Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Methyl Tertiary-butyl Ether and Trichloroethene from Natural Water

Download Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Methyl Tertiary-butyl Ether and Trichloroethene from Natural Water PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 149 pages
Book Rating : 4.:/5 (472 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Methyl Tertiary-butyl Ether and Trichloroethene from Natural Water by : Patricia Ann Quinlivan

Download or read book Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Methyl Tertiary-butyl Ether and Trichloroethene from Natural Water written by Patricia Ann Quinlivan and published by . This book was released on 2001 with total page 149 pages. Available in PDF, EPUB and Kindle. Book excerpt: Keywords: activated carbon, chemical treatment, surface treatment, adsorption properties, microporosity.

Effects of Activated Carbon Surface Chemistry and Pore Structure on the Absorption of Methyl Tertiary-Butyl Ether and Trichloroethene from Natural Water

Download Effects of Activated Carbon Surface Chemistry and Pore Structure on the Absorption of Methyl Tertiary-Butyl Ether and Trichloroethene from Natural Water PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (656 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Surface Chemistry and Pore Structure on the Absorption of Methyl Tertiary-Butyl Ether and Trichloroethene from Natural Water by :

Download or read book Effects of Activated Carbon Surface Chemistry and Pore Structure on the Absorption of Methyl Tertiary-Butyl Ether and Trichloroethene from Natural Water written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Activated carbon adsorption is the best available treatment technology for thecontrol of many objectionable trace organic compounds. Activated carbons are frequentlycharacterized by the iodine number and BET surface area, but these parameters do notcorrelate well with trace organic compound removal from natural water. Therefore, theobjective of this research was to develop activated carbon selection criteria that assure theeffective removal of trace organic contaminants from natural water and to base theselection criteria on the adsorbent's pore structure and surface chemistry. Tosystematically evaluate pore structure and surface chemistry effects, a matrix of activatedcarbon fibers (ACFs) with three activation levels and four surface chemistry levels wasstudied. To evaluate whether adsorption trends established for ACFs were also valid forgranular activated carbon (GAC), ACF results were compared with those obtained forthree commercially available GACs. Adsorption capacities were determined for naturalorganic matter (NOM), for relatively hydrophilic methyl tertiary-butyl ether (MTBE) andrelatively hydrophobic trichloroethene (TCE) in organic-free water, and for MTBE andTCE in the presence of NOM. NOM isotherms showed that DOC adsorption occurredprimarily in pores with diameters in the 11 to 500 Å range and that electrostaticinteractions between NOM and the carbon surface played a role in NOM adsorption. According to both single-solute isotherms and micropollutant isotherms in the presence of NOM, hydrophobic adsorbents more effectively removed TCE and MTBE thanhydrophilic adsorbents. Effective adsorbents for drinking water treatment shouldtherefore contain little oxygen and nitrogen whose presence increases the polarity of theadsorbent surface. Based on the elemental composition of the low-ash carbons evaluatedin this study, activated carbons should have oxygen and nitrogen contents that sum to nomore than 2 to 3 mmol/g to assure sufficient hydrophobicity. In a.

Effects of Activated Carbon Characteristics on Organic Contaminant Removal

Download Effects of Activated Carbon Characteristics on Organic Contaminant Removal PDF Online Free

Author :
Publisher : IWA Publishing
ISBN 13 : 1843398419
Total Pages : 100 pages
Book Rating : 4.8/5 (433 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Characteristics on Organic Contaminant Removal by : Detlef R. U. Knappe

