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Dynamical Processes At Solid Surfaces
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Book Synopsis Dynamic Processes on Solid Surfaces by : Kenzi Tamaru
Download or read book Dynamic Processes on Solid Surfaces written by Kenzi Tamaru and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: When we see a jumbo jet at the airport, we sometimes wonder how such a huge, heavy plane can fly high in the sky. To the extent that we think in a static way, it is certainly not understandable. In such a manner, dynamics yields behavior quite different from statics. When we want to prepare an iron nitride, for example, one of the most orthodox ways is to put iron in a nitrogen atmosphere under pressures higher than the dissociation pressure of the iron nitride at temperatures sufficiently high to let the nitrogen penetrate into the bulk iron. This is the way thermodynamics tells us to proceed, which requires an elaborate, expensive high-pressure apparatus, sophisticated techniques, and great efforts. However, if we flow ammonia over the iron, even under low pressures, we can easily prepare the nitride-provided the hydrogen pressure is sufficiently low. Since the nitrogen desorption rate is the determining step of the ammonia decomposition on the iron surface, the virtual pressure of nitrogen at the surface can reach an extremely high level (as is generally accepted) because, in such a dynamic system, the driving force of the ammonia decomposition reaction pushes the nitrogen into the bulk iron to form the nitride. Thus, dynamics is an approach considerably different from statics.
Book Synopsis Dynamic Chemical Processes on Solid Surfaces by : Ken-ichi Tanaka
Download or read book Dynamic Chemical Processes on Solid Surfaces written by Ken-ichi Tanaka and published by Springer. This book was released on 2017-02-07 with total page 194 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the author determines that a surface is itself a new material for chemical reaction, and the reaction of the surface provides additional new materials on that surface. The revelation of that peculiarity is what makes this book different from an ordinary textbook, and this new point of view will help to provide a new impetus when graduate students and researchers consider their results. The reaction of surface atoms provides additional new compounds, but these compounds cannot be detached from the surface. Some compounds are passive, but others work as catalysts. One superior feature of the surface is the dynamic cooperation of two or more different functional materials or sites on the same surface. This fact has been well established in the preferential oxidation of CO on platinum supported on a carbon nanotube with Ni-MgO at its terminal end. The Pt and Ni-MgO are perfectly separated, but these two are indispensable for the selective oxidation of CO in H2, where the H2O molecule plays a key role. The reader will understand that the complexity of catalysis is due to the complexity of the dynamic processes on the surface.
Book Synopsis Dynamical Processes and Ordering on Solid Surfaces by : A. Yoshimori
Download or read book Dynamical Processes and Ordering on Solid Surfaces written by A. Yoshimori and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is the proceedings of the Seventh Taniguchi International Sympo sium on the Theory of Condensed Matter. The symposium was held for five days from September 10 to 14, 1984 at Kashikojima, Mie, Japan. Dynamical proces ses and ordering on solid surfaces are the subjects of the symposium. About twenty participants stayed together at Shima Kanko Hotel, the symposium site, during the period. The intense and productive discussion in the bright sea s ide atmosphere of Kashi koj ima is bel i eved to have been impress i ve to all the participants. Dynamical processes on solid surfaces are the target of recent theoreti cal efforts in surface physics. Even if some of them are still in their in fant stage, important aspects begin to appear and vital concepts start to shape themselves. Some topics in the symposium were the energy transfer re lated with internal degrees of freedom of molecules, attempts to go beyond the trajectory approximati on, charge transfer and energy transfer between particles and solid surfaces, and related fundamental problems like adiaba tic potentials and electronic structures. In particular, really actively di scussed was the time-dependent Newns-Anderson model wi thout and wi th the intraatomic Coulomb interaction and sometimes with the interaction to the surface plasmons or phonons. Surface effects on the optical processes were discussed with great interest, such as the ABC-related problems of exciton polaritons and rare gas adsorbates on metal surfaces.
Book Synopsis Elementary Physicochemical Processes on Solid Surfaces by : V.P. Zhdanov
Download or read book Elementary Physicochemical Processes on Solid Surfaces written by V.P. Zhdanov and published by Springer Science & Business Media. This book was released on 1991-11-30 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . 1 . . . . . . . . Chapter 1. Vibrational Relaxation of Adsorbed Particles . . . .. . 5 1.1. General Approach to Describing Vibrational Relaxation ..... 5 1.2. Phonon Mechanism of Relaxation .................... 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation .. . . . . . . . . . .. . . 9 . 1.2.2. One-Mode Approximation .................. . .. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium ........................... 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium ........................... 14 1.2.5. Results and Discussion ....................... 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 18 . . . . . . . . . 1.3.1. Dipole Approximation ......... '.' . . . . . . . . .. . . 18 .
Book Synopsis Elementary Physicochemical Processes on Solid Surfaces by : V.P. Zhdanov
Download or read book Elementary Physicochemical Processes on Solid Surfaces written by V.P. Zhdanov and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . 1 . . . . . . . . Chapter 1. Vibrational Relaxation of Adsorbed Particles . . . .. . 5 1.1. General Approach to Describing Vibrational Relaxation ..... 5 1.2. Phonon Mechanism of Relaxation .................... 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation .. . . . . . . . . . .. . . 9 . 1.2.2. One-Mode Approximation .................. . .. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium ........................... 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium ........................... 14 1.2.5. Results and Discussion ....................... 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 18 . . . . . . . . . 1.3.1. Dipole Approximation ......... '.' . . . . . . . . .. . . 18 .
Book Synopsis Elementary Processes in Excitations and Reactions on Solid Surfaces by : Ayao Okiji
Download or read book Elementary Processes in Excitations and Reactions on Solid Surfaces written by Ayao Okiji and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Elementary Processes in Excitations and Reactions on Solid Surfaces explores the fundamental nature of dynamics on solid surfaces. Attempts are made to reveal various aspects of elementary processes in excitations and reactions on solid surfaces by recent theoretical and experimental developments of the subjects such as molecular beams interacting with surfaces, ion beam scattering, laser-induced dynamical processes, electronically induced dynamical processes, and optical properties of solid surfaces. This volume is devided into three parts. Part I is concerned mainly with the rich reaction dynamics on potential-energy surfaces. Part II is devoted to the interplay of excitations. In Part III, new and rapidly developing methods are introduced.
Book Synopsis Reactions at Solid Surfaces by : Gerhard Ertl
Download or read book Reactions at Solid Surfaces written by Gerhard Ertl and published by John Wiley & Sons. This book was released on 2010-06-17 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expanding on the ideas first presented in Gerhard Ertl's acclaimed Baker Lectures at Cornell University, Reactions at Solid Surfaces comprises an authoritative, self-contained, book-length introduction to surface reactions for both professional chemists and students alike. Outlining our present understanding of the fundamental processes underlying reactions at solid surfaces, the book provides the reader with a complete view of how chemistry works at surfaces, and how to understand and probe the dynamics of surface reactions. Comparing traditional surface probes with more modern ones, and bringing together various disciplines in a cohesive manner, Gerhard Ertl's Reactions at Solid Surfaces serves well as a primary text for graduate students in introductory surface science or chemistry, as well as a self-teaching resource for professionals in surface science, chemical engineering, or nanoscience.
Book Synopsis Electronic Processes At Solid Surfaces by : E Ilisca
Download or read book Electronic Processes At Solid Surfaces written by E Ilisca and published by World Scientific. This book was released on 1996-10-28 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of surface physics has now grown to become an exciting interdisciplinary field of research with important practical applications.The purpose of this book is to provide a guided tour of some recent advances, key research issues and approaches in electronic processes at solid surfaces.Apart from a few structural studies, selected topics have been chosen to illustrate the dynamical response of the solid surface to external probes, with the main emphasis on electron transfer phenomena.
Book Synopsis Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces by : W.A. Steele
Download or read book Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces written by W.A. Steele and published by Elsevier. This book was released on 1996-12-17 with total page 909 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems.Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.
Book Synopsis Dynamical Processes and Ordering on Solid Surfaces by : Akio Yoshimori
Download or read book Dynamical Processes and Ordering on Solid Surfaces written by Akio Yoshimori and published by Springer. This book was released on 1985 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dynamic Processes in Solids by : James E. House
Download or read book Dynamic Processes in Solids written by James E. House and published by Elsevier. This book was released on 2023-05-26 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: The results obtained from kinetic studies on reactions in solids often depend on numerous factors. Therefore, it is important for researchers to understand how both chemical factors related to composition and procedural choices may influence outcomes. Dynamic Processes in Solids provides an authoritative overview of reactions in solids and helps readers interpret the results obtained from kinetic studies. In chapters written by active researchers, the reader will learn about choosing appropriate experimental techniques and their limitations for studying various types of reactions. Beginning with an introduction to numerous aspects of rate processes in solids and experimental techniques, information is provided on rate laws, factors affecting rates, diffusion, and sintering. Subsequent chapters deal with electrical conductivity in dispersed phase polymers, thermochemical reactions for producing solid materials, reactions in coordination compounds, dynamic observations on plastic deformation, light driven phenomena in quantum materials, decomposition of perovskite photovoltaic compounds, and reaction of oxygen radicals with surfaces. This book is a practical introduction to the field for chemists and researchers whose work is directly related to dynamic changes in solids, and additionally for those in related fields whose work would be enhanced by an understanding of these types of rate processes. - Presents useful discussions of the applications of several experimental techniques - Describes approaches for synthesis of solid materials by thermochemical reactions - Presents theoretical interpretation structural dynamics and processes at the molecular level in solids - Provides information on the relationships between performance and rate processes in several types of materials related to electronic behavior
Book Synopsis Dynamics at Solid State Surfaces and Interfaces, Volume 2 by : Uwe Bovensiepen
Download or read book Dynamics at Solid State Surfaces and Interfaces, Volume 2 written by Uwe Bovensiepen and published by John Wiley & Sons. This book was released on 2012-04-16 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: This two-volume work covers ultrafast structural and electronic dynamics of elementary processes at solid surfaces and interfaces, presenting the current status of photoinduced processes. Providing valuable introductory information for newcomers to this booming field of research, it investigates concepts and experiments, femtosecond and attosecond time-resolved methods, as well as frequency domain techniques. The whole is rounded off by a look at future developments.
Book Synopsis Potential Energy Surfaces and Dynamics Calculations by : Donald Truhlar
Download or read book Potential Energy Surfaces and Dynamics Calculations written by Donald Truhlar and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 859 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume is concerned with two of the central questions of chemical dynamics. What do we know about the energies of interaction of atoms and molecules with each other and with solid surfaces? How can such interaction energies be used to understand and make quantitative predictions about dynamical processes like scattering, energy transfer, and chemical reactions? It is becoming clearly recognized that the computer is leading to rapid progress in answering these questions. The computer allows probing dynamical mechanisms in fine detail and often allows us to answer questions that cannot be addressed with current experimental techniques. As we enter the 1980's, not only are more powerful and faster computers being used, but techniques and methods have been honed to a state where exciting and reliable data are being generated on a variety of systems at an unprecedented pace. The present volume presents a collection of work that illustrates the capabilities and some of the successes of this kind of computer-assisted research. In a 1978 Chemical Society Report, Frey and Walsh pointed out that "it is extremely doubtful if a calculated energy of activation for any unimolecular decomposition can replace an experimental deter mination. " However they also recorded that they "believe[d] that some of the elaborate calculations being performed at present do suggest that we may be approaching a time when a choice between reaction mechanisms will be helped by such [computational] work.
Download or read book Dynamics written by and published by Elsevier. This book was released on 2008-10-09 with total page 1037 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume of the Handbook of Surface Science covers all aspects of the dynamics of surface processes. Two dozen world leading experts in this field address the subjects of energy exchange in gas atoms, surface collisions, the rules governing dissociative adsorption on surfaces, the formation of nanostructures on surfaces by self-assembly, and the study of surface phenomena using ultra-fast lasers. The chapters are written for both newcomers to the field as well as researchers.• Covers all aspects of the dynamics of surface processes • Provides understanding of this unique field utilizing a multitude of accurate experiments and advanced microscopic theory that allows quantum-level comparisons • Presents the concepts and tools relevant beyond surface science for catalysis, nanotechnology, biology, medicine, and materials
Book Synopsis Fundamentals of Interface and Colloid Science by : J. Lyklema
Download or read book Fundamentals of Interface and Colloid Science written by J. Lyklema and published by Elsevier. This book was released on 1995-10-17 with total page 787 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interface and colloid science is an important, though often under-valued, branch of science. It has applications and ramifications in domains as disparate as agriculture, mineral dressing, oil recovery, chemical industry, biotechnology, medical science, and many more. Proper application of interface and colloid science requires factual knowledge and insight into the many basic laws of physics and chemistry upon which it is based. Fundamentals of Interface and Colloid Science is the first book to cover this field in the depth neccessary to be a valuable reference and an excellent textbook.From the beginning to the end of the book, systems of growing complexity are treated gradually. The presentation is particularly suited to emphasize that interfaces are not autonomous phases. As a rule, interfacial properties can be varied only by changing the adjoining phases, so that the properties of these bulk phases must be understood first. The text also recognizes common principles behind a variety of phenomena, and helps the reader to understand them and to develop and improve processes. The systematic treatment of the material in the book makes this clear, and makes the text itself an important contribution to the field. - Systematic treatment of information - An excellent addition to volume I - Two chapters contributed by other experts in the field - Uses a deductive approach to increase the order of complexity - Written by a leading expert in the field - Two chapters contributed by other outstanding scientists - Uses a systematic and deductive approach - First comprehensive review of the topic
Book Synopsis Introduction To Nonadiabatic Dynamics by : Hiroki Nakamura
Download or read book Introduction To Nonadiabatic Dynamics written by Hiroki Nakamura and published by World Scientific. This book was released on 2019-09-26 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nonadiabatic transition is a highly multi-disciplinary concept and phenomenon, constituting a fundamental mechanism of state and phase changes in various dynamical processes of physics, chemistry and biology. This book is intended to be readable to a broad audience so that they can deepen their understanding of the basic concepts of both time-independent and time-dependent nonadiabatic transitions. Quantum mechanically intriguing phenomena such as complete reflection and nonadiabatic tunneling are emphasized. The Zhu-Nakamura theory that can deal with non-negligible classically forbidden transitions is explained. Furthermore, by controlling nonadiabatic transitions induced by an external field such as laser, designing chemical reaction dynamics as we desire is shown to be theoretically possible.
Book Synopsis Heterogeneous Reaction Dynamics by : S. Bernasek
Download or read book Heterogeneous Reaction Dynamics written by S. Bernasek and published by John Wiley & Sons. This book was released on 1995-10-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is an in-depth monograph covering the topic of energy transfer and reactions on solid surfaces. This topic is of great interest now because of its applications to catalysis and solid-state electronics, including the manufacture of semiconductors, integrated circuits and other solid state devices. Initially it describes what is meant by heterogenous reaction dynamics. Basically, this is the study, on a molecular level, of the elementary dynamics of energy transfer and reactions at surface. The emphasis of the book will be on well characterized solid surfaces. Energy transfer and reactions are broadly defined to include phase transitions in adsorbed layers, diffusion, the absorption process itself, and energy transfer between adsorbate and subtrate, as well as gas-surface energy transfer, catalytic and oxidative type surface reactions.