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Chemical Characterization Of Dissolved Organic Matter
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Book Synopsis Biogeochemistry of Marine Dissolved Organic Matter by : Dennis A. Hansell
Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Academic Press. This book was released on 2014-10-02 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: Marine dissolved organic matter (DOM) is a complex mixture of molecules found throughout the world's oceans. It plays a key role in the export, distribution, and sequestration of carbon in the oceanic water column, posited to be a source of atmospheric climate regulation. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, focuses on the chemical constituents of DOM and its biogeochemical, biological, and ecological significance in the global ocean, and provides a single, unique source for the references, information, and informed judgments of the community of marine biogeochemists. Presented by some of the world's leading scientists, this revised edition reports on the major advances in this area and includes new chapters covering the role of DOM in ancient ocean carbon cycles, the long term stability of marine DOM, the biophysical dynamics of DOM, fluvial DOM qualities and fate, and the Mediterranean Sea. Biogeochemistry of Marine Dissolved Organic Matter, Second Edition, is an extremely useful resource that helps people interested in the largest pool of active carbon on the planet (DOC) get a firm grounding on the general paradigms and many of the relevant references on this topic. Features up-to-date knowledge of DOM, including five new chapters The only published work to synthesize recent research on dissolved organic carbon in the Mediterranean Sea Includes chapters that address inputs from freshwater terrestrial DOM
Book Synopsis Biogeochemistry of Marine Dissolved Organic Matter by : Dennis A. Hansell
Download or read book Biogeochemistry of Marine Dissolved Organic Matter written by Dennis A. Hansell and published by Elsevier. This book was released on 2002-07-06 with total page 807 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in marine dissolved organic matter (DOM) is very high because it plays an important role in oceanic and global carbon cycling, which in turn impacts weather. Understanding the processes involved in the transformations of carbon, phosphorus, nitrogen, and other major elements in the oceans has been a primary goal of marine biogeochemists and oceanographers over the past decade.This book, in 16 chapters with over 170 figures and tables, reports on the major advances in this area by a distinguished group of international chemical and biological oceanographers. Additionally, it focuses on the role of DOM in elemental cycling - where the greatest informational need currently exists. Biological cycling of the major elements through DOM is assessed throughout, with particular emphasis on the role of marine microbes as active agents in the processing of this materialThe ocean science community's advances for inclusion of DOM in both ecosystem and global circulation models are evaluated
Book Synopsis Chemical Characterization of Dissolved Organic Matter in Relation with Hydrography in the Arctive Ocean by : Zhiyuan Gao
Download or read book Chemical Characterization of Dissolved Organic Matter in Relation with Hydrography in the Arctive Ocean written by Zhiyuan Gao and published by . This book was released on 2016 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Characterization of Dissolved Organic Matter and Its Influence on the Chemistry of River Water by : Johannes Helmut Reuter
Download or read book Chemical Characterization of Dissolved Organic Matter and Its Influence on the Chemistry of River Water written by Johannes Helmut Reuter and published by . This book was released on 1972 with total page 66 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters by : Christopher L. Osburn
Download or read book Linking Optical and Chemical Properties of Dissolved Organic Matter in Natural Waters written by Christopher L. Osburn and published by Frontiers Media SA. This book was released on 2017-01-17 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: A substantial increase in the number of studies using the optical properties (absorbance and fluorescence) of dissolved organic matter (DOM) as a proxy for its chemical properties in estuaries and the coastal and open ocean has occurred during the last decade. We are making progress on finding the actual chemical compounds or phenomena responsible for DOM’s optical properties. Ultrahigh resolution mass spectrometry, in particular, has made important progress in making the key connections between optics and chemistry. But serious questions remain and the last major special issue on DOM optics and chemistry occurred nearly 10 years ago. Controversies remain from the non-specific optical properties of DOM that are not linked to discrete sources, and sometimes provide conflicting information. The use of optics, which is relatively easier to employ in synoptic and high resolution sampling to determine chemistry, is a critical connection to make and can lead to major advances in our understanding of organic matter cycling in all aquatic ecosystems. The contentions and controversies raised by our poor understanding of the linkages between optics and chemistry of DOM are bottlenecks that need to be addressed and overcome.
