Crossed Molecular Beam Study of the Reactions of Oxygen and Fluorine Atoms

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Total Pages : 82 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Crossed Molecular Beam Study of the Reactions of Oxygen and Fluorine Atoms by : Yuan T. Lee

Download or read book Crossed Molecular Beam Study of the Reactions of Oxygen and Fluorine Atoms written by Yuan T. Lee and published by . This book was released on 1978 with total page 82 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rapid developments in the study of oxygen reaction chemistry occurred as it is succeeded in obtaining an O(1D) beam source and commenced investigating the dynamics of several important reactions of O(3P) and O(1D). In the reaction of O(3P) with C6H6 and C6D6, two competing channels, one producing a stabilized addition complex and the other forming radical products C6H50 + H has been identified. Studies of the effects of collision energy and of deuteration were used to clarify the reaction mechanism. The reaction of O(3P) with another aromatic hydrocarbon toluene, results in competition between two substitution channels, loss of H atom and loss of CH3. In contrast to the 0 + C6H6 reaction, no stabilized oxygen-toluene adduct was observed.

Crossed Molecular Beam Study of the Reactions of Oxygen Atoms and Free Radicals

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ISBN 13 :
Total Pages : 11 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Crossed Molecular Beam Study of the Reactions of Oxygen Atoms and Free Radicals by : Yuan Tseh Lee

Download or read book Crossed Molecular Beam Study of the Reactions of Oxygen Atoms and Free Radicals written by Yuan Tseh Lee and published by . This book was released on 1975 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The development of rare gas seeded fluorine atom beam source and reactions studied by this new source are main subject of this brief final report. F+CH3I to IF + CH3 reaction has been studied.

Crossed Molecular Beam Studies of the Reactions of Oxygen and Fluorine Atoms

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ISBN 13 :
Total Pages : 83 pages
Book Rating : 4.:/5 (227 download)

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Book Synopsis Crossed Molecular Beam Studies of the Reactions of Oxygen and Fluorine Atoms by : Y. T. Lee

Download or read book Crossed Molecular Beam Studies of the Reactions of Oxygen and Fluorine Atoms written by Y. T. Lee and published by . This book was released on 1985 with total page 83 pages. Available in PDF, EPUB and Kindle. Book excerpt: This annual report describes the primary photodissociation of acetylene (C2H2) and bromoiodomethane (CH2BrI) using a new molecular beam photofragmentation translational spectrometer. The new third generation molecular beam photofragmentation translational spectrometer constructed during the past year is described in detail. This apparatus incorporates many new ideas and allows us to study some of the primary dissociation processes of polyatomic molecules which were not possible in the past. The dissociation of Ch2BrI at 248 and 193 nm is extremely interesting. The competition between C-I and CC-Br bond rupture is the key question, but dissociations at 193 nm also produces IBr products. Secondary photodissociations of primary products were also found to be important. These two systems are carried out partly for the purpose of evaluating the performance of the new molecular beam photofragmentation apparatus. The results clearly show that the performance of the apparatus is as good as our original expectation and that it should be capable of handling molecules with very low vapor pressures; studies of these molecules, such as the nitroamines, are planned. Additional keywords: Unimolecular decay photochemistry; rocket fuels; energetic materials; polyatomic molecules; Naval Research. (Author).

Crossed Molecular Beam Studies of Atmospheric Chemical Reaction Dynamics

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Total Pages : 466 pages
Book Rating : 4.:/5 (33 download)

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Book Synopsis Crossed Molecular Beam Studies of Atmospheric Chemical Reaction Dynamics by : Jingsong Zhang

Download or read book Crossed Molecular Beam Studies of Atmospheric Chemical Reaction Dynamics written by Jingsong Zhang and published by . This book was released on 1993 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics. [Angular and Velocity Distributions].

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Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics. [Angular and Velocity Distributions]. by :

Download or read book Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics. [Angular and Velocity Distributions]. written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of seven radical-molecule reactions using the crossed molecular beam technique with supersonic nozzle beams is reported. Product angular and velocity distributions were obtained and compared with statistical calculations in order to identify dynamical features of the reactions. In the reaction of chlorine and fluorine atoms with vinyl bromide, the product energy distributions are found to deviate from predictions of the statistical model. A similar effect is observed in the reaction of chlorine atoms with 1, 2 and 3-bromopropene. The reaction of oxygen atoms with ICl and CF3I has been used to obtain an improved value of the IO bond energy, 55.0 +- 2.0 kcal mol−1. In all reactions studied, the product energy and angular distributions are found to be coupled, and this is attributed to a kinematic effect of the conservation of angular momentum.

Crossed Molecular Beam Studies of Ground State Oxygen Atom Reactions

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ISBN 13 :
Total Pages : 126 pages
Book Rating : 4.:/5 (644 download)

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Book Synopsis Crossed Molecular Beam Studies of Ground State Oxygen Atom Reactions by : Martin Philip Hall

Download or read book Crossed Molecular Beam Studies of Ground State Oxygen Atom Reactions written by Martin Philip Hall and published by . This book was released on 1997 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Crossed Molecular Beam Study on the Reaction Dynamics of Fluorine Molecule with Propene

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ISBN 13 :
Total Pages : 59 pages
Book Rating : 4.:/5 (317 download)

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Book Synopsis Crossed Molecular Beam Study on the Reaction Dynamics of Fluorine Molecule with Propene by : 方靜雯

Download or read book Crossed Molecular Beam Study on the Reaction Dynamics of Fluorine Molecule with Propene written by 方靜雯 and published by . This book was released on 2008 with total page 59 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics

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ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.:/5 (35 download)

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Book Synopsis Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics by : Richard James Buss

Download or read book Crossed Molecular Beam Studies of Unimolecular Reaction Dynamics written by Richard James Buss and published by . This book was released on 1979 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Molecular Beam Studies of Oxygen Atom Reactions with Unsaturated Hydrocarbons

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Total Pages : 628 pages
Book Rating : 4.:/5 (7 download)

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Book Synopsis Molecular Beam Studies of Oxygen Atom Reactions with Unsaturated Hydrocarbons by : Annemarie Schmoltner

Download or read book Molecular Beam Studies of Oxygen Atom Reactions with Unsaturated Hydrocarbons written by Annemarie Schmoltner and published by . This book was released on 1989 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Crossed-molecular-beams Reactive Scattering of Oxygen Atoms

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Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Crossed-molecular-beams Reactive Scattering of Oxygen Atoms by :

Download or read book Crossed-molecular-beams Reactive Scattering of Oxygen Atoms written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The reactions of O(3P) with six prototypical unsaturated hydrocarbons, and the reaction of O(1D) with HD, have been studied in high-resolution crossed-molecular-beams scattering experiments with mass-spectrometric detection. The observed laboratory-product angular and velocity distributions unambiguously identify parent-daughter ion pairs, distinguish different neutral sources of the same ion, and have been used to identify the primary products of the reactions. The derived center-of-mass product angular and translational energy distributions have been used to elucidate the detailed reaction dynamics. These results demonstrate that O(3P)-unsaturated hydrocarbon chemistry is dominated by single bond cleavages, leading to radical products exclusively.

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 1152 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1985 with total page 1152 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Toxicology Research Projects Directory

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ISBN 13 :
Total Pages : 884 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Toxicology Research Projects Directory by :

Download or read book Toxicology Research Projects Directory written by and published by . This book was released on 1980-10 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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ISBN 13 :
Total Pages : 1740 pages
Book Rating : 4.U/5 (183 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1981 with total page 1740 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Science Abstracts

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ISBN 13 :
Total Pages : 658 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Nuclear Science Abstracts by :

Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1976 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Technical Abstract Bulletin

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ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Technical Abstract Bulletin by :

Download or read book Technical Abstract Bulletin written by and published by . This book was released on with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:

ERDA Energy Research Abstracts

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ISBN 13 :
Total Pages : 600 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration

Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration and published by . This book was released on with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:

ERDA Energy Research Abstracts

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ISBN 13 :
Total Pages : 588 pages
Book Rating : 4.3/5 (129 download)

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Book Synopsis ERDA Energy Research Abstracts by : United States. Energy Research and Development Administration. Technical Information Center

Download or read book ERDA Energy Research Abstracts written by United States. Energy Research and Development Administration. Technical Information Center and published by . This book was released on 1976 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: