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Microfluidic Fuel Cells And Batteries
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Book Synopsis Microfluidic Fuel Cells and Batteries by : Erik Kjeang
Download or read book Microfluidic Fuel Cells and Batteries written by Erik Kjeang and published by . This book was released on 2014-07-31 with total page 88 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Microfluidic Fuel Cells and Batteries by : Erik Kjeang
Download or read book Microfluidic Fuel Cells and Batteries written by Erik Kjeang and published by Springer. This book was released on 2014-06-14 with total page 81 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microfluidic fuel cells and batteries represent a special type of electrochemical power generators that can be miniaturized and integrated in a microfluidic chip. Summarizing the initial ten years of research and development in this emerging field, this SpringerBrief is the first book dedicated to microfluidic fuel cell and battery technology for electrochemical energy conversion and storage. Written at a critical juncture, where strategically applied research is urgently required to seize impending technology opportunities for commercial, analytical, and educational utility, the intention is for this book to be a ‘one-stop shop’ for current and prospective researchers in the general area of membraneless, microfluidic electrochemical energy conversion. As the overall goal of the book is to provide a comprehensive resource for both research and technology development, it features extensive descriptions of the underlying fundamental theory, fabrication methods, and cell design principles, as well as a thorough review of previous contributions in this field and a future outlook with recommendations for further work. It is hoped that the content will entice and enable new research groups and engineers to rapidly gain traction in their own laboratories towards the development of next generation microfluidic electrochemical cells.
Book Synopsis High Performance Fuel-Breathing Microfluidic Fuel Cells by : Yifei Wang
Download or read book High Performance Fuel-Breathing Microfluidic Fuel Cells written by Yifei Wang and published by . This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "High Performance Fuel-breathing Microfluidic Fuel Cells" by Yifei, Wang, 王夷飞, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of the thesis entitled "HIGH PERFORMANCE FUEL-BREATHING MICROFLUIDIC FUEL CELLS" Submitted by Yifei, Wang for the degree of Doctor of Philosophy at The University of Hong Kong in September 2016 Fuel cells are broadly regarded as one of the most promising power sources. A fuel cell is generally composed of a thin membrane electrolyte sandwiched by two porous electrodes, which has a similar structure with batteries. Fuel cells are very advantageous considering their high energy density, uninterrupted operation and environmental friendliness. To date, the application of this technology is vigorously promoted by the government and industry especially for large-power applications. As for applications with small rated power, the progress is, however, impeded by their high cost, leading to less competitiveness against the mature battery technology. To lower down the cost, microfluidic fuel cell (MFC), also known as the membraneless fuel cell or laminar flow fuel cell, has been proposed recently. A MFC generally utilizes two laminar flows in parallel as electrolyte instead of any solid membrane, therefore, lowering the fabrication cost. To prevent the flows from violent mixing, micro-channel, normally with characteristic length less than 1mm, is requisite. In this manner, the mixing process is dominated by slow diffusion, forming a flow interface in the middle of the channel as a virtual membrane. Despite of its cost advantage, there are still many unsolved problems in MFCs such as poor energy density, trade-off between cell performance and fuel utilization, complex fluidic management, etc. In this thesis, research works on MFC development have been done to improve their cell performance, energy efficiency, energy density, long-term stability, etc. In addition, a novel MFC stacking strategy has been proposed, which was proved to be competent for practical applications. First, conventional liquid-feed MFCs with either co-flow or counter-flow configuration were studied. Their cell performance and fuel utilization were optimized, which were used as benchmarks in subsequent studies. To solve the intractable restrictions in liquid-feed MFCs, vapor-feed MFCs were proposed which breathed fuel vapor from outside the cell instead of acquiring dissolved fuel from the inside electrolyte, therefore, -2 achieving both high power