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Kinetics Of Atom Transfer Radical Polymerization
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Book Synopsis Controlled/Living Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Controlled/Living Radical Polymerization written by Krzysztof Matyjaszewski and published by OUP USA. This book was released on 2007-01-04 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.
Book Synopsis Handbook of Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Handbook of Radical Polymerization written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2003-04-14 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.
Book Synopsis The Chemistry of Radical Polymerization by : Graeme Moad
Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Book Synopsis Controlled/living Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Controlled/living Radical Polymerization written by Krzysztof Matyjaszewski and published by Academic. This book was released on 2009 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent progress in the field of controlled/living radical polymerization.
Book Synopsis Organic-Inorganic Hybrid Nanomaterials by : Susheel Kalia
Download or read book Organic-Inorganic Hybrid Nanomaterials written by Susheel Kalia and published by Springer. This book was released on 2014-12-04 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Book Synopsis Handbook of Polymer Synthesis, Characterization, and Processing by : Enrique Saldivar-Guerra
Download or read book Handbook of Polymer Synthesis, Characterization, and Processing written by Enrique Saldivar-Guerra and published by John Wiley & Sons. This book was released on 2013-02-28 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering a broad range of polymer science topics, Handbook of Polymer Synthesis, Characterization, and Processing provides polymer industry professionals and researchers in polymer science and technology with a single, comprehensive handbook summarizing all aspects involved in the polymer production chain. The handbook focuses on industrially important polymers, analytical techniques, and formulation methods, with chapters covering step-growth, radical, and co-polymerization, crosslinking and grafting, reaction engineering, advanced technology applications, including conjugated, dendritic, and nanomaterial polymers and emulsions, and characterization methods, including spectroscopy, light scattering, and microscopy.
Book Synopsis Fundamentals of Controlled/Living Radical Polymerization by : Nicolay V Tsarevsky
Download or read book Fundamentals of Controlled/Living Radical Polymerization written by Nicolay V Tsarevsky and published by Royal Society of Chemistry. This book was released on 2013-04-25 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.
Book Synopsis Monitoring Polymerization Reactions by : Wayne F. Reed
Download or read book Monitoring Polymerization Reactions written by Wayne F. Reed and published by John Wiley & Sons. This book was released on 2014-01-21 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.
Book Synopsis Fundamentals of Polymerization by : Broja Mohan Mandal
Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Book Synopsis Polymer Surfaces and Interfaces by : Manfred Stamm
Download or read book Polymer Surfaces and Interfaces written by Manfred Stamm and published by Springer Science & Business Media. This book was released on 2008-01-26 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: In what is an extremely practical and applicable new work, experts provide concise explanations, with examples and illustrations, of the key techniques in this important field. In each case, after basic principles have been reviewed, applications of the experimental techniques are discussed and illustrated with specific examples. Scientists and engineers in research and development will benefit from an application-oriented book that helps them to find solutions to both fundamental and applied problems. They will know that the surfaces and interfaces of polymers play an important role in most of the application areas of polymers, from moulds, foils, and composites, to biomaterials and applications in micro- and nanotechnology.
Book Synopsis Catalytic Polymerization of Cycloolefins by : V. Dragutan
Download or read book Catalytic Polymerization of Cycloolefins written by V. Dragutan and published by Elsevier. This book was released on 2000-06-26 with total page 1293 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.
Book Synopsis Template Polymerization by : Stefan Polowinski
Download or read book Template Polymerization written by Stefan Polowinski and published by ChemTec Publishing. This book was released on 1997 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Template polymerization is a new field in polymer synthesis but common practice in the biosynthesis since DNA is the most popular template or matrix on which proteins are built by living species. This field is relevant to the synthesis of polymers of controlled structure but its application goes beyond the synthesis. Materials are formulated in complex mixtures always containing components which can be regarded as templates on which other materials are formed, modified, or are interacted with. In the new product development the relevance of these phenomena is controlled by the order of addition which affects probabilities and preferences of interaction. The current publication outlines mechanisms of template polymerization, polycondensation, and copolymerization. These mechanisms, illustrated with numerous examples, indicate a range of possibilities which can be encountered in materials and utilized to modify their properties. Orientation of substrates on template and their effect on modification of their reactivity and properties such as, for example, absorption of light or water are also discussed. Several chapters contain information on these studies discussed with sufficient detail to give reader comprehensive understanding of the methods used in various research laboratories and their findings."--Publisher's description.
Book Synopsis Hydrogel Micro and Nanoparticles by : L. Andrew Lyon
Download or read book Hydrogel Micro and Nanoparticles written by L. Andrew Lyon and published by John Wiley & Sons. This book was released on 2012-09-24 with total page 633 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book provides experienced as well as young researchers with a topical view of the vibrant field of soft nanotechnology. In addition to elucidating the underlying concepts and principles that drive continued innovation, major parts of each chapter are devoted to detailed discussions of potential and already realized applications of micro- and nanogel- based materials. Examples of the diverse areas impacted by these materials are biocompatible coatings for implants, films for controlled drug release, self-healing soft materials and responsive hydrogels that react to varying pH conditions, temperature or light.
Book Synopsis The Chemistry of Polymers by : John W. Nicholson
Download or read book The Chemistry of Polymers written by John W. Nicholson and published by Royal Society of Chemistry. This book was released on 1997-12-31 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introductory text written from an applied angle, primarily for recent graduates now working in industry who haven't previously studied polymer chemistry. Available in the US from CRC Press. Annotation copyrighted by Book News, Inc., Portland, OR
Book Synopsis Chemical Kinetics and Reaction Dynamics by : Santosh K. Upadhyay
Download or read book Chemical Kinetics and Reaction Dynamics written by Santosh K. Upadhyay and published by Springer Science & Business Media. This book was released on 2007-04-29 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.
Book Synopsis Controlled and Living Polymerizations by : Krzysztof Matyjaszewski
Download or read book Controlled and Living Polymerizations written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.
Book Synopsis Polymer and Biopolymer Brushes by : Omar Azzaroni
Download or read book Polymer and Biopolymer Brushes written by Omar Azzaroni and published by John Wiley & Sons. This book was released on 2017-11-20 with total page 846 pages. Available in PDF, EPUB and Kindle. Book excerpt: Serves as a guide for seasoned researchers and students alike, who wish to learn about the cross-fertilization between biology and materials that is driving this emerging area of science This book covers the most relevant topics in basic research and those having potential technological applications for the field of biopolymer brushes. This area has experienced remarkable increase in development of practical applications in nanotechnology and biotechnology over the past decade. In view of the rapidly growing activity and interest in the field, this book covers the introductory features of polymer brushes and presents a unifying and stimulating overview of the theoretical aspects and emerging applications. It immerses readers in the historical perspective and the frontiers of research where our knowledge is increasing steadily—providing them with a feeling of the enormous potential, the multiple applications, and the many up-and-coming trends behind the development of macromolecular interfaces based on the use of polymer brushes. Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials offers chapters on: Functionalization of Surfaces Using Polymer Brushes; Polymer Brushes by ATRP and Surface-Mediated RAFT Polymerization for Biological Functions; Electro-Induced Copper Catalyzed Surface Modification with Monolayer and Polymer Brush; Polymer Brushes on Flat and Curved Substrates; Biomimetic Anchors for Antifouling Polymer Brush Coating; Glycopolymer Brushes Presenting Sugars in Their Natural Form; Smart Surfaces Modified with Phenylboronic Acid-Containing Polymer Brushes; DNA Brushes; Polymer Brushes as Interfacial Materials for Soft Metal Conductors and Electronics; and more. Presents a comprehensive theory/simulation section that will be valuable for all readers Includes chapters not only on the biological applications of polymer brushes but also on biological systems that resemble polymer brushes on flat surfaces Addresses applications in coatings, friction, sensors, microelectromechanical systems, and biomaterials Devotes particular attention to the functional aspects of hybrid nanomaterials employing polymer brushes as functional units Polymer and Biopolymer Brushes: Fundamentals and Applications in Materials is aimed at both graduate students and researchers new to this subject as well as scientists already engaged in the study and development of polymer brushes.
