Isotopic Assessment Of Heterogeneous Catalysis

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Isotopic Assessment of Heterogeneous Catalysis

Author : John Happel
Publisher : Elsevier
ISBN 13 : 0323160182
Total Pages : 209 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Isotopic Assessment of Heterogeneous Catalysis by : John Happel

Download or read book Isotopic Assessment of Heterogeneous Catalysis written by John Happel and published by Elsevier. This book was released on 2012-12-02 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt: Isotopic Assessment of Heterogeneous Catalysis deals with the use of isotopic tracing to study the reaction mechanisms involved in heterogeneous catalysis. It presents special methods for using isotopic and radioactive atomic species for obtaining meaningful kinetic data that can be quantitatively used in mechanistic modeling. It also considers a number of industrial reactions under steady-state reaction conditions in which superposed tracer transfer is also at steady state. This book is comprised of eight chapters and begins with an introduction to heterogeneous catalysis and an approach to reaction modeling, as well as the experimental reactors for obtaining the type of measurements and data needed in transient modeling. The application of isotopes in studies of heterogeneous catalysis is also discussed. Subsequent chapters focus on the choice of intermediates and reaction steps in tracer experiments; the number of overall stoichiometric chemical reactions that can occur in order to generate product molecules from reactants; superposition modeling of mechanisms; and steady-state tracing. Transient tracing and the development of rate equations are also described. This monograph is intended primarily for students and teachers of such subjects as physical chemistry, as well as research scientists and technologists.

Isotopes In Heterogeneous Catalysis

Author : Justin S J Hargreaves
Publisher : World Scientific
ISBN 13 : 1783260157
Total Pages : 306 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Isotopes In Heterogeneous Catalysis by : Justin S J Hargreaves

Download or read book Isotopes In Heterogeneous Catalysis written by Justin S J Hargreaves and published by World Scientific. This book was released on 2006-04-11 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this book is to review the current, state-of-the-art application of isotopic methods to the field of heterogeneous catalysis. Isotopic studies are arguably the ultimate technique in in situ methods for heterogeneous catalysis. In this review volume, chapters have been contributed by experts in the field and the coverage includes both the application of specific isotopes — Deuterium, Tritium, Carbon-14, Sulfur-35 and Oxygen-18 - as well as isotopic techniques — determination of surface mobility, steady state transient isotope kinetic analysis, and positron emission profiling.

Isotopic Assessment of Heterogeneous Adsorbents

Author : Marilyn May-Lin Ho
Publisher :
ISBN 13 :
Total Pages : 390 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Isotopic Assessment of Heterogeneous Adsorbents by : Marilyn May-Lin Ho

Download or read book Isotopic Assessment of Heterogeneous Adsorbents written by Marilyn May-Lin Ho and published by . This book was released on 1995 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces

Author : Dennis R. Salahub
Publisher : Springer Science & Business Media
ISBN 13 : 9401128227
Total Pages : 428 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces by : Dennis R. Salahub

Download or read book Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces written by Dennis R. Salahub and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-ligand interactions are currently being studied in different fields, from a variety of points of view, and recent progress has been substantial. Whole new classes of compounds and reactions have been found; an arsenal of physical methods has been developed; mechanistic detail can be ascertained to an increasingly minute degree; and the theory is being developed to handle systems of ever-growing complexity. As usual, such multidisciplinarity leads to great opportunities, coupled with great problems of communication between specialists. It is in its promotion of interactions across these fields that Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces makes its timely contribution: the tools, both theoretical and experimental, are highly developed, and fundamental questions remain unanswered. The most fundamental of these concerns the nature of the microscopic interactions between metal atoms (clusters, surfaces) and ligands (atoms, molecules, absorbates, reagents, products) and the changes in these interactions during physical and chemical transformation. In Metal-Ligand Interactions, leading experts discuss the following, vital aspects: ab initio theory, semi-empirical theory, density functional theory, complexes and clusters, surfaces, and catalysis.

Complexity and Complex Chemo-Electric Systems

Author : Stanislaw Sieniutycz
Publisher : Elsevier
ISBN 13 : 0128236361
Total Pages : 324 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Complexity and Complex Chemo-Electric Systems by : Stanislaw Sieniutycz

Download or read book Complexity and Complex Chemo-Electric Systems written by Stanislaw Sieniutycz and published by Elsevier. This book was released on 2021-02-09 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Complexity and Complex Chemo-Electric Systems presents an analysis and synthesis of chemo-electric systems, providing insights on transports in electrolytes, electrode reactions, electrocatalysis, electrochemical membranes, and various aspects of heterogeneous systems and electrochemical engineering. The book describes the properties of complexity and complex chemo-electric systems as the consequence of formulations, definitions, tools, solutions and results that are often consistent with the best performance of the system. The book handles cybernetics, systems theory and advanced contemporary techniques such as optimal control, neural networks and stochastic optimizations (adaptive random search, genetic algorithms, and simulated annealing). A brief part of the book is devoted to issues such as various definitions of complexity, hierarchical structures, self-organization examples, special references, and historical issues. This resource complements Sieniutycz' recently published book, Complexity and Complex Thermodynamic Systems, with its inclusion of complex chemo-electric systems in which complexities, emergent properties and self-organization play essential roles. - Covers the theory and applications of complex chemo-electric systems through modeling, analysis, synthesis and optimization - Provides a clear presentation of the applications of transport theory to electrolyte solutions, heterogeneous electrochemical systems, membranes, electro-kinetic phenomena and interface processes - Includes numerous explanatory graphs and drawings that illustrate the properties and complexities in complex chemo-electric systems - Written by an experienced expert in the field of advanced methods in thermodynamics and related aspects of macroscopic physics

Aqueous Systems at Elevated Temperatures and Pressures

Author : Roberto Fernandez-Prini
Publisher : Elsevier
ISBN 13 : 0080471994
Total Pages : 767 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Aqueous Systems at Elevated Temperatures and Pressures by : Roberto Fernandez-Prini

Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds

Catalysis

Author : James J Spivey
Publisher : Royal Society of Chemistry
ISBN 13 : 1847553249
Total Pages : 354 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Catalysis by : James J Spivey

Download or read book Catalysis written by James J Spivey and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr

Preparation of Compounds Labeled with Tritium and Carbon-14

Author : Rolf Voges
Publisher : John Wiley & Sons
ISBN 13 : 9780470743430
Total Pages : 682 pages
Book Rating : 4.7/5 (434 download)

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Book Synopsis Preparation of Compounds Labeled with Tritium and Carbon-14 by : Rolf Voges

Download or read book Preparation of Compounds Labeled with Tritium and Carbon-14 written by Rolf Voges and published by John Wiley & Sons. This book was released on 2009-03-12 with total page 682 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compounds labeled with carbon-14 and tritium are indispensable tools for research in biomedical sciences, discovery and development of pharmaceuticals and agrochemicals. Preparation of Compounds Labeled with Tritium and Carbon-14 is a comprehensive, authoritative and up-to-date discussion of the strategies, synthetic approaches, reactions techniques, and resources for the preparation of compounds labeled with either of these isotopes. A large number of examples are presented for the use of isotopic sources and building blocks in the preparation of labeled target compounds, illustrating the range of possibilities for embedding isotopic labels in selected moieties of complex structures. Topics include: Formulation of synthetic strategies for preparing labeled compounds Isotope exchange methods and synthetic alternatives for preparing tritiated compounds In-depth discussion of carbon-14 building blocks and their utility in synthesis Preparation of enantiomerically pure isotopically labeled compounds Applications of biotransformations Preparation of Compounds Labeled with Tritium and Carbon-14 is an essential guide to the specialist strategies and tactics used by chemists to prepare compounds tagged with theradioactive atoms carbon-14 and tritium.

Novel Production Methods for Ethylene, Light Hydrocarbons, and Aromatics

Author : Lyle Albright
Publisher : CRC Press
ISBN 13 : 9780824785888
Total Pages : 568 pages
Book Rating : 4.7/5 (858 download)

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Book Synopsis Novel Production Methods for Ethylene, Light Hydrocarbons, and Aromatics by : Lyle Albright

Download or read book Novel Production Methods for Ethylene, Light Hydrocarbons, and Aromatics written by Lyle Albright and published by CRC Press. This book was released on 1991-09-25 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Infrared Spectroscopy of Ultrathin Films

Author : Valeri P. Tolstoy
Publisher : John Wiley & Sons
ISBN 13 : 047135404X
Total Pages : 741 pages
Book Rating : 4.4/5 (713 download)

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Book Synopsis Handbook of Infrared Spectroscopy of Ultrathin Films by : Valeri P. Tolstoy

Download or read book Handbook of Infrared Spectroscopy of Ultrathin Films written by Valeri P. Tolstoy and published by John Wiley & Sons. This book was released on 2003-06-10 with total page 741 pages. Available in PDF, EPUB and Kindle. Book excerpt: Because of the rapid increase in commercially available Fourier transform infrared spectrometers and computers over the past ten years, it has now become feasible to use IR spectrometry to characterize very thin films at extended interfaces. At the same time, interest in thin films has grown tremendously because of applications in microelectronics, sensors, catalysis, and nanotechnology. The Handbook of Infrared Spectroscopy of Ultrathin Films provides a practical guide to experimental methods, up-to-date theory, and considerable reference data, critical for scientists who want to measure and interpret IR spectra of ultrathin films. This authoritative volume also: Offers information needed to effectively apply IR spectroscopy to the analysis and evaluation of thin and ultrathin films on flat and rough surfaces and on powders at solid-gaseous, solid-liquid, liquid-gaseous, liquid-liquid, and solid-solid interfaces. * Provides full discussion of theory underlying techniques * Describes experimental methods in detail, including optimum conditions for recording spectra and the interpretation of spectra * Gives detailed information on equipment, accessories, and techniques * Provides IR spectroscopic data tables as appendixes, including the first compilation of published data on longitudinal frequencies of different substances * Covers new approaches, such as Surface Enhanced IR spectroscopy (SEIR), time-resolved FTIR spectroscopy, high-resolution microspectroscopy and using synchotron radiation

Honoring The Eightieth Birthday Of John Happel

Author : W. R. Moser
Publisher : CRC Press
ISBN 13 : 9782881243806
Total Pages : 296 pages
Book Rating : 4.2/5 (438 download)

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Book Synopsis Honoring The Eightieth Birthday Of John Happel by : W. R. Moser

Download or read book Honoring The Eightieth Birthday Of John Happel written by W. R. Moser and published by CRC Press. This book was released on 1989 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Intelligent Systems in Process Engineering, Part I: Paradigms from Product and Process Design

Author :
Publisher : Academic Press
ISBN 13 : 0080565689
Total Pages : 345 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Intelligent Systems in Process Engineering, Part I: Paradigms from Product and Process Design by :

Download or read book Intelligent Systems in Process Engineering, Part I: Paradigms from Product and Process Design written by and published by Academic Press. This book was released on 1995-11-14 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volumes 21 and 22 of Advances in Chemical Engineering contain ten prototypical paradigms which integrate ideas and methodologies from artificial intelligence with those from operations research, estimation andcontrol theory, and statistics. Each paradigm has been constructed around an engineering problem, e.g. product design, process design, process operations monitoring, planning, scheduling, or control. Along with the engineering problem, each paradigm advances a specific methodological theme from AI, such as: modeling languages; automation in design; symbolic and quantitative reasoning; inductive and deductive reasoning; searching spaces of discrete solutions; non-monotonic reasoning; analogical learning;empirical learning through neural networks; reasoning in time; and logic in numerical computing. Together the ten paradigms of the two volumes indicate how computers can expand the scope, type, and amount of knowledge that can be articulated and used in solving a broad range of engineering problems. - Sets the foundations for the development of computer-aided tools for solving a number of distinct engineering problems - Exposes the reader to a variety of AI techniques in automatic modeling, searching, reasoning, and learning - The product of ten-years experience in integrating AI into process engineering - Offers expanded and realistic formulations of real-world problems

Encyclopedia of Surface and Colloid Science

Author : P. Somasundaran
Publisher : CRC Press
ISBN 13 : 9780849396038
Total Pages : 1014 pages
Book Rating : 4.3/5 (96 download)

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Book Synopsis Encyclopedia of Surface and Colloid Science by : P. Somasundaran

Download or read book Encyclopedia of Surface and Colloid Science written by P. Somasundaran and published by CRC Press. This book was released on 2006 with total page 1014 pages. Available in PDF, EPUB and Kindle. Book excerpt:

New Frontiers in Catalysis, Parts A-C

Author : L. Guczi
Publisher : Elsevier
ISBN 13 : 0080887147
Total Pages : 2955 pages
Book Rating : 4.0/5 (88 download)

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Book Synopsis New Frontiers in Catalysis, Parts A-C by : L. Guczi

Download or read book New Frontiers in Catalysis, Parts A-C written by L. Guczi and published by Elsevier. This book was released on 1993-04-20 with total page 2955 pages. Available in PDF, EPUB and Kindle. Book excerpt: These volumes comprise the proceedings of the major international meeting on catalysis which is held at 4 year intervals. The programme focussed on New Frontiers in Catalysis including nontraditional catalytic materials and environmental catalysis. The contributions cover a wide range of fundamental, applied, industrial and engineering aspects of catalysis. The extensive range of highly efficient industrial techniques for observing and characterizing catalytically important surfaces is evident.The programme covered the following sessions: Mechanism, theory, in situ methods; Catalytic reaction on atomically clean surfaces; Catalytic reaction on zeolites and related substances; New methods and principles for catalyst preparation; Hydrotreatment reactions (HDS, HDN); Characterization of catalysts, application of novel techniques; Selective oxidation; New catalytic aspects of heteropoly acids and related compounds; Reaction of hydrocarbons; Nontraditional catalytic materials; Fuel upgrading; Alkane activation; Acid-base catalysis; New selective catalytic reactons, fine chemicals; Environmental catalysis; Industrial catalysis, deactivation, reactivation; Synthesis from syngas; Electrocatalysis; Photocatalysis.The invited lectures and 433 papers included in these volumes present an update on all areas of catalysis and applications.

Characterization of Solid Materials and Heterogeneous Catalysts

Author : Michel Che
Publisher : John Wiley & Sons
ISBN 13 : 3527645330
Total Pages : 1313 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Characterization of Solid Materials and Heterogeneous Catalysts by : Michel Che

Download or read book Characterization of Solid Materials and Heterogeneous Catalysts written by Michel Che and published by John Wiley & Sons. This book was released on 2012-04-16 with total page 1313 pages. Available in PDF, EPUB and Kindle. Book excerpt: This two-volume book provides an overview of physical techniques used to characterize the structure of solid materials, on the one hand, and to investigate the reactivity of their surface, on the other. Therefore this book is a must-have for anyone working in fields related to surface reactivity. Among the latter, and because of its most important industrial impact, catalysis has been used as the directing thread of the book. After the preface and a general introduction to physical techniques by M. Che and J.C. Vedrine, two overviews on physical techniques are presented by G. Ertl and Sir J.M. Thomas for investigating model catalysts and porous catalysts, respectively. The book is organized into four parts: Molecular/Local Spectroscopies, Macroscopic Techniques, Characterization of the Fluid Phase (Gas and/ or Liquid), and Advanced Characterization. Each chapter focuses upon the following important themes: overview of the technique, most important parameters to interpret the experimental data, practical details, applications of the technique, particularly during chemical processes, with its advantages and disadvantages, conclusions.

The Microkinetics of Heterogeneous Catalysis

Author : J. A. Dumesic
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 340 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Microkinetics of Heterogeneous Catalysis by : J. A. Dumesic

Download or read book The Microkinetics of Heterogeneous Catalysis written by J. A. Dumesic and published by Wiley-VCH. This book was released on 1993-04-20 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Defines the emerging field of catalytic reaction synthesis in the search for new catalysts and catalytic processes. Illustrates how experimental data from diverse sources can be consolidated to form a quantitative description of the essential chemistry taking place on the catalyst surface. Elucidates the possible relationships between catalyst kinetic properties and surface chemical bonding properties. Offers examples of microkinetic analysis and catalytic reaction synthesis for a variety of catalytic reactions over metals, oxides, and zeolite catalysts. Illustrates the underlying strategy used to formulate a microkinetic model, calibrate the model to the existing experimental data, and assess the critical aspects of the essential surface chemistry involved in the catalytic process.

Principles and Practice of Heterogeneous Catalysis

Author : John Meurig Thomas
Publisher : John Wiley & Sons
ISBN 13 : 352731458X
Total Pages : 768 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Principles and Practice of Heterogeneous Catalysis by : John Meurig Thomas

Download or read book Principles and Practice of Heterogeneous Catalysis written by John Meurig Thomas and published by John Wiley & Sons. This book was released on 2015-02-09 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: This long-awaited second edition of the successful introduction to the fundamentals of heterogeneous catalysis is now completely revised and updated. Written by internationally acclaimed experts, this textbook includes fundamentals of adsorption, characterizing catalysts and their surfaces, the significance of pore structure and surface area, solid-state and surface chemistry, poisoning, promotion, deactivation and selectivity of catalysts, as well as catalytic process engineering. A final section provides a number of examples and case histories. With its color and numerous graphics plus references to help readers to easily find further reading, this is a pivotal work for an understanding of the principles involved.