Mixed Valence Systems

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Mixed-Valence Systems

Author : Yuwu Zhong
Publisher : John Wiley & Sons
ISBN 13 : 3527349804
Total Pages : 517 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Mixed-Valence Systems by : Yuwu Zhong

Download or read book Mixed-Valence Systems written by Yuwu Zhong and published by John Wiley & Sons. This book was released on 2023-05-30 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.

Mixed Valency Systems: Applications in Chemistry, Physics and Biology

Author : K. Prassides
Publisher : Springer Science & Business Media
ISBN 13 : 9401136068
Total Pages : 456 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Mixed Valency Systems: Applications in Chemistry, Physics and Biology by : K. Prassides

Download or read book Mixed Valency Systems: Applications in Chemistry, Physics and Biology written by K. Prassides and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed valency is one of various names used to describe compounds which contain ions of the same element in two different formal states of oxidation. The existence of mixed valency systems goes far back into the geological evolutionary history of the earth and other planets, while a plethora of mixed valency minerals has attracted attention since antiquity. Indeed, control of the oxidation states of Fe in its oxides (FeO, Fe304' Fe203) was elegantly used in vase painting by the ancient Greeks to produce the characteristic black and red Attic ceramics (Z. Goffer, "Archaeological Chemistry", Wiley, New York, 1980). It was, however, only 25 years ago that two reviews of mixed valency appeared in the literature almost simultaneously, signalling the first attempt to treat mixed valency systems as a separate class of compounds whose properties can be correlated with the molecular and the electronic structure of their members. Then mixed valency phenomena attracted the interest of disparate classes of scientists, ranging from synthetic chemists to solid state physicists and from biologists to geologists. This activity culminated with the NATO ASI meeting in Oxford in 1979. The 1980's saw again a continuing upsurge of interest in mixed valency. Its presence is a necessary factor in the search for highly conducting materials, including molecular metals and superconductors. The highly celebrated high T c ceramic superconducting oxides are indeed mixed valency compounds.

Mixed-Valence Compounds

Author : D.B. Brown
Publisher : Springer Science & Business Media
ISBN 13 : 9400990766
Total Pages : 517 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Mixed-Valence Compounds by : D.B. Brown

Download or read book Mixed-Valence Compounds written by D.B. Brown and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has been a decade since two seminal reviews demonstrated that mixed-valence compounds share many unique and fascinating features. The insight pro vided by those early works has promoted a great deal of both experimental and theoretical study. As a result of extensive efforts, our understanding of the bonding and properties of mixed-valence compounds has advanced substantially. There has been no compre hensive treatment of mixed-valence compounds since 1967, and the meeting convened at Oxford in September, 1979, provided a unique opportunity to examine the subject and its many ramifications. Mixed-valence compounds play an important role in many fields. Although the major impact of the subject has been in chemistry, its importance has become increasingly clear in solid state physics, geology, and biology. Extensive interest and effort in the field of molecular metals has demonstrated that mixed-valency is a prerequisite for high elec trical conductivity. The intense colors of many minerals have been shown to be due to mixed-valency, and the electron-transfer properties of certain mixed-valence metalloproteins are important in biological processes. Experts from all of these areas participated in this meeting, and the truly interdisciplinary nature of the subject made it a unique learning experience for all in attendance.

Advances in Inorganic Chemistry

Author :
Publisher : Academic Press
ISBN 13 : 008057890X
Total Pages : 489 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Inorganic Chemistry by :

Download or read book Advances in Inorganic Chemistry written by and published by Academic Press. This book was released on 1994-09-29 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Inorganic Chemistry presents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry ranging from bio-inorganic to solid state studies. Thisacclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistry contains an index, and each chapter is fully referenced.

Molecules Into Materials: Case Studies In Materials Chemistry - Mixed Valency, Magnetism And Superconductivity

Author : Peter Day
Publisher : World Scientific
ISBN 13 : 9814476994
Total Pages : 607 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Molecules Into Materials: Case Studies In Materials Chemistry - Mixed Valency, Magnetism And Superconductivity by : Peter Day

Download or read book Molecules Into Materials: Case Studies In Materials Chemistry - Mixed Valency, Magnetism And Superconductivity written by Peter Day and published by World Scientific. This book was released on 2007-01-24 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last decade has seen the emergence and explosive growth of a new field of condensed matter science: materials chemistry. Transcending the traditional boundaries of organic, inorganic and physical chemistry, this new approach aims to create new molecular and lattice ensembles with unusual physical properties. One of its pioneers, the author has worked on structure-property relations in the inorganic and metal-organic solid state for over 40 years. His seminal work on mixed-valency compounds and inorganic charge transfer spectra in the 1960s set the scene for this new type of chemistry, and his discovery of transparent metal-organic ferromagnets in the 1970s laid the ground rules for much current work on molecular magnets. He has also published extensively on molecular metals and superconductors, especially on charge transfer salts combining conductivity with magnetism. This indispensable volume brings together for the first time a selection of his articles on all these topics, grouped according to theme. Each group is prefaced by a brief introduction for the general reader, putting the articles into their context in the evolution of the subject and describing the intellectual circumstances in which each project was conceived and executed.

Mixed-Valence Systems

Author : Yu-Wu Zhong
Publisher : John Wiley & Sons
ISBN 13 : 352783527X
Total Pages : 517 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Mixed-Valence Systems by : Yu-Wu Zhong

Download or read book Mixed-Valence Systems written by Yu-Wu Zhong and published by John Wiley & Sons. This book was released on 2023-03-09 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mixed-Valence Systems Comprehensive overview on the advanced development of mixed-valence chemistry Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics. In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as: Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.

Correlations in Clusters and Related Systems

Author : Jean-patrick Connerade
Publisher : World Scientific
ISBN 13 : 9814530948
Total Pages : 274 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Correlations in Clusters and Related Systems by : Jean-patrick Connerade

Download or read book Correlations in Clusters and Related Systems written by Jean-patrick Connerade and published by World Scientific. This book was released on 1996 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Correlations In Clusters And Related Systems, New Perspectives On The Many-body Problem

Author : Jean-patrick Connerade
Publisher : World Scientific
ISBN 13 : 9814547581
Total Pages : 274 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Correlations In Clusters And Related Systems, New Perspectives On The Many-body Problem by : Jean-patrick Connerade

Download or read book Correlations In Clusters And Related Systems, New Perspectives On The Many-body Problem written by Jean-patrick Connerade and published by World Scientific. This book was released on 1996-05-25 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: This proceedings volume describes many-body effects in highly correlated systems with special emphasis on metal clusters and transition from the free atom to the solid state limit and on strong laser field effects. The interdisciplinary nature of the subject should be stressed: clusters are a novel area of research, involving atomic, molecular, solid state and nuclear physics.

Rare Earth Transition Metal Borocarbides (Nitrides)

Author : Karl-Hartmut Müller
Publisher : Springer Science & Business Media
ISBN 13 : 9780792368793
Total Pages : 470 pages
Book Rating : 4.3/5 (687 download)

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Book Synopsis Rare Earth Transition Metal Borocarbides (Nitrides) by : Karl-Hartmut Müller

Download or read book Rare Earth Transition Metal Borocarbides (Nitrides) written by Karl-Hartmut Müller and published by Springer Science & Business Media. This book was released on 2001-03-31 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the NATO Advanced Research Workshop, Dresden, Germany, June 13-18, 2000

Electron Spin Resonance

Author : P B Ayscough
Publisher : Royal Society of Chemistry
ISBN 13 : 1847553400
Total Pages : 450 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Electron Spin Resonance by : P B Ayscough

Download or read book Electron Spin Resonance written by P B Ayscough and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Comprehensive Coordination Chemistry II

Author : J. A. McCleverty
Publisher : Newnes
ISBN 13 : 0080913164
Total Pages : 11845 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Advances in Inorganic Chemistry and Radiochemistry

Author :
Publisher : Academic Press
ISBN 13 : 0080578594
Total Pages : 481 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Inorganic Chemistry and Radiochemistry by :

Download or read book Advances in Inorganic Chemistry and Radiochemistry written by and published by Academic Press. This book was released on 1967 with total page 481 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Inorganic Chemistry and Radiochemistry

Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions

Author : L.C. Gupta
Publisher : Springer Science & Business Media
ISBN 13 : 1461309476
Total Pages : 749 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions by : L.C. Gupta

Download or read book Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions written by L.C. Gupta and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 749 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the Koln meeting (August 28-31, 1984), Irdia was chosen as the venue for the next International Conference on Valence Fluctuations. lhis was in recognition ard appreciation of the work done, both experimental ard theoretical, by the Irdian scientists in this area during the last decade. We decided to hold this Conference in the month of January, 1987 at Bangalore. lhe subject of Valence Fluctuations has kept itself alive ard active as it has provided many shocks ard suprises particularly among the Ce- ard U-based intermetallies. lhe richness of many interesting physical phenomena occurring in mixed valent materials, the flexibility of modifying their physical properties (by alloying, for example) ard the possibility of synthesizing a wide variety of new such materials seem to be the key factors in this regard. Barely six months before this Conference, an International Conference on Anomalous Rare Earths and Actinides (ICAREA) had been held at Grenoble (July, 1986) which also focussed on mixed valence ard heavy fermion phenomena. In spite of this, the response to this' Conference was very enthusiastic and encouraging. Many interesting ard important results were presented at this Conference which have been included in this volume.

Progress in Inorganic Chemistry, Volume 28

Author : Stephen J. Lippard
Publisher : John Wiley & Sons
ISBN 13 : 0470166797
Total Pages : 474 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Progress in Inorganic Chemistry, Volume 28 by : Stephen J. Lippard

Download or read book Progress in Inorganic Chemistry, Volume 28 written by Stephen J. Lippard and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 474 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.

Moment Formation In Solids

Author : W. J. L. Buyers
Publisher : Springer Science & Business Media
ISBN 13 : 1475715382
Total Pages : 341 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Moment Formation In Solids by : W. J. L. Buyers

Download or read book Moment Formation In Solids written by W. J. L. Buyers and published by Springer Science & Business Media. This book was released on 2013-12-01 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: The problem of moment formation in metallic systems lies at the interface of localized and itinerant magnetism. The phenomena observed correspond to destruction rather than to formation of spin-correlations. They give rise to the progression from local ized ground states through Kondo and mixed-valence behaviour to itinerant magnetic or non-magnetic systems. Somewhere in the pro gression superconductivity can occur in the presence of f-moments. To bring together the disparate ideas and methods, previously the subject of intense debate only at a number of topical confer ences, a two-week Advanced Study Institute was held August 21 - September 02, 1983, at Lester B. Pearson College of the Pacific, Vancouver Island. In the stimulating environment provided by the pines and fiord at the site of this remote United World College on the Canadian West Coast, scientists and students from around the globe gathered to hear lectures by experts. The Study Institute involved seventy-six people and followed in the tradition . of pre vious "Banff" summer schools organized by the Canadian Association of Physicists. It was made possible by grants from the North Atlantic Treaty Organization, the Natural Sciences & Engineering Research Council of Canada and Atomic Energy of Canada. The grants permitted many young scientists from Nato and non-Nato countries to learn the fundamentals as well as the latest results in the field.

Electrons in Molecules

Author : Jean-Pierre Launay
Publisher : Oxford University Press, USA
ISBN 13 : 0199297789
Total Pages : 511 pages
Book Rating : 4.1/5 (992 download)

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Book Synopsis Electrons in Molecules by : Jean-Pierre Launay

Download or read book Electrons in Molecules written by Jean-Pierre Launay and published by Oxford University Press, USA. This book was released on 2014 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to provide the reader with essential keys to a unified understanding of the rapidly expanding field of molecular materials and devices: electronic structures and bonding, magnetic, electrical and photo-physical properties, and the mastering of electrons in molecular electronics. Chemists will discover how basic quantum concepts allow us to understand the relations between structures, electronic structures, and properties of molecular entities and assemblies, and to design new molecules and materials. Physicists and engineers will realize how the molecular world fits in with their need for systems flexible enough to check theories or provide original solutions to exciting new scientific and technological challenges. The non-specialist will find out how molecules behave in electronics at the most minute, sub-nanosize level. The comprehensive overview provided in this book is unique and will benefit undergraduate and graduate students in chemistry, materials science, and engineering, as well as researchers wanting a simple introduction to the world of molecular materials.

Mössbauer Effect Methodology

Author : Irwin J. Gruverman
Publisher : Springer Science & Business Media
ISBN 13 : 1468431625
Total Pages : 284 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Mössbauer Effect Methodology by : Irwin J. Gruverman

Download or read book Mössbauer Effect Methodology written by Irwin J. Gruverman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the eighth volume of a continuing series intended to provide a forum for publication of develop ments in Mossbauer effect methodology and in spectroscopy and its applications. Mossbauer Effect Methodology, Volume 8, records the proceedings of the Eighth Symposium on Mossbauer Effect Methodology. The symposium was sponsored by the New England Nuclear Corporation, with emphasis on application and some attention to spectroscopy and methodology. The Symposium was held in the Mercury Ballroom of the New York Hilton on January 28, 1973. Dr. J. J. Zuckerman presided over the afternoon and evening sessions. Almost two hundred participants attended, despite the pressures of travel budget limitations, indicating a continuing high level of interest in the field. Contri buting Sponsors were Austin Science Associates, Elron, Nuclear Science Instruments and Ranger Electronics. The MOssbauer equipment demonstrated by these organizations continued to evolve and improve year by year, and was well received by symposium participants. A one-year break in the symposium series resulted in submission of a very large number of papers. A Selection Committee was formed and selected 16 papers for inclusion in the symposium. Regrettably, many worthwhile papers could not be included. Applications were stressed.