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Development Of Bamboo Derived Sorbents For Gas Phase Adsorption Of Elemental Mercury
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Book Synopsis Development of Bamboo Derived Sorbents for Gas Phase Adsorption of Elemental Mercury by : Naved Ahmed Siddiqui
Download or read book Development of Bamboo Derived Sorbents for Gas Phase Adsorption of Elemental Mercury written by Naved Ahmed Siddiqui and published by . This book was released on 2009 with total page 110 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mercury is a serious hazard which, when emitted into the atmosphere, reaches back to the earth. Coal-fired plants in the U.S. emit mercury upon the burning of coal in the particulate, oxidized and elemental state. Of these, elemental mercury is the most difficult to capture. U.S. coal-fired plants emit approximately 48 tons of mercury per year. Based on the U.S. EPA Clean Air Mercury Rule, these emissions need to be capped by 90%. This project deals with the Development of Bamboo Derived Sorbents for the capture of elemental mercury in gas phase. Results and analyses of these sorbents depict successful capture of mercury in nitrogen atmosphere. Treatments such as carbon dioxide activation and hydrochloric acid functionalization are very effective in enhancing mercury adsorption. This project acts as a stepping stone for the development of bamboo derived material.
Book Synopsis Issues in Global Environment—Pollution and Waste Management: 2013 Edition by :
Download or read book Issues in Global Environment—Pollution and Waste Management: 2013 Edition written by and published by ScholarlyEditions. This book was released on 2013-05-01 with total page 1073 pages. Available in PDF, EPUB and Kindle. Book excerpt: Issues in Global Environment—Pollution and Waste Management: 2013 Edition is a ScholarlyEditions™ book that delivers timely, authoritative, and comprehensive information about Particle and Fiber Toxicology. The editors have built Issues in Global Environment—Pollution and Waste Management: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Particle and Fiber Toxicology in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Issues in Global Environment—Pollution and Waste Management: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Book Synopsis Advanced Adsorbents for Capture of Vapor-phase Mercury and Other Toxic Components from Flue Gas by : Juan He
Download or read book Advanced Adsorbents for Capture of Vapor-phase Mercury and Other Toxic Components from Flue Gas written by Juan He and published by . This book was released on 2013 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: During coal combustion, mercury and arsenic are volatized and are present in multiple forms in the gas phase; similarly, the formation of nitrogen oxides in flue gas depends on nitrogen content of the coal and oxygen available to react with nitrogen. New approaches for cost-effective control of mercury and other pollutants are necessary. In this work, a group of room temperature ionic liquid coated nanostructured chelating adsorbents was developed and used for gas-phase mercury and arsenic adsorption; the simultaneous removal of mercury and nitrogen oxide using ceria-modified manganese oxide/titania materials was investigated. Three thermally robust adsorbents, 25 wt% [bmim]Cl coated-MPTS-Si, 25 wt% [bmim]Cl-MPTS-MCF and 25 wt% [bmim]Cl-Ambersep[superscript TM] GT74 were synthesized and demonstrated to be effective adsorbents for simultaneous capture of oxidized and elemental mercury at 160°C. Mercury from vapor phase dissolves in the [bmim]Cl ionic liquid layer;and subsequently bonds to the chelating ligands of MPTS or directly coordinates with the sulfur-containing groups from Ambersep[superscript TM]GT74 resin. In fixed-bed adsorption experiments, the 25 wt% [bmim]Cl-MPTS-Si exhibited the largest mercury (Hg2 and Hg0) capacity in an inert atmosphere. A mathematical model was developed to describe mercury removal based on the experimental data measured at laboratory-scale. To synthesize adsorbents for both mercury and arsenic capture, both [bmim]Cl and an amino acid-based RTIL, [TBP][Tau], were supported on a silica gel with high surface area and accessible mesopores. In both fixed-bed and batch adsorption modes, all of the RTIL-coated silica adsorbents can effectively remove Hg0 and As(III) simultaneously, and exhibited high As(III) capacities. Because of the high solubility of CO2 in the [TBP][Tau] RTIL, the presence of CO2 caused a negative effect on the Hg0 and As(III) adsorption performance of [TBP][Tau]-Si. High surface area ceria-titania materials are used as supports for manganese oxide for both warm-gas mercury capture and low temperature selective catalytic reduction. Remarkably, these materials exhibit high Hg0 adsorption capacities and excellent NO removal performance both in single-component tests and in combined NO and Hg0 removal experiments at 175°C. For the Hg0 adsorption, MnOx/CeO2-TiO2 adsorbents had large Hg0 capacities up to 37 mg g−1. SO2 inhibited Hg0 adsorption on the surface of MnOx, but the CeO2-TiO2 support retained most of its Hg0 capacity in the presence of 100 ppm SO2 The simultaneous capture of Hg0 and Hg2 at 175°C was observed using CeO2-TiO2 support. Both the NO adsorption and co-adsorption of NO + CO can be found over the surface of MnOx/CeO2-TiO2 materials. The results of XPS analysis suggest that the presence of lattice oxygen play important role on the mercury and NO adsorption, with great formation of HgO and nitrate species; in the presence of CO in the feed gas, mercury adsorption doesn't inhibit the SCR activity of NO. In summary, the nanostructured, RTILs coated chelating adsorbents and manganese supported on ceria-titania oxide materials were successfully developed and studied for removal of gas-phase mercury and other toxic components. The experimental results suggest these novel adsorbents could be technically feasible for multi-pollutants control in coal combustion.
Book Synopsis Development and Evaluation of Low-cost Sorbents for Removal of Mercury Emissions from Coal Combustion Flue Gas by :
Download or read book Development and Evaluation of Low-cost Sorbents for Removal of Mercury Emissions from Coal Combustion Flue Gas written by and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: "Determining how physical and chemical properties of sorbents affect vapor-phase mercury adsorption has led to potential approached for tailoring the properties of sorbents for more effective mercury removal. ... Objectives: to determine how physical and chemical properties of sorbents affect mercury adsoprtion; to develop more cost-effective sorbents"--P. v.
Book Synopsis Novel Nano-structured Sorbents for Elemental and Oxidized Mercury Removal from Flue Gas by : Lei Ji
Download or read book Novel Nano-structured Sorbents for Elemental and Oxidized Mercury Removal from Flue Gas written by Lei Ji and published by . This book was released on 2008 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermally robust chelating adsorbents, 3-mercaptopropyltrimethoxysilane silica (MPTS-silica) and 3-aminopropyltiethoxysilane 2-mercaptobenzothialzole silica (APTS-MBT-silica), were proven to be very effective in capture HgCl2 from simulated flue gas at elevated temperatures in a fixed-bed mode. For MPTS-silica, a minimum of 58 mg/g HgCl2 capacity was observed. Pore size of the silica substrate does not have significant effect while particle size was found to have a significant effect on mercury capture; this effect was believed to be due to an enhanced channeling effect for the larger particle size adsorbent. A new approach for simultaneous removal of elemental and oxidized mercury from flue gas was successfully developed by using a room temperature ionic liquid (RTIL) coating layer. Six RTILs were synthesized and tested for their potential of elemental and oxidized mercury capture. These RTIL coating layers are all thermally stable above 160°C and the coating of these RTIL does not have any negative effect on the thermal stability of the chelating ligands. 1-butyl-3-methyl-imidazolium chloride ([bmim]Cl) was identified to be the most promising RTIL for simultaneous elemental and oxidized mercury removal from flue gas. 25 wt% [bmim]Cl coated MPTS-silica showed a 10 mg/g saturated elemental mercury capacity and a minimum of 38 mg/g oxidized mercury capacity in a fixed-bed mode. A low temperature selective catalytic reduction (SCR) catalyst, manganese oxide supported on titania, was tested as a sorbent for elemental mercury capture from flue gas at high temperatures. It was shown that this material showed high mercury capacity and remained active for mercury capture even after use for NOx reduction. Water vapor and manganese loading do not have a significant effect on mercury capture. However, SO2 has a strong negative effect on mercury removal process. Bed temperature was found to have a significant effect on mercury capture process. HgO formed during the mercury adsorption process by this material and it was believed that the mercury adsorption follows Mars-Maessen mechanism.
Book Synopsis Biochar for Environmental Management by : Johannes Lehmann
Download or read book Biochar for Environmental Management written by Johannes Lehmann and published by Routledge. This book was released on 2012-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar is the carbon-rich product when biomass (such as wood, manure or crop residues) is heated in a closed container with little or no available air. It can be used to improve agriculture and the environment in several ways, and its stability in soil and superior nutrient-retention properties make it an ideal soil amendment to increase crop yields. In addition to this, biochar sequestration, in combination with sustainable biomass production, can be carbon-negative and therefore used to actively remove carbon dioxide from the atmosphere, with major implications for mitigation of climate change. Biochar production can also be combined with bioenergy production through the use of the gases that are given off in the pyrolysis process. This book is the first to synthesize the expanding research literature on this topic. The book's interdisciplinary approach, which covers engineering, environmental sciences, agricultural sciences, economics and policy, is a vital tool at this stage of biochar technology development. This comprehensive overview of current knowledge will be of interest to advanced students, researchers and professionals in a wide range of disciplines.
Book Synopsis Pyrolysis of Biomass by : Shurong Wang
Download or read book Pyrolysis of Biomass written by Shurong Wang and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-12-05 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the development of societies fossil energy is no longer the only energy resource, and increasing attention had been paid to alternative energy. Biomass is considered to be one of the alternatives due to efficiency and low cost. This book presents biomass pyrolysis behavior for three main components: Cellulose, Hemicellulose and Lignin, and discusses the influence of mineral salts , zeolite catalysts and metal oxide on their pyrolysis.
Book Synopsis Biosorbents for Metal Ions by : D A John Wase
Download or read book Biosorbents for Metal Ions written by D A John Wase and published by CRC Press. This book was released on 1997-08-05 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metals can be dispersed, both naturally and by man's activities, into any of the Earth's elements - soil, water or air. Biological techniques for removing metal pollutants from soil, air or water are now attracting great interest, both because they are seen as more environmentally friendly than chemical treatments, and because, in some cases at lea
Book Synopsis Inorganic Pollutants in Water by : Pooja Devi
Download or read book Inorganic Pollutants in Water written by Pooja Devi and published by Elsevier. This book was released on 2020-03-18 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Pollutants in Water provides a clear understanding of inorganic pollutants and the challenges they cause in aquatic environments. The book explores the point of source, how they enter water, the effects they have, and their eventual detection and removal. Through a series of case studies, the authors explore the success of the detection and removal techniques they have developed. Users will find this to be a single platform of information on inorganic pollutants that is ideal for researchers, engineers and technologists working in the fields of environmental science, environmental engineering and chemical engineering/ sustainability. Through this text, the authors introduce new researchers to the problem of inorganic contaminants in water, while also presenting the current state-of-the-art in terms of research and technologies to tackle this problem. Presents existing solutions to pollution problems, along with their challenges Includes case studies that detail success stories, challenges and the implementation of these tools Provides solutions that are both economically and ecologically sustainable
Book Synopsis Applications of Biochar for Environmental Safety by : Ahmed Abdelhafez
Download or read book Applications of Biochar for Environmental Safety written by Ahmed Abdelhafez and published by BoD – Books on Demand. This book was released on 2020-07-22 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar is a carbon-rich material produced from the pyrolysis of organic materials from agricultural and forestry biomass at a relatively low temperature in the absence of oxygen. As such, it has potential for solving many agricultural and environmental problems.This book is divided into five sections: “Introduction,” “Production and Legislation of Biochar,” “Applications of Biochar for Soil Fertility Improvement,” “Role of Biochar for Soil Remediation and Ameliorating Salinity Effects” and “Applications of Biochar for Water Treatment.” Chapters address topics such as the pros and cons of biochar, its production, and its role in remediating and treating contaminated soils and water.
Book Synopsis Coal Gasification and Its Applications by : David A. Bell
Download or read book Coal Gasification and Its Applications written by David A. Bell and published by William Andrew. This book was released on 2010-12-08 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Skyrocketing energy costs have spurred renewed interest in coal gasification. Currently available information on this subject needs to be updated, however, and focused on specific coals and end products. For example, carbon capture and sequestration, previously given little attention, now has a prominent role in coal conversion processes.This book approaches coal gasification and related technologies from a process engineering point of view, with topics chosen to aid the process engineer who is interested in a complete, coal-to-products system. It provides a perspective for engineers and scientists who analyze and improve components of coal conversion processes.The first topic describes the nature and availability of coal. Next, the fundamentals of gasification are described, followed by a description of gasification technologies and gas cleaning processes. The conversion of syngas to electricity, fuels and chemicals is then discussed. Finally, process economics are covered. Emphasis is given to the selection of gasification technology based on the type of coal fed to the gasifier and desired end product: E.g., lower temperature gasifiers produce substantial quantities of methane, which is undesirable in an ammonia synthesis feed. This book also reviews gasification kinetics which is informed by recent papers and process design studies by the US Department of Energy and other groups, and also largely ignored by other gasification books.• Approaches coal gasification and related technologies from a process engineering point of view, providing a perspective for engineers and scientists who analyze and improve components of coal conversion processes • Describes the fundamentals of gasification, gasification technologies, and gas cleaning processes • Emphasizes the importance of the coal types fed to the gasifier and desired end products • Covers gasification kinetics, which was largely ignored by other gasification books Provides a perspective for engineers and scientists who analyze and improve components of the coal conversion processes Describes the fundamentals of gasification, gasification technologies, and gas cleaning processes Covers gasification kinetics, which was largely ignored by other gasification books
Book Synopsis Biochar from Biomass and Waste by : Yong Sik Ok
Download or read book Biochar from Biomass and Waste written by Yong Sik Ok and published by Elsevier. This book was released on 2018-11-02 with total page 463 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar from Biomass and Waste: Fundamentals and Applications provides the fundamentals of biochar, such as its basic concepts, production technology and characterization methods, also including comprehensive examples for readers. This book includes information on state-of-art biochar application technologies in the fields of agriculture, energy and environmental sciences with step-by-step case studies. Biochar has received worldwide interests in the past decade because it encompasses high priority research areas, including bioenergy production, global warming mitigation and sustainable agriculture. Offers comprehensive coverage of biochar production, characterization and modification methods Provides global case studies covering a wide range of application fields, including environmental, agricultural, syngas and bio-oil Covers the sustainability and future of biochar
Book Synopsis Biochar As A Renewable-based Material: With Applications In Agriculture, The Environment And Energy by : Joan J Manya
Download or read book Biochar As A Renewable-based Material: With Applications In Agriculture, The Environment And Energy written by Joan J Manya and published by World Scientific. This book was released on 2020-08-14 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biochar and its implementation as a renewable-based material is one of the topics on which the research community has focused the greatest energy in the last twenty years. This book provides readers with a scientific and technological overview of biochar, including new technologies for biochar production, new environmental and agronomic applications (e.g. biochar as growing media component or biochar application for mine land reclamation) and some emerging biochar applications in different fields (e.g. energy storage and catalysis). A special emphasis is placed on analyzing the links between the different stages of the value chain, underpinning the economic viability of biochar systems.Biochar as a Renewable-Based Material: With Applications in Agriculture, the Environment and Energy is designed as a textbook for graduate and postgraduate courses as well as a handbook for early-stage scientists, policy makers and potential technology customers. The book is written by internationally recognized scientists with a variety of complementary backgrounds.
Book Synopsis Green Adsorbents by : George Z. Kyzas
Download or read book Green Adsorbents written by George Z. Kyzas and published by Bentham Science Publishers. This book was released on 2015-12-01 with total page 127 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption technology is a promising avenue for wastewater treatment. Numerous adsorbent materials are presently synthesized. Green or environmental friendly adsorbents are derived from plants and agricultural crop sources, giving them a very low production cost when compared to synthetic polymers. This monograph explains the basic principles of green adsorption technology, their production processes and strategies to remove different categories of environmental pollutants (dyes, heavy metals and phenols/pesticides). The book explains details in terms of features such as adsorption capacity, physico-chemical kinetics and reuse potential. A summary of the economics and future prospect for green adsorption technology is also given. This text is a handy reference for environmental chemistry students, researchers and policy makers.
Book Synopsis Novel Bioderived Composites from Wastes by : Andrea Petrella
Download or read book Novel Bioderived Composites from Wastes written by Andrea Petrella and published by MDPI. This book was released on 2020-11-20 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: The recovery of solid wastes for the preparation of innovative composite materials not only represents an economic advantage, but also offers an ecological opportunity for the utilization of by-products which would otherwise be landfilled. Specifically, the reuse and recycling of waste lead to important savings of raw materials and energy, since these by-products, generally deriv from agricultural or industrial activities, are abundant in nature. Moreover, a reduction of the environmental and related sanitary impacts can be also achieved. For this reason, a recycling operation is fundamental for the improvement of the environmental sustainability, because these secondary raw materials become a resource that can be easily reused without the modification of the peculiar characteristics, in order to obtain new and performing composites, with a low specific weight, high durability, and long life cycle.
Book Synopsis Activated Carbon Surfaces in Environmental Remediation by : Teresa J. Bandosz
Download or read book Activated Carbon Surfaces in Environmental Remediation written by Teresa J. Bandosz and published by Elsevier. This book was released on 2006-02-27 with total page 587 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activated Carbon Surfaces in Environmental Remediation provides a comprehensive summary of the environmental applications of activated carbons. In order to understand the removal of contaminants and pollutants on activated carbons, the theoretical bases of adsorption phenomena are discussed. The effects of pore structure and surface chemistry are also addressed from both science and engineering perspectives. Each chapter provides examples of real applications with an emphasis on the role of the carbon surface in adsorption or reactive adsorption. The practical aspects addressed in this book cover the broad spectrum of applications from air and water cleaning and energy storage to warfare gas removal and biomedical applications. This book can serve as a handbook or reference book for graduate students, researchers and practitioners with an interest in filtration, water treatment, adsorbents and air cleaning, in addition to environmental policies and regulations. Addresses fundamental carbon science and how it relates to applications of carbon surfaces Describes the broad spectrum of activated carbon applications in environmental remediation Serves as a handbook or reference book for graduate students, researchers and practitioners in the field
Book Synopsis Biosorption of Heavy Metals by : Bohumil Volesky
Download or read book Biosorption of Heavy Metals written by Bohumil Volesky and published by CRC Press. This book was released on 1990-08-15 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: This state-of-the-art volume represents the first comprehensively written book which focuses on the new field of biosorption. This fascinating work conveys essential fundamental information and outlines the perspectives of biosorption. It summarizes the metal-sorbing properties of nonliving bacterial, fungal, and algal biomass, plus highlights relevant metal-binding mechanisms. This volume also discusses the aspects of obtaining and processing microbial biomass and metal-chelating chemicals into industrially applicable biosorbent products. Microbiologists, chemists, and engineers with an interest in new technological and scientific horizons will find this reference indispensable.
