Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
Download Kinetic Investigations Of Free Radical Addition Reactions full books in PDF, epub, and Kindle. Read online Kinetic Investigations Of Free Radical Addition Reactions ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Author : James S. Poole
Publisher :
ISBN 13 :
Total Pages : 530 pages
Book Rating : 4.:/5 (222 download)
Download or read book Kinetic Investigations of Free Radical Addition Reactions written by James S. Poole and published by . This book was released on 1999 with total page 530 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael Silaev
Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659373565
Total Pages : 60 pages
Book Rating : 4.3/5 (735 download)
Download or read book The Kinetic Investigation of the Free-Radical Addition written by Michael Silaev and published by LAP Lambert Academic Publishing. This book was released on 2013 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt: Five reaction schemes are suggested for the initiated nonbranched-chain addition of free radicals to the multiple bonds of the unsaturated compounds. The proposed schemes include the reaction competing with chain propagation reactions through a reactive free radical. The chain evolution stage in these schemes involves three or four types of free radicals. One of them is relatively low-reactive and inhibits the chain process by shortening of the kinetic chain length. Based on the suggested schemes, nine rate equations (containing one to three parameters to be determined directly) are deduced using quasi-steady-state treatment. These equations provide good fits for the nonmonotonic (peaking) dependences of the formation rates of the molecular products (1:1 adducts) on the concentration of the unsaturated component in binary systems consisting of a saturated component (hydrocarbon, alcohol, etc.) and an unsaturated component (olefin, allyl alcohol, formaldehyde, or dioxygen). The unsaturated compound in these systems is both a reactant and an autoinhibitor generating low-reactive free radicals. The energetics of the key radical-molecule reactions is considered.
Author : Howard Maskill
Publisher : John Wiley & Sons
ISBN 13 : 0470994169
Total Pages : 392 pages
Book Rating : 4.4/5 (79 download)
Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.
Author : E. T. Denisov
Publisher : John Wiley & Sons
ISBN 13 : 0471281832
Total Pages : 903 pages
Book Rating : 4.4/5 (712 download)
Download or read book Handbook of Free Radical Initiators written by E. T. Denisov and published by John Wiley & Sons. This book was released on 2005-01-14 with total page 903 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Author : Milan Lazar
Publisher : CRC Press
ISBN 13 : 9780849353871
Total Pages : 322 pages
Book Rating : 4.3/5 (538 download)
Download or read book Free Radicals in Chemistry and Biology written by Milan Lazar and published by CRC Press. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.
Author : V. Tamara Perchyonok
Publisher : Royal Society of Chemistry
ISBN 13 : 1849730008
Total Pages : 142 pages
Book Rating : 4.8/5 (497 download)
Download or read book Radical Reactions in Aqueous Media written by V. Tamara Perchyonok and published by Royal Society of Chemistry. This book was released on 2010 with total page 142 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.
Author : Le Zeng
Publisher :
ISBN 13 :
Total Pages : 260 pages
Book Rating : 4.:/5 (224 download)
Download or read book Kinetic Studies on Free Radical Reactions Involving Chiral Radicals written by Le Zeng and published by . This book was released on 2005 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Hamish Cattanach Low
Publisher :
ISBN 13 :
Total Pages : 354 pages
Book Rating : 4.:/5 (651 download)
Download or read book Kinetic Studies of Free Radical Reactions written by Hamish Cattanach Low and published by . This book was released on 1977 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Edgar William Richard Steacie
Publisher :
ISBN 13 :
Total Pages : 568 pages
Book Rating : 4.3/5 (21 download)
Download or read book Atomic and Free Radical Reactions written by Edgar William Richard Steacie and published by . This book was released on 1946 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : D. I. Davies
Publisher : Springer Science & Business Media
ISBN 13 : 3642669220
Total Pages : 181 pages
Book Rating : 4.6/5 (426 download)
Download or read book Free Radicals in Organic Synthesis written by D. I. Davies and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : José A. Martinho Simões
Publisher : Springer Science & Business Media
ISBN 13 : 9780751403787
Total Pages : 328 pages
Book Rating : 4.4/5 (37 download)
Download or read book Energetics of Organic Free Radicals written by José A. Martinho Simões and published by Springer Science & Business Media. This book was released on 1996-04-30 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current volume consists of eight chapters which interweave various aspects of the structure, energetics and reactivity of organic free radicals, all combining pedagogical insights with current research. The first is by Walling in which a personalized overview is given by one of the modern pioneers of the discipline. In the next two chapters, Tsang, and Traeger and Kompe, present key thermochemical and kinetic quantities from the complementary vantage points of the studies of neutral and cationic species. The fourth chapter by Francisco and Montgomery discusses the armamentarium of modern theory as applied to species with unpaired electrons, while the next chapter by Goodman presents the theory, methodology and results from photoacoustic calorimetry, a novel and powerful experimental technique. Martinho Simoes and Minas da Piedade interrelate organometallic and free radical chemistry, while Greenberg and Liebman consider resonance energy and rearrangements as applied to small molecules and enzyme cofactors alike. The volume ends with the chapter by Tanko and Suleman, which describes the surprising and diverse solvent effects which modulate free radical chem istry. This volume will make it apparent to entry-level graduate students and senior researchers alike that much is known and much remains to be done in both the qualitative understanding and quantitative insights of the chemistry of organic free radicals. Jose Artur Martinho Simoes Arthur Greenberg Joel F. Liebman vii Editorial Advisory Board WESTON T. BORDEN ALAN P.
Author : Rayson L. Huang
Publisher : Hodder Education
ISBN 13 :
Total Pages : 264 pages
Book Rating : 4.F/5 ( download)
Download or read book The Chemistry of Free Radicals written by Rayson L. Huang and published by Hodder Education. This book was released on 1974 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kopin Liu
Publisher : World Scientific
ISBN 13 : 9789810229832
Total Pages : 488 pages
Book Rating : 4.2/5 (298 download)
Download or read book The Chemical Dynamics and Kinetics of Small Radicals written by Kopin Liu and published by World Scientific. This book was released on 1995 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights recent progress in the chemistry of radicals. Developments include the growing use of lasers to generate radicals, the application of lasers to provide state, angular, polarization, energy and real-time resolution in kinetics and dynamics experiments, the development of theories for handling the reactions of radicals, and the simulation of the reaction dynamics of increasingly larger systems for direct comparison to experimental results. The book emphasizes the increasing interaction between experimental dynamics, kinetics and theory. It is appropriate for chemistry graduate students and researchers about to enter the field. However, the discussions of some topics progress to a more advanced level so that even an expert will find the book useful.
Author : William Pryor
Publisher : Elsevier
ISBN 13 : 032315221X
Total Pages : 400 pages
Book Rating : 4.3/5 (231 download)
Download or read book Frontiers of Free Radical Chemistry written by William Pryor and published by Elsevier. This book was released on 2012-12-02 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Frontiers of Free Radical Chemistry covers the proceedings of the 1979 symposium on Frontiers of Free Radical Chemistry, held in Louisiana State University Chemistry Department, supported by the Exxon Education Foundation. The contributors discuss the mechanisms of hydrocarbon cracking; oxidation processes; inhibition; and the theory of organic radical reactions, halogenations, and organic peroxide chemistry. This book is organized into three parts encompassing 15 chapters. Part I deals with the understanding of molecular and free radical mechanisms in predicting thermochemical data for radicals and molecules. This part also describes the relationship between distortions of organic molecules and the reactions of pericyclic, ionic, and radical molecules. Part II presents quantitative evaluations of gas phase reactions or carbynes and hydrocarbon pyrolysis and cracking. Discussions on the reactions of free atoms and radicals in the chemistry of the stratosphere and natural troposphere, with an emphasis on the ozone layer and its potential depletion by artificial pollutants, are included in this part. Part III explores the pertinent free radical reactions related to fuel research. Petroleum chemists, researchers, and engineers will find this book invaluable.
Author : Nathan Price
Publisher : American Chemical Society
ISBN 13 : 0841299706
Total Pages : 218 pages
Book Rating : 4.8/5 (412 download)
Download or read book Radical Reactions written by Nathan Price and published by American Chemical Society. This book was released on 2023-03-31 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical Reactions provides the reader a brief overview of radical reactions, an overview overlooked in most undergraduate chemistry curriculums. Most of the exciting developments in the field of radical and radical ion chemistry came about because someone understood the fundamentals and was able to design new chemistry based upon that understanding. The target audience is individuals who have had at least one semester of organic chemistry.
Author : Malcolm D. Forbes
Publisher : John Wiley & Sons
ISBN 13 : 9780470584101
Total Pages : 300 pages
Book Rating : 4.5/5 (841 download)
Download or read book Carbon-Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Author : Cheves Walling
Publisher :
ISBN 13 :
Total Pages : 654 pages
Book Rating : 4.:/5 (38 download)
Download or read book Free Radicals in Solution written by Cheves Walling and published by . This book was released on 1957 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt:
