Kinetics Of Multistep Reactions

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Kinetics of Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
ISBN 13 : 0080473180
Total Pages : 508 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Kinetics of Multistep Reactions by : Friedrich G. Helfferich

Download or read book Kinetics of Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2004-09-15 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms

Kinetics of Homogeneous Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
ISBN 13 : 0080535267
Total Pages : 427 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Kinetics of Homogeneous Multistep Reactions by : Friedrich G. Helfferich

Download or read book Kinetics of Homogeneous Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2001-01-25 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on "fundamental" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.

Comprehensive Chemical Kinetics

Author : Nicholas Green
Publisher : Elsevier
ISBN 13 : 0080543448
Total Pages : 263 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Comprehensive Chemical Kinetics by : Nicholas Green

Download or read book Comprehensive Chemical Kinetics written by Nicholas Green and published by Elsevier. This book was released on 2003-11-21 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances. . Presents considerable advances in the field made during the last decade.. Treats both the statistical as well as the fully quantum mechanical view.

Comprehensive Chemical Kinetics: Kinetics of multistep reactions

Author : C. H. Bamford
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (74 download)

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Book Synopsis Comprehensive Chemical Kinetics: Kinetics of multistep reactions by : C. H. Bamford

Download or read book Comprehensive Chemical Kinetics: Kinetics of multistep reactions written by C. H. Bamford and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Chemical Kinetics

Author :
Publisher :
ISBN 13 : 9780444416315
Total Pages : 410 pages
Book Rating : 4.4/5 (163 download)

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Book Synopsis Comprehensive Chemical Kinetics by :

Download or read book Comprehensive Chemical Kinetics written by and published by . This book was released on 2001 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Chemical Kinetics: Kinetics of homogeneous multistep reactions

Author : Charles Frank Howlett Tipper
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (74 download)

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Book Synopsis Comprehensive Chemical Kinetics: Kinetics of homogeneous multistep reactions by : Charles Frank Howlett Tipper

Download or read book Comprehensive Chemical Kinetics: Kinetics of homogeneous multistep reactions written by Charles Frank Howlett Tipper and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Chemical Kinetics

Author : C.H. Bamford
Publisher :
ISBN 13 : 9780444416315
Total Pages : pages
Book Rating : 4.4/5 (163 download)

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Book Synopsis Comprehensive Chemical Kinetics by : C.H. Bamford

Download or read book Comprehensive Chemical Kinetics written by C.H. Bamford and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics of Homogeneous Multistep Reactions

Author : F. G. Helfferich
Publisher :
ISBN 13 : 9780444416315
Total Pages : 410 pages
Book Rating : 4.4/5 (163 download)

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Book Synopsis Kinetics of Homogeneous Multistep Reactions by : F. G. Helfferich

Download or read book Kinetics of Homogeneous Multistep Reactions written by F. G. Helfferich and published by . This book was released on 2001 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reaction Rate Theory and Rare Events

Author : Baron Peters
Publisher : Elsevier
ISBN 13 : 0444594701
Total Pages : 636 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Reaction Rate Theory and Rare Events by : Baron Peters

Download or read book Reaction Rate Theory and Rare Events written by Baron Peters and published by Elsevier. This book was released on 2017-03-22 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition state theory, RRKM theory, catalysis, diffusion limited kinetics, mean first passage times, Kramers theory, Grote-Hynes theory, transition path theory, non-adiabatic reactions, electron transfer, and topics from reaction network analysis. It is an essential reference for students, professors and scientists who use reaction rate theory or the theory of rare events. In addition, the book discusses transition state search algorithms, tunneling corrections, transmission coefficients, microkinetic models, kinetic Monte Carlo, transition path sampling, and importance sampling methods. The unified treatment in this book explains why chemical reactions and other rare events, while having many common theoretical foundations, often require very different computational modeling strategies. Offers an integrated approach to all simulation theories and reaction network analysis, a unique approach not found elsewhere Gives algorithms in pseudocode for using molecular simulation and computational chemistry methods in studies of rare events Uses graphics and explicit examples to explain concepts Includes problem sets developed and tested in a course range from pen-and-paper theoretical problems, to computational exercises

Chemical Kinetics with Mathcad and Maple

Author : Viktor Korobov
Publisher : Springer Science & Business Media
ISBN 13 : 3709105315
Total Pages : 353 pages
Book Rating : 4.7/5 (91 download)

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Book Synopsis Chemical Kinetics with Mathcad and Maple by : Viktor Korobov

Download or read book Chemical Kinetics with Mathcad and Maple written by Viktor Korobov and published by Springer Science & Business Media. This book was released on 2011-05-26 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: The authors explain at length the principles of chemical kinetics and approaches to computerized calculations in modern software suites — mathcad and maple. Mathematics is crucial in determining correlations in chemical processes and requires various numerical approaches. Often significant issues with mathematical formalizations of chemical problems arise and many kinetic problems can ́t be solved without computers. Numerous problems encountered in solving kinetics ́ calculations with detailed descriptions of the numerical tools are given. Special attention is given to electrochemical reactions, which fills a gap in existing texts not covering this topic in detail. The material demonstrates how these suites provide quick and precise behavior predictions for a system over time (for postulated mechanisms).Examples, i.e., oscillating and non-isothermal reactions, help explain the use of mathcad more efficiently. Also included are the results of authors’ own research toward effective computations.

CK-12 Chemistry - Second Edition

Author : CK-12 Foundation
Publisher : CK-12 Foundation
ISBN 13 : 1935983490
Total Pages : 995 pages
Book Rating : 4.9/5 (359 download)

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Book Synopsis CK-12 Chemistry - Second Edition by : CK-12 Foundation

Download or read book CK-12 Chemistry - Second Edition written by CK-12 Foundation and published by CK-12 Foundation. This book was released on 2011-10-14 with total page 995 pages. Available in PDF, EPUB and Kindle. Book excerpt: CK-12 Foundation's Chemistry - Second Edition FlexBook covers the following chapters:Introduction to Chemistry - scientific method, history.Measurement in Chemistry - measurements, formulas.Matter and Energy - matter, energy.The Atomic Theory - atom models, atomic structure, sub-atomic particles.The Bohr Model of the Atom electromagnetic radiation, atomic spectra. The Quantum Mechanical Model of the Atom energy/standing waves, Heisenberg, Schrodinger.The Electron Configuration of Atoms Aufbau principle, electron configurations.Electron Configuration and the Periodic Table- electron configuration, position on periodic table.Chemical Periodicity atomic size, ionization energy, electron affinity.Ionic Bonds and Formulas ionization, ionic bonding, ionic compounds.Covalent Bonds and Formulas nomenclature, electronic/molecular geometries, octet rule, polar molecules.The Mole Concept formula stoichiometry.Chemical Reactions balancing equations, reaction types.Stoichiometry limiting reactant equations, yields, heat of reaction.The Behavior of Gases molecular structure/properties, combined gas law/universal gas law.Condensed Phases: Solids and Liquids intermolecular forces of attraction, phase change, phase diagrams.Solutions and Their Behavior concentration, solubility, colligate properties, dissociation, ions in solution.Chemical Kinetics reaction rates, factors that affect rates.Chemical Equilibrium forward/reverse reaction rates, equilibrium constant, Le Chatelier's principle, solubility product constant.Acids-Bases strong/weak acids and bases, hydrolysis of salts, pHNeutralization dissociation of water, acid-base indicators, acid-base titration, buffers.Thermochemistry bond breaking/formation, heat of reaction/formation, Hess' law, entropy, Gibb's free energy. Electrochemistry oxidation-reduction, electrochemical cells.Nuclear Chemistry radioactivity, nuclear equations, nuclear energy.Organic Chemistry straight chain/aromatic hydrocarbons, functional groups.Chemistry Glossary

Rates of Soil Chemical Processes

Author : Donald L. Sparks
Publisher :
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Rates of Soil Chemical Processes by : Donald L. Sparks

Download or read book Rates of Soil Chemical Processes written by Donald L. Sparks and published by . This book was released on 1991 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kinetics of soil chemical reactions. Methods of obtaining and analyzin kinetic data. Relaxation methods for studying kinetics of soil chemical phenomena. Kinetics of ion sorptionon humic substances. Kinetics of sorption/desorption processes in soils. Modelling nonequilibrium reactions of inorganic solutes in soil columns. Sorption kinetics of organic chemicals: methods, models, and mechanisms.

Kinetics of Chemical Reactions

Author : Guy B. Marin
Publisher : John Wiley & Sons
ISBN 13 : 3527342958
Total Pages : 462 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Kinetics of Chemical Reactions by : Guy B. Marin

Download or read book Kinetics of Chemical Reactions written by Guy B. Marin and published by John Wiley & Sons. This book was released on 2019-04-29 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.

