High And Low Valent Tris N Heterocyclic Carbene Iron Complexes

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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes

Author : Carola S. Vogel
Publisher : Springer Science & Business Media
ISBN 13 : 3642272533
Total Pages : 145 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes by : Carola S. Vogel

Download or read book High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes written by Carola S. Vogel and published by Springer Science & Business Media. This book was released on 2012-02-03 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

Chemistry of Iron

Author : J. Silver
Publisher : Springer Science & Business Media
ISBN 13 : 9401121400
Total Pages : 316 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Chemistry of Iron by : J. Silver

Download or read book Chemistry of Iron written by J. Silver and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is designed to be of use to the reader in two different ways. First, it is intended to provide a general introduction to all aspects of iron chemistry for readers from a variety of different scientific backgrounds. It has been written at a level suitable for use by graduates and advanced undergraduates in chemistry and biochemistry, and graduates in physics, geology, materials science, metallurgy and biology. It is not designed to be a dictionary of iron compounds but rather to provide each user with the necessary tools and background to pursue their ,individual interests in the wide areas that are influenced by the chemistry of iron. To achieve this goal each chapter has been written by a contemporary expert active in the subject so that the reader will benefit from their individual insight. Although it is generally assumed that the reader will have an understanding of bonding theories and general chemistry, the book is well referenced so that any deficiencies in the reader's background can be addressed. The book was also designed as a general reference book for initial pointers into a scientific literature that is growing steadily as the understanding and uses of this astonishingly versatile element continue to develop. To meet this aim the book attempts some coverage of all aspects of the chemistry of iron, not only outlining what understanding has been achieved to date but also identifying targets to be aimed at in the future.

Organic Synthesis

Author : Belakatte Parameshwarappa Nandeshwarappa
Publisher : BoD – Books on Demand
ISBN 13 : 1789859433
Total Pages : 250 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Organic Synthesis by : Belakatte Parameshwarappa Nandeshwarappa

Download or read book Organic Synthesis written by Belakatte Parameshwarappa Nandeshwarappa and published by BoD – Books on Demand. This book was released on 2020-05-27 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

Author : Catherine S.J. Cazin
Publisher : Springer
ISBN 13 : 9789400733701
Total Pages : 340 pages
Book Rating : 4.7/5 (337 download)

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Book Synopsis N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis by : Catherine S.J. Cazin

Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis written by Catherine S.J. Cazin and published by Springer. This book was released on 2012-12-01 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ... Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.

Palladium Catalyzed Oxidation of Hydrocarbons

Author : P. Henry
Publisher : Springer Science & Business Media
ISBN 13 : 940099446X
Total Pages : 449 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Palladium Catalyzed Oxidation of Hydrocarbons by : P. Henry

Download or read book Palladium Catalyzed Oxidation of Hydrocarbons written by P. Henry and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.

Click Triazoles

Author : Janez Košmrlj
Publisher : Springer
ISBN 13 : 3642294294
Total Pages : 236 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Click Triazoles by : Janez Košmrlj

Download or read book Click Triazoles written by Janez Košmrlj and published by Springer. This book was released on 2012-05-30 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: B. R. Buckley and H. Heaney: Mechanistic Investigations of Copper(I)- Catalyzed Alkyne–Azide Cycloaddition Reactions.- J. D. Crowley and D. A. McMorran: “Click-Triazole” Coordination Chemistry: Exploiting 1,4-Disubstituted-1,2,3-Triazoles as Ligands.- S. Lee and A. H. Flood: Binding Anions in Rigid and Reconfigurable Triazole Receptors.- M. Watkinson: Click Triazoles as Chemosensors.- H.-F. Chow, C.-M. Lo and Y. Chen: Triazole-Based Polymer Gels.- T. Zheng, S. H. Rouhanifard, A. S. Jalloh, P. Wu: Click Triazoles for Bioconjugation.- S. Mignani, Y. Zhou, T. Lecourt and L. Micouin: Recent Developments in the Synthesis 1,4,5-Trisubstituted Triazoles.

Pushing Electrons

Author : Daniel P. Weeks
Publisher : Cengage Learning
ISBN 13 : 9781133951889
Total Pages : 0 pages
Book Rating : 4.9/5 (518 download)

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Book Synopsis Pushing Electrons by : Daniel P. Weeks

Download or read book Pushing Electrons written by Daniel P. Weeks and published by Cengage Learning. This book was released on 2013-01-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief guidebook assists you in mastering the difficult concept of pushing electrons that is vital to your success in Organic Chemistry. With an investment of only 12 to 16 hours of self-study you can have a better understanding of how to write resonance structures and will become comfortable with bond-making and bond-breaking steps in organic mechanisms. A paper-on-pencil approach uses active involvement and repetition to teach you to properly push electrons to generate resonance structures and write organic mechanisms with a minimum of memorization. Compatible with any organic chemistry textbook. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.

The Organometallic Chemistry of the Transition Metals

Author : Robert H. Crabtree
Publisher : John Wiley & Sons
ISBN 13 : 0471718750
Total Pages : 600 pages
Book Rating : 4.4/5 (717 download)

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Book Synopsis The Organometallic Chemistry of the Transition Metals by : Robert H. Crabtree

Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Mössbauer Spectroscopy

Author : N. N. Greenwood
Publisher : Springer Science & Business Media
ISBN 13 : 9400956975
Total Pages : 668 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Mössbauer Spectroscopy by : N. N. Greenwood

Download or read book Mössbauer Spectroscopy written by N. N. Greenwood and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 668 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rudolph Mossbauer discovered the phenomenon of recoil-free nuclear resonance fluorescence in 1957-58 and the first indications of hyperfine interactions in a chemical compound were obtained by Kistner and Sunyar in 1960. From these beginnings the technique of Mossbauer spectroscopy rapidly emerged and the astonishing versatility of this new technique soon led to its extensive application to a wide variety of chemical and solid-state problems. This book reviews the results obtained by Mossbauer spectroscopy during the past ten years in the belief that this will provide a firm basis for the continued development and application of the technique to new problems in the future. It has been our aim to write a unified and consistent treatment which firstly presents the basic principles underlying the phenomena involved, then outlines the experimental techniques used, and finally summarises the wealth of experimental and theoretical results which have been obtained. We have tried to give some feeling for the physical basis of the Mossbauer effect with out extensive use of mathematical formalism, and some appreciation of the experimental methods employed without embarking on a detailed discussion of electronics and instrumentation. However, full references to the original literature are provided and particular points can readily be pursued in more detail if required.

Carbene Chemistry

Author : Guy Bertrand
Publisher : CRC Press
ISBN 13 : 0824743210
Total Pages : 278 pages
Book Rating : 4.8/5 (247 download)

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Book Synopsis Carbene Chemistry by : Guy Bertrand

Download or read book Carbene Chemistry written by Guy Bertrand and published by CRC Press. This book was released on 2002-05-14 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlights recent discoveries in the development of rapid kinetic techniques that allow for direct visualization and state-of-the-art computational methods.

Activation of Small Molecules

Author : William B. Tolman
Publisher : John Wiley & Sons
ISBN 13 : 3527609377
Total Pages : 382 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Activation of Small Molecules by : William B. Tolman

Download or read book Activation of Small Molecules written by William B. Tolman and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.

Cyclometalation Reactions

Author : Iwao Omae
Publisher : Springer Science & Business Media
ISBN 13 : 4431546049
Total Pages : 208 pages
Book Rating : 4.4/5 (315 download)

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Book Synopsis Cyclometalation Reactions by : Iwao Omae

Download or read book Cyclometalation Reactions written by Iwao Omae and published by Springer Science & Business Media. This book was released on 2014-01-23 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.

Carbon Ligands

Author : Yves Canac
Publisher : Mdpi AG
ISBN 13 : 9783036513508
Total Pages : 312 pages
Book Rating : 4.5/5 (135 download)

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Book Synopsis Carbon Ligands by : Yves Canac

Download or read book Carbon Ligands written by Yves Canac and published by Mdpi AG. This book was released on 2021-06-30 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.

Comprehensive Coordination Chemistry II

Author : J. A. McCleverty
Publisher : Newnes
ISBN 13 : 0080913164
Total Pages : 17046 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 17046 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

N-Heterocyclic Carbenes

Author : Silvia Diez-Gonzalez
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626816
Total Pages : 636 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis N-Heterocyclic Carbenes by : Silvia Diez-Gonzalez

Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Iron Catalysis in Organic Chemistry

Author : Bernd Plietker
Publisher : John Wiley & Sons
ISBN 13 : 3527623280
Total Pages : 295 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Iron Catalysis in Organic Chemistry by : Bernd Plietker

Download or read book Iron Catalysis in Organic Chemistry written by Bernd Plietker and published by John Wiley & Sons. This book was released on 2008-09-08 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.

Transition Metal-Dinitrogen Complexes

Author : Yoshiaki Nishibayashi
Publisher : John Wiley & Sons
ISBN 13 : 352734425X
Total Pages : 496 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Transition Metal-Dinitrogen Complexes by : Yoshiaki Nishibayashi

Download or read book Transition Metal-Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.