Download or read book Effects of Activated Carbon Characteristics on Organic Contaminant Removal written by Detlef R. U. Knappe and published by IWA Publishing. This book was released on 2004-01-01 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many water treatment plants need to remove objectionable trace organic compounds, and activated carbon adsorption is often the best available technology. Utilities face the challenge of having to choose from a large variety of activated carbons, and iodine number or BET surface area values are often utilized in the selection process. Although neither parameter correlates well with adsorption capacities, alternative activated carbon selection criteria based on fundamental adsorbent and adsorbate properties are lacking to date. The first objective of this research was to systematically evaluate the effects of activated carbon pore structure and surface chemistry on the adsorption of two common drinking water contaminants: the relatively polar fuel oxygenate methyl tertiary-butyl ether (MTBE) and the relatively nonpolar solvent trichloroethene (TCE). The second objective was to develop simple descriptors of activated carbon characteristics that facilitate the selection of suitable adsorbents for the removal of organic contaminants from drinking water.Originally published by AwwaRF for its subscribers in 2003 This publication can also be purchased and downloaded via Pay Per View on Water Intelligence Online - click on the Pay Per View icon below

Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution

Download Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (656 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution by :

Download or read book Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The principal objectives of this research were (1) to identify activated pore structure and surface chemistry characteristics that assure the effective removal of trace organic contaminants from aqueous solution, and (2) to develop a procedure to predict the adsorption capacity of activated carbons from fundamental adsorbent and adsorbate properties. To systematically evaluate pore structure and surface chemistry effects on the adsorption of organic micropollutants from aqueous solution, a matrix of activated carbon fibers (ACFs) with three activation levels and four surface chemistry levels was prepared and characterized. In addition, three commercially available granular activated carbons (GACs) were studied to verify whether correlations developed for the ACF matrix are valid for adsorbents that are typically used for water treatment. BET surface area, pore size distribution, elemental composition, point of zero charge and infrared spectroscopy data were obtained to characterize the adsorbents. The results showed that the ACF matrix prepared in this study permits a fairly independent evaluation of surface chemistry and pore structure effects on organic contaminant adsorption from aqueous solution. Methyl tertiary-butyl ether (MTBE), a relatively hydrophilic adsorbate, and trichloroethene (TCE), a relatively hydrophobic adsorbate, served as adsorbate probes. To evaluate the effects of natural organic matter (NOM) on MTBE and TCE adsorption capacities, isotherm experiments were conducted in ultrapure water and Sacramento-San Joaquin Delta water. With respect to surface chemistry, both single-solute isotherms and isotherms in the presence of NOM indicated that hydrophobic adsorbents more effectively removed TCE and MTBE from aqueous solution than hydrophilic adsorbents. Enhanced water adsorption on polar surface sites explained the poorer performance of the hydrophilic adsorbents. Based on the elemental composition of the low-ash carbons evaluated in this study, act.

Effect of Surface Groups on Adsorption of Pollutants

Download Effect of Surface Groups on Adsorption of Pollutants PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 44 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Effect of Surface Groups on Adsorption of Pollutants by : Robert W. Coughlin

Download or read book Effect of Surface Groups on Adsorption of Pollutants written by Robert W. Coughlin and published by . This book was released on 1970 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Alternative Adsorbents for the Removal of Polar Organic Contaminants

Download Alternative Adsorbents for the Removal of Polar Organic Contaminants PDF Online Free

Author :
Publisher : American Water Works Association
ISBN 13 : 1583215425
Total Pages : 136 pages
Book Rating : 4.5/5 (832 download)

DOWNLOAD NOW!


Book Synopsis Alternative Adsorbents for the Removal of Polar Organic Contaminants by : Detlef R. U. Knappe

Download or read book Alternative Adsorbents for the Removal of Polar Organic Contaminants written by Detlef R. U. Knappe and published by American Water Works Association. This book was released on 2007 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This project studies the application of high-silica zeolites for the removal of polar organic contaminants, i.e., antimicrobial compounds and the fuel additive methyl tertiary-butyl ether (MTBE), from drinking water. Recently published data show that high-silica zeolites, a class of crystalline adsorbents with well defined pore sizes, exhibit considerably larger single-solute MTBE adsorption capacities than activated carbons and carbonaceous resins. The effectiveness of high-silica zeolites is compared to that of activated carbons and a carbonaceous resin.

Adsorption Processes for Water Treatment

Download Adsorption Processes for Water Treatment PDF Online Free

Author :
Publisher : Elsevier
ISBN 13 : 148316263X
Total Pages : 522 pages
Book Rating : 4.4/5 (831 download)

DOWNLOAD NOW!


Book Synopsis Adsorption Processes for Water Treatment by : Samuel D. Faust

Download or read book Adsorption Processes for Water Treatment written by Samuel D. Faust and published by Elsevier. This book was released on 2013-10-22 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption Processes for Water Treatment discusses the application of adsorption in water purification. The book is comprised of 10 chapters that detail the carbon and resin adsorptive processes for potable water treatment. The text first covers the elements of surface chemistry and then proceeds to discussing adsorption models. Chapter 3 tackles the kinetics of adsorption, while Chapter 4 deals with batch systems and fixed fluid beds. Next, the book talks about the physical and chemical properties of carbon. The next two chapters discuss the adsorption of organic compounds and the removal of inorganic compounds, respectively. The eighth chapter presents operational, pilot plant, and case studies. Chapter 9 discusses the biological activated carbon treatment of drinking water, and Chapter 10 covers the adsorption of macroreticular resins. The book will be of great use to both researchers and professionals involved in the research and development of water treatment process.

Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution

Download Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 159 pages
Book Rating : 4.:/5 (55 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution by : Lei Li

Download or read book Effects of Activated Carbon Surface Chemistry and Pore Structure on the Adsorption of Trace Organic Contaminants from Aqueous Solution written by Lei Li and published by . This book was released on 2002 with total page 159 pages. Available in PDF, EPUB and Kindle. Book excerpt: Keywords: trace organic contaminants, pore structure, surface chemistry, adsorbent.

Dissertation Abstracts International

Download Dissertation Abstracts International PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 674 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2003 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Encyclopedia of Surface and Colloid Science

Download Encyclopedia of Surface and Colloid Science PDF Online Free

Author :
Publisher : CRC Press
ISBN 13 : 9780849395741
Total Pages : 1084 pages
Book Rating : 4.3/5 (957 download)

DOWNLOAD NOW!


Book Synopsis Encyclopedia of Surface and Colloid Science by : P. Somasundaran

Download or read book Encyclopedia of Surface and Colloid Science written by P. Somasundaran and published by CRC Press. This book was released on 2006 with total page 1084 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Effect of Surface Chemistry and Porsity of Activated Carbons on the Adsorption of Water and Organic Pollutants

Download Effect of Surface Chemistry and Porsity of Activated Carbons on the Adsorption of Water and Organic Pollutants PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 298 pages
Book Rating : 4.:/5 (112 download)

DOWNLOAD NOW!


Book Synopsis Effect of Surface Chemistry and Porsity of Activated Carbons on the Adsorption of Water and Organic Pollutants by : Issa I. Salame

Download or read book Effect of Surface Chemistry and Porsity of Activated Carbons on the Adsorption of Water and Organic Pollutants written by Issa I. Salame and published by . This book was released on 2002 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Water Quality & Treatment: A Handbook on Drinking Water

Download Water Quality & Treatment: A Handbook on Drinking Water PDF Online Free

Author :
Publisher : McGraw Hill Professional
ISBN 13 : 0071630104
Total Pages : 1696 pages
Book Rating : 4.0/5 (716 download)

DOWNLOAD NOW!


Book Synopsis Water Quality & Treatment: A Handbook on Drinking Water by : American Water Works Association

Download or read book Water Quality & Treatment: A Handbook on Drinking Water written by American Water Works Association and published by McGraw Hill Professional. This book was released on 2010-12-06 with total page 1696 pages. Available in PDF, EPUB and Kindle. Book excerpt: The definitive water quality and treatment resource--fully revised and updated Comprehensive, current, and written by leading experts, Water Quality & Treatment: A Handbook on Drinking Water, Sixth Edition covers state-of-the-art technologies and methods for water treatment and quality control. Significant revisions and new material in this edition reflect the latest advances and critical topics in water supply and treatment. Presented by the American Water Works Association, this is the leading source of authoritative information on drinking water quality and treatment. NEW CHAPTERS ON: Chemical principles, source water composition, and watershed protection Natural treatment systems Water reuse for drinking water augmentation Ultraviolet light processes Formation and control of disinfection by-products DETAILED COVERAGE OF: Drinking water standards, regulations, goals, and health effects Hydraulic characteristics of water treatment reactors Gas-liquid processes and chemical oxidation Coagulation, flocculation, sedimentation, and flotation Granular media and membrane filtration Ion exchange and adsorption of inorganic contaminants Precipitation, coprecipitation, and precipitative softening Adsorption of organic compounds by activated carbon Chemical disinfection Internal corrosion and deposition control Microbiological quality control in distribution systems Water treatment plant residuals management

Impact of Surface Chemistry on Adsorption: Tailoring of Activated Carbon

Download Impact of Surface Chemistry on Adsorption: Tailoring of Activated Carbon PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 132 pages
Book Rating : 4.:/5 (72 download)

DOWNLOAD NOW!


Book Synopsis Impact of Surface Chemistry on Adsorption: Tailoring of Activated Carbon by : Morgana T. Bach

Download or read book Impact of Surface Chemistry on Adsorption: Tailoring of Activated Carbon written by Morgana T. Bach and published by . This book was released on 2007 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present work summarizes research into the impact of the surface chemistry of activated carbon on the water treatment phenomena of pH excursions, the tailoring of activated carbon through manipulation of the dissolved oxygen (DO) content of the water used to create steam for activation, and, most importantly, the impact of these changes in surface chemistry on adsorption.

Polyelectrolyte Adsorption by Activated Carbon and the Effects of Preloading on Trichloroethylene Adsorption

Download Polyelectrolyte Adsorption by Activated Carbon and the Effects of Preloading on Trichloroethylene Adsorption PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 686 pages
Book Rating : 4.3/5 (91 download)

DOWNLOAD NOW!


Book Synopsis Polyelectrolyte Adsorption by Activated Carbon and the Effects of Preloading on Trichloroethylene Adsorption by : James Edward Kilduff

Download or read book Polyelectrolyte Adsorption by Activated Carbon and the Effects of Preloading on Trichloroethylene Adsorption written by James Edward Kilduff and published by . This book was released on 1995 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Effects of Activated Carbon Surface Chemistry Modification on the Adsorption of Mercury from Aqueous Solution

Download Effects of Activated Carbon Surface Chemistry Modification on the Adsorption of Mercury from Aqueous Solution PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 129 pages
Book Rating : 4.:/5 (864 download)

DOWNLOAD NOW!


Book Synopsis Effects of Activated Carbon Surface Chemistry Modification on the Adsorption of Mercury from Aqueous Solution by : Emily Kaye Faulconer

Download or read book Effects of Activated Carbon Surface Chemistry Modification on the Adsorption of Mercury from Aqueous Solution written by Emily Kaye Faulconer and published by . This book was released on 2012 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mercury (Hg), a naturally occurring element, is toxic and can lead to negative health impacts for humans and ecosystems. Activated carbon adsorption is effective in treating Hg-laden aqueous effluent for safe discharge. Two modifications of commercially available activated carbon were investigated: iron impregnation to allow for magnetic sorbent recapture and wet chemical oxidation to enhance aqueous Hg capture. The modified carbons were characterized by nitrogen adsorption-desorption, XRD, pHpzc, vibrating sample magnetometry, elemental analysis, and total acidity titration. The 3:1 C:Fe magnetic powdered activated carbon (MPAC) retained a high surface area of 790 m2/g and was 95% magnetically recoverable, with the iron present primarily as maghemite. The characteristics of the surface oxygen modified carbons varied based on the nature of the modifying reagent and its concentration. The modified carbons were applied to trace level Hg solutions (100 μg/L). The 3:1 MPAC achieved the highest adsorption capacity, reaching 91% Hg removal with 2% volatilized and 84% adsorbed. Adsorption occurs primarily as chemisorption, thus allowing for non-hazardous residuals disposal until reaching a loading of greater than 800 μg Hg/ g MPAC.

The Influence of Activated Carbon Surface Chemistry and Solvent Interactions on the Adsorption of 2-methylisoborneol

Download The Influence of Activated Carbon Surface Chemistry and Solvent Interactions on the Adsorption of 2-methylisoborneol PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.:/5 (39 download)

DOWNLOAD NOW!


Book Synopsis The Influence of Activated Carbon Surface Chemistry and Solvent Interactions on the Adsorption of 2-methylisoborneol by : Robert Considine

Download or read book The Influence of Activated Carbon Surface Chemistry and Solvent Interactions on the Adsorption of 2-methylisoborneol written by Robert Considine and published by . This book was released on 1997 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Mechanisms of Competitive Adsorption Between Trace Organic Contaminants and Natural Organic Matter on Activated Carbon

Download Mechanisms of Competitive Adsorption Between Trace Organic Contaminants and Natural Organic Matter on Activated Carbon PDF Online Free

Author :
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (774 download)

DOWNLOAD NOW!


Book Synopsis Mechanisms of Competitive Adsorption Between Trace Organic Contaminants and Natural Organic Matter on Activated Carbon by : Li Ding

Download or read book Mechanisms of Competitive Adsorption Between Trace Organic Contaminants and Natural Organic Matter on Activated Carbon written by Li Ding and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Activated carbon adsorption is widely used in water treatment for removal of various organic micropollutants; nonetheless, the presence of natural organic matter (NOM) in source water can reduce its efficiency for micropollutant removal. NOM has been shown to compete with target contaminant via different mechanisms: direct competition for available adsorption sites which reduces equilibrium capacity for target compounds, blocking of pore entrance which reduces diffusion rate of the target compounds, and covering of surface sites which may actually enhances diffusion rate of the target compounds. The objective of this dissertation study was to further elucidate the individual competitive effects, to investigate how pore sizes of adsorbents and molecular structure of competing compounds affect competition and to gain a comprehensive understanding of the competitive adsorption. Atrazine, a widely used herbicide in the United States, was used as the trace-level target contaminant and NOM from different source waters as well as NOM surrogates were used as the competing compounds. Powdered activated carbons (PACs) with different pore size distribution (PSD) were used. The PSD was found to have great influence on the pore blockage (PB) effect caused by NOM. The equilibrium capacity of the NOM used in this study was best correlated to the amount of pores of diameter 15-50 ©5, which was also inversely related to the magnitude of the pore blockage effect. Activated carbon that has more surface area in this pore size range had a smaller PB effect on atrazine adsorption kinetics at the same NOM loading. This finding indicated that mesopores are important in realizing adsorption capacity for trace compounds by alleviating the adverse PB effect. The site covering effect was confirmed with additional types of PACs and various competing compounds. More important, the correlation equation that describes the enhanced surface diffusion coefficient for atrazine as a function of the loading of the site-covering compounds was found to be independent of either the PAC type or the competing compound type. The key component was to quantify the competing compound as the equivalent background compound (EBC), which reflected the extent of active sites being covered. iii The site competing effect, the site covering effect and the pore blocking effect were evaluated for five NOM surrogates with different sizes. The smaller molecules were generally more effective in reducing the equilibrium capacity of the target compound. However, for molecules of similar molecular weight, elongated molecules tended to have more equilibrium effect than round molecules. From a kinetic perspective, the enhancement in diffusivity was within one order of magnitude for all five surrogates, while the extent of the PB effect was greatly relying on molecular size that large-sized surrogates caused a much stronger PB effect. Therefore, the overall kinetic effect was dependent on molecular size and the PB effect was usually dominant except for very small molecules. Consistent with the enhanced kinetics associated with pre-adsorbed site-covering competing compounds, atrazine preloading was found to also increase the diffusion coefficient of atrazine, and the extent of enhancement caused by atrazine was greater than that caused by competing compounds. Several explanations were proposed for the difference, which include the micropore filling hypothesis and the artifact associated with the EBC method that was used for site-covering loading quantification.