Chemical and Catalytic Reaction Engineering

Author : James J. Carberry
Publisher : Courier Corporation
ISBN 13 : 9780486417363
Total Pages : 676 pages
Book Rating : 4.4/5 (173 download)

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Book Synopsis Chemical and Catalytic Reaction Engineering by : James J. Carberry

Download or read book Chemical and Catalytic Reaction Engineering written by James J. Carberry and published by Courier Corporation. This book was released on 2001-01-01 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Designed to give chemical engineers background for managing chemical reactions, this text examines the behavior of chemical reactions and reactors; conservation equations for reactors; heterogeneous reactions; fluid-fluid and fluid-solid reaction systems; heterogeneous catalysis and catalytic kinetics; diffusion and heterogeneous catalysis; and analyses and design of heterogeneous reactors. 1976 edition.

Chemical Kinetics and Mechanism

Author : Michael Mortimer
Publisher : Royal Society of Chemistry
ISBN 13 : 9780854046706
Total Pages : 270 pages
Book Rating : 4.0/5 (467 download)

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Book Synopsis Chemical Kinetics and Mechanism by : Michael Mortimer

Download or read book Chemical Kinetics and Mechanism written by Michael Mortimer and published by Royal Society of Chemistry. This book was released on 2002 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation This book considers the role of the rate of reaction, starting with an introduction to chemical kinetics (measuring rates of reaction, order of reaction, reaction mechanisms). It then illustrates how the outcome of predictions can be made, where this is determined by the reaction rate. The concept of the functional group is introduced and is followed by a discussion of the characteristic reactions of several functional groups and the common mechanisms of organic reactions, substitution and elimination. An interactive CD-ROM accompanies the book. This book is part of The Molecular World series which aims to provide a broad foundation in chemistry.

Chemical Kinetics

Author : Manju Singh, 1st
Publisher :
ISBN 13 : 9781685760069
Total Pages : pages
Book Rating : 4.7/5 (6 download)

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Book Synopsis Chemical Kinetics by : Manju Singh, 1st

Download or read book Chemical Kinetics written by Manju Singh, 1st and published by . This book was released on 2021-09-24 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical kinetics is the study of how fast or slow chemical reactions occur. Rate of a chemical reaction is change in the concentration of reactants or products over a time period. It relates the rate of formation of products and the rate of disappearance of reactants in a given balanced chemical equation for the reaction. It explains how the activation energy affects the rates of chemical reaction. Use of Arrhenius Equation for the temperature dependence of rate of a chemical reaction and prediction of a rate law for a reaction having multistep mechanism given the individual steps in the mechanism are incorporated in the book. Chemical Kinetics is a core topic in all undergraduate chemistry courses. In this book, I have intended that it should provide a complete coverage of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, ad Chemical Engineering. The book explores the various factors that affect the rate of a chemical reaction. I hope the present book shall provide such knowledge of Chemical kinetics as is required by the average serious student of chemistry.

Fundamentals of Electrochemical Deposition

Author : Milan Paunovic
Publisher : John Wiley & Sons
ISBN 13 : 047000939X
Total Pages : 388 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis Fundamentals of Electrochemical Deposition by : Milan Paunovic

Download or read book Fundamentals of Electrochemical Deposition written by Milan Paunovic and published by John Wiley & Sons. This book was released on 2006-08-11 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: Excellent teaching and resource material . . . it is concise, coherently structured, and easy to read . . . highly recommended for students, engineers, and researchers in all related fields." -Corrosion on the First Edition of Fundamentals of Electrochemical Deposition From computer hardware to automobiles, medical diagnostics to aerospace, electrochemical deposition plays a crucial role in an array of key industries. Fundamentals of Electrochemical Deposition, Second Edition is a comprehensive introduction to one of today's most exciting and rapidly evolving fields of practical knowledge. The most authoritative introduction to the field so far, the book presents detailed coverage of the full range of electrochemical deposition processes and technologies, including: * Metal-solution interphase * Charge transfer across an interphase * Formation of an equilibrium electrode potential * Nucleation and growth of thin films * Kinetics and mechanisms of electrodeposition * Electroless deposition * In situ characterization of deposition processes * Structure and properties of deposits * Multilayered and composite thin films * Interdiffusion in thin film * Applications in the semiconductor industry and the field of medicine This new edition updates the prior edition to address the new developments in the science and its applications, with new chapters on innovative applications of electrochemical deposition in semiconductor technology, magnetism and microelectronics, and medical instrumentation. Added coverage includes such topics as binding energy, nanoclusters, atomic force, and scanning tunneling microscopy.Example problems at the end of chapters and other features clarify and improve understanding of the material. Written by an author team with extensive experience in both industry and academe, this reference and text provides a well-rounded introduction to the field for students, as well as a means for professional chemists, engineers, and technicians to expand and sharpen their skills in using the technology.