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Groundwater Flow Path Investigation Using Stable Isotopes Of Water Dissolved Organic Carbon And A Groundwater Flow And Transport Model
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Book Synopsis Groundwater Flow Path Investigation Using Stable Isotopes of Water, Dissolved Organic Carbon, and a Groundwater Flow and Transport Model by : Seann D. McClure
Download or read book Groundwater Flow Path Investigation Using Stable Isotopes of Water, Dissolved Organic Carbon, and a Groundwater Flow and Transport Model written by Seann D. McClure and published by . This book was released on 2008 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Environmental Tracers by : Trevor Elliot
Download or read book Environmental Tracers written by Trevor Elliot and published by MDPI. This book was released on 2018-10-08 with total page 1 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is a printed edition of the Special Issue "Environmental Tracers" that was published in Water
Book Synopsis Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data by :
Download or read book Yucca Mountain Area Saturated Zone Dissolved Organic Carbon Isotopic Data written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Groundwater samples in the Yucca Mountain area were collected for chemical and isotopic analyses and measurements of water temperature, pH, specific conductivity, and alkalinity were obtained at the well or spring at the time of sampling. For this project, groundwater samples were analyzed for major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). The U.S. Geological Survey (USGS) performed all the fieldwork on this project including measurement of water chemistry field parameters and sample collection. The major ions dissolved in the groundwater, deuterium, oxygen-18, and carbon isotopes of dissolved inorganic carbon (DIC) were analyzed by the USGS. All preparation and processing of samples for DOC carbon isotopic analyses and geochemical modeling were performed by the Desert Research Institute (DRI). Analysis of the DOC carbon dioxide gas produced at DRI to obtain carbon-13 and carbon-14 values was conducted at the University of Arizona Accelerator Facility (a NSHE Yucca Mountain project QA qualified contract facility). The major-ion chemistry, deuterium, oxygen-18, and carbon isotopes of DIC were used in geochemical modeling (NETPATH) to determine groundwater sources, flow paths, mixing, and ages. The carbon isotopes of DOC were used to calculate groundwater ages that are independent of DIC model corrected carbon-14 ages. The DIC model corrected carbon-14 calculated ages were used to evaluate groundwater travel times for mixtures of water including water beneath Yucca Mountain. When possible, groundwater travel times were calculated for groundwater flow from beneath Yucca Mountain to down gradient sample sites. DOC carbon-14 groundwater ages were also calculated for groundwaters in the Yucca Mountain area. When possible, groundwater travel times were estimated for groundwater flow from beneath Yucca Mountain to down gradient groundwater sample sites using the DOC calculated groundwater ages. The DIC calculated groundwater ages were compared with DOC calculated groundwater ages and both of these ages were compared to travel times developed in ground-water flow and transport models. If nuclear waste is stored in Yucca Mountain, the saturated zone is the final barrier against the release of radionuclides to the environment. The most recent rendition of the TSPA takes little credit for the presence of the saturated zone and is a testament to the inadequate understanding of this important barrier. If radionuclides reach the saturated zone beneath Yucca Mountain, then there is a travel time before they would leave the Yucca Mountain area and flow down gradient to the Amargosa Valley area. Knowing how long it takes groundwater in the saturated zone to flow from beneath Yucca Mountain to down gradient areas is critical information for potential radionuclide transport. Radionuclide transport in groundwater may be the quickest pathway for radionuclides in the proposed Yucca Mountain repository to reach land surface by way of groundwater pumped in Amargosa Valley. An alternative approach to ground-water flow and transport models to determine the travel time of radionuclides from beneath Yucca Mountain to down gradient areas in the saturated zone is by carbon-14 dating of both inorganic and organic carbon dissolved in the groundwater. A standard method of determining ground-water ages is to measure the carbon-13 and carbon-14 of DIC in the groundwater and then correct the measured carbon-14 along a flow path for geochemical reactions that involve carbon containing phases. These geochemical reactions are constrained by carbon-13 and isotopic fractionations. Without correcting for geochemical reactions, the ground-water ages calculated from only the differences in carbon-14 measured along a flow path (assuming the decrease in carbon-14 is due strictly to radioactive decay) could be tens of thousands of years too old. The computer program NETPATH, developed by the USGS, is the best geochemical program for correcting carbon-14 activities for geochemical reactions. The DIC carbon-14 corrected ages can be further constrained by measuring the carbon isotopes of DOC. Because the only source of organic carbon in aquifers is almost always greater than 40,000 years old, any organic carbon that may be added to the groundwater would contain no carbon-14. Thus, ground-water ages determined by carbon isotopes of DOC should be maximum ages that can be used to constrain DIC corrected ages.
