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Experimental Protocol For Determining Hydroxyl Radical Reaction Rate Constants
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Book Synopsis Experimental Protocol for Determining Hydroxyl Radical Reaction Rate Constants by : James N. Pitts
Download or read book Experimental Protocol for Determining Hydroxyl Radical Reaction Rate Constants written by James N. Pitts and published by . This book was released on 1982 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Experimental Protocol for Determining Hydroxyl Radical Reaction Rate Constants for Organic Compounds by : James N. Pitts
Download or read book Experimental Protocol for Determining Hydroxyl Radical Reaction Rate Constants for Organic Compounds written by James N. Pitts and published by . This book was released on 1985 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Experimental Determination of Rate Constants for Reactions of the Hydroxyl Radical with Alkanes and Alcohols by : Genny Anne Pang
Download or read book Experimental Determination of Rate Constants for Reactions of the Hydroxyl Radical with Alkanes and Alcohols written by Genny Anne Pang and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Over one quarter of the energy usage in the United States currently occurs in the transportation sector. Improvements in energy conversion efficiency and sustainability in transportation applications, therefore, can substantially contribute to improved energy security in our future. The design of advanced high-efficiency energy conversion devices for transportation applications can be facilitated with complex computer models of combustion processes. The development of these models requires a large experimental database to ensure accuracy of the computational predictions. This thesis discusses how experimental studies are utilized to create a database of rate constants for elementary reactions; these rate constants are integral components of any computational model of combustion chemistry. During a combustion process, the reaction of the hydroxyl (OH) radical, a highly reactive chemical intermediate, with a combustible fuel molecule is a major fuel consumption pathway under many combustion conditions. Thus, the rate constants for these types of reactions must be accurately known to develop a computational model that correctly describes the combustion chemistry. This thesis presents an experimental method for measuring rate constants in the reaction family of OH + Fuel -> Products using a shock tube reactor, laser diagnostics, and tert-butylhydroperoxide (TBHP) as an OH radical precursor. Important rate constant parameters describing subsequent reactions of TBHP decomposition are also studied. Current transportation fuels of interest in the combustion community include molecules in the alkane and butanol classes. Alkane molecules are a major component of many petroleum-derived fuels such as gasoline and jet fuel. Isomers of the butanol molecule are gaining popularity as a potential renewable alternative to gasoline because of their high energy density and the many known methods of production from biomass and agricultural byproducts. The rate constant measurement method is applied to the reaction of OH with three alkane molecules (n-pentane, n-heptane, and n-nonane) and four isomers of butanol (n-butanol, iso-butanol, sec-butanol, tert-butanol), and the results are reported in this thesis. Comparison of the rate constant results to estimation methods in the literature are presented, and, for several of the isomers of butanol studied, the measured data are also used to validate and/or suggest refinements to existing detailed kinetic mechanisms.
Book Synopsis Experimental Protocol for Determining Ozone Reaction Rate Constants by :
Download or read book Experimental Protocol for Determining Ozone Reaction Rate Constants written by and published by . This book was released on 1981 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Experimental and Theoretical Determination of the Temperature Dependent Rate Constant for the Reaction of Hydroxyl Radicals with Some Volatile Organic Compounds by : Paul E. Carey (Jr.)
Download or read book Experimental and Theoretical Determination of the Temperature Dependent Rate Constant for the Reaction of Hydroxyl Radicals with Some Volatile Organic Compounds written by Paul E. Carey (Jr.) and published by . This book was released on 2015 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Rate Constants of Hydroxyl Radical Reactions with Cyclic Parafins by : Yoshinobu Yamada
Download or read book Rate Constants of Hydroxyl Radical Reactions with Cyclic Parafins written by Yoshinobu Yamada and published by . This book was released on 1974 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Atmospheric Ozone Research and its Policy Implications by : S.D. Lee
Download or read book Atmospheric Ozone Research and its Policy Implications written by S.D. Lee and published by Elsevier. This book was released on 1989-01-01 with total page 1067 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings describe the current state-of-the-art of ozone research. A wide range of topics is discussed including: emissions, transport and transformation of precursors of ozone and of ozone itself, the distribution of ozone, the deposition of ozone at the earth's surface, and its effects on man and the environment. Attention is also given to the role of stratospheric ozone and the role of the ultraviolet radiation which is transmitted through the ozone layer. Finally it describes in detail present and future policy measures to reduce the ozone in the lower atmosphere and to protect the ozone layer in the stratosphere.Many of the papers describe recent developments and new research results. Research carried out in both in Europe and in the United States is described, as are the policy measures which are being taken by both European and U.S. governments.
Book Synopsis A Shock Tube Study of the Reactions of the Hydroxyl Radical with Combustion Species and Pollutants by :
Download or read book A Shock Tube Study of the Reactions of the Hydroxyl Radical with Combustion Species and Pollutants written by and published by . This book was released on 1992 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: To extend the database of reliable high temperature measurements of OH radicals with hydrocarbons and other fuels and their decomposition products, we undertook, a research program with both experimental and computational tasks. The experimental goal was to design a procedure for measuring, at combustion temperatures, the reaction rate coefficients of OH radicals with fuels and other species of importance in combustion or propulsion systems. The computational effort was intended to refine the semi-empirical thermochemical kinetics/ transition-state-theory (TK-TST) procedures for extrapolating rate coefficients of reactions of OH with combustion species of interest, for predicting rate coefficients for species not studied in the laboratory, and to examine the ability of the theory to predict rate coefficients for different pathways in cases where the reagent possessed nonequivalent H atoms.
Book Synopsis ORD Publications Announcement by : Center for Environmental Research Information (U.S.)
Download or read book ORD Publications Announcement written by Center for Environmental Research Information (U.S.) and published by . This book was released on 1990 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1986 with total page 1162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1986 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Indexes by : United States. Environmental Protection Agency
Download or read book Indexes written by United States. Environmental Protection Agency and published by . This book was released on 1983 with total page 1760 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Acid Precipitation written by and published by . This book was released on 1986 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Monthly Catalog of United States Government Publications by :
Download or read book Monthly Catalog of United States Government Publications written by and published by . This book was released on 1981 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Monthly Catalogue, United States Public Documents by :
Download or read book Monthly Catalogue, United States Public Documents written by and published by . This book was released on 1983 with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :United States. Congress. House. Committee on Science. Subcommittee on Energy and Environment Publisher : ISBN 13 : Total Pages :910 pages Book Rating :4.0/5 ( download)
Book Synopsis EPA's Rule on Paints and Coatings by : United States. Congress. House. Committee on Science. Subcommittee on Energy and Environment
Download or read book EPA's Rule on Paints and Coatings written by United States. Congress. House. Committee on Science. Subcommittee on Energy and Environment and published by . This book was released on 1998 with total page 910 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis EPA Publications Bibliography by : United States. Environmental Protection Agency
Download or read book EPA Publications Bibliography written by United States. Environmental Protection Agency and published by . This book was released on 1985 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: