Kinetics And Mechanisms Of Free Radical Ring Opening Polymerization

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Free-Radical Polymerization: Kinetics and Mechanism

Author : Michael Buback
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 328 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Free-Radical Polymerization: Kinetics and Mechanism by : Michael Buback

Download or read book Free-Radical Polymerization: Kinetics and Mechanism written by Michael Buback and published by Wiley-VCH. This book was released on 2002-09-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the past 15 years, free-radical polymerization has undergone a dramatic revitalization. "Living polymerization," ATRP (atomic transfer radical polymerization) and RAFT (reversible addition-fragmentation chain-transfer) polymerization have come to dominate research in this area. Powerful experimental and analytical techniques are now used to probe the basic kinetics and mechanisms of the processes involved. High degrees of control over physical and chemical properties have lead to more efficient polymer production and new products. The state of the art in all these areas was presented and discussed at the IUPAC-sponsored "International Symposium on Free-Radical Polymerization: Kinetics and Mechanism" (SML '01) held in IL Ciocco, Italy, in June 2001. This volume of Macromolecular Symposia presents an excellent overview of modern research in free-radical polymerization.

Cationic Ring-Opening Polymerization

Author : Stanislaw Penczek
Publisher : Springer
ISBN 13 : 9783662152584
Total Pages : 317 pages
Book Rating : 4.1/5 (525 download)

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Book Synopsis Cationic Ring-Opening Polymerization by : Stanislaw Penczek

Download or read book Cationic Ring-Opening Polymerization written by Stanislaw Penczek and published by Springer. This book was released on 2014-03-12 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Particles

Author : Masayoshi Okubo
Publisher : Springer Science & Business Media
ISBN 13 : 9783540229230
Total Pages : 388 pages
Book Rating : 4.2/5 (292 download)

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Book Synopsis Polymer Particles by : Masayoshi Okubo

Download or read book Polymer Particles written by Masayoshi Okubo and published by Springer Science & Business Media. This book was released on 2005-02-10 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.

Free-Radical Polymerization: Kinetics and Mechanism

Author : I. Meisel
Publisher : Wiley-VCH
ISBN 13 : 9783527304721
Total Pages : 328 pages
Book Rating : 4.3/5 (47 download)

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Book Synopsis Free-Radical Polymerization: Kinetics and Mechanism by : I. Meisel

Download or read book Free-Radical Polymerization: Kinetics and Mechanism written by I. Meisel and published by Wiley-VCH. This book was released on 2002-09-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the past 15 years, free-radical polymerization has undergone a dramatic revitalization. "Living polymerization," ATRP (atomic transfer radical polymerization) and RAFT (reversible addition-fragmentation chain-transfer) polymerization have come to dominate research in this area. Powerful experimental and analytical techniques are now used to probe the basic kinetics and mechanisms of the processes involved. High degrees of control over physical and chemical properties have lead to more efficient polymer production and new products. The state of the art in all these areas was presented and discussed at the IUPAC-sponsored "International Symposium on Free-Radical Polymerization: Kinetics and Mechanism" (SML '01) held in IL Ciocco, Italy, in June 2001. This volume of Macromolecular Symposia presents an excellent overview of modern research in free-radical polymerization.

Alternating Copolymers

Author : J.M.G. Cowie
Publisher : Springer Science & Business Media
ISBN 13 : 1475791399
Total Pages : 292 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Alternating Copolymers by : J.M.G. Cowie

Download or read book Alternating Copolymers written by J.M.G. Cowie and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Examination of the early literature attests to the fact that the study of copolymerization was initiated when polymer science was in its infancy. It has continued to grow to a subject of major importance and has been a source of interest to both academic and industrialist alike. The wide spectrum of structures and properties available in the statistical copolymer has made this a fruitful field of exploration, but one particular and more restricted form which has held its own fascination for many is the limiting case of the strictly alternating copolymer. This is formed, in the ideal situation, when two monomers in a reaction mixture add consecutively to create a polymer chain with a regular {ABABAB} structure, irrespective of the monomer feed ratio. When this happens the resulting copolymer will always have the same composition, a feature which can be advantageous but also somewhat restrictive, as the ability to vary the properties is then limited. Within a series entitled Speciality Polymers it seems appropriate then to deal with this subject, particularly as no previous attempt has been made to draw together the various facets of alternating copolymerization into one volume. It also seems timely to present a more unified picture of the subject which will also illustrate the progress made.

Expanding Monomers

Author : Rajender Kumar Sadhir
Publisher : CRC Press
ISBN 13 : 1000098540
Total Pages : 416 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Expanding Monomers by : Rajender Kumar Sadhir

Download or read book Expanding Monomers written by Rajender Kumar Sadhir and published by CRC Press. This book was released on 2020-07-25 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expanding Monomers: Synthesis, Characterization, and Applications provides a thorough discussion of expanding polymer systems and their potential applications. The scope of the book includes background information on conventional monomers, their polymeric systems, and associated shrinkage problems. Monomers that expand during polymerization are covered in detail, including their synthesis and characterization. Polymerization (homopolymerization and copolymerization) of expanding monomers is discussed, in addition to mechanisms and kinetics of several polymerization processes, such as cationic initiation and free radical ring-opening polymerization. The book also explores various applications in which expanding polymer systems have potential. These applications include coatings, casting and potting materials, composite adhesives, and electrical insulations. Expanding Monomers: Synthesis, Characterization, and Applications will be valuable as a reference for manufacturers, researchers, teachers, and students in polymer and materials science, in addition to industry and university libraries.

The Chemistry of Radical Polymerization

Author : Graeme Moad
Publisher : Elsevier
ISBN 13 : 0080442889
Total Pages : 667 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis The Chemistry of Radical Polymerization by : Graeme Moad

Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.

Introduction to Polymers, Third Edition

Author : Robert J. Young
Publisher : CRC Press
ISBN 13 : 0849339294
Total Pages : 690 pages
Book Rating : 4.8/5 (493 download)

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Book Synopsis Introduction to Polymers, Third Edition by : Robert J. Young

Download or read book Introduction to Polymers, Third Edition written by Robert J. Young and published by CRC Press. This book was released on 2011-06-27 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thoroughly updated, Introduction to Polymers, Third Edition presents the science underpinning the synthesis, characterization and properties of polymers. The material has been completely reorganized and expanded to include important new topics and provide a coherent platform for teaching and learning the fundamental aspects of contemporary polymer science. New to the Third Edition Part I This first part covers newer developments in polymer synthesis, including ‘living’ radical polymerization, catalytic chain transfer and free-radical ring-opening polymerization, along with strategies for the synthesis of conducting polymers, dendrimers, hyperbranched polymers and block copolymers. Polymerization mechanisms have been made more explicit by showing electron movements. Part II In this part, the authors have added new topics on diffusion, solution behaviour of polyelectrolytes and field-flow fractionation methods. They also greatly expand coverage of spectroscopy, including UV visible, Raman, infrared, NMR and mass spectroscopy. In addition, the Flory–Huggins theory for polymer solutions and their phase separation is treated more rigorously. Part III A completely new, major topic in this section is multicomponent polymer systems. The book also incorporates new material on macromolecular dynamics and reptation, liquid crystalline polymers and thermal analysis. Many of the diagrams and micrographs have been updated to more clearly highlight features of polymer morphology. Part IV The last part of the book contains major new sections on polymer composites, such as nanocomposites, and electrical properties of polymers. Other new topics include effects of chain entanglements, swelling of elastomers, polymer fibres, impact behaviour and ductile fracture. Coverage of rubber-toughening of brittle plastics has also been revised and expanded. While this edition adds many new concepts, the philosophy of the book remains unchanged. Largely self-contained, the text fully derives most equations and cross-references topics between chapters where appropriate. Each chapter not only includes a list of further reading to help readers expand their knowledge of the subject but also provides problem sets to test understanding, particularly of numerical aspects.

Polymer Reaction Engineering

Author : Jose Asua
Publisher : John Wiley & Sons
ISBN 13 : 0470691425
Total Pages : 392 pages
Book Rating : 4.4/5 (76 download)

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Book Synopsis Polymer Reaction Engineering by : Jose Asua

Download or read book Polymer Reaction Engineering written by Jose Asua and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers are an example of “products-by-process”, where the final product properties are mostly determined during manufacture, in the reactor. An understanding of processes occurring in the polymerization reactor is therefore crucial to achieving efficient, consistent, safe and environmentally friendly production of polymeric materials. Polymer Reaction Engineering provides the link between the fundamentals of polymerization kinetics and polymer microstructure achieved in the reactor. Organized according to the type of polymerization, each chapter starts with a description of the main polymers produced by the particular method, their key microstructural features and their applications Polymerization kinetics and its effect on reactor configuration, mass and energy balances and scale-up are covered in detail. The text is illustrated with examples emphasizing general concepts, principles and methodology. Written as an authoritative guide for chemists and chemical engineers in industry and academe, Polymer Reaction Engineering will also be a key reference source for advanced courses in polymer chemistry and technology.

Nitroxides

Author : Olivier Ouari
Publisher : Royal Society of Chemistry
ISBN 13 : 1788019660
Total Pages : 611 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Nitroxides by : Olivier Ouari

Download or read book Nitroxides written by Olivier Ouari and published by Royal Society of Chemistry. This book was released on 2021-05-13 with total page 611 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.

Handbook of Ring-Opening Polymerization

Author : Philippe Dubois
Publisher : John Wiley & Sons
ISBN 13 : 3527319530
Total Pages : 427 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Handbook of Ring-Opening Polymerization by : Philippe Dubois

Download or read book Handbook of Ring-Opening Polymerization written by Philippe Dubois and published by John Wiley & Sons. This book was released on 2009-03-02 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes. Of much interest to chemists in academia and industry.

Concise Polymeric Materials Encyclopedia

Author : Joseph C. Salamone
Publisher : CRC Press
ISBN 13 : 9780849322266
Total Pages : 1778 pages
Book Rating : 4.3/5 (222 download)

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Book Synopsis Concise Polymeric Materials Encyclopedia by : Joseph C. Salamone

Download or read book Concise Polymeric Materials Encyclopedia written by Joseph C. Salamone and published by CRC Press. This book was released on 1998-08-28 with total page 1778 pages. Available in PDF, EPUB and Kindle. Book excerpt: Concise Polymeric Materials Encyclopedia culls the most used, widely applicable articles from the Polymeric Materials Encyclopedia - more than 1,100 - and presents them to you in a condensed, well-ordered format. Featuring contributions from more than 1,800 scientists from all over the world, the book discusses a vast array of subjects related to the: synthesis, properties, and applications of polymeric materials development of modern catalysts in preparing new or modified polymers modification of existing polymers by chemical and physical processes biologically oriented polymers This comprehensive, easy-to-use resource on modern polymeric materials serves as an invaluable addition to reference collections in the polymer field.

Carraher's Polymer Chemistry, Eighth Edition

Author : Charles E. Carraher Jr.
Publisher : CRC Press
ISBN 13 : 1439809569
Total Pages : 804 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Carraher's Polymer Chemistry, Eighth Edition by : Charles E. Carraher Jr.

Download or read book Carraher's Polymer Chemistry, Eighth Edition written by Charles E. Carraher Jr. and published by CRC Press. This book was released on 2010-10-13 with total page 804 pages. Available in PDF, EPUB and Kindle. Book excerpt: Updated to reflect a growing focus on green chemistry in the scientific community and in compliance with the American Chemical Society’s Committee on Professional Training guidelines, Carraher’s Polymer Chemistry, Eighth Edition integrates the core areas that contribute to the growth of polymer science. It supplies the basic understanding of polymers essential to the training of science, biomedical, and engineering students. New in the Eighth Edition: Updating of analytical, physical, and special characterization techniques Increased emphasis on carbon nanotubes, tapes and glues, butyl rubber, polystyrene, polypropylene, polyethylene, poly(ethylene glycols), shear-thickening fluids, photo-chemistry and photophysics, dental materials, and aramids New sections on copolymers, including fluoroelastomers, nitrile rubbers, acrylonitrile-butadiene-styrene terpolymers, and EPDM rubber New units on spliceosomes, asphalt, and fly ash and aluminosilicates Larger focus on the molecular behavior of materials, including nano-scale behavior, nanotechnology, and nanomaterials Continuing to provide a user-friendly approach to the world of polymeric materials, the book allows students to integrate their chemical knowledge and establish a connection between fundamental and applied chemical information. It contains all of the elements of an introductory text with synthesis, property, application, and characterization. Special sections in each chapter contain definitions, learning objectives, questions, and additional reading, with case studies woven into the text fabric. Symbols, trade names, websites, and other useful ancillaries appear in the appendices to supplement the text.

Expanding Monomers

Author : Rajender Kumar Sadhir
Publisher : CRC Press
ISBN 13 : 9780849351563
Total Pages : 414 pages
Book Rating : 4.3/5 (515 download)

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Book Synopsis Expanding Monomers by : Rajender Kumar Sadhir

Download or read book Expanding Monomers written by Rajender Kumar Sadhir and published by CRC Press. This book was released on 1992-07-06 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expanding Monomers: Synthesis, Characterization, and Applications provides a thorough discussion of expanding polymer systems and their potential applications. The scope of the book includes background information on conventional monomers, their polymeric systems, and associated shrinkage problems. Monomers that expand during polymerization are covered in detail, including their synthesis and characterization. Polymerization (homopolymerization and copolymerization) of expanding monomers is discussed, in addition to mechanisms and kinetics of several polymerization processes, such as cationic initiation and free radical ring-opening polymerization. The book also explores various applications in which expanding polymer systems have potential. These applications include coatings, casting and potting materials, composite adhesives, and electrical insulations. Expanding Monomers: Synthesis, Characterization, and Applications will be valuable as a reference for manufacturers, researchers, teachers, and students in polymer and materials science, in addition to industry and university libraries.

CVD Polymers

Author : Karen K. Gleason
Publisher : John Wiley & Sons
ISBN 13 : 352769028X
Total Pages : 484 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis CVD Polymers by : Karen K. Gleason

Download or read book CVD Polymers written by Karen K. Gleason and published by John Wiley & Sons. This book was released on 2015-04-01 with total page 484 pages. Available in PDF, EPUB and Kindle. Book excerpt: The method of CVD (chemical vapor deposition) is a versatile technique to fabricate high-quality thin films and structured surfaces in the nanometer regime from the vapor phase. Already widely used for the deposition of inorganic materials in the semiconductor industry, CVD has become the method of choice in many applications to process polymers as well. This highly scalable technique allows for synthesizing high-purity, defect-free films and for systematically tuning their chemical, mechanical and physical properties. In addition, vapor phase processing is critical for the deposition of insoluble materials including fluoropolymers, electrically conductive polymers, and highly crosslinked organic networks. Furthermore, CVD enables the coating of substrates which would otherwise dissolve or swell upon exposure to solvents. The scope of the book encompasses CVD polymerization processes which directly translate the chemical mechanisms of traditional polymer synthesis and organic synthesis in homogeneous liquids into heterogeneous processes for the modification of solid surfaces. The book is structured into four parts, complemented by an introductory overview of the diverse process strategies for CVD of polymeric materials. The first part on the fundamentals of CVD polymers is followed by a detailed coverage of the materials chemistry of CVD polymers, including the main synthesis mechanisms and the resultant classes of materials. The third part focuses on the applications of these materials such as membrane modification and device fabrication. The final part discusses the potential for scale-up and commercialization of CVD polymers.

Fundamentals of Polymerization

Author : Broja Mohan Mandal
Publisher : World Scientific
ISBN 13 : 9814322466
Total Pages : 468 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Fundamentals of Polymerization by : Broja Mohan Mandal

Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.

Free-Radical Retrograde-Precipitation Polymerization (FRRPP)

Author : Gerard Caneba
Publisher : Springer Science & Business Media
ISBN 13 : 3642030254
Total Pages : 318 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Free-Radical Retrograde-Precipitation Polymerization (FRRPP) by : Gerard Caneba

Download or read book Free-Radical Retrograde-Precipitation Polymerization (FRRPP) written by Gerard Caneba and published by Springer Science & Business Media. This book was released on 2010-01-08 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing insight on the free-radical retrograde-precipitation polymerization process, this volume examines the phenomenological aspects in comparison to other materials, such as nanoscale confinement behavior and nucleated hot spots.