Book Synopsis Controls on Groundwater Flow in a Peat Dominated Wetland/stream Complex, Allequash Wetland, Northern Wisconsin by : Christopher S. Lowry
Download or read book Controls on Groundwater Flow in a Peat Dominated Wetland/stream Complex, Allequash Wetland, Northern Wisconsin written by Christopher S. Lowry and published by . This book was released on 2008 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Radiogenic and Stable Isotope and Hydrogeochemical Investigation of Groundwater, Pajarito Plateau and Surrounding Areas, New Mexico by :
Download or read book Radiogenic and Stable Isotope and Hydrogeochemical Investigation of Groundwater, Pajarito Plateau and Surrounding Areas, New Mexico written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: From October 2004 through February 2006, Los Alamos National Laboratory, the New Mexico Environment Department-Department of Energy Oversight Bureau, and the United States Geological Survey conducted a hydrochemical investigation. The purpose of the investigation was to evaluate groundwater flow paths and determine groundwater ages using tritium/helium-3 and carbon-14 along with aqueous inorganic chemistry. Knowledge of groundwater age and flow paths provides a technical basis for selecting wells and springs for monitoring. Groundwater dating is also relevant to groundwater resource management, including aquifer sustainability, especially during periods of long-term drought. At Los Alamos, New Mexico, groundwater is either modern (post-1943), submodern (pre-1943), or mixed (containing both pre- and post-1943 components). The regional aquifer primarily consists of submodern groundwater. Mixed-age groundwater results from initial infiltration of surface water, followed by mixing with perched alluvial and intermediate-depth groundwater and the regional aquifer. No groundwater investigation is complete without using tritium/helium-3 and carbon-14 dating methods to quantify amounts of modern, mixed, and/or submodern components present in samples. Computer models of groundwater flow and transport at Los Alamos should be calibrated to groundwater ages for perched intermediate zones and the regional aquifer determined from this investigation. Results of this study clearly demonstrate the occurrence of multiple flow paths and groundwater ages occurring within the Sierra de los Valles, beneath the Pajarito Plateau, and at the White Rock Canyon springs. Localized groundwater recharge occurs within several canyons dissecting the Pajarito Plateau. Perched intermediate-depth groundwater and the regional aquifer beneath Pueblo Canyon, Los Alamos Canyon, Sandia Canyon, Mortandad Canyon, Pajarito Canyon, and Canon de Valle contain a modern component. This modern component consists of tritium, nitrate, perchlorate, chromate, boron, uranium, and/or high explosive compounds. It is very unlikely that there is only one transport or travel time, ranging from 25 to 62 years, for these conservative chemicals migrating from surface water to the regional water table. Lengths of groundwater flow paths vary within deep saturated zones containing variable concentrations of tritium. The 4-series springs discharging within White Rock Canyon contain a modern component of groundwater, primarily tritium. Average groundwater ages for the regional aquifer beneath the Pajarito Plateau varied from 565 to 10,817 years, based on unadjusted carbon-14 measurements.
Book Synopsis Selected Water Resources Abstracts by :
Download or read book Selected Water Resources Abstracts written by and published by . This book was released on 1991 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Isotope Tracers in Catchment Hydrology by : C. Kendall
Download or read book Isotope Tracers in Catchment Hydrology written by C. Kendall and published by Elsevier. This book was released on 2012-12-02 with total page 870 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book represents a new "earth systems" approach to catchments that encompasses the physical and biogeochemical interactions that control the hydrology and biogeochemistry of the system. The text provides a comprehensive treatment of the fundamentals of catchment hydrology, principles of isotope geochemistry, and the isotope variability in the hydrologic cycle -- but the main focus of the book is on case studies in isotope hydrology and isotope geochemistry that explore the applications of isotope techniques for investigating modern environmental problems. Isotope Tracers in Catchment Hydrology is the first synthesis of physical hydrology and isotope geochemistry with catchment focus, and is a valuable reference for professionals and students alike in the fields of hydrology, hydrochemistry, and environmental science. This important interdisciplinary text provides extensive guidelines for the application of isotope techniques for all investigatores facing the challenge of protecting precious water, soil, and ecological resources from the ever-increasing problems associated with population growth and environmental change, including those from urban development and agricultural land uses.
Book Synopsis Characterizing Groundwater Recharge by : J. Moran
Download or read book Characterizing Groundwater Recharge written by J. Moran and published by IWA Publishing. This book was released on 2004-01-01 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of the project was to demonstrate the value of age-dating and isotopic tracers in characterizing the flow dynamics and water quality changes in a complex groundwater domain that includes high capacity municipal pumping wells, a geologic fault, and artificial recharge facilities with deep lake-like recharge ponds. Characterizing water quality changes during recharge and transport in groundwater was also an objective of this investigation. Below (west of) the Hayward Fault (BHF), water ages correlated well with aquifer layer sequence. BHF tracers did not reach the BHF wellfield within the time frame of the experiment. Above (east of) the fault, (AHF) tracers reached the targeted wellfield in only 60 days, indicating substantial heterogeneity and a fast travel time along preferential pathways compared to the average travel time of 2+ years indicated by age-dating and more classical estimating methods. A reconnaissance of water quality, conducted concurrently with the tracer studies, suggested certain water quality improvements occurring in either the pond sediment or the near-pond aquifer media. Variations in groundwater age depended on location and depth. A survey of natural isotopes indicated mixing of young and older water in wells, increasing age with depth of aquifer layer, and possible dissolution of carbonate minerals. AHF tracer experiments, along with other analysis, suggested that tracers probably percolated preferentially at shallow depths in the pond near the shoreline. Much of the tracer remained in deep pond water over time, increasing residence time in down-gradient wells. The tracer studies provided evidence of preferential pathways and heterogeneity in the AHF aquifer and a fast minimum travel time to the AHF wellfield. The tracer added to BHF ponds was detected in just two monitoring wells, but not at the BHF wellfield over the 10-month period. An AHF tracer from a small pond spanning the fault did, however, appear at the BHF wellfield. BHF pond water flows mainly to distal portions of the groundwater basin, or reaches the wellfield over a slow, circuitous route. Originally published by AwwaRF for its subscribers in 2003 This publication can also be purchased and downloaded via Pay Per View on Water Intelligence Online - click on the Pay Per View icon below
Download or read book Treatise on Geochemistry written by and published by Newnes. This book was released on 2013-10-19 with total page 14787 pages. Available in PDF, EPUB and Kindle. Book excerpt: This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!
Book Synopsis Water-resources Investigations Report by :
Download or read book Water-resources Investigations Report written by and published by . This book was released on 1991 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis U.S. Geological Survey Toxic Substances Hydrology Program by : Gail E. Mallard
Download or read book U.S. Geological Survey Toxic Substances Hydrology Program written by Gail E. Mallard and published by . This book was released on 1992 with total page 748 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Water-resources Investigations Report by :
Download or read book Water-resources Investigations Report written by and published by . This book was released on 1989 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dissolved Organic Carbon 14C in Southern Nevada Groundwater and Implications for Groundwater Travel Times by :
Download or read book Dissolved Organic Carbon 14C in Southern Nevada Groundwater and Implications for Groundwater Travel Times written by and published by . This book was released on 2016 with total page 59 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved inorganic carbon (DIC) carbon-14 (14C) ages must be corrected for complex chemical and physical reactions and processes that change the amount of 14C in groundwater as it flows from recharge to downgradient areas. Because of these reactions, DIC 14C can produce unrealistically old ages and long groundwater travel times that may, or may not, agree with travel times estimated by other methods. Dissolved organic carbon (DOC) 14C ages are often younger than DIC 14C ages because there are few chemical reactions or physical processes that change the amount of DOC 14C in groundwater. However, there are several issues that create uncertainty in DOC 14C groundwater ages including limited knowledge of the initial (A0) DOC 14C in groundwater recharge and potential changes in DOC composition as water moves through an aquifer. This study examines these issues by quantifying A0 DOC 14C in recharge areas of southern Nevada groundwater flow systems and by evaluating changes in DOC composition as water flows from recharge areas to downgradient areas. The effect of these processes on DOC 14C groundwater ages is evaluated and DOC and DIC 14C ages are then compared along several southern Nevada groundwater flow paths. Twenty-seven groundwater samples were collected from springs and wells in southern Nevada in upgradient, midgradient, and downgradient locations. DOC 14C for upgradient samples ranged from 96 to 120 percent modern carbon (pmc) with an average of 106 pmc, verifying modern DOC 14C ages in recharge areas, which decreases uncertainty in DOC 14C A0 values, groundwater ages, and travel times. The HPLC spectra of groundwater along a flow path in the Spring Mountains show the same general pattern indicating that the DOC compound composition does not change along this flow path. Although DOC concentration decreases from recharge-area to downgradient groundwater, the organic compounds are similar, indicating that DOC 14C is unaffected by other processes such as microbial degradation. A small amount of organic carbon was leached from crushed volcanic and carbonate aquifer outcrop rock in rock-leaching experiments. The leached DOC was high in 14C (75 pmc carbonate rocks, 91 pmc volcanic) suggesting that the leached DOC likely came from microbes in the rock samples. The small amount of DOC and high 14C indicates that the amount of old organic carbon in these rocks is low so there should be minimal impact on groundwater DOC 14C ages. Based on the results from this study, DOC 14C ages do not require additional corrections. Several correction models were applied to DIC 14C ages to correct for water-rock reactions along two carbonate and two volcanic flow paths and the corresponding travel times were compare to DOC 14C travel times. The DOC 14C travel times were hundreds to thousands of years shorter than uncorrected and corrected DIC 14C travel times except for the upper section of one carbonate flow path. DOC 14C travel times ranged from 400 to 5,400 years as compared to DIC 14C that ranged from modern to 20,900 years. The DIC 14C ages are greatly influenced by carbonate mineral and gas reactions and other processes such as matrix diffusion, isotope exchange, or adsorption, which are not always adequately accounted for in DIC 14C groundwater age correction models.
