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Development Of A Palladium Based Membrane Reactor System For Production Of Ultra Pure Hydrogen From Liquefied Petroleum Gas
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Book Synopsis Development of a Palladium Based Membrane Reactor System for Production of Ultra-pure Hydrogen from Liquefied Petroleum Gas by : Lungela Ethel Kula
Download or read book Development of a Palladium Based Membrane Reactor System for Production of Ultra-pure Hydrogen from Liquefied Petroleum Gas written by Lungela Ethel Kula and published by . This book was released on 2017 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications by : A Doukelis
Download or read book Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications written by A Doukelis and published by Elsevier. This book was released on 2014-10-20 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. Review of manufacture and design issues for palladium membranes Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production Examples of the technology in operation
Book Synopsis Membrane Reactors for Hydrogen Production Processes by : Marcello De Falco
Download or read book Membrane Reactors for Hydrogen Production Processes written by Marcello De Falco and published by Springer Science & Business Media. This book was released on 2011-03-25 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.
Book Synopsis High-Performance Palladium Based Membrane for Hydrogen Separation and Purification by :
Download or read book High-Performance Palladium Based Membrane for Hydrogen Separation and Purification written by and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The mission of the DOE's Fuel Cell Technologies'Hydrogen Fuels R & D effort is to research, develop, and validate technologies for producing, storing, and delivering hydrogen in an efficient, clean, safe, reliable, and affordable manner. A key program technical milestone for hydrogen technology readiness is to produce hydrogen from diverse, domestic resources at $2.00-$3.00 per gallon of gasoline equivalent (gge) delivered, untaxed. Low-cost, high-temperature hydrogen separation membranes represent a key enabling technology for small-scale distributed hydrogen production units. Availability of such membranes with high selectivity and high permeability for hydrogen will allow their integration with hydrocarbon reforming and water gas shift reactions, potentially reducing the cost of hydrogen produced. Pd-metal-based dense membranes are known for their excellent hydrogen selectivity and permeability characteristics, however, utilization of these membranes has so far been limited to small scale niche markets for hydrogen purification primarily due to the relatively high cost of Pd-alloy tubes compared to pressure swing adsorption (PSA) units. This project was aimed at development of thin-film Pd-alloy membranes deposited on Pall Corporation's DOE-based AccuSep® porous metal tube substrates to form a composite hydrogen separation membrane for these applications. Pall's composite membrane development addressed the typical limitations of composite structures by developing robust membranes capable of withstanding thermal and mechanical stresses resulting from high temperature (400C), high pressure (400 psi steam methane reformer and 1000 psi coal) operations and thermal cycling involved in conventional hydrogen production. In addition, the Pd-alloy membrane composition was optimized to be able to offer the most stability in the typical synthesis gas environments produced by reforming of natural gas and bio-derived liquid fuels (BILI) validating the technical effectiveness and economic feasibility of the technology demonstrated. Results from this research added technology and product design information that offers the potential to significantly advance the commercial viability of hydrogen production.
Book Synopsis On-board Hydrogen Production from Natural Gas Via a Metallic Pd-based Membrane Reactor by : Bryce Anzelmo
Download or read book On-board Hydrogen Production from Natural Gas Via a Metallic Pd-based Membrane Reactor written by Bryce Anzelmo and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This work describes the application of palladium-based composite membrane reactors (MRs) for performing steam methane reforming (SMR) and natural gas steam reforming reactions to produce a high-purity hydrogen stream for CO2 capture from the transportation sector. In particular, the effect of different operating conditions on the performance of several MRs has been investigated. Moreover, thin pure palladium and palladium-gold alloy membranes have been synthesized via electroless plating and housed in the membrane module for reaction and permeation testing. In particular, the SMR reaction across porous stainless steel-supported Pd membranes has been investigated with a focus on low temperature and pressure conditions to showcase the ability of the MR to obtain high conversions even at mild conditions. The feed composition ratio, i.e., H2O/CH4, was kept above the stoichiometric limit to enhance conversion, while a permeate sweep gas was used to promote the permeation of hydrogen through the membrane. This application of the Pd-based MR resulted in high methane conversion (84%) and hydrogen recovery (82%) with a pure hydrogen stream obtained from the permeate side at temperatures as low as 400 °C. Stable methane conversions and hydrogen permeation rates were obtained for> 700 reaction hours. Using a Pd-Au composite MR, further reaction testing took place with a real natural gas feed at 450 °C and 300 kPa. This MR operated under a SMR reaction continuously for> 250 hours without a decrease in performance, highlighting the long-term stability of the MR to produce pure hydrogen for long periods of time. More specifically, the conversion of higher hydrocarbons, e.g., propane, ethane, and butane, within the reactor were> 85% throughout the experimental tests. Using a membrane module comprised of a dense Pd77Ag23 membrane, hydrogen permeation decreased when exposed to H2S. This decrease in hydrogen flux was temporary and complete recovery was realized with 200 ppm and 40 ppm H2S exposure tests showing no long-term effects on the membrane. These results allow for an alternative use of pure Pd membranes, which are irreversibly poisoned by H2S.
Book Synopsis Membranes for Membrane Reactors by : Angelo Basile
Download or read book Membranes for Membrane Reactors written by Angelo Basile and published by John Wiley & Sons. This book was released on 2010-12-20 with total page 661 pages. Available in PDF, EPUB and Kindle. Book excerpt: A membrane reactor is a device for simultaneously performing a reaction and a membrane-based separation in the same physical device. Therefore, the membrane not only plays the role of a separator, but also takes place in the reaction itself. This text covers, in detail, the preparation and characterisation of all types of membranes used in membranes reactors. Each membrane synthesis process used by membranologists is explained by well known scientists in their specific research field. The book opens with an exhaustive review and introduction to membrane reactors, introducing the recent advances in this field. The following chapters concern the preparation of both organic and inorganic, and in both cases, a deep analysis of all the techniques used to prepare membrane are presented and discussed. A brief historical introduction for each technique is also included, followed by a complete description of the technique as well as the main results presented in the international specialized literature. In order to give to the reader a summary look to the overall work, a conclusive chapter is included for collecting all the information presented in the previous chapters. Key features: Fills a gap in the market for a scientific book describing the preparation and characterization of all the kind of membranes used in membrane reactors Discusses an important topic - there is increasing emphasis on membranes in general, due to their use as energy efficient separation tools and the ‘green’ chemistry opportunities they offer Includes a review about membrane reactors, several chapters concerning the preparation organic, inorganic, dense, porous, and composite membranes and a conclusion with a comparison among the different membrane preparation techniques
Book Synopsis Advances in Membrane Technologies by : Amira Abdelrasoul
Download or read book Advances in Membrane Technologies written by Amira Abdelrasoul and published by BoD – Books on Demand. This book was released on 2020-03-04 with total page 226 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane technologies are currently the most effective and sustainable methods utilized in diversified water filtration, wastewater treatment, as well as industrial and sustainable energy applications. This book covers essential subsections of membrane separation and bioseparation processes from the perspectives of technical innovation, novelty, and sustainability. The book offers a comprehensive overview of the latest improvements and concerns with respect to membrane fouling remediation techniques, issues of bioincompatibility for biomedical applications, and various subareas of membrane separation processes, which will be an efficient resource for engineers.
Book Synopsis Pure Hydrogen Production from Gasoline Reforming Using a Palladium Membrane Reactor by : Stephen A. Birdsell
Download or read book Pure Hydrogen Production from Gasoline Reforming Using a Palladium Membrane Reactor written by Stephen A. Birdsell and published by . This book was released on 1998 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Palladium Composite Membranes for Hydrogen Production and Separation by : Samhun Yun
Download or read book Palladium Composite Membranes for Hydrogen Production and Separation written by Samhun Yun and published by LAP Lambert Academic Publishing. This book was released on 2012-04 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, we developed a new preparation technique for palladium composite membranes which results in an ultra-thin and defect-free selective layer with outstanding performance properties and long life. In the method, a palladium precursor and a reducing agent on opposite sides of a substrate of porous alumina hollow fibers were placed and used an electric field to cause migration of metal ions to the outer surface where they are reduced to form seeds at high concentration in a narrow spatial region. The ethanol steam reforming was conducted in a membrane reactor with the Pd membrane and the performance of this reactor was compared with results from a packed bed reactor under identical conditions. For all conditions studied, enhancement of ethanol conversion and hydrogen yield were observed in the membrane reactor compared to the packed bed reactor.
Book Synopsis SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS. by :
Download or read book SEPARATION OF HYDROGEN AND CARBON DIOXIDE USING A NOVEL MEMBRANE REACTOR IN ADVANCED FOSSIL ENERGY CONVERSION PROCESS. written by and published by . This book was released on 2005 with total page 87 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic membrane reactors offer the possibility of combining reaction and separation in a single operation at high temperatures to overcome the equilibrium limitations experienced in conventional reactor configurations. Such attractive features can be advantageously utilized in a number of potential commercial opportunities, which include dehydrogenation, hydrogenation, oxidative dehydrogenation, oxidation and catalytic decomposition reactions. However, to be cost effective, significant technological advances and improvements will be required to solve several key issues which include: (a) permselective thin solid film, (b) thermal, chemical and mechanical stability of the film at high temperatures, and (c) reactor engineering and module development in relation to the development of effective seals at high temperature and high pressure. In this project, we are working on the development and application of palladium and palladium-silver alloy thin-film composite membranes in membrane reactor-separator configuration for simultaneous production and separation of hydrogen and carbon dioxide at high temperature. From our research on Pd-composite membrane, we have demonstrated that the new membrane has significantly higher hydrogen flux with very high perm-selectivity than any of the membranes commercially available. The steam reforming of methane by equilibrium shift in Pd-composite membrane reactor is being studied to demonstrate the potential application of this new development. A two-dimensional, pseudo-homogeneous membrane-reactor model was developed to investigate the steam-methane reforming (SMR) reactions in a Pd-based membrane reactor. Radial diffusion was taken into consideration to account for the concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system. The equations were solved by finite difference method. The solution of the model equations is complicated by the coupled reactions. At the inlet, if there is no hydrogen, rate expressions become singular. To overcome this problem, the first element of the reactor was treated as a continuous stirred tank reactor (CSTR). Several alternative numerical schemes were implemented in the solution algorithm to get a converged, stable solution. The model was also capable of handling steam-methane reforming reactions under non-membrane condition and equilibrium reaction conversions. Some of the numerical results were presented in the previous report. To test the membrane reactor model, we fabricated Pd-stainless steel membranes in tubular configuration using electroless plating method coupled with osmotic pressure. Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray (EDX) were used to characterize the fabricated Pd-film composite membranes. Gas-permeation tests were performed to measure the permeability of hydrogen, nitrogen and helium using pure gas. The membranes showed excellent perm-selectivity for hydrogen. This makes the Pd-composite membrane attractive for selective separation and recovery of H2 from mixed gases at elevated temperature.
Book Synopsis PEM Water Electrolysis by : Dmitri Bessarabov
Download or read book PEM Water Electrolysis written by Dmitri Bessarabov and published by Academic Press. This book was released on 2018-08-04 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: PEM Water Electrolysis, a volume in the Hydrogen Energy and Fuel Cell Primers series presents the most recent advances in the field. It brings together information that has thus far been scattered in many different sources under one single title, making it a useful reference for industry professionals, researchers and graduate students. Volumes One and Two allow readers to identify technology gaps for commercially viable PEM electrolysis systems for energy applications and examine the fundamentals of PEM electrolysis and selected research topics that are top of mind for the academic and industry community, such as gas cross-over and AST protocols. The book lays the foundation for the exploration of the current industrial trends for PEM electrolysis, such as power to gas application and a strong focus on the current trends in the application of PEM electrolysis associated with energy storage. Presents the fundamentals and most current knowledge in proton exchange membrane water electrolyzers Explores the technology gaps and challenges for commercial deployment of PEM water electrolysis technologies Includes unconventional systems, such as ozone generators Brings together information from many different sources under one single title, making it a useful reference for industry professionals, researchers and graduate students alike
Book Synopsis Membrane Technologies for Biohydrogen Production and Purification by : Angelo Basile
Download or read book Membrane Technologies for Biohydrogen Production and Purification written by Angelo Basile and published by Elsevier. This book was released on 2025-03-01 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane Technologies for Biohydrogen Production and Purification: Current Trends and Future Developments in Bio-Membranes focuses on the introduction, analysis, and application of membrane technologies for biohydrogen production, purification, storage, and transport. The book provides comprehensive coverage of emerging membrane-based technologies for the production and purification of biohydrogen by integrated engineering approaches with a special focus on novel membrane-based techniques for maximizing biohydrogen yields. It details recent developments in materials, design, and engineering aspects of membranes-assisted biohydrogen technology, illustrating their advantages over conventional systems, improved performance, and industry potential. The book sheds light and gives a broad, but very detailed, view from the point of view of scientists, researchers, students, and industrial engineers working in the field of biohydrogen and its technology transfer from laboratory to industry. It also includes an exclusive chapter on case studies of pilot-scale demonstrations of membrane-assisted biohydrogen production and purification, assuring the industrial potential of the book's topic. This makes it a key reference for experts and R&D managers interested in the industrial development of biohydrogen production as well as academic researchers and postgraduate students working in the wider areas of membrane technology and biohydrogen technology. Emphasizes significance and impacts of deploying bio-hydrogen at an industrial scale Discusses in detail different membrane-based technologies for bio-hydrogen production Resumes advanced 2D materials and integrated membrane systems for simultaneous biohydrogen production and purification Reviews membrane technologies for biohydrogen storage and transportation Highlights prospective pilot scale studies of membranes-assisted biohydrogen technology showcasing their industrial potential
Book Synopsis The Development of Improved Electroless Plating in Fabricating Pd-based Membrane and Membrane Reactor Application for Hydrogen Separation by : Mohammad A. Islam
Download or read book The Development of Improved Electroless Plating in Fabricating Pd-based Membrane and Membrane Reactor Application for Hydrogen Separation written by Mohammad A. Islam and published by . This book was released on 2008 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt: Studies the fabrication of palladium (Pd)-film membranes on microporous stainless steel substrates (MPSS) using the electroless plating method. Investigates the application of the Pd-MPSS membrane in membrane-reactor configurations for simultaneous production and separation of hydrogen using the steam methanol reforming (SMR) reaction. Validates the membrane reactor work with mathematical modeling.
Book Synopsis Hydrogen Production Technologies by : Mehmet Sankir
Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.
Book Synopsis Model Development and Validation of Palladium-based Membranes for Hydrogen Separation in Pem Fuel Cell Systems by : Atul Bhargav
Download or read book Model Development and Validation of Palladium-based Membranes for Hydrogen Separation in Pem Fuel Cell Systems written by Atul Bhargav and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Membrane Reactor Technology for Ultrapure Hydrogen Production by : Charudatta Subhash Patil
Download or read book Membrane Reactor Technology for Ultrapure Hydrogen Production written by Charudatta Subhash Patil and published by . This book was released on 2005 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Membrane Reactors for Hydrogen Production Processes by : Marcello De Falco
Download or read book Membrane Reactors for Hydrogen Production Processes written by Marcello De Falco and published by Springer. This book was released on 2011-04-08 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.