density (55.4mWcm ) and high energy efficiency (9.4%) at the same time. To better understand the mechanism behind its performance, numerical (R) simulation on vapor-feed MFCs was also conducted using COMSOL 4.2. To achieve practical power output, a circular stacking strategy was proposed, which was especially suitable for fuel-breathing MFCs. A six- cell stack was designed and tested, proving that such a stacking strategy was not only highly efficient but also potentially robust to external flow disturbance. The same stacking strategy was also applied to H -fueled MFCs to further improve the power output. By utilizing Al-H O reaction for H generation, 2 2 the proposed Al-feed MFC stack achieved a peak power output of 530mW. Meanwhile, difficulties in hydrogen storage and waste electrolyte management were eliminated. In MFCs with enlarged electrode areas, cathode flooding was inevitably aggravated and cell performance dropped significantly. By cracking the cathode catalyst layer, this problem was greatly alleviated, leading to a m
Book Synopsis Advances in Microfluidics by : Xiao-Ying Yu
Download or read book Advances in Microfluidics written by Xiao-Ying Yu and published by BoD – Books on Demand. This book was released on 2016-11-23 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Increasing innovations and applications make microfluidics a versatile choice for researchers in many disciplines. This book consists of multiple review chapters that aim to cover recent advances and new applications of microfluidics in biology, electronics, energy, and materials sciences. It provides comprehensive views of various aspects of microfluidics ranging from fundamentals of fabrication, flow control, and droplet manipulation to the most recent exploration in emerging areas such as material synthesis, imaging and novel spectroscopy, and marriage with electronics. The chapters have many illustrations showcasing exciting results. This book should be useful for those who are eager to learn more about microfluidics as well as researchers who want to pick up new concepts and developments in this fast-growing field.
Book Synopsis Membraneless Microfluidic Fuel Cells by : Kamil S. Salloum
Download or read book Membraneless Microfluidic Fuel Cells written by Kamil S. Salloum and published by . This book was released on 2010 with total page 111 pages. Available in PDF, EPUB and Kindle. Book excerpt: Portable devices rely on battery systems that contribute largely to the overall device form factor and delay portability due to recharging. Membraneless microfluidic fuel cells are considered as the next generation of portable power sources for their compatibility with higher energy density reactants. Microfluidic fuel cells are potentially cost effective and robust because they use low Reynolds number flow to maintain fuel and oxidant separation instead of ion exchange membranes. However, membraneless fuel cells suffer from poor efficiency due to poor mass transport and Ohmic losses. Current microfluidic fuel cell designs suffer from reactant cross-diffusion and thick boundary layers at the electrode surfaces, which result in a compromise between the cell's power output and fuel utilization. This dissertation presents novel flow field architectures aimed at alleviating the mass transport limitations. The first architecture provides a reactant interface where the reactant diffusive concentration gradients are aligned with the bulk flow, mitigating reactant mixing through diffusion and thus crossover. This cell also uses porous electro-catalysts to improve electrode mass transport which results in higher extraction of reactant energy. The second architecture uses porous electrodes and an inert conductive electrolyte stream between the reactants to enhance the interfacial electrical conductivity and maintain complete reactant separation. This design is stacked hydrodynamically and electrically, analogous to membrane based systems, providing increased reactant utilization and power. These fuel cell architectures decouple the fuel cell's power output from its fuel utilization. The fuel cells are tested over a wide range of conditions including variation of the loads, reactant concentrations, background electrolytes, flow rates, and fuel cell geometries. These experiments show that increasing the fuel cell power output is accomplished by increasing reactant flow rates, electrolyte conductivity, and ionic exchange areas, and by decreasing the spacing between the electrodes. The experimental and theoretical observations presented in this dissertation will aid in the future design and commercialization of a new portable power source, which has the desired attributes of high power output per weight and volume and instant rechargeability.
Download or read book Micro Fuel Cells written by Tim Zhao and published by Academic Press. This book was released on 2009-07-07 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today's consumers of portable electronics consumers are demanding devices not only deliver more power but also work healthy for the environment. This fact alone has lead major corporations like Intel, BIC, Duracell and Microsoft to believe that Microfuel Cells could be the next-generation power source for electronic products. Compact and readable, Microfuels Principles and Applications, offers engineers and product designers a reference unsurpassed by any other in the market. The book starts with a clear and rigorous exposition of the fundamentals engineering principles governing energy conversion for small electronic devices, followed by self-contained chapters concerning applications. The authors provide original points of view on all types of commercially available micro fuel cells types, including micro proton exchange membrane fuel cells, micro direct methanol fuel cells, micro solid oxide fuel cells and micro bio-fuel cells. The book also contains a detailed introduction to the fabrication of the components and the assembly of the system, making it a valuable reference both in terms of its application to product design and understanding micro engineering principles. An overview of the micro fuel cell systems and applications A detailed introduction to the fabrication of the components and the assembly of the system Original points of view on prospects of micro fuel cells
Book Synopsis Advances in Sustainable Polymers by : Vimal Katiyar
Download or read book Advances in Sustainable Polymers written by Vimal Katiyar and published by Springer Nature. This book was released on 2019-11-05 with total page 483 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a systematic overview of the processing and applications of sustainable polymers. The volume covers recent advances in biomedical, food packaging, fuel cell, membrane, and other emerging applications. The book begins by addressing different sections of biomedical application including use of carbohydrate-based therapeutics, nanohybrids, nanohydrogels, bioresorbable polymers and their composites, polymer-grafted nanobiomaterials for biomedical devices and implants, nanofibres, and others. The second part of this book discusses various processing and packaging materials for food packaging applications. The last section discusses other emerging applications, including using microbial fuel cells for waste water treatment, microfluidic fuel cells for low power applications, among others. This volume will be relevant to researchers working to improve the properties of bio-based materials for their advanced application and wide commercialization.
Download or read book Microfluidic Fuel Cells written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Microfluidic fuel cell architectures are presented in this thesis. This work represents the mechanical and microfluidic portion of a microfluidic biofuel cell project. While the microfluidic fuel cells developed here are targeted to eventual integration with biocatalysts, the contributions of this thesis have more general applicability. The cell architectures are developed and evaluated based on conventional non-biological electrocatalysts. The fuel cells employ co-laminar flow of fuel and oxidant streams that do not require a membrane for physical separation, and comprise carbon or gold electrodes compatible with most enzyme immobilization schemes developed to date. The demonstrated microfluidic fuel cell architectures include the following: a single cell with planar gold electrodes and a grooved channel architecture that accommodates gaseous product evolution while preventing crossover effects; a single cell with planar carbon electrodes based on graphite rods; a three-dimensional hexagonal array cell based on multiple graphite rod electrodes with unique scale-up opportunities; a single cell with porous carbon electrodes that provides enhanced power output mainly attributed to the increased active area; a single cell with flow-through porous carbon electrodes that provides improved performance and overall energy conversion efficiency; and a single cell with flow-through porous gold electrodes with similar capabilities and reduced ohmic resistance. As compared to previous results, the microfluidic fuel cells developed in this work show improved fuel cell performance (both in terms of power density and efficiency). In addition, this dissertation includes the development of an integrated electrochemical velocimetry approach for microfluidic devices, and a computational modeling study of strategic enzyme patterning for microfluidic biofuel cells with consecutive reactions.
Book Synopsis Bioelectrochemical Systems by : Korneel Rabaey
Download or read book Bioelectrochemical Systems written by Korneel Rabaey and published by IWA Publishing. This book was released on 2009-12-01 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the context of wastewater treatment, Bioelectrochemical Systems (BESs) have gained considerable interest in the past few years, and several BES processes are on the brink of application to this area. This book, written by a large number of world experts in the different sub-topics, describes the different aspects and processes relevant to their development. Bioelectrochemical Systems (BESs) use micro-organisms to catalyze an oxidation and/or reduction reaction at an anodic and cathodic electrode respectively. Briefly, at an anode oxidation of organic and inorganic electron donors can occur. Prime examples of such electron donors are waste organics and sulfides. At the cathode, an electron acceptor such as oxygen or nitrate can be reduced. The anode and the cathode are connected through an electrical circuit. If electrical power is harvested from this circuit, the system is called a Microbial Fuel Cell; if electrical power is invested, the system is called a Microbial Electrolysis Cell. The overall framework of bio-energy and bio-fuels is discussed. A number of chapters discuss the basics – microbiology, microbial ecology, electrochemistry, technology and materials development. The book continues by highlighting the plurality of processes based on BES technology already in existence, going from wastewater based reactors to sediment based bio-batteries. The integration of BESs into existing water or process lines is discussed. Finally, an outlook is provided of how BES will fit within the emerging biorefinery area.
Book Synopsis Materials for Low-Temperature Fuel Cells by : Bradley Ladewig
Download or read book Materials for Low-Temperature Fuel Cells written by Bradley Ladewig and published by John Wiley & Sons. This book was released on 2015-03-09 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in Low-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in low-temperature fuel cells. A related book will cover key materials in high-temperature fuel cells. The two books form part of the "Materials for Sustainable Energy & Development" series. Key Materials in Low-Temperature Fuel Cells brings together world leaders and experts in this field and provides a lucid description of the materials assessment of fuel cell technologies. With an emphasis on the technical development and applications of key materials in low-temperature fuel cells, this text covers fundamental principles, advancement, challenges, and important current research themes. Topics covered include: proton exchange membrane fuel cells, direct methanol and ethanol fuel cells, microfluidic fuel cells, biofuel cells, alkaline membrane fuel cells, functionalized carbon nanotubes as catalyst supports, nanostructured Pt catalysts, non-PGM catalysts, membranes, and materials modeling. This book is an essential reference source for researchers, engineers and technicians in academia, research institutes and industry working in the fields of fuel cells, energy materials, electrochemistry and materials science and engineering.
Book Synopsis 3D Printing for Energy Applications by : Albert Tarancón
Download or read book 3D Printing for Energy Applications written by Albert Tarancón and published by John Wiley & Sons. This book was released on 2021-03-03 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: 3D PRINTING FOR ENERGY APPLICATIONS Explore current and future perspectives of 3D printing for the fabrication of high value-added complex devices 3D Printing for Energy Applications delivers an insightful and cutting-edge exploration of the applications of 3D printing to the fabrication of complex devices in the energy sector. The book covers aspects related to additive manufacturing of functional materials with applicability in the energy sector. It reviews both the technology of printable materials and 3D printing strategies itself, and its use in energy devices or systems. Split into three sections, the book covers the 3D printing of functional materials before delving into the 3D printing of energy devices. It closes with printing challenges in the production of complex objects. It also presents an interesting perspective on the future of 3D printing of complex devices. Readers will also benefit from the inclusion of: A thorough introduction to 3D printing of functional materials, including metals, ceramics, and composites An exploration of 3D printing challenges for production of complex objects, including computational design, multimaterials, tailoring AM components, and volumetric additive manufacturing Practical discussions of 3D printing of energy devices, including batteries, supercaps, solar panels, fuel cells, turbomachinery, thermoelectrics, and CCUS Perfect for materials scientists, 3D Printing for Energy Applications will also earn a place in the libraries of graduate students in engineering, chemistry, and material sciences seeking a one-stop reference for current and future perspectives on 3D printing of high value-added complex devices.
Book Synopsis Performance Enhancements of Microfluidic Fuel Cells with Flow-through Porous Electrodes by : Jin Wook Lee
Download or read book Performance Enhancements of Microfluidic Fuel Cells with Flow-through Porous Electrodes written by Jin Wook Lee and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis presents performance improvements of microfluidic fuel cells with flow-through porous electrodes. The baseline cell is a laminar flow-based, membraneless, microfluidic fuel cell employing vanadium redox species (as electrolytes). The main objective of the current work is to establish a design guideline for microfluidic fuel cells and to propose new design strategies that lead to better performing cells. The fundamental physics including fluid flow, electrochemical reactions in porous media, and convective/diffusive mass transport is closely investigated. Various loss elements during the baseline cell operation such as activation, ohmic, and mass transport losses are identified and compared. Some feasible and practical remedies to reduce the overall losses are proposed and successfully demonstrated: thin film current collector for the overall ohmic loss; nanofoam material as electrodes to reduce the activation loss; and novel concept to overcome mass transport limited performances. Further improvements would be anticipated if both ohmic and fluidic resistances of the nanofoam material are reduced. Uniform distribution of the pore sizes is also important to maximize the utilization of active electrode areas. When combined, the demonstrated technologies and design improvements are anticipated to bring this unique membraneless and catalyst-free fuel cell closer to commercialization as a low-cost power source.
Book Synopsis Biochemical Fuel Cells by : Miroslav Cenek
Download or read book Biochemical Fuel Cells written by Miroslav Cenek and published by . This book was released on 1969 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: A review is provided which covers the development, present status, and future outlook of biochemical fuel cell research. Its contents include: Bioelectrochemistry; Biofuel cells; (Fuels for Biofuel cells, Oxidation agents for biofuel cells, Organisms for biofuel cells, Classification of biofuel cells, Electrochemical and biological metabolism, Interelectrode separation, Suitability of materials used in Biofuel Cells, The influence of the Electrode on the Biological Substance); Biogalvanic cells; Biosolar cells; Bioanodes; Biocathodes; Some types of biofuel cells (Biofuel cell urea-oxygen-urease, Biofuel cell lactate-atmospheric oxygen); Comparison of biofuel cells with fuel cells (Advantages of biofuel cells over fuel cells, Drawbacks of biofuel cells in comparison with fuel cells); The medium of the ocean as a giant biofuel cell.
Download or read book Biofuel Cells written by Inamuddin and published by John Wiley & Sons. This book was released on 2021-08-03 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rapid industrialization and urbanization associated with the environment changes calls for reduced pollution and thereby least use of fossil fuels. Biofuel cells are bioenergy resources and biocompatible alternatives to conventional fuel cells. Biofuel cells are one of the new sustainable renewable energy sources that are based on the direct conversion of chemical matters to electricity with the aid of microorganisms or enzymes as biocatalysts. The gradual depletion of fossil fuels, increasing energy needs, and the pressing problem of environmental pollution have stimulated a wide range of research and development efforts for renewable and environmentally friendly energy. Energy generation from biomass resources by employing biofuel cells is crucial for sustainable development. Biofuel cells have attracted considerable attention as micro- or even nano-power sources for implantable biomedical devices, such as cardiac pacemakers, implantable self-powered sensors, and biosensors for monitoring physiological parameters. This book covers the most recent developments and offers a detailed overview of fundamentals, principles, mechanisms, properties, optimizing parameters, analytical characterization tools, various types of biofuel cells, all-category of materials, catalysts, engineering architectures, implantable biofuel cells, applications and novel innovations and challenges in this sector. This book is a reference guide for anyone working in the areas of energy and the environment.
Book Synopsis Microfluidics for Fuel Cell Applications by : Ian Stewart
Download or read book Microfluidics for Fuel Cell Applications written by Ian Stewart and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, a microfluidics approach is applied to two fuel cell related projects; the study of deformation and contact angle hysteresis on water invasion in porous media and the introduction of bubble fuel cells. This work was carried out as collaboration between the microfluidics and CFCE groups in the Department of Mechanical Engineering at the University of Victoria. Understanding water transport in the porous media of Polymer Electrolyte Membrane fuel cells is crucial to improve performance. One popular technique for both numeric simulations and experimental micromodels is pore network modeling, which predicts flow behavior as a function of capillary number and relative viscosity. An open question is the validity of pore network modeling for the small highly non-wetting pores in fuel cell porous media. In particular, current pore network models do not account for deformable media or contact angle hysteresis. We developed and tested a deformable microfluidic network with an average hydraulic diameter of 5?m, the smallest sizes to date. At a capillary number and relative viscosity for which conventional theory would predict strong capillary fingering behavior, we report almost complete saturation. This work represents the first experimental pore network model to demonstrate the combined effects of material deformation and contact angle hysteresis. Microfluidic fuel cells are small scale energy conversion devices that take advantage of microscale transport phenomena to reduce size, complexity and cost. They are particularly attractive for portable electronic devices, due to their potentially high energy density. The current state of the art microfluidic fuel cell uses the laminar flow of liquid fuel and oxidant as a membrane. Their performance is plagued by a number of factors including mixing, concentration polarization, ohmic polarization and low fuel utilization. In this work, a new type of microfluidic fuel cell is conceptualized and developed that uses bubbles to transport fuel and oxidant within an electrolyte. Bubbles offer a phase boundary to prevent mixing, higher rates of diffusion, and independent electrolyte selection. One particular bubble fuel cell design produces alternating current. This work presents, to our knowledge, the first microfluidic chip to produce bubbles of alternating composition in a single channel, class of fuel cells that use bubbles to transport fuel and oxidant and fuel cell capable of generating alternating current.
Book Synopsis Materials and Methods for Microfluidic Fuel Cells by : Ben Nearingburg
Download or read book Materials and Methods for Microfluidic Fuel Cells written by Ben Nearingburg and published by . This book was released on 2014 with total page 207 pages. Available in PDF, EPUB and Kindle. Book excerpt: Microfluidic fuel cell (MFC) devices are a promising route towards on-chip power generation for microfluidic and lab-on-a-chip systems. Current MFCs leverage fabrication techniques and materials that have been inherited from micromachining technology and macro-scale fuel cell devices. Both, these methods and materials can be costly and difficult to integrate into larger microfluidic networks or lab-on-a-chip devices. In order to fully explore the utility of MFCs, device should be composed of common microfluidic materials (i.e. formed from the same materials as the rest of the device) and amendable to fabrication alongside other components of microfluidic devices (i.e. not require specialized equipment/techniques for patterning). This thesis set out to improve the applicability of MFC devices by enhancing fabrication methods and describing new functional materials to better align MFCs with microfluidic device architectures. To achieve this goal, I focused my efforts on improving individual sub-components of the MFC device architecture to yield more effective devices. Throughout this thesis, emphasis was placed upon leveraging techniques amenable to low-cost bench-top processing (i.e. those that do not require expensive capital equipment) to broaden the applicability of MFC devices. My work was applied to three components of planar MFC devices (where a device consists of a single sided microchannel and a flat capping layer). First, proton exchange membranes capable of in situ patterning were developed and characterized. Second, oxygen transport through air breathing polymer layers was assessed through finite element modelling to better understand factors governing air breathing MFC devices. Finally, a new technique, multi-layer in situ laminar flow lithography, was introduced and characterized. This technique was shown to allow for patterning of multi-layer metal films to yield independent catalytic electrodes. Functional alkaline direct methanol fuel cell devices were then fabricated and characterized using the technique. The utility and applicability of each of these techniques to both MFCs and the wider field of microfluidics was assessed and possible applications discussed.
Book Synopsis Enzymatic Fuel Cells by : Heather R. Luckarift
Download or read book Enzymatic Fuel Cells written by Heather R. Luckarift and published by John Wiley & Sons. This book was released on 2014-05-06 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Summarizes research encompassing all of the aspects required to understand, fabricate and integrate enzymatic fuel cells Contributions span the fields of bio-electrochemistry and biological fuel cell research Teaches the reader to optimize fuel cell performance to achieve long-term operation and realize commercial applicability Introduces the reader to the scientific aspects of bioelectrochemistry including electrical wiring of enzymes and charge transfer in enzyme fuel cell electrodes Covers unique engineering problems of enzyme fuel cells such as design and optimization