Author :National Academies of Sciences, Engineering, and Medicine Publisher :National Academies Press ISBN 13 :0309465591 Total Pages :113 pages Book Rating :4.3/5 (94 download)
Book Synopsis Investigative Strategies for Lead-Source Attribution at Superfund Sites Associated with Mining Activities by : National Academies of Sciences, Engineering, and Medicine
Download or read book Investigative Strategies for Lead-Source Attribution at Superfund Sites Associated with Mining Activities written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2017-10-31 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Superfund program of the US Environmental Protection Agency (EPA) was created in the 1980s to address human-health and environmental risks posed by abandoned or uncontrolled hazardous-waste sites. Identification of Superfund sites and their remediation is an expensive multistep process. As part of this process, EPA attempts to identify parties that are responsible for the contamination and thus financially responsible for remediation. Identification of potentially responsible parties is complicated because Superfund sites can have a long history of use and involve contaminants that can have many sources. Such is often the case for mining sites that involve metal contamination; metals occur naturally in the environment, they can be contaminants in the wastes generated at or released from the sites, and they can be used in consumer products, which can degrade and release the metals back to the environment. This report examines the extent to which various sources contribute to environmental lead contamination at Superfund sites that are near lead-mining areas and focuses on sources that contribute to lead contamination at sites near the Southeast Missouri Lead Mining District. It recommends potential improvements in approaches used for assessing sources of lead contamination at or near Superfund sites.
Download or read book Le sens de l'unité written by and published by . This book was released on 1947 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Environmental Tracers in Subsurface Hydrology by : Peter G. Cook
Download or read book Environmental Tracers in Subsurface Hydrology written by Peter G. Cook and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Tracers in Subsurface Hydrology synthesizes the research of specialists into a comprehensive review of the application of environmental tracers to the study of soil water and groundwater flow. The book includes chapters which cover ionic tracers, noble gases, chlorofluorocarbons, tritium, chlorine-36, oxygen-18, deuterium, and isotopes of carbon, strontium, sulphur and nitrogen. Applications of the tracers include the estimation of vertical and horizontal groundwater velocities, groundwater recharge rates, inter-aquifer leakage and mixing processes, chemical processes and palaeohydrology. Practicing hydrologists, soil physicists and hydrology professors and students will find the book to be a valuable support in their work.
Book Synopsis Hydrological and Geochemical Characterization of Shallow Aquifer Water Following a Nearby Deep CO2 Injection in Wellington, Kansas by : Ian E. Andree
Download or read book Hydrological and Geochemical Characterization of Shallow Aquifer Water Following a Nearby Deep CO2 Injection in Wellington, Kansas written by Ian E. Andree and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Domestic and irrigation well water quality in south-central Kansas is threatened by multiple sources of contamination including CO2-EOR activities, evaporite dissolution and oilfield brine release. This research identifies potential groundwater flow paths for contaminant migration in a concentrated area mixed with oil, injection, irrigation and domestic wells. Groundwater (GW) sampling took place before and after CO2 injections into the Mississippian in to assess temporal changes in water quality in a ~2 mile radius around injection well KGS 2-32. Samples were analyzed for stable isotopes, rare earth elements (REE), major and trace ions, dissolved organic carbon (DOC) with a select few analyzed for dissolved CO2 and hydrocarbons. Results of major ion chemistry reveal an evaporite control on geochemistry in wells screened within the paleoterrace as opposed to the incised valley. Bedrock channeling due to erosional scouring of the paleovalley is speculated to have led to secondary porosity thereby increasing GW flow. Similar stable isotopic and Br/Cl mass ratios between SW-3, Shepherd and Zehr indicate water is similarly sourced; lower total dissolved solids within incised valley could result from dilution from infiltration through overburden sediments. Br/Cl, SO4/Cl, Na/Cl and (Ca+Mg)/Na ratios indicate Shepherd, Zehr and SW-3 are possibly impacted by a recent salt plume movement through this portion of the shallow aquifer. An increase in total dissolved solids and Mg/Ca ratios with temperatures less than 25°C over a 25 to 200 ft. depth interval into the Permian Shale of the uplands could have resulted from increasing calcitization and reduction in effective porosity. Dissolved REEs showed most domestic and surface waters contain similar signatures, indicating similarly sourced water. Additionally, there was no CO2 leakage found within the sampling timeframe and a future leaked plume may be impeded by decreasing porosity from current secondary mineralization processes taking place in the Permian Shale.
