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Author : John Houston Miller
Publisher :
ISBN 13 :
Total Pages : 304 pages
Book Rating : 4.:/5 (821 download)
Download or read book Matrix Isolation Spectroscopy of Molecular Ions and Free Radicals written by John Houston Miller and published by . This book was released on 1980 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Gerhard Herzberg
Publisher : Courier Corporation
ISBN 13 : 048665821X
Total Pages : 242 pages
Book Rating : 4.4/5 (866 download)
Download or read book The Spectra and Structures of Simple Free Radicals written by Gerhard Herzberg and published by Courier Corporation. This book was released on 1988-01-01 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Authoritative and clearly written."—Applied Optics The direct observation of short-lived free radicals and the consequent study of their structure and reactions have led to important developments in almost every branch of chemistry as well as in other areas. This volume by a Nobel laureate offers an excellent introduction to the essentials of molecular spectroscopy. The introductory chapter discusses experimental methods and illustrates the observed spectra of various molecules and free radicals. Subsequent chapters explore rotational, vibrational, and electronic energy levels of diatomic molecules and ions; radiative transitions; linear and nonlinear polyatomic radicals and ions; continuous and diffuse spectra; predissociation and pre-ionization; and recombination. The well-illustrated text features more than 100 figures and spectra. A distilled version of the author's monumental three-volume study, Molecular Spectra and Molecular Structure, it constitutes a superb resource for anyone wishing a concise but complete treatment of the fundamentals of molecular spectroscopy.
Author : Lester Andrews
Publisher :
ISBN 13 :
Total Pages : 448 pages
Book Rating : 4.3/5 (91 download)
Download or read book Chemistry and Physics of Matrix-isolated Species written by Lester Andrews and published by . This book was released on 1989 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
Author : A. Barnes
Publisher : Springer Science & Business Media
ISBN 13 : 9400985401
Total Pages : 602 pages
Book Rating : 4.4/5 (9 download)
Download or read book Matrix Isolation Spectroscopy written by A. Barnes and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 602 pages. Available in PDF, EPUB and Kindle. Book excerpt: The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author : Harry Evans Hallam
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 464 pages
Book Rating : 4.:/5 (5 download)
Download or read book Vibrational Spectroscopy of Trapped Species written by Harry Evans Hallam and published by Wiley-Interscience. This book was released on 1973 with total page 464 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Matthew John Almond
Publisher :
ISBN 13 :
Total Pages : 552 pages
Book Rating : 4.:/5 (44 download)
Download or read book Spectroscopy of Matrix Isolated Species written by Matthew John Almond and published by . This book was released on 1989-08-15 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intended as a standard reference in the subject of matrix isolation spectroscopy. Leads the reader logically through experimental techniques, physical processes in matrices, photochemistry in matrices, low energy species and interconversions, high-energy species, atoms and small clusters, astrochemistry and atmospheric processes. Also, a unique feature is a detailed compilation of the results of matrix-isolation experiments in the decade of 1977-1986.
Author :
Publisher :
ISBN 13 :
Total Pages : 800 pages
Book Rating : 4.F/5 ( download)
Download or read book NBS Special Publication written by and published by . This book was released on 1968 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 31 pages
Book Rating : 4.:/5 (227 download)
Download or read book Spectroscopy of Reaction Intermediates in Nitramine Decomposition and Combustion written by and published by . This book was released on 1991 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt: The infrared spectra of a number of free radicals and molecular ions which are expected to be important in nitramine decomposition and combustion have been obtained in solid neon. The molecular ion studies resulted in the first infrared spectral detection of dimer ions in a non-interactive environment. The ions chosen for study are important in the lower ionosphere and in combustion and high energy processes involving carbon- and nitrogen- containing materials. Other studies used monomethylnitramine (MMN) as a model compound for elucidating the chemistry of nitramine decomposition. The infrared spectrum of MMN isolated in solid neon was obtained using a manifold designed for matrix isolation sampling of low vapor pressure materials. Supporting evidence was obtained for a mechanism recently proposed by Melius for water- catalyzed nitramine decomposition. The photodecomposition of matrix-isolated MMN was studied. Evidence was obtained supporting initial detachment of NO2 and cage recombination to form the nitrite in a solid environment. Infrared and near infrared studies of other free radicals are briefly described.
Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 572 pages
Book Rating : 4.:/5 (31 download)
Download or read book Journal of Research of the National Bureau of Standards written by United States. National Bureau of Standards and published by . This book was released on 1980 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 668 pages
Book Rating : 4.3/5 (91 download)
Download or read book Publications written by United States. National Bureau of Standards and published by . This book was released on 1980 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.3/5 (91 download)
Download or read book Publications of the National Bureau of Standards, 1973 Catalog written by United States. National Bureau of Standards and published by . This book was released on 1974 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : National Institute of Standards and Technology (U.S.)
Publisher :
ISBN 13 :
Total Pages : 318 pages
Book Rating : 4.:/5 (31 download)
Download or read book Publications of the National Institute of Standards and Technology ... Catalog written by National Institute of Standards and Technology (U.S.) and published by . This book was released on 1974 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Leonid Khriachtchev
Publisher : CRC Press
ISBN 13 : 0429533780
Total Pages : 388 pages
Book Rating : 4.4/5 (295 download)
Download or read book Physics and Chemistry at Low Temperatures written by Leonid Khriachtchev and published by CRC Press. This book was released on 2019-05-08 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tunneling reactions in chemistry are characterized by the low-temperature limit when the classical contribution is negligible. Many practical applications benefit from the lack of heat and have a deep physical basis. Interesting advantages of chemical synthesis at low temperatures have also been demonstrated. This book covers fundamental and practical aspects of the processes and experimental and theoretical methods used in the field. The chapters are written by leading scientists who have very strong experience in the selected topics, and many practical recommendations can be found in this book.
Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 650 pages
Book Rating : 4.3/5 (91 download)
Download or read book Publications of the National Bureau of Standards, 1979 Catalog written by United States. National Bureau of Standards and published by . This book was released on 1980 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Camille Sandorfy
Publisher : Springer Science & Business Media
ISBN 13 : 9401021538
Total Pages : 599 pages
Book Rating : 4.4/5 (1 download)
Download or read book Chemical Spectroscopy and Photochemistry in the Vacuum-Ultraviolet written by Camille Sandorfy and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 599 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is probably safe to predict that the future of chemistry is linked to the excited states of molecules and to other short lived species, ions and free radicals. Molecules have only one ground state but many excited states. However large the scope of normal, ground state chemistry might be, above and beyond it lies the world of excited states, each one having its own chemis try. The electronic transitions leading to the excited states, either discrete of continuous, are examined in molecular elec tronic spectroscopy. Electronic spectroscopy is the queen of all spectroscopies: for if we have the resolution we have everything. Vnfortunately, the chemist who is interested in the structure and reactions of larger molecules must often renounce all that infor mation. The spectra are complex and often diffuse; resolution does not always help. To understand such spectra he must look at whole families of molecules; to some extent structural analogies help. Let us call this chemical spectroscopy and handle it with care. In order to understand the properties of molecules we also need theory. We know that molecular problems are, in principle, soluble by the methods of quantum mechanics. Present time quan tum chemistry is able to provide a nearly accurate description of not too large molecules in their ground states. It is probablY again safe to predict that the future of quantum chemistry is connected with molecular excited states or, generally spoken, the accurate handling of the open-shell problem.
Author : United States. National Bureau of Standards
Publisher :
ISBN 13 :
Total Pages : 548 pages
Book Rating : 4.3/5 ( download)
Download or read book Publications of the National Bureau of Standards ... Catalog written by United States. National Bureau of Standards and published by . This book was released on 1974 with total page 548 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anders Lund
Publisher : Springer Science & Business Media
ISBN 13 : 9401137501
Total Pages : 498 pages
Book Rating : 4.4/5 (11 download)
Download or read book Radical Ionic Systems written by Anders Lund and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.
