Stereoselective Polymerization with Single-Site Catalysts

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Publisher : CRC Press
ISBN 13 : 142001708X
Total Pages : 698 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Stereoselective Polymerization with Single-Site Catalysts by : Lisa S. Baugh

Download or read book Stereoselective Polymerization with Single-Site Catalysts written by Lisa S. Baugh and published by CRC Press. This book was released on 2007-11-29 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of

Olefin Metathesis and Polymerization Catalysts

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Publisher : Springer Science & Business Media
ISBN 13 : 940113328X
Total Pages : 567 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Olefin Metathesis and Polymerization Catalysts by : Yavuz Imamogammalu

Download or read book Olefin Metathesis and Polymerization Catalysts written by Yavuz Imamogammalu and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.

Metalorganic Catalysts for Synthesis and Polymerization

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Publisher : Springer Science & Business Media
ISBN 13 : 3642601782
Total Pages : 674 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis Metalorganic Catalysts for Synthesis and Polymerization by : Walter Kaminsky

Download or read book Metalorganic Catalysts for Synthesis and Polymerization written by Walter Kaminsky and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt: 45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.

Sequence-Controlled Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527342370
Total Pages : 532 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Sequence-Controlled Polymers by : Jean-François Lutz

Download or read book Sequence-Controlled Polymers written by Jean-François Lutz and published by John Wiley & Sons. This book was released on 2018-04-09 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.

Ring Opening Metathesis Polymerisation and Related Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 9401003734
Total Pages : 489 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Ring Opening Metathesis Polymerisation and Related Chemistry by : Ezat Khosravi

Download or read book Ring Opening Metathesis Polymerisation and Related Chemistry written by Ezat Khosravi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.

Alternating Copolymers

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Publisher : Springer Science & Business Media
ISBN 13 : 1475791399
Total Pages : 292 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Alternating Copolymers by : J.M.G. Cowie

Download or read book Alternating Copolymers written by J.M.G. Cowie and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examination of the early literature attests to the fact that the study of copolymerization was initiated when polymer science was in its infancy. It has continued to grow to a subject of major importance and has been a source of interest to both academic and industrialist alike. The wide spectrum of structures and properties available in the statistical copolymer has made this a fruitful field of exploration, but one particular and more restricted form which has held its own fascination for many is the limiting case of the strictly alternating copolymer. This is formed, in the ideal situation, when two monomers in a reaction mixture add consecutively to create a polymer chain with a regular {ABABAB} structure, irrespective of the monomer feed ratio. When this happens the resulting copolymer will always have the same composition, a feature which can be advantageous but also somewhat restrictive, as the ability to vary the properties is then limited. Within a series entitled Speciality Polymers it seems appropriate then to deal with this subject, particularly as no previous attempt has been made to draw together the various facets of alternating copolymerization into one volume. It also seems timely to present a more unified picture of the subject which will also illustrate the progress made.

Catalytic Polymerization of Cycloolefins

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Publisher : Elsevier
ISBN 13 : 0080528627
Total Pages : 1293 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Catalytic Polymerization of Cycloolefins by : V. Dragutan

Download or read book Catalytic Polymerization of Cycloolefins written by V. Dragutan and published by Elsevier. This book was released on 2000-06-26 with total page 1293 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.

Polymers

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Publisher : CRC Press
ISBN 13 : 9780748740734
Total Pages : 452 pages
Book Rating : 4.7/5 (47 download)

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Book Synopsis Polymers by : J.M.G. Cowie

Download or read book Polymers written by J.M.G. Cowie and published by CRC Press. This book was released on 1991-06-01 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text follows a broad sequence of preparation, characterization, physical and mechanical properties and structure-property relations. Polymers: Chemistry and Physics of Modern Materials, Second Edition covers several methods of polymerization, properties, and advanced applications such as liquid crystals and polymers used in the electronics industry. Topics also include Step-Growth, Free Radical Addition, and Ionic Polymerization; Copolymerization; Polymer Stereochemistry and Characterization; Structure-Property Relationship; Polymer Liquid Crystals; and Polymers for the Electronics Industry.

Chemistry of Waste Minimization

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Publisher : Springer Science & Business Media
ISBN 13 : 9401106231
Total Pages : 573 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Chemistry of Waste Minimization by : J.H. Clark

Download or read book Chemistry of Waste Minimization written by J.H. Clark and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 573 pages. Available in PDF, EPUB and Kindle. Book excerpt: Political pressure has translated into legislation requiring industry to reduce waste. There is an unprecedented opportunity for chemists to develop and apply new methods that result in waste reduction, and this book describes examples of new chemical methods used to reduce waste at source and to treat toxic waste.

Polymer Synthesis

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Publisher : Springer Science & Business Media
ISBN 13 : 9783540217114
Total Pages : 228 pages
Book Rating : 4.2/5 (171 download)

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Book Synopsis Polymer Synthesis by :

Download or read book Polymer Synthesis written by and published by Springer Science & Business Media. This book was released on 2004-10-08 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: 1. T. Takata, N. Kihara, Y. Furusho: Polyrotaxanes and Polycatenanes: Recent Advances in Syntheses and Applications of Polymers Comprising of Interlocked Structures.- 2. M. Suginome, Y. Ito: Transition Metal-Mediated Polymerization of Isocyanides.- 3. K. Osakada, D. Takeuchi: Coordination Polymerization of Dienes, Allenes and Methylenecycloalkanes.

Polymer Journal

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Publisher :
ISBN 13 :
Total Pages : 716 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Polymer Journal by :

Download or read book Polymer Journal written by and published by . This book was released on 2002 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Sustainable Polymers from Biomass

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Publisher : John Wiley & Sons
ISBN 13 : 352734019X
Total Pages : 458 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Sustainable Polymers from Biomass by : Chuanbing Tang

Download or read book Sustainable Polymers from Biomass written by Chuanbing Tang and published by John Wiley & Sons. This book was released on 2017-02-21 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering a unique perspective summarizing research on this timely important topic around the globe, this book provides comprehensive coverage of how molecular biomass can be transformed into sustainable polymers. It critically discusses and compares a few classes of biomass - oxygen-rich, hydrocarbon-rich, hydrocarbon and non-hydrocarbon (including carbon dioxide) as well as natural polymers - and equally includes products that are already commercialized. A must-have for both newcomers to the field as well as established researchers in both academia and industry.

Polymer Science: A Comprehensive Reference

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Author :
Publisher : Newnes
ISBN 13 : 0080878628
Total Pages : 7752 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis Polymer Science: A Comprehensive Reference by :

