Metalloporphyrins Catalyzed Oxidations

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Publisher : Springer Science & Business Media
ISBN 13 : 9401722471
Total Pages : 364 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Metalloporphyrins Catalyzed Oxidations by : F. Montanari

Download or read book Metalloporphyrins Catalyzed Oxidations written by F. Montanari and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidative catalysis by metalloporphyrin systems occupies a prominent role in the current research in the fields of chemical and biological catalysis. Our particular interest and approach has been to collect in the same volume papers dealing with both the chemical and biological aspects of the reactivity of heme systems because of the realization that a better understanding of the complementary discipline can be extremely useful for the researchers from either field. The current progress of the research on synthetic metalloporphyrin catalysts has led to the development of several systems that are able to reproduce the heme-enzyme mediated oxygenation and oxidation reactions, at least in terms of reaction types, mechanisms and often rates. These achievements have stimulated the of creating metalloporphyrin catalysts which are both ambitious project efficient and stable enough to become competitive for large-scale industrial processes. Although this project is still far from being realized, the efforts in this direction parallel those aimed at the application of heme enzymes to chemical technologies, e. g. for the mild, selective oxidation of organics or the detoxification of pollutants. Both the two approaches will be advantageous because while the enzyme systems can achieve selectivities which are probably unattainable by synthetic catalysts, the latter can be active under experimental conditions that would readily inactivate the enzymes.

Metalloporphyrins in Catalytic Oxidations

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Publisher : CRC Press
ISBN 13 : 9780824792282
Total Pages : 412 pages
Book Rating : 4.7/5 (922 download)

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Book Synopsis Metalloporphyrins in Catalytic Oxidations by : Roger A. Sheldon

Download or read book Metalloporphyrins in Catalytic Oxidations written by Roger A. Sheldon and published by CRC Press. This book was released on 1994-06-28 with total page 412 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides an in-depth overview of the chemistry of metalloporphyrins as oxidation catalysts in chemical and biological systems. It discusses practical techniques for the synthesis of metalloporphyrins and introduces useful methods of immobilization to improve their synthetic utility. Detailed discussions of underlying mechanistic features are provided.

Advanced Graphic Communication, Printing and Packaging Technology

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Publisher : Springer Nature
ISBN 13 : 9811518645
Total Pages : 883 pages
Book Rating : 4.8/5 (115 download)

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Book Synopsis Advanced Graphic Communication, Printing and Packaging Technology by : Pengfei Zhao

Download or read book Advanced Graphic Communication, Printing and Packaging Technology written by Pengfei Zhao and published by Springer Nature. This book was released on 2020-04-09 with total page 883 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book includes a selection of peer-reviewed papers presented at the 10th China Academic Conference on Printing and Packaging, which was held in Xi'an, China, on November 14–17, 2019. The conference was jointly organized by the China Academy of Printing Technology, Beijing Institute of Graphic Communication, and Shaanxi University of Science and Technology. With 9 keynote talks and 118 papers on graphic communication and packaging technologies, the conference attracted more than 300 scientists. The proceedings cover the latest findings in a broad range of areas, including color science and technology, image processing technology, digital media technology, mechanical and electronic engineering, Information Engineering and Artificial Intelligence Technology, materials and detection, digital process management technology in printing and packaging, and other technologies. As such, the book appeals to university researchers, R&D engineers and graduate students in the graphic arts, packaging, color science, image science, material science, computer science, digital media, and network technology.

The Porphyrin Handbook

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Publisher : Elsevier
ISBN 13 : 9780123932297
Total Pages : 238 pages
Book Rating : 4.9/5 (322 download)

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Book Synopsis The Porphyrin Handbook by : Karl Kadish

Download or read book The Porphyrin Handbook written by Karl Kadish and published by Elsevier. This book was released on 2000 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Porphyrin Handbook, Volume 19: Applications of Phthalocyanines provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the basic photobiology of phthalocyanines, their structure-activity relationships, mechanisms of action in a variety of biological systems, and their potential applications for various medical purposes. This text then examines the type of organization of the molecules in the solid state and the intensity of the intermolecular interactions. Other chapters consider the applications of phthalocyanines as decorative and functional materials, with emphasis on properties and structures of phthalocyanines with industrial relevance. This book discusses as well the enzyme-like catalytic functions of metal complexes derivatives and their practical applications as odor-removing systems and bacterial systems based on their effective catalytic activities. This book is a valuable resource for research scientists, engineers, and clinicians.

The Activation of Dioxygen and Homogeneous Catalytic Oxidation

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Publisher : Springer Science & Business Media
ISBN 13 : 1461530008
Total Pages : 503 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis The Activation of Dioxygen and Homogeneous Catalytic Oxidation by : D.H.R. Barton

Download or read book The Activation of Dioxygen and Homogeneous Catalytic Oxidation written by D.H.R. Barton and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.

Catalytic Oxidations with Hydrogen Peroxide as Oxidant

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Publisher : Springer Science & Business Media
ISBN 13 : 940170984X
Total Pages : 287 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Catalytic Oxidations with Hydrogen Peroxide as Oxidant by : G. Strukul

Download or read book Catalytic Oxidations with Hydrogen Peroxide as Oxidant written by G. Strukul and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.

Biomimetic Oxidations Catalyzed by Transition Metal Complexes

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Publisher : World Scientific
ISBN 13 : 1783262389
Total Pages : 696 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Biomimetic Oxidations Catalyzed by Transition Metal Complexes by : Bernard Meunier

Download or read book Biomimetic Oxidations Catalyzed by Transition Metal Complexes written by Bernard Meunier and published by World Scientific. This book was released on 2000-03-08 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with. This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students. Contents:Thermodynamic Influences of C–H Bond Oxidation (J M Mayer)Distinguishing Biomimetic Oxidations from Oxidations Mediated by Freely Diffusing Radicals (K U Ingold & P A MacFaul)Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates (J L McLain et al.)Models of Heme Peroxidases and Catalases (B Meunier)Non-Heme Peroxidases and Catalases: Mechanistic Implications from the Studies of Manganese and Vanadium Model Compounds (C Slebodnick et al.)Methane Monooxygenase Models (Z-B Hu & S M Gorun)Models of Copper Enzymes and Heme-Copper Oxidases (M A Kopf & K D Karlin)Iron-Containing Models of Catechol Dioxygenases (H-J Krüger)Biomimetic Chemistry of Molybdenum (C G Young)Models of Superoxide Dismutases (D E Cabelli et al.)Modeling the Oxygen-Evolving Complex in Photosystem II (J Limburg et al.)Asymmetric Biomimetic Oxidations (A Robert & B Meunier)Bioinspired Oxidations Catalyzed by Ruthenium Complexes (S-I Murahashi & N Komiya)Biocatalytic and Biomimetic Oxidations from an Industrial Perspective (R A Sheldon) Readership: Postgraduate students and researchers in biochemistry and chemistry. Keywords:EPR Spectroscopy;Functional Model Chemistry;Isotope Labeling;Manganese Complexes;Mechanism;Oxygen Evolution;Photosystem II;Redox Chemistry;Water Splitting Chemistry;X-Ray Spectroscopy;Oxidation;Oxygenation;Transition Metal Complexes;Asymmetric Oxidation;Oxidase;Oxygenase;Metal-Oxo;Peroxide, Peroxo;Metalloporphyrin;MMO Models;P450 Models

Metal Organic Frameworks as Heterogeneous Catalysts

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1849735727
Total Pages : 446 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Metal Organic Frameworks as Heterogeneous Catalysts by : Francesc X. Llabrés i Xamena

Download or read book Metal Organic Frameworks as Heterogeneous Catalysts written by Francesc X. Llabrés i Xamena and published by Royal Society of Chemistry. This book was released on 2013-07-01 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.

Porphyrin-based Supramolecular Architectures

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Publisher : Royal Society of Chemistry
ISBN 13 : 1839164948
Total Pages : 384 pages
Book Rating : 4.8/5 (391 download)

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Book Synopsis Porphyrin-based Supramolecular Architectures by : Shengqian Ma

Download or read book Porphyrin-based Supramolecular Architectures written by Shengqian Ma and published by Royal Society of Chemistry. This book was released on 2021-12-03 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porphyrin-based Supramolecular Architectures focuses on the most recent developments in the field, emphasizing the cutting-edge research in a diverse range of applications. Designed for readers considering the unprecedented prosperity of porous materials research, chapters will cover both strategies for structure design (such as MOFs and COFs) as well as emerging applications including CO2 fixation, catalysis and photodynamic therapy. With contributions from global experts, this title will be of interest to graduate students and researchers in supramolecular chemistry, organic chemistry, inorganic chemistry, physical chemistry, organometallic chemistry, solid-state chemistry, catalysis and (porous) materials science.

Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations

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Publisher : Springer
ISBN 13 : 3540465928
Total Pages : 327 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations by : B. Meunier

Download or read book Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations written by B. Meunier and published by Springer. This book was released on 2003-09-04 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world’s renowned experts.

Alkane Functionalization

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Publisher : John Wiley & Sons
ISBN 13 : 111937880X
Total Pages : 680 pages
Book Rating : 4.1/5 (193 download)

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Book Synopsis Alkane Functionalization by : Armando J. L. Pombeiro

Download or read book Alkane Functionalization written by Armando J. L. Pombeiro and published by John Wiley & Sons. This book was released on 2019-03-11 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

Handbook of Macrocyclic Supramolecular Assembly

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Publisher : Springer
ISBN 13 : 9789811526855
Total Pages : 1818 pages
Book Rating : 4.5/5 (268 download)

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Book Synopsis Handbook of Macrocyclic Supramolecular Assembly by : Yu Liu

Download or read book Handbook of Macrocyclic Supramolecular Assembly written by Yu Liu and published by Springer. This book was released on 2020-07-19 with total page 1818 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook presents recent advances and offers a comprehensive reference resource covering the developments in and applications of macrocyclic supramolecular assembly, with a focus on their construction, structural characters and biological functions. The main topics addressed include: Construction and structure of macrocyclic supramolecular assembly – key building blocks, construction methods, structural motifs, and stimuli responsive control Approach and technology – controllable synthesis, molecular recognition, spectral and thermodynamic study, supramolecular assembly at interfaces, orthogonal self-assembly, the supramolecular organic framwork (SOF), molecular induced aggregation, supramolecule assisted 3D printing, theoretical calculation and molecular simulation Biological applications – chemical and biological sensing, theranostic tools, molecule/ion channels, drug/gene delivery, supramolecule assisted biomolecule production, supramolecule assisted transmembrane transport, supramolecule assisted immunity regulation, supramolecule-based medicinal drug, etc. This handbook appeals to graduate and undergraduate students as well as scientists with interests in supramolecular chemistry, biochemistry, functional material and nanotechnology.

Hypervalent Iodine in Organic Synthesis

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Publisher : Academic Press
ISBN 13 : 0080534368
Total Pages : 245 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Hypervalent Iodine in Organic Synthesis by : A. Varvoglis

Download or read book Hypervalent Iodine in Organic Synthesis written by A. Varvoglis and published by Academic Press. This book was released on 1996-11-14 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Features up-to-date coverage of a wide range of topics Includes many tables featuring a diversity of reactivity, and a comprehensive index Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry Contains a section on unusual efficiency of hypervalent iodine reactions

Iron Porphyrins

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Publisher : Wiley-VCH
ISBN 13 : 9780471187158
Total Pages : 322 pages
Book Rating : 4.1/5 (871 download)

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Book Synopsis Iron Porphyrins by : A. B. P. Lever

Download or read book Iron Porphyrins written by A. B. P. Lever and published by Wiley-VCH. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porphyrins play a vital role in many biological functions including oxygen transport, electron transfer and catalyzing the incorporation of oxygen into other molecules. This current survey discusses the use of modern physical techniques to probe porphyrin structure and function. The authors review the data available through a particular technique and show what can be learned therefrom about the (electronic) structure and function of biologically important porphyrins. The techniques include magnetic circular dichroism, X-ray absorption fine structure (EXAFS) and Mössbauer spectroscopies. All contributors are well known in their respective fields, enjoying world-wide reputation.

Catalytic Activation of Dioxygen by Metal Complexes

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Publisher : Springer Science & Business Media
ISBN 13 : 9401128502
Total Pages : 407 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Catalytic Activation of Dioxygen by Metal Complexes by : László I. Simándi

Download or read book Catalytic Activation of Dioxygen by Metal Complexes written by László I. Simándi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.

Cytochrome P-450

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Publisher : Springer Science & Business Media
ISBN 13 : 9780306421471
Total Pages : 572 pages
Book Rating : 4.4/5 (214 download)

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Book Synopsis Cytochrome P-450 by : Paul Ortiz De Monetllano

Download or read book Cytochrome P-450 written by Paul Ortiz De Monetllano and published by Springer Science & Business Media. This book was released on 1986-03 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Major advances have been made in recent years in clarifying the molecular properties of the cytochrome P-450 system. These advances stem, in practical terms, from the generally recognized importance of cytochrome P-450 in the metabolism of drugs and in the bioactivation of xenobiotics to toxic products. The fascinating multiplicity and differential regulation of cytochrome P-450 isozymes, and their ability to catalyze extraordinarily difficult chemical transformations, have independently drawn many chemists and biochemists into the P-450 circle. Progress in the field, from a technical point of view, has been propelled by the de velopment of reliable procedures for the purification of membrane-bound enzymes, by the growing repertoire of molecular biological techniques, and by the development of chemical models that mimic the catalytic action of P-450. As a result, our understanding of the P-450 system is moving from the descriptive, pharmacological level into the tangible realm of atomic detail. The rapid progress and multidisciplinary character of the cytochrome P-450 field, which cuts across the lines that traditionally divide disciplines as diverse as inorganic chemistry and genetics, have created a need for an up-to-date evaluation of the advances that have been made. It is hoped that this book, with its molecular focus on the cytochrome P-450 system, will alleviate this need. The authors of the individual chapters have strived to emphasize recent results without sacrificing the background required to make their chapters comprehensible to informed nonspecialists.

Industrial Organic Chemicals

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Publisher : John Wiley & Sons
ISBN 13 : 9780471443858
Total Pages : 698 pages
Book Rating : 4.4/5 (438 download)

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Book Synopsis Industrial Organic Chemicals by : Harold A. Wittcoff

Download or read book Industrial Organic Chemicals written by Harold A. Wittcoff and published by John Wiley & Sons. This book was released on 2004 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: Publisher Description