Electrode Kinetics and Species Transport in Direct Oxidation Methanol Fuel Cells

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ISBN 13 :
Total Pages : 60 pages
Book Rating : 4.X/5 (4 download)

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Book Synopsis Electrode Kinetics and Species Transport in Direct Oxidation Methanol Fuel Cells by : Pertti S. Kauranen

Download or read book Electrode Kinetics and Species Transport in Direct Oxidation Methanol Fuel Cells written by Pertti S. Kauranen and published by . This book was released on 1996 with total page 60 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Proceedings of the Workshop on Direct Methanol-Air Fuel Cells

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Publisher :
ISBN 13 :
Total Pages : 252 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Proceedings of the Workshop on Direct Methanol-Air Fuel Cells by : Albert R. Landgrebe

Download or read book Proceedings of the Workshop on Direct Methanol-Air Fuel Cells written by Albert R. Landgrebe and published by . This book was released on 1992 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Investigation of Methanol Transport and Reaction Kinetics in Direct Methanol Fuel Cells

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Publisher :
ISBN 13 : 9781124240503
Total Pages : pages
Book Rating : 4.2/5 (45 download)

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Book Synopsis Investigation of Methanol Transport and Reaction Kinetics in Direct Methanol Fuel Cells by : Srikanth Arisetty

Download or read book Investigation of Methanol Transport and Reaction Kinetics in Direct Methanol Fuel Cells written by Srikanth Arisetty and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methanol Fuel Cells (DMFCs) have been demonstrated extensively as electrical power sources for portable applications. In DMFCs, the chemical energy stored in methanol is converted directly to electrical energy through a number of chemical, transport and kinetic processes. The overall efficiency of the DMFC system can be improved by optimizing these processes with precise control over operating conditions. The goal of this research is to evaluate optimal operating conditions and system design for improving the DMFC's electrical performance through a combination of experimental strategies and process models. A DMFC system incorporating metal foams as the flow field was designed to increase system efficiency. The influence of metal foam parameters and operating conditions on fuel cell performance was investigated. Our results indicated that due to the opposing effects of methanol concentration on anode and cathode kinetics, there exists an optimal value of methanol concentration at each current density that will yield the highest electrical performance. A control algorithm employing feedback from the fuel cell voltage was implemented to dynamically adjust the methanol feed concentration for peak DMFC performance. Additionally, water and methanol crossover fluxes across the membrane were also measured to understand their transport rates under different conditions. The physico-chemical processes in DMFCs were investigated by developing an accurate mathematical model coupling mass transport with reaction kinetics within the five-layer membrane electrode assembly of the DMFC. An experimental scheme was developed to measure the overpotential contributions of anode methanol oxidation, cathode oxygen reduction and cathode methanol oxidation. Subsequently, the kinetic constants for these three reactions are characterized for various catalyst loadings. The model predicted that methanol undergoes electrochemical adsorption on the Pt/C cathode catalyst layer, followed by both electrochemical and chemical oxidation. The overpotential loss due to methanol oxidation on the cathode with 2 mg/cm 2 catalyst loading is as large as 80 mV at 20 mA/cm 2 . Our model indicated that most of the methanol adsorbed on the cathode catalyst undergoes purely chemical oxidation with oxygen and causes mass transport limitations for oxygen electro-reduction. We also found that the transport of methanol to the anode catalyst layer was significantly enhanced by the convection of CO 2 bubbles towards the flow field. This model should prove useful in optimizing the supply rates of methanol and oxygen in DMFCs.

Electrocatalysis of Direct Methanol Fuel Cells

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Publisher : John Wiley & Sons
ISBN 13 : 3527323775
Total Pages : 605 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Electrocatalysis of Direct Methanol Fuel Cells by : Jiujun Zhang

Download or read book Electrocatalysis of Direct Methanol Fuel Cells written by Jiujun Zhang and published by John Wiley & Sons. This book was released on 2009-10-26 with total page 605 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to focus on a comprehensive description on DMFC electrocatalysis draws a clear picture of the current status of DMFC technology, especially the advances, challenges and perspectives in the field. Leading researchers from universities, government laboratories and fuel cell industries in North America, Europe and Asia share their knowledge and information on recent advances in the fundamental theories, experimental methodologies and research achievements. In order to help readers better understand the science and technology of the subject, some important and representative figures, tables, photos, and comprehensive lists of reference papers are also included, such that all the information needed on this topic may be easily located. An indispensable source for physical, catalytic, electro- and solid state chemists, as well as materials scientists and chemists in industry.

Direct Methanol Fuel Cell Technology

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Publisher : Elsevier
ISBN 13 : 0128191597
Total Pages : 565 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Direct Methanol Fuel Cell Technology by : Kingshuk Dutta

Download or read book Direct Methanol Fuel Cell Technology written by Kingshuk Dutta and published by Elsevier. This book was released on 2020-02-25 with total page 565 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. - Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells - Includes modeling of direct methanol fuel cells to understand their scaling up potentials - Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects

Fuel Cell Engineering

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Publisher : Academic Press
ISBN 13 : 0123868750
Total Pages : 481 pages
Book Rating : 4.1/5 (238 download)

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Book Synopsis Fuel Cell Engineering by :

Download or read book Fuel Cell Engineering written by and published by Academic Press. This book was released on 2012-08-14 with total page 481 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cells are attractive electrochemical energy converters featuring potentially very high thermodynamic efficiency factors. The focus of this volume of Advances in Chemical Engineering is on quantitative approaches, particularly based on chemical engineering principles, to analyze, control and optimize the steady state and dynamic behavior of low and high temperature fuel cells (PEMFC, DMFC, SOFC) to be applied in mobile and stationary systems. - Updates and informs the reader on the latest research findings using original reviews - Written by leading industry experts and scholars - Reviews and analyzes developments in the field

Catalysts for Alcohol-fuelled Direct Oxidation Fuel Cells

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849734054
Total Pages : 265 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Catalysts for Alcohol-fuelled Direct Oxidation Fuel Cells by : Zhen-Xing Liang

Download or read book Catalysts for Alcohol-fuelled Direct Oxidation Fuel Cells written by Zhen-Xing Liang and published by Royal Society of Chemistry. This book was released on 2012 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a state-of-the-art review on recent advances in nanocatalysts and electrocatalysis in DOFCs.

Direct Alcohol Fuel Cells for Portable Applications

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Publisher : Academic Press
ISBN 13 : 0128118989
Total Pages : 356 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Direct Alcohol Fuel Cells for Portable Applications by : Alexandra M. F. R. Pinto

Download or read book Direct Alcohol Fuel Cells for Portable Applications written by Alexandra M. F. R. Pinto and published by Academic Press. This book was released on 2018-09-08 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Alcohol Fuel Cells for Portable Applications: Fundamentals, Engineering and Advances presents the fundamental concepts, technological advances and challenges in developing, modeling and deploying fuel cells and fuel cell systems for portable devices, including micro and mini fuel cells. The authors review the fundamental science of direct alcohol fuel cells, covering, in detail, thermodynamics, electrode kinetics and electrocatalysis of charge-transfer reactions, mass and heat transfer phenomena, and basic modeling aspects. In addition, the book examines other fuels in DAFCs, such as formic acid, ethylene glycol and glycerol, along with technological aspects and applications, including case studies and cost analysis. Researchers, engineering professionals, fuel cell developers, policymakers and senior graduate students will find this a valuable resource. The book's comprehensive coverage of fundamentals is especially useful for graduate students, advanced undergraduate students and those new to the field. - Provides a comprehensive understanding of the fundamentals of DAFCs and their basic components, design and performance - Presents current and complete information on the state-of-the-art of DAFC technology and its most relevant challenges for commercial deployment - Includes practical application examples, problems and case studies - Covers the use of other fuels, such as formic acid, ethylene glycol and glycerol

Direct Methanol Fuel Cells

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Publisher :
ISBN 13 :
Total Pages : 366 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Direct Methanol Fuel Cells by : Electrochemical Society. Energy Technology Division

Download or read book Direct Methanol Fuel Cells written by Electrochemical Society. Energy Technology Division and published by . This book was released on 2001 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Energy Technology, Physical Electrochemistry and Battery Divisions."

Advances in Fuel Cells

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Publisher : Elsevier
ISBN 13 : 0080471005
Total Pages : 499 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Advances in Fuel Cells by :

Download or read book Advances in Fuel Cells written by and published by Elsevier. This book was released on 2007-04-23 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cells have been recognized to be destined to form the cornerstone of energy technologies in the twenty-first century. The rapid advances in fuel cell system development have left current information available only in scattered journals and Internet sites. Advances in Fuel Cells fills the information gap between regularly scheduled journals and university level textbooks by providing in-depth coverage over a broad scope. The present volume provides informative chapters on thermodynamic performance of fuel cells, macroscopic modeling of polymer-electrolyte membranes, the prospects for phosphonated polymers as proton-exchange fuel cell membranes, polymer electrolyte membranes for direct methanol fuel cells, materials for state of the art PEM fuel cells, and their suitability for operation above 100°C, analytical modelling of direct methanol fuel cells, and methanol reforming processes. - Includes contributions by leading experts working in both academic and industrial R&D - Disseminates the latest research discoveries - A valuable resource for senior undergraduates and graduate students, it provides in-depth coverage over a broad scope

Characterization of Novel Catalysts for Methanol Oxidation and Oxygen Reduction in Direct Methanol Fuel Cells

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Publisher :
ISBN 13 :
Total Pages : 388 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Characterization of Novel Catalysts for Methanol Oxidation and Oxygen Reduction in Direct Methanol Fuel Cells by : Hwangchan Yoo

Download or read book Characterization of Novel Catalysts for Methanol Oxidation and Oxygen Reduction in Direct Methanol Fuel Cells written by Hwangchan Yoo and published by . This book was released on 2001 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Direct Methanol Fuel Cell Development

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ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Direct Methanol Fuel Cell Development by :

Download or read book Direct Methanol Fuel Cell Development written by and published by . This book was released on 1999 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The focus of the first year of this two-year program was the development of an electrolyte system for fuel cells and other electrochemical reactors, which allows proton transfer through the electrolyte system but prevents crossover of lager chemical species from one electrode side to the other electrode side of the fuel cell. The first year effort of this program resulted in the filing of a U.S. patent application in Jan. 16, 1996 that was issued on Dec. 8, 1998 (United States Patent 5,846,669). The patent was based on work published in 1995 by Cong Pu, Wenhua Huang, K.L. Ley and E.S. Smotkin, "A Methanol Impermeable Proton Conducting Composite Electrolyte System," J. Electrochem. Soc., 142, L119-L120 (1995). This work was attributed to the DARPA grant. The second year of the program was focused on the development of new anodes for direct methanol fuel cells. This work resulted in a second patent entitled "Single Phase Ternary Pt-Ru-Os Catalysts for Direct Oxidation Fuel Cells" (United States Patent 5,856,036). Ley et al. based this patent on a publication, "Methanol Oxidation on single-Phase Pt-Ru-Os Ternary Alloys", "J. Electrochem. Soc., 144, 1543-1548 (1997). This work was attributed to the DARPA grant.

NASA Conference Publication

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Publisher :
ISBN 13 :
Total Pages : 692 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis NASA Conference Publication by :

Download or read book NASA Conference Publication written by and published by . This book was released on 1991 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Micro & Nano-Engineering of Fuel Cells

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Publisher : CRC Press
ISBN 13 : 1315815079
Total Pages : 337 pages
Book Rating : 4.3/5 (158 download)

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Book Synopsis Micro & Nano-Engineering of Fuel Cells by : Dennis Y.C. Leung

Download or read book Micro & Nano-Engineering of Fuel Cells written by Dennis Y.C. Leung and published by CRC Press. This book was released on 2015-04-24 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cells are clean and efficient energy conversion devices expected to be the next generation power source. During more than 17 decades of research and development, various types of fuel cells have been developed with a view to meet the different energy demands and application requirements. Scientists have devoted a great deal of time and effort

PEM Fuel Cell Electrocatalysts and Catalyst Layers

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Publisher : Springer Science & Business Media
ISBN 13 : 1848009364
Total Pages : 1147 pages
Book Rating : 4.8/5 (48 download)

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Book Synopsis PEM Fuel Cell Electrocatalysts and Catalyst Layers by : Jiujun Zhang

Download or read book PEM Fuel Cell Electrocatalysts and Catalyst Layers written by Jiujun Zhang and published by Springer Science & Business Media. This book was released on 2008-08-26 with total page 1147 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proton exchange membrane (PEM) fuel cells are promising clean energy converting devices with high efficiency and low to zero emissions. Such power sources can be used in transportation, stationary, portable and micro power applications. The key components of these fuel cells are catalysts and catalyst layers. “PEM Fuel Cell Electrocatalysts and Catalyst Layers” provides a comprehensive, in-depth survey of the field, presented by internationally renowned fuel cell scientists. The opening chapters introduce the fundamentals of electrochemical theory and fuel cell catalysis. Later chapters investigate the synthesis, characterization, and activity validation of PEM fuel cell catalysts. Further chapters describe in detail the integration of the electrocatalyst/catalyst layers into the fuel cell, and their performance validation. Researchers and engineers in the fuel cell industry will find this book a valuable resource, as will students of electrochemical engineering and catalyst synthesis.

Space Electrochemical Research and Technology

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Publisher :
ISBN 13 :
Total Pages : 256 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Space Electrochemical Research and Technology by :

Download or read book Space Electrochemical Research and Technology written by and published by . This book was released on 1991 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Kinetics and Mass Transfer in a Direct Methanol Fuel Cell

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Publisher :
ISBN 13 :
Total Pages : 304 pages
Book Rating : 4.:/5 (156 download)

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Book Synopsis Kinetics and Mass Transfer in a Direct Methanol Fuel Cell by : Brenda Lee García-Díaz

Download or read book Kinetics and Mass Transfer in a Direct Methanol Fuel Cell written by Brenda Lee García-Díaz and published by . This book was released on 2007 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: