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Catalytic Oxidative Cleavage Of Terminal Olefins By Metal Stearate Complexes
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Book Synopsis Catalytic Oxidative Cleavage of Terminal Olefins by Metal Stearate Complexes by :
Download or read book Catalytic Oxidative Cleavage of Terminal Olefins by Metal Stearate Complexes written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Selective functionalization of olefins is not only an industrially important process, but also has many synthetic utilities in academic point of view. This work focuses on the development of a new synthetic methodology for the preparation of carbonyl compounds from the oxidative cleavage of terminal olefins using alpha-methylstyrene as a model compound. With the use of TBHP as an oxidant in combination with chromium(III) stearate catalyst, selective oxidation of conjugated double bonds with aromatic ring or carbonyl group was achieved at ambient temperature in 24 hours in moderate to excellent yield. Both the catalyst and TBHP are essential in promoting the reaction. The oxidative cleavage works well in aprotic solvents such as isooctane, acetonitrile, and 1,2-dichloroethane. The optimized condition was accomplishedly applied in the oxidative cleavage of a variety of different terminal olefins. The oxidative cleavage of electron rich alpha-methylstyrene derivatives proceeds in good to excellent yield. Lower yields were observed in alpha-methylstyrene derivatives containing an electron withdrawing group. The oxidative cleavage is selective for electron rich conjugated double bond with aromatic ring or carbonyl group. This developed oxidation reaction was believed to undergo via free radical process and high valent chromium oxo species.
Author :Giuliano Giambastiani Publisher :Springer Science & Business Media ISBN 13 :9048138159 Total Pages :296 pages Book Rating :4.0/5 (481 download)
Book Synopsis Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I by : Giuliano Giambastiani
Download or read book Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I written by Giuliano Giambastiani and published by Springer Science & Business Media. This book was released on 2011-04-29 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
Book Synopsis Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I by : Giuliano Giambastiani
Download or read book Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes I written by Giuliano Giambastiani and published by Springer. This book was released on 2011-05-10 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
Download or read book Iron Catalysis written by Bernd Plietker and published by Springer Science & Business Media. This book was released on 2011-01-05 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt: Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.
Book Synopsis Iron Catalysis in Organic Chemistry by : Bernd Plietker
Download or read book Iron Catalysis in Organic Chemistry written by Bernd Plietker and published by John Wiley & Sons. This book was released on 2008-09-08 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.
Book Synopsis Catalytic Oxidations with Hydrogen Peroxide as Oxidant by : G. Strukul
Download or read book Catalytic Oxidations with Hydrogen Peroxide as Oxidant written by G. Strukul and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.
Book Synopsis Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes by : A.E. Shilov
Download or read book Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes written by A.E. Shilov and published by Springer Science & Business Media. This book was released on 2001-11-30 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.
Book Synopsis Supported Metal Complexes by : F.R. Hartley
Download or read book Supported Metal Complexes written by F.R. Hartley and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is now IS years since the first patents in polymer supported metal complex catalysts were taken out. In the early days ion-exchange resins were used to support ionic metal complexes. Soon covalent links were developed, and after an initially slow start there was a period of explosive growth in the mid to late 1970s during which virtually every homogeneous metal complex catalyst ever reported was also studied bound to a support. Both polymers and inorganic oxides were studied as supports, although the great preponderance of workers studied polymeric supports, and of these polystyrene was by far the commonest used. This period served to show that by very careful design polymer-supported metal complex catalysts could have specific advantages over homogeneous metal complex catalysts. However the subject was a complicated one. Merely immobilising a successful metal complex catalyst to a functionalised support rarely yielded other than an inferior version of the catalyst. Amongst the many discouraging results of the 1970s, there were more than enough results that were sufficiently encouraging to demonstrate that, by careful design, supported metal complex catalysts could be prepared in which both the metal complex and the support combined together to produce an active catalyst which, due to the combination of support and complex, had advantages of activity, selectivity and specificity not found in homogeneous catalysts. Thus a new generation of catalysts was being developed.
Book Synopsis Pandex Current Index to Scientific and Technical Literature by :
Download or read book Pandex Current Index to Scientific and Technical Literature written by and published by . This book was released on 1969 with total page 1196 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Sustainable Industrial Chemistry by : Fabrizio Cavani
Download or read book Sustainable Industrial Chemistry written by Fabrizio Cavani and published by John Wiley & Sons. This book was released on 2009-09-22 with total page 621 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years the need for sustainable process design and alternative reaction routes to reduce industry?s impact on the environment has gained vital importance. The book begins with a general overview of new trends in designing industrial chemical processes which are environmentally friendly and economically feasible. Specific examples written by experts from industry cover the possibilities of running industrial chemical processes in a sustainable manner and provide an up-to-date insight into the main concerns, e.g., the use of renewable raw materials, the use of alternative energy sources in chemical processes, the design of intrinsically safe processes, microreactor and integrated reaction/ separation technologies, process intensification, waste reduction, new catalytic routes and/or solvent and process optimization.
Book Synopsis N-Heterocyclic Carbenes by : Silvia Diez-Gonzalez
Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.
Book Synopsis Lipid Oxidation by : Edwin N. Frankel
Download or read book Lipid Oxidation written by Edwin N. Frankel and published by Elsevier. This book was released on 2014-01-23 with total page 487 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this second edition, Edwin Frankel has updated and extended his now well-known book Lipid oxidation which has come to be regarded as the standard work on the subject since the publication of the first edition seven years previously. His main objective is to develop the background necessary for a better understanding of what factors should be considered, and what methods and lipid systems should be employed, to achieve suitable evaluation and control of lipid oxidation in complex foods and biological systems. The oxidation of unsaturated fatty acids is one of the most fundamental reactions in lipid chemistry. When unsaturated lipids are exposed to air, the complex, volatile oxidation compounds that are formed cause rancidity. This decreases the quality of foods that contain natural lipid components as well as foods in which oils are used as ingredients. Furthermore, products of lipid oxidation have been implicated in many vital biological reactions, and evidence has accumulated to show that free radicals and reactive oxygen species participate in tissue injuries and in degenerative disease. Although there have been many significant advances in this challenging field, many important problems remain unsolved. This second edition of Lipid oxidation follows the example of the first edition in offering a summary of the many unsolved problems that need further research. The need to understand lipid oxidation is greater than ever with the increased interest in long-chain polyunsaturated fatty acids, the reformulation of oils to avoid hydrogenation and trans fatty acids, and the enormous attention given to natural phenolic antioxidants, including flavonoids and other phytochemicals.
Book Synopsis Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control by : Benedetto Corain
Download or read book Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control written by Benedetto Corain and published by Elsevier. This book was released on 2011-08-11 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control deals with the synthesis of metal nanoclusters along all known methodologies. Physical and chemical properties of metal nanoclusters relevant to their applications in chemical processing and materials science are covered thoroughly. Special attention is given to the role of metal nanoclusters size and shape in catalytic processes and catalytic applications relevant to industrial chemical processing.An excellent text for expanding the knowledge on the chemistry and physics of metal nanoclusters. Divided in two parts; Part I deals with general aspects of the matter and Part II has to be considered a useful handbook dealing with the production of metal nanoclusters, especially from their size-control point of view. * Divided into two parts for ease of reference: general and operational * Separation of synthetic aspects, physical properties and applications* Specific attention is given to the task of metal nanoclusters size-control
Book Synopsis Irradiation of Polymers by : Roger Lee Clough
Download or read book Irradiation of Polymers written by Roger Lee Clough and published by . This book was released on 1996 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discusses structural and physiochemical effects of irradiation and presents techniques to model and monitor radiation events. Describes the use of radiation as a sterilization method in the biomedical, pharmaceutical, and food industries. Examines current topics in the stability and stabilization of polymers exposed to ionizing radiation. Reviews advances in the use of radiation with photosensitive metathesis polymers, chemical amplification, and dry-develop resist technology.
Book Synopsis Handbook on Coal, Coke, Cotton, Lignin, Hemicellulose, Wood, Wood-Polymer Composites, Lignocellulosic-Plastic Composites from Recycled Materials, Wood Fiber, Rosin and Rosin Derivatives by : Dr. Himadri Panda
Download or read book Handbook on Coal, Coke, Cotton, Lignin, Hemicellulose, Wood, Wood-Polymer Composites, Lignocellulosic-Plastic Composites from Recycled Materials, Wood Fiber, Rosin and Rosin Derivatives written by Dr. Himadri Panda and published by NIIR PROJECT CONSULTANCY SERVICES. This book was released on 2018-01-11 with total page 277 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coal is the product of plants, mainly trees that died tens or hundreds of millions of years ago. Coal is a fossil fuel and is the altered remains of prehistoric vegetation that originally accumulated in swamps and peat bogs. The energy we get from coal today comes from the energy that plants absorbed from the sun millions of years ago. Coal is used primarily as an energy source, either for heat or electricity. It was once heavily used to heat homes and power locomotives and factories. Bituminous coal is also used to produce coke for making steel and other industrial process heating. Lignin is a constituent of the cell walls of almost all dry land plant cell walls. It is the second most abundant natural polymer in the world, surpassed only by cellulose. Lignin is found in all vascular plants, mostly between the cells, but also within the cells, and in the cell walls. Wood is an aggregate of cells essentially cellulose in composition, which are cemented together by a substance called lignin. The cells are made of three substances called cellulose (about 50 percent), lignin (which makes up a fifth to a quarter of hardwoods but a quarter to a third of softwoods), and hemicellulose. Rosin refers to an extraction process that utilizes a combination of heat and pressure to nearly instantaneously squeeze resinous sap from your initial starting material In India's energy sector, coal accounts for the majority of primary commercial energy supply. With the economy poised to grow at the rate of 8-10% per annum, energy requirements will also rise at a reasonable level. The Indian coal industry aspires to reach the 1.5 billion tonne (BT) mark by FY 2020. In fore-coming years, the industry will naturally need to focus on building on the success, and be on track for reaching the FY 2020 goal. One of the primary goals of the Government of India is to ensure that it is able to meet the country's power generation needs. Another aim is to lower the country's reliance on coal imports by boosting the coal production quickly. The Major contents of the book are Coal, Analysis of Coal and Coke, Cotton, Lignin and Hemicelluloses, Degradation of Wood, CCA-Treated Wood, Wood-Polymer Composites, Lignocellulosic-Plastic Composites from Recycled Materials, Chemical Modification of Wood Fiber, Delignification of Wood with Pernitric Acid, Rosin and Rosin Derivatives, Polymerizable Half Esters of Rosin and Photographs of Plant & Machinery with Supplier’s Contact Details. It will be a standard reference book for professionals, entrepreneurs, those studying and researching in this important area and others interested in the field of these industries. TAGS Coal Preparation Plant, Coal Processing, Processing of Coal, Coal Processing Plant, Coal Preparation Process, Lignin Processing, Processing of Lignin, Process for Producing Lignin, Wood Processing, Wood Processing Plant, Wood Processing Industry, Coal, Lignin, Wood and Rosin Processing, Business Plan for Coal and Lignin Processing, Business Idea for Wood and Rosin Processing, Chemical Composition of Rosin, Coal and Lignin Processing, Coal Preparation Technology, How to Start Coal and Lignin Business, How to Start Successful Coal and Lignin Business, How to Start Successful Wood and Rosin Business, How to Start Coal and Lignin Processing Industry in India, How to Start Coal And Lignin Production Business, Most Profitable Coal and Lignin Processing Business Ideas, Coal Industry in India, Coal Sector in India, Processing of Lignin, Lignin Production, Production of Lignin, Industrial Lignin Production, Lignin Extraction, Wood Processing Business, Manufacturing Process of Rosin, Coal Processing project ideas, Small scale industries ideas, Coal Processing Based Small Scale Industries , Project profile on small scale industries, How to Start Coal Processing Industry in India, Coal Processing , New project profile on Coal Processing industries, Project Report on Wood and Rosin Processing Industry, Detailed Project Report on Wood and Rosin Processing, Project Report on Wood and Rosin Processing, Pre-Investment Feasibility Study on Wood and Rosin Processing, Techno-Economic feasibility study on Coal Processing, Feasibility report on Coal Processing, Free Project Profile on Coal and Lignin Processing, Project profile on Coal and Lignin Processing, Download free project profile on Coal and Lignin Processing, Industrial Project Report, Startup Project for Coal Processing Plant
Book Synopsis Autoxidation in Food and Biological Systems by : M.G. Simic
Download or read book Autoxidation in Food and Biological Systems written by M.G. Simic and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt: The material presented in this book deals with basic mechanisms of free radical reactions in autoxidation processes and anitoxidant suppression of autoxidation of foods, biochemical models and biologi cal systems. Autoxidation in foods and corresponding biological effects are usually approached separately although recent mechanistic developments in the biochemistry and free radical chemistry of per oxides and their precursors tend to bring these two fields closer. Apparent ability of antioxidants in diets to reduce the inci dence of cancer has resulted in scrutiny of autoxidized products and their precursors as possibly toxic, mutagenic and carcinogenic agents. Mechanisms of any of these effects have been barely ad dressed. Yet we know now that free radicals, as esoteric as they were only a few decades ago, are being discovered in foods, biochem ical and biological systems and do play a role in the above-mentioned causalities. The purpose of the Workshop and the resulting book was to give a unifying approach towards study of beneficial and deleterious effects of autoxidation, based on rigorous scientific considerations. It is our hope that the material presented in this book will not only provide a review of the "state of the art" of autoxidation and anti oxidants, but also reflect the interaction which occurred during the Workshop between workers using model sytems, and food and biological systems.
Book Synopsis Ruthenium Oxidation Complexes by : William P. Griffith
Download or read book Ruthenium Oxidation Complexes written by William P. Griffith and published by Springer Science & Business Media. This book was released on 2010-11-03 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ruthenium Oxidation Complexes explores ruthenium complexes, particularly those in higher oxidation states, which function as useful and selective organic oxidation catalysts. Particular emphasis is placed on those systems which are of industrial significance. The preparation, properties and applications of the ruthenium complexes are described, followed by a presentation of their oxidative properties and summary of the different mechanisms involved in the organic oxidations (e.g. oxidations of alcohols, alkenes, arenes and alkynes, alkanes, amines, ethers, phopshines and miscellaneous substrates). Moreover, future trends and developments in the area are discussed. This monograph is aimed at inorganic, organic, industrial and catalysis chemists, especially those who wish to carry out specific organic oxidations using catalytic methods.
