book was released on 2000 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis And Applications In Chemistry And Materials (In 4 Volumes)

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Publisher : World Scientific
ISBN 13 : 9811279950
Total Pages : 2103 pages
Book Rating : 4.8/5 (112 download)

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Book Synopsis Synthesis And Applications In Chemistry And Materials (In 4 Volumes) by : Armando J L Pombeiro

Download or read book Synthesis And Applications In Chemistry And Materials (In 4 Volumes) written by Armando J L Pombeiro and published by World Scientific. This book was released on 2024-01-16 with total page 2103 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemistry and Material Sciences naturally depend greatly on Synthesis as the initial stage for the existence of compounds and materials with desired behaviors, within the overall streamline of Design/Synthesis — Properties — Application/Function, and their relations. Such a general approach is of a too wide scope to be properly treated in a single set of publications, but this one on 'Synthesis and Applications in Chemistry and Materials' restricts itself by aiming to show the strength and international character of the current research in synthetic chemistry that is being developed in Portugal or abroad by teams that cooperate with this country. Hence, it gathers representative contributions of main Portuguese research groups and foreign collaborating ones. Nevertheless, the topic should be understood in a wide sense, being open to types of studies with significance on sustainable synthesis and applications in chemistry, materials and/or related sciences.

Zeitschrift Für Naturforschung

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ISBN 13 :
Total Pages : 940 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Zeitschrift Für Naturforschung by :

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Homogeneous Oxidation Reactions

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Publisher : Elsevier
ISBN 13 : 0443156212
Total Pages : 346 pages
Book Rating : 4.4/5 (431 download)

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Book Synopsis Homogeneous Oxidation Reactions by : Mohammad Reza Rahimpour

Download or read book Homogeneous Oxidation Reactions written by Mohammad Reza Rahimpour and published by Elsevier. This book was released on 2024-09-27 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous Oxidation Reactions, a volume in the Advances Homogeneous in Catalysis series, covers oxidation and hydrogenation reactions in detail. Split into two sections, the first is devoted to various homogeneous oxidation processes, such as oxidation of olefins, phenols, and aromatic acids. The second presents homogeneous hydrogenation reactions and related processes, including hydrogenation of alkenes, esters, and olefins. Relevant reactor design, industrial case studies, economic analysis and environmental issues of both oxidation and hydrogenation homogeneous reactions are considered. This book will be of particular interest and benefit to catalysts users, manufacturers, and creators. Includes fundamentals, reactor design and process description of oxidation homogeneous reactions Describes various oxidation homogeneous reactions Explains oxidation economic and environmental challenges

Synthesis of Molybdenum(VI) Alkylidene Complexes as Catalysts for Living Polymerizations of Terminal Acetylenes and Olefin Metathesis

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ISBN 13 :
Total Pages : 558 pages
Book Rating : 4.:/5 (299 download)

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Book Synopsis Synthesis of Molybdenum(VI) Alkylidene Complexes as Catalysts for Living Polymerizations of Terminal Acetylenes and Olefin Metathesis by : Harold Hamilton Fox

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Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry

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Publisher : World Scientific
ISBN 13 : 1783263342
Total Pages : 1035 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by : Daniel Duprez

Download or read book Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry written by Daniel Duprez and published by World Scientific. This book was released on 2014-07-24 with total page 1035 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.

Metal Organic Frameworks as Heterogeneous Catalysts

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849735727
Total Pages : 446 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Metal Organic Frameworks as Heterogeneous Catalysts by : Francesc X. Llabrés i Xamena

Download or read book Metal Organic Frameworks as Heterogeneous Catalysts written by Francesc X. Llabrés i Xamena and published by Royal Society of Chemistry. This book was released on 2013-07-01 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.

Semicarbazones—Advances in Research and Application: 2013 Edition

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Publisher : ScholarlyEditions
ISBN 13 : 149010450X
Total Pages : 56 pages
Book Rating : 4.4/5 (91 download)

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Book Synopsis Semicarbazones—Advances in Research and Application: 2013 Edition by :

Download or read book Semicarbazones—Advances in Research and Application: 2013 Edition written by and published by ScholarlyEditions. This book was released on 2013-05-01 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semicarbazones—Advances in Research and Application: 2013 Edition is a ScholarlyBrief™ that delivers timely, authoritative, comprehensive, and specialized information about ZZZAdditional Research in a concise format. The editors have built Semicarbazones—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about ZZZAdditional Research in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Semicarbazones—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Chiral Molybdenum and Tungsten Imido Alkylidene Complexes as Catalysts for Asymmetric Ring-closing Metathesis (ARCM)

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ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (445 download)

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Book Synopsis Chiral Molybdenum and Tungsten Imido Alkylidene Complexes as Catalysts for Asymmetric Ring-closing Metathesis (ARCM) by : John Bryson Alexander

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Third Report on Organization in Industry, Commerce and the Professions in Canada

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ISBN 13 :
Total Pages : 106 pages
Book Rating : 4.:/5 (72 download)

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Book Synopsis Third Report on Organization in Industry, Commerce and the Professions in Canada by :

Download or read book Third Report on Organization in Industry, Commerce and the Professions in Canada written by and published by . This book was released on 1924 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterisation of Some Molybdenum Complexes and Their Use as Epoxidation Catalysts

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ISBN 13 :
Total Pages : 400 pages
Book Rating : 4.:/5 (94 download)

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Book Synopsis Synthesis and Characterisation of Some Molybdenum Complexes and Their Use as Epoxidation Catalysts by :

Download or read book Synthesis and Characterisation of Some Molybdenum Complexes and Their Use as Epoxidation Catalysts written by and published by . This book was released on 1986 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Inorganic Chemistry

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Publisher : Academic Press
ISBN 13 : 0124046401
Total Pages : 341 pages
Book Rating : 4.1/5 (24 download)

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Book Synopsis Advances in Inorganic Chemistry by :

Download or read book Advances in Inorganic Chemistry written by and published by Academic Press. This book was released on 2013-01-03 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. Features comprehensive reviews on the latest developments Includes contributions from leading experts in the field Serves as an indispensable reference to advanced researchers

Molybdenum and Tungsten Enzymes

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782628843
Total Pages : 341 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Molybdenum and Tungsten Enzymes by : Russ Hille

Download or read book Molybdenum and Tungsten Enzymes written by Russ Hille and published by Royal Society of Chemistry. This book was released on 2016-10-10 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: There has been enormous progress in our understanding of molybdenum and tungsten enzymes and relevant inorganic complexes of molybdenum and tungsten over the past twenty years. This set of three books provides a timely and comprehensive overview of the field and documents the latest research. Building on the first and second volumes that focussed on biochemistry and bioinorganic chemistry aspects, the third volume focusses on spectroscopic and computational methods that have been applied to both enzymes and model compounds. A particular emphasis is placed on how these important studies have been used to reveal critical components of enzyme mechanisms. This text will be a valuable reference to workers both inside and outside the field, including graduate students and young investigators interested in developing new research programs in this area.

Synthesis and Catalytic Application of Monomeric Organomolybdenum Complexes

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ISBN 13 : 9783899631487
Total Pages : 432 pages
Book Rating : 4.6/5 (314 download)

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Book Synopsis Synthesis and Catalytic Application of Monomeric Organomolybdenum Complexes by : Jin Zhao

Download or read book Synthesis and Catalytic Application of Monomeric Organomolybdenum Complexes written by Jin Zhao and published by . This book was released on 2005 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metallomics and the Cell

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Publisher : Springer Science & Business Media
ISBN 13 : 9400755619
Total Pages : 642 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Metallomics and the Cell by : Lucia Banci

Download or read book Metallomics and the Cell written by Lucia Banci and published by Springer Science & Business Media. This book was released on 2013-04-18 with total page 642 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metallomics and the Cell provides in an authoritative and timely manner in 16 stimulating chapters, written by 37 internationally recognized experts from 9 nations, and supported by more than 3000 references, several tables, and 110 illustrations, mostly in color, a most up-to-date view of the "metallomes" which, as defined in the "omics" world, describe the entire set of biomolecules that interact with or are affected by each metal ion. The most relevant tools for visualizing metal ions in the cell and the most suitable bioinformatic tools for browsing genomes to identify metal-binding proteins are also presented. Thus, MILS-12 is of relevance for structural and systems biology, inorganic biological chemistry, genetics, medicine, diagnostics, as well as teaching, etc.