Download or read book Polymer Science: A Comprehensive Reference written by and published by Newnes. This book was released on 2012-12-05 with total page 7752 pages. Available in PDF, EPUB and Kindle. Book excerpt: The progress in polymer science is revealed in the chapters of Polymer Science: A Comprehensive Reference, Ten Volume Set. In Volume 1, this is reflected in the improved understanding of the properties of polymers in solution, in bulk and in confined situations such as in thin films. Volume 2 addresses new characterization techniques, such as high resolution optical microscopy, scanning probe microscopy and other procedures for surface and interface characterization. Volume 3 presents the great progress achieved in precise synthetic polymerization techniques for vinyl monomers to control macromolecular architecture: the development of metallocene and post-metallocene catalysis for olefin polymerization, new ionic polymerization procedures, and atom transfer radical polymerization, nitroxide mediated polymerization, and reversible addition-fragmentation chain transfer systems as the most often used controlled/living radical polymerization methods. Volume 4 is devoted to kinetics, mechanisms and applications of ring opening polymerization of heterocyclic monomers and cycloolefins (ROMP), as well as to various less common polymerization techniques. Polycondensation and non-chain polymerizations, including dendrimer synthesis and various "click" procedures, are covered in Volume 5. Volume 6 focuses on several aspects of controlled macromolecular architectures and soft nano-objects including hybrids and bioconjugates. Many of the achievements would have not been possible without new characterization techniques like AFM that allowed direct imaging of single molecules and nano-objects with a precision available only recently. An entirely new aspect in polymer science is based on the combination of bottom-up methods such as polymer synthesis and molecularly programmed self-assembly with top-down structuring such as lithography and surface templating, as presented in Volume 7. It encompasses polymer and nanoparticle assembly in bulk and under confined conditions or influenced by an external field, including thin films, inorganic-organic hybrids, or nanofibers. Volume 8 expands these concepts focusing on applications in advanced technologies, e.g. in electronic industry and centers on combination with top down approach and functional properties like conductivity. Another type of functionality that is of rapidly increasing importance in polymer science is introduced in volume 9. It deals with various aspects of polymers in biology and medicine, including the response of living cells and tissue to the contact with biofunctional particles and surfaces. The last volume is devoted to the scope and potential provided by environmentally benign and green polymers, as well as energy-related polymers. They discuss new technologies needed for a sustainable economy in our world of limited resources. Provides broad and in-depth coverage of all aspects of polymer science from synthesis/polymerization, properties, and characterization methods and techniques to nanostructures, sustainability and energy, and biomedical uses of polymers Provides a definitive source for those entering or researching in this area by integrating the multidisciplinary aspects of the science into one unique, up-to-date reference work Electronic version has complete cross-referencing and multi-media components Volume editors are world experts in their field (including a Nobel Prize winner)

Olefin Metathesis and Metathesis Polymerization

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Author :
Publisher : Elsevier
ISBN 13 : 0080537979
Total Pages : 489 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Olefin Metathesis and Metathesis Polymerization by : K. J. Ivin

Download or read book Olefin Metathesis and Metathesis Polymerization written by K. J. Ivin and published by Elsevier. This book was released on 1997-01-07 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis. Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering. - Discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst - Considers commercial processes with examples from existing and new technologies - Provides a complete overview of the subject from its beginning to the present day

Polymeric Materials Encyclopedia, Twelve Volume Set

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Publisher : CRC Press
ISBN 13 : 100071411X
Total Pages : 792 pages
Book Rating : 4.0/5 (7 download)

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Book Synopsis Polymeric Materials Encyclopedia, Twelve Volume Set by : Joseph C. Salamone

Download or read book Polymeric Materials Encyclopedia, Twelve Volume Set written by Joseph C. Salamone and published by CRC Press. This book was released on 2020-07-16 with total page 792 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Polymeric Materials Encyclopedia presents state-of-the-art research and development on the synthesis, properties, and applications of polymeric materials. This groundbreaking work includes the largest number of contributors in the world for a reference publication in polymer science, and examines many fields not covered in any other reference. With multiple articles on many subjects, the encyclopedia offers you a broad-based perspective on a multitude of topics, as well as detailed research information, figures, tables, illustrations, and references. Updates published as new research unfolds will continue to provide you with the latest advances in polymer science, and will keep the encyclopedia at the forefront of the field well into the future. From novices to experienced researchers in the field, anyone and everyone working in polymer science today needs this complete assessment of the state of the art. The entire 12-volume set will be available in your choice of printed or CD-ROM format.

Fundamentals of Polymerization

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Author :
Publisher : World Scientific
ISBN 13 : 9814322466
Total Pages : 468 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Fundamentals of Polymerization by : Broja Mohan Mandal

Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.

Neodymium Based Ziegler Catalysts - Fundamental Chemistry

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Author :
Publisher : Springer
ISBN 13 : 3540348115
Total Pages : 297 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Neodymium Based Ziegler Catalysts - Fundamental Chemistry by : Oskar Nuyken

Download or read book Neodymium Based Ziegler Catalysts - Fundamental Chemistry written by Oskar Nuyken and published by Springer. This book was released on 2006-09-21 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: