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Cascades For Hydrogen Isotope Separation Using Metal Hydrides
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Book Synopsis Cascades for Hydrogen Isotope Separation Using Metal Hydrides by :
Download or read book Cascades for Hydrogen Isotope Separation Using Metal Hydrides written by and published by . This book was released on 1982 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cascades for Hydrogen Isotope Separation Using Metal Hydrides by :
Download or read book Cascades for Hydrogen Isotope Separation Using Metal Hydrides written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Designs are presented for continuous countercurrent hydrogen isotope separation cascades based on the use of metal hydrides. The cascades are made up of pressure swing adsorption (PSA) or temperature swing adsorption (TSA) stages. The designs were evolved from consideration of previously conducted studies of the separation performance of four types of PSA and TSA processes.
Book Synopsis Hydrogen Materials Science and Chemistry of Metal Hydrides by : Michael D. Hampton
Download or read book Hydrogen Materials Science and Chemistry of Metal Hydrides written by Michael D. Hampton and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 471 pages. Available in PDF, EPUB and Kindle. Book excerpt: In September, 1999, with the generous support of NATO, scientists from 18 different nations gathered in Katsiveli, Yalta, Ukraine at the NATO Advanced Research Workshop on Hydrogen Materials Science and Chemistry of Metal Hydrides to present their research and to discuss world energy problems and possible solutions, interactions of hydrogen with materials, the role of hydrogen in materials science, and the chemistry of metal hydrides. High level and highly professional presentations were accompanied by a great deal of discussion and debate of the issues from both fundamental and global perspectives. The result was a large number of new collaborations, new directions, and better understanding of energy and materials issues. The research presented at this meeting can be found in this volume. These papers range from global perspectives such as the new vision of energy and how hydrogen fits into that future, to reviews such as a look at nickel hydride over the last 40 years, to very specific current research. A large number of papers are included on hydrogen and materials. These papers include articles on properties such as superconductivity, diffusion EMF, magnetic properties, physico chemical properties, phase composition, and permeability as a result of the interaction with or incorporation of hydrogen. Also included are papers discussing the use of hydrogen as a processing or alloying agent. The use of hydrogen in the synthesis of battery electrode materials, composite materials, and alloys is also presented.
Book Synopsis Metal Hydride Compacts for Hydrogen Isotope Separation by :
Download or read book Metal Hydride Compacts for Hydrogen Isotope Separation written by and published by . This book was released on 1990 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt: A column packed with pellets of copper plated LaNi{sub 4.25}Al{sub 0.75} has been evaluated for its separation efficiency using a displacement method. Deuterium breakthrough curves were produced experimentally and compared with those calculated with a stage model. The height equivalent to a theoretical plate was attained and its dependence on temperature and gas flow rate was established. 6 refs., 4 figs.
Book Synopsis The Role of Sidestream Recycle in Hydrogen Isotope