Book Synopsis The Effect of Iron on Chemical Characterization of Dissolved Organic Matter Using Spectroscopic Techniques by : Brittany N. Papworth
Download or read book The Effect of Iron on Chemical Characterization of Dissolved Organic Matter Using Spectroscopic Techniques written by Brittany N. Papworth and published by . This book was released on 2012 with total page 70 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Characterization of Dissolved Organic Matter by : James Hunt
Download or read book Chemical Characterization of Dissolved Organic Matter written by James Hunt and published by . This book was released on 2006 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater by :
Download or read book Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Funding for this research was provided by the National Science Foundation (OCE-981 8654) and the Department of Energy (DEFG0200ERG62999). Student support was also provided by a National Science Foundation Graduate Student Fellowship.
Book Synopsis Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater by : Tracy Michelle Quan
Download or read book Chemical Characterization of Dissolved Organic Matter (DOM) in Seawater written by Tracy Michelle Quan and published by . This book was released on 2005 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: (Cont.) This new separation protocol utilized various chromatographic techniques, including cation exchange chromatography and high- pressure liquid chromatography (HPLC) using C18 and strong cation exchange (SCX) columns. Six amino acids were isolated from a HMWDOM sample with sufficient purity and quantity for radiocarbon analysis. These amino acids had a range of A'4C values, from 121%o to -454%o. The final section investigates biological controls on the dissolved organic nitrogen (DON) pool. Total hydrolyzable amino acids (THAA), and nucleic acids were measured for four incubations: a control incubation, a grazer added incubation, a zero virus incubation, and a 10 times virus incubation. Comparison to the control showed THAA and nucleic acid release were influenced by viruses but not grazers.
Book Synopsis Reactivity and Chemical Characterization of Dissolved Organic Matter in an Estuary by : Hussain A. Abdulla
Download or read book Reactivity and Chemical Characterization of Dissolved Organic Matter in an Estuary written by Hussain A. Abdulla and published by . This book was released on 2009 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Partial Chemical Characterization of Estuarine Dissolved Organic Matter by : Richard A. Kerr
Download or read book Partial Chemical Characterization of Estuarine Dissolved Organic Matter written by Richard A. Kerr and published by . This book was released on 1979 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Characterization of Dissolved Organic Matter by Using Chemical Fractionation and High Resolution Organic Structural Spectroscopy by : Yan Li
Download or read book Comprehensive Characterization of Dissolved Organic Matter by Using Chemical Fractionation and High Resolution Organic Structural Spectroscopy written by Yan Li and published by . This book was released on 2017 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aquatic Organic Matter Fluorescence by : Paula G. Coble
Download or read book Aquatic Organic Matter Fluorescence written by Paula G. Coble and published by Cambridge University Press. This book was released on 2014-07-14 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: A core text on principles, laboratory/field methodologies, and data interpretation for fluorescence applications in aquatic science, for advanced students and researchers.
Book Synopsis Encyclopedia of Geochemistry by : William M. White
Download or read book Encyclopedia of Geochemistry written by William M. White and published by Springer. This book was released on 2018-07-24 with total page 1680 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.
Book Synopsis Advances in the Physicochemical Characterization of Dissolved Organic Matter by : Fernando Rosario-Ortiz
Download or read book Advances in the Physicochemical Characterization of Dissolved Organic Matter written by Fernando Rosario-Ortiz and published by . This book was released on 2014 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Molecular and Optical Characterization of Dissolved Organic Matter in the Central Arctic Ocean by : Xianyu Kong
Download or read book Molecular and Optical Characterization of Dissolved Organic Matter in the Central Arctic Ocean written by Xianyu Kong and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dissolved organic matter (DOM) in the ocean is a complex mixture of molecules derived from autochthonous (marine) or allochthonous (terrestrial) origins. DOM plays an important role in marine biogeochemical cycles by attenuating light available for primary production, serving as an energy and nutrient source for heterotrophic communities, regulating the ultraviolet and visible light absorption, undergoing photochemical processing, and acting as a trace metal ligand. DOM in the Central Arctic Ocean (CAO) is influenced by increased freshwater input and associated terrestrial materials in recent decades due to rapid climate change. The quantification of DOM sources (terrestrial versus marine) in the water column of the CAO is not well constrained. Few studies have systematically investigated the seasonality and spatial variability of DOM by combining optical and molecular-level analytical techniques in the CAO, especially during winter. State of the art chemical characterization of DOM is subject to major challenges: Solid phase extraction (SPE) that is often used to desalt and pre-concentrate marine DOM introduces chemical fractionation effects, which limits the comparability between analytical results for original samples and those carried out for SPE-DOM. There is no specific method to quantify fractionation effects, nor specific guidelines to avoid fractionation. Using mass spectrometry, quantitative DOM analyses is challenged by selective ionization of molecules and the large number of unresolved structural isomers that prevent classical external calibration. In the first part of this thesis, a method was developed to quantitatively track optical or chemical fractionation during SPE and investigate the potential mechanisms. We found a decrease in extraction efficiency of dissolved organic carbon (DOC), fluorescence and absorbance, and polar organic substances with increasing carbon loading on the SPE column. As the surface loading of the solid-phase increased, the dominant extraction mechanism shifted from PPL physisorption to increased DOM self-assembly, resulting in optical and chemical fractionation. The relative DOC loading (DOCload) was used to assess the carbon loading during SPE, and a double sigmoid model was applied to our online permeate fluorescence data as a function of DOCload, which allowed us to assess the degree of variability induced by DOCload. This finding has ample implications for the future processing and previous interpretation of chemical characteristics in SPE-DOM of aquatic organic matter. For the second part of the thesis, original water samples were acquired from the “Multidisciplinary Drifting Observatory for the Study of Arctic Climate” (MOSAiC) expedition. The water column samples covered a full year (2019 / 2020) and included the regions Amundsen Basin, western Nansen Basin and Yermak Plateau and Fram Strait. Samples were analyzed using optical spectroscopy to determine chromophoric DOM (CDOM) and fluorescent DOM (FDOM). In addition, a new method was applied that used Fourier transform ion cyclotron resonance mass spectrometry hyphenated to high performance liquid chromatography (LC-FTMS). The method allowed DOM analysis in original filtered water and thus avoided the chemical fractionation introduced by SPE. During the MOSAiC expedition, DOC concentrations and CDOM characteristics in the water column were primarily influenced by regional differences. These differences were largely dependent on terrestrially-derived DOM (tDOM) input by the transpolar drift (TPD) as indicative of average 136% and 45% higher aCDOM(350) and DOC concentration, respectively, in the Amundsen compared to the western Nansen Basin and Yermak Plateau, and slightly modified by seasonal changes. Despite the convenient identification of tDOM, optical spectroscopy was not suitable to quantify the contribution of tDOM to bulk DOC or to track sea ice derived DOM in the water column. In contrast, using LC-FTMS, we found quantitative linear correlation between the summed mass peak magnitudes for each sample (intsum) and DOC concentration. By combing LC-FTMS and source identification with optical parameters, we were able to quantify DOM sources (terrestrial versus marine) in the water column: 83% of the summed peak magnitude of all samples could be related to marine or terrestrial sources. tDOM contributed ∼17% (or 8 μmol kg-1) to deep DOC (~2000 m) in the CAO and was more refractory and had a higher state of unsaturation compared to marine DOM. The quantitative characterization of DOM in original seawater from different origin is a major step in the field of research. It provides a unique and new insight into the molecular changes in marine DOM composition and an improved understanding of the terrestrial DOM distribution in the CAO.
Book Synopsis Organic geochemistry of natural waters by : E.M. Thurman
Download or read book Organic geochemistry of natural waters written by E.M. Thurman and published by Springer Science & Business Media. This book was released on 1985-04-30 with total page 524 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is written as a reference on organic substances in natural waters and as a supplementary text for graduate students in water chemistry. The chapters address five topics: amount, origin, nature, geochemistry, and characterization of organic carbon. Of these topics, the main themes are the amount and nature of dissolved organic carbon in natural waters (mainly fresh water, although seawater is briefly discussed). It is hoped that the reader is familiar with organic chemistry, but it is not necessary. The first part of the book is a general overview of the amount and general nature of dissolved organic carbon. Over the past 10 years there has been an exponential increase in knowledge on organic substances in water, which is the result of money directed toward the research of organic compounds, of new methods of analysis (such as gas chromatography and mass spectrometry), and most importantly, the result of more people working in this field. Because of this exponential increase in knowledge, there is a need to pull together and summarize the data that has accumulated from many disciplines over the last decade.