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Half A Century Of Free Radical Chemistry
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Book Synopsis Half a Century of Free Radical Chemistry by : Derek H. R. Barton
Download or read book Half a Century of Free Radical Chemistry written by Derek H. R. Barton and published by Cambridge University Press. This book was released on 1993-04-15 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.
Book Synopsis Free-Radical Chemistry by : D. C. Nonhebel
Download or read book Free-Radical Chemistry written by D. C. Nonhebel and published by CUP Archive. This book was released on 1974-01-31 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of Free Radicals by : Rayson L. Huang
Download or read book The Chemistry of Free Radicals written by Rayson L. Huang and published by Hodder Education. This book was released on 1974 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Free Radical Chemistry by : S.Z. Zard
Download or read book Advances in Free Radical Chemistry written by S.Z. Zard and published by Elsevier. This book was released on 2000-01-31 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series is designed to provide a vehicle in which investigators, who have demonstrated a high degree of competence in some aspect of free radical chemistry, can present a particular area of interest. The series encompasses a wide variety of topics which are of current interest.
Book Synopsis Free Radicals in Solution by : Cheves Walling
Download or read book Free Radicals in Solution written by Cheves Walling and published by . This book was released on 1957 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Fifty Years of Free Radicals by : Cheves Walling
Download or read book Fifty Years of Free Radicals written by Cheves Walling and published by Wiley-VCH. This book was released on 1995-09 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is the autobiography of Cheves Walling, famous American organic chemist and previously Professor of Chemistry at Columbia University and the University of Utah. Noted for his discoveries in the field of free radical chemistry, Walling bridged the university-industrial gap. Many of his discoveries played an important role in the development of polymer chemistry. Walling was, for many years, Editor-in-Chief of the Journal of the American Chemical Society. Many photographs depict both the professional as well as the personal side of this renowned chemist.
Book Synopsis The Chemistry of Free Radicals by : Zeev B. Alfassi
Download or read book The Chemistry of Free Radicals written by Zeev B. Alfassi and published by Wiley. This book was released on 1998-11-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals play a major role as intermediates in many chemical reactions. They contribute to transformations in the atmosphere, living organisms, chemical synthesis, combustion and detonation amongst others. This comprehensive and conclusive book discusses all these aspects. N-centered Radicals deals with NOx and NCO, relatively stable radicals whose presence in the atmosphere influences the metabolism of living organisms. Also included are NHx, NCH and N3, important in radical studies, chemical synthesis, detonation and metabolism. Until now there has been no single volume bringing together all aspects of N-centered radical chemistry, from formation, to their chemistry in aqueous environments, biological systems and the atmosphere. N-centered Radicals is essential reading for researchers in organic, physical and environmental chemistry, biology and all others examining the effects of N-centered radicals.
Book Synopsis Frontiers of Free Radical Chemistry by : William Pryor
Download or read book Frontiers of Free Radical Chemistry written by William Pryor and published by Elsevier. This book was released on 2012-12-02 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Frontiers of Free Radical Chemistry covers the proceedings of the 1979 symposium on Frontiers of Free Radical Chemistry, held in Louisiana State University Chemistry Department, supported by the Exxon Education Foundation. The contributors discuss the mechanisms of hydrocarbon cracking; oxidation processes; inhibition; and the theory of organic radical reactions, halogenations, and organic peroxide chemistry. This book is organized into three parts encompassing 15 chapters. Part I deals with the understanding of molecular and free radical mechanisms in predicting thermochemical data for radicals and molecules. This part also describes the relationship between distortions of organic molecules and the reactions of pericyclic, ionic, and radical molecules. Part II presents quantitative evaluations of gas phase reactions or carbynes and hydrocarbon pyrolysis and cracking. Discussions on the reactions of free atoms and radicals in the chemistry of the stratosphere and natural troposphere, with an emphasis on the ozone layer and its potential depletion by artificial pollutants, are included in this part. Part III explores the pertinent free radical reactions related to fuel research. Petroleum chemists, researchers, and engineers will find this book invaluable.
Book Synopsis Free Radicals in Organic Synthesis by : D. I. Davies
Download or read book Free Radicals in Organic Synthesis written by D. I. Davies and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Free Radicals in Organic Chemistry by : Jacques Fossey
Download or read book Free Radicals in Organic Chemistry written by Jacques Fossey and published by . This book was released on 1995-11-09 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radicals constitute the most frequently used class of reaction intermediates in organic chemistry. This study describes the structure and reactivity of free radicals, and explores their role in both natural phenomena and in the design of new reaction pathways.
Book Synopsis Free Radicals in Chemistry, Biology and Medicine by : Toshikazu Yoshikawa
Download or read book Free Radicals in Chemistry, Biology and Medicine written by Toshikazu Yoshikawa and published by . This book was released on 2000 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Carbon-Centered Free Radicals and Radical Cations by : Malcolm D. Forbes
Download or read book Carbon-Centered Free Radicals and Radical Cations written by Malcolm D. Forbes and published by John Wiley & Sons. This book was released on 2010-01-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.
Book Synopsis Frontiers of Free Radical Chemistry by : William A. Pryor
Download or read book Frontiers of Free Radical Chemistry written by William A. Pryor and published by . This book was released on 1980 with total page 385 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :José A. Martinho Simões Publisher :Springer Science & Business Media ISBN 13 :9780751403787 Total Pages :328 pages Book Rating :4.4/5 (37 download)
Book Synopsis Energetics of Organic Free Radicals by : José A. Martinho Simões
Download or read book Energetics of Organic Free Radicals written by José A. Martinho Simões and published by Springer Science & Business Media. This book was released on 1996-04-30 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current volume consists of eight chapters which interweave various aspects of the structure, energetics and reactivity of organic free radicals, all combining pedagogical insights with current research. The first is by Walling in which a personalized overview is given by one of the modern pioneers of the discipline. In the next two chapters, Tsang, and Traeger and Kompe, present key thermochemical and kinetic quantities from the complementary vantage points of the studies of neutral and cationic species. The fourth chapter by Francisco and Montgomery discusses the armamentarium of modern theory as applied to species with unpaired electrons, while the next chapter by Goodman presents the theory, methodology and results from photoacoustic calorimetry, a novel and powerful experimental technique. Martinho Simoes and Minas da Piedade interrelate organometallic and free radical chemistry, while Greenberg and Liebman consider resonance energy and rearrangements as applied to small molecules and enzyme cofactors alike. The volume ends with the chapter by Tanko and Suleman, which describes the surprising and diverse solvent effects which modulate free radical chem istry. This volume will make it apparent to entry-level graduate students and senior researchers alike that much is known and much remains to be done in both the qualitative understanding and quantitative insights of the chemistry of organic free radicals. Jose Artur Martinho Simoes Arthur Greenberg Joel F. Liebman vii Editorial Advisory Board WESTON T. BORDEN ALAN P.
Book Synopsis Free Radicals in Synthesis and Biology by : F. Minisci
Download or read book Free Radicals in Synthesis and Biology written by F. Minisci and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free-radical reactions have been for long time the domain of the physical chemists and the basic chemical industry (polymerization of vinyl monomers, oxidation by molecular oxygen, chlorination of methane etc.), where the use of simple molecules and the possibility of partial conversions without heavy problems of product separations makes less dramatic the aspects of regio and chemoselectivity. As synonym of unselectivity, free radical reactions were considered of poor use in the synthesis of fine chemicals or sophisticated molecules, where a high selectivity is an essential condition for the success, or in the involvement of biological processes. Within the last 15 years, however, an authentic explosion of synthetic applications of free radical reactions occurred; they have gained a remarkable position among the selective methods of synthesis. At the same time the great importance of free radical reactions in fundamental biological processes and in the metabolism of drugs has been recognized. Thus a specialized meeting on these topics was generally felt appropriate. I had the honour and the onus to organize this workshop because for more than 30 years I have been involved in the research of free radical reactions. Thanks to a generous grant from NATO Scientific Affairs Division and the financial support of CNR and chemical industry (Montedison, Enichem, Zambon) such a meeting among almost 50 specialists and 15 observers of sufficient standard to take advantage of the discussion, became possible at Bardolino (Italy).
Book Synopsis Free Radicals in Chemistry and Biology by : Milan Lazar
Download or read book Free Radicals in Chemistry and Biology written by Milan Lazar and published by CRC Press. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary radical reactions are described in terms of fundamental knowledge of organic chemistry and chemical physics in this valuable reference text. The complex radical processes of nonchain and chain mechanisms, such as dimerization, alkylation, polymerization, telomerization, halogenation pyrolysis, oxidation and combustion, are complemented by reactions in chemical lasers and in the cosmos, as well as by reactions in biological objects under normal or pathological metabolism. The text also provides the synthesis of facts from various fields of research and involves mechanisms where free radicals appear either as main or side intermediates in one of the several alternatives of the reaction pathway. Highlights include 38 tables and 39 figures.
Book Synopsis Reagents for Radical and Radical Ion Chemistry by : David Crich
Download or read book Reagents for Radical and Radical Ion Chemistry written by David Crich and published by John Wiley & Sons. This book was released on 2013-05-30 with total page 1874 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.
