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Investigation Of Mixed Metal Sorbent
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Book Synopsis INVESTIGATION OF MIXED METAL SORBENT by :
Download or read book INVESTIGATION OF MIXED METAL SORBENT written by and published by . This book was released on 2001 with total page 73 pages. Available in PDF, EPUB and Kindle. Book excerpt: Simultaneous removal of SO2 and NO(subscript x) using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO2 and NO(subscript x) removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO2 can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO(subscript x) by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO2 and NO(subscript x) from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO(subscript x).
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration written by and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October--December 1994 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October--December 1994 written by and published by . This book was released on 1995 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Removal reaction of H2S from coal gas mixtures with ZT-4 or other promising sorbents of fine solid particles, and regeneration reaction of sulfur-loaded sorbents will be carried on in a batch reactor or a continuous differential reactor. The objectives of this research project are to find intrinsic initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of concentrations of coal gas components such as hydrogen, carbon monoxide, carbon dioxide, oxygen, nitrogen and moisture on equilibrium reaction rate constants of the reaction system at various reaction temperatures and pressures, to identify regeneration kinetics of sulfur-loaded metal oxide sorbents, and to formulate promising metal oxide sorbent for the removal of sulfur from coal gas mixtures. Promising durable metal oxide sorbents of high-sulfur-absorbing capacity will be formulated by mixing active metal oxide powders with inert metal oxide powders and calcining these powder mixtures, or impregnating active metal oxide sorbents on supporting metal oxide matrixes.
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, April 1--June 30, 1996 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, April 1--June 30, 1996 written by and published by . This book was released on 1996 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Removal reaction of H2S from coal gas mixtures with promising sorbents of fine solid was carried on in a batch reactor. The objectives of this research project are to formulate promising durable metal oxide sorbents for the removal of sulfur compounds from coal gas mixtures, to find intrinsic initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to obtain effects of concentrations of coal gas components such as hydrogen and moisture on equilibrium absorption as well as dynamic absorption of hydrogen sulfide into formulated sorbents for the reaction system at various reaction temperatures and pressures, and to obtain effects of concentrations of coal gas components such as hydrogen and moisture on reaction rates of hydrogen sulfide with formulated sorbents at various reaction temperatures and pressures.
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, April--June 1995 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, April--June 1995 written by and published by . This book was released on 1995 with total page 19 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Removal reaction of H2S from coal gas mixtures with ZT-4 or other promising sorbents of fine solid particles, and regeneration reaction of sulfur-loaded sorbents will be carried on in a batch reactor or a continuous differential reactor. The objectives of this research project are to find intrinsic initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of concentrations of coal gas components such as hydrogen, carbon monoxide, carbon dioxide, oxygen, nitrogen and moisture on equilibrium reaction rate constants of the reaction system at various reaction temperatures and pressures, to identify regeneration kinetics of sulfur-loaded metal oxide sorbents, and to formulate promising metal oxide sorbents for the removal of sulfur from coal gas mixtures. Promising durable metal oxide sorbents of high-sulfur-absorbing capacity will be formulated by mixing active metal oxide powders with inert metal oxide powders and calcining these powder mixtures, or impregnating active metal oxide sorbents on supporting metal oxide matrixes. The Research Triangle Institute, a sub-contractor of this research project, will also prepare promising metal oxide sorbents for this research project, plan experiments on removal of sulfur compounds from coal gases with metal oxide sorbents as well as regeneration of sulfur-loaded metal oxide sorbents, and review experimental results.
Book Synopsis INVESTIGATION ON DURABILITY AND REACTIVITY OF PROMISING METAL OXIDE SORBENTS DURING SULFIDATION AND REGENERATION. QUARTERLY AND FINAL REPORT. by :
Download or read book INVESTIGATION ON DURABILITY AND REACTIVITY OF PROMISING METAL OXIDE SORBENTS DURING SULFIDATION AND REGENERATION. QUARTERLY AND FINAL REPORT. written by and published by . This book was released on 1998 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Experiments on removal reaction of H2S from coal gas mixtures with formulated metal oxide sorbents were conducted in a batch reactor or a differential reactor. The objectives of this research project are to formulate promising metal oxide sorbents for removal of sulfur from coal gas mixtures, to find initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of hydrogen, nitrogen and moisture on dynamic absorption and equilibrium absorption at various absorption temperatures. Promising durable metal oxide sorbents with high-sulfur-absorbing capacity were formulated by mixing active metal oxide powders with inert metal oxide powders, and calcining these powder mixtures. The Research Triangle Institute (RTI), a sub-contractor of this research project, will also prepare promising metal oxide sorbents for this research project, plan experiments on removal of sulfur compounds from coal gases with metal oxide, and review experimental results.
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, January--March 1995 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, January--March 1995 written by and published by . This book was released on 1995 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Removal reaction of H2S from coal gas mixtures with ZT-4 or other promising sorbents of fine solid particles, and regeneration reaction of sulfur-loaded sorbents will be carried on in a batch reactor or a continuous differential reactor. The objectives of this research project are to find intrinsic initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of concentrations of coal gas components such as hydrogen, carbon monoxide, carbon dioxide, oxygen, nitrogen and moisture on equilibrium reaction rate constants of the reaction system at various reaction temperatures and pressures, to identify regeneration kinetics of sulfur-loaded metal oxide sorbents, and to formulate promising metal oxide sorbents for the removal of sulfur from coal gas mixtures. Promising durable metal oxide sorbents of high-sulfur-absorbing capacity will be formulated by mixing active metal oxide powders with inert metal oxide powders and calcining these powder mixtures, or impregnating active metal oxide sorbents on supporting metal oxide matrixes.
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, July 1 - September 30, 1995 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, July 1 - September 30, 1995 written by and published by . This book was released on 1995 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hot-gas desulfurization for the integrated gasification combined cycle process has been investigated by many to remove effectively hydrogen sulfide with various metal oxide sorbents at high pressures and high temperatures. Metal oxides such as zinc titanate oxides, zinc ferrite oxide, copper oxide, manganese oxide and calcium oxide, were found to be promising sorbents in comparison with other removal methods such as membrane separations and reactive membrane separations. Some metal oxide sorbents exhibited the quite favorable performance in terms of attrition resistance and sulfur capacity. Removal reaction of H2S from coal gas mixtures with ZT-4 or other promising sorbents of fine solid particles, and regeneration reaction of sulfur-loaded sorbents will be carried on in a batch reactor or a continuous differential reactor. The objectives of this project are to find intrinsic initial reaction kinetics for the metal oxide-hydrogen sulfide heterogeneous reaction system, to obtain effects of concentrations of coal gas components such as hydrogen, carbon monoxide, carbon dioxide, nitrogen and moisture on equilibrium reaction rate constants of the reaction system at various reaction temperatures and pressures, to identify regeneration kinetics of sulfur-loaded metal oxide sorbents, and to formulate promising metal oxide sorbents for the removal of sulfur from coal gas mixtures. Promising durable metal oxide sorbents of high-sulfur- absorbing capacity will be formulated by mixing active metal oxide powders with inert metal oxide powders and calcining these powder mixtures, or impregnating active metal oxide sorbents on supporting metal oxide matrixes. The Research Triangle Institute will also prepare promising metal oxide sorbents for this research project, plan experiments on removal of sulfur compounds from coal gases with metal oxide sorbents as well as regeneration of sulfur-loaded metal oxide sorbents, and review experimental results. 1 ref., 10 figs., 11 tabs.
Book Synopsis Investigation of Various Known Metal Organic Frameworks as Solid Phase Extraction Sorbent For Extracting Clarithromycin from Aqeous Solution by : Esraa Mohammed Al-Adawi ($e author)
Download or read book Investigation of Various Known Metal Organic Frameworks as Solid Phase Extraction Sorbent For Extracting Clarithromycin from Aqeous Solution written by Esraa Mohammed Al-Adawi ($e author) and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare by : Alexander Samokhvalov
Download or read book Adsorption on Mesoporous Metal-Organic Frameworks in Solution for Clean Energy, Environment and Healthcare written by Alexander Samokhvalov and published by CRC Press. This book was released on 2017-04-07 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption and desorption in solution play significant roles in separations, detoxification of waste streams, in purification, chromatography, heterogeneous catalysis, metabolism of medicinal drugs, and beyond. Metal-Organic Frameworks (MOFs) are well-ordered 3-dimensional hybrid organic-inorganic polymers which contain metal cations and the structure-building organic "linker" units. Mesoporous MOFs with pore sizes 2-50 nm are particularly suitable for adsorption and adsorption-based separations of large molecules of organic and bio-organic compounds. Thousands of organic compounds and, in particular, aromatic and heterocyclic compounds are widely used as feedstock for industrial chemical synthesis, as fine chemicals, major components of liquid fossil fuels, dyestuffs, industrial solvents, agricultural chemicals, medicinal drugs, pharmaceuticals and personal care products (PPCPs), and active pharmaceutical ingredients (APIs). There is a strong interest towards synthesis, characterization and studies of both known and newly synthesized mesoporous MOFs for adsorption in solution to achieve the high adsorption capacity, selectivity, and the possibility of multiple regeneration of "spent" sorbent. This book covers experimental fundamental research on using mesoporous MOFs in emerging applications of major industrial, environmental and academic importance, especially purification of water and liquid fossil fuels and in advanced biomedical technologies.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1995 with total page 782 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October 1 - December 31, 1995 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October 1 - December 31, 1995 written by and published by . This book was released on 1995 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The main objectives of this research project during this quarter are to conduct experiments on equilibrium absorption of hydrogen sulfide into formulated sorbents at 500°C, to identify effects of hydrogen partial pressures on equilibrium absorption of hydrogen sulfide into formulated sorbents, and develop a cylindrical rod model to evaluate intraparticular diffusivity of H2S into sorbents in the batch reactor.
Book Synopsis Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October 1--December 31, 1996 by :
Download or read book Investigation on Durability and Reactivity of Promising Metal Oxide Sorbents During Sulfidation and Regeneration. Quarterly Report, October 1--December 31, 1996 written by and published by . This book was released on 1997 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The main objectives of this research project during this quarter are to design a micro differential reactor, design a differential reactor assembly, and select and order necessary parts as well as accessories for the reactor and its assembly.
Book Synopsis Reactivity of Metal Oxide Sorbents for Removal of H2S. by :
Download or read book Reactivity of Metal Oxide Sorbents for Removal of H2S. written by and published by . This book was released on 1996 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: Removal of hydrogen sulfide contained in hot coal gases produced from integrated gasification combined cycle power generation systems is required to protect downstream combustion turbines from being corroded with sulfur compounds. Removal of sulfur compounds from hot coal gas products is investigated by using various metal oxide sorbents and membrane separation methods. The main requirements of these metal oxide sorbents are durability and high sulfur loading capacity during absorption-regeneration cycles. In this research, durable metal oxide sorbents were formulated. Reactivity of the formulated metal oxide sorbents with simulated coal gas mixtures was examined to search for an ideal sorbent formulation with a high-sulfur loading capacity suitable for removal of hydrogen sulfide from coal gases. The main objectives of this research are to formulate durable metal oxide sorbents with high-sulfur loading capacity by a physical mixing method, to investigate reaction kinetics on the removal of sulfur compounds from coal gases at high temperature and pressure, to study reaction kinetics on the regeneration of sulfided sorbents, to identify effects of hydrogen partial pressures and moisture on equilibrium/dynamic absorption of hydrogen sulfide into formulated metal oxide sorbents as well as initial reaction rates of H2S with formulated metal oxide sorbents, and to evaluate intraparticular diffusivity of H2S into formulated sorbents at various reaction conditions. The metal oxide sorbents such as TU-1, TU-19, TU-24, TU-25 and TU-28 were formulated with zinc oxide powder as an active sorbent ingredient, bentonite as a binding material and titanium oxide as a supporting metal oxide.
Book Synopsis Hot Gas Desulfurization with Sorbents Containing Mixed Metal Oxides. Final Report, October 1, 1990--December 31, 1992 by :
Download or read book Hot Gas Desulfurization with Sorbents Containing Mixed Metal Oxides. Final Report, October 1, 1990--December 31, 1992 written by and published by . This book was released on 1992 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this project the sulfidation and regeneration behavior of vanadium-promoted zinc ferrite sorbents was investigated by microreactor studies and physical characterization of the promoted sorbents. The discussion of results are presented for the fresh and used sorbent characterizations Zn-Fe-V-O, and standard sulfidation and regeneration experiments followed by the discussion of the effects of sulfidation temperature, calcination temperature, and the water vapor content of the simulated fuel gas.
Book Synopsis Advances in Hydrogen Production, Storage and Distribution by : Adolfo Iulianelli
Download or read book Advances in Hydrogen Production, Storage and Distribution written by Adolfo Iulianelli and published by Elsevier. This book was released on 2014-07-16 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Hydrogen Production, Storage and Distribution reviews recent developments in this key component of the emerging "hydrogen economy," an energy infrastructure based on hydrogen. Since hydrogen can be produced without using fossil fuels, a move to such an economy has the potential to reduce greenhouse gas emissions and improve energy security. However, such a move also requires the advanced production, storage and usage techniques discussed in this book. Part one introduces the fundamentals of hydrogen production, storage, and distribution, including an overview of the development of the necessary infrastructure, an analysis of the potential environmental benefits, and a review of some important hydrogen production technologies in conventional, bio-based, and nuclear power plants. Part two focuses on hydrogen production from renewable resources, and includes chapters outlining the production of hydrogen through water electrolysis, photocatalysis, and bioengineered algae. Finally, part three covers hydrogen production using inorganic membrane reactors, the storage of hydrogen, fuel cell technology, and the potential of hydrogen as a fuel for transportation. Advances in Hydrogen Production, Storage and Distribution provides a detailed overview of the components and challenges of a hydrogen economy. This book is an invaluable resource for research and development professionals in the energy industry, as well as academics with an interest in this important subject. - Reviews developments and research in this dynamic area - Discusses the challenges of creating an infrastructure to store and distribute hydrogen - Reviews the production of hydrogen using electrolysis and photo-catalytic methods
Book Synopsis Central Illinois Public Service Company V. Allianz Underwriters Insurance Company by :
Download or read book Central Illinois Public Service Company V. Allianz Underwriters Insurance Company written by and published by . This book was released on 1992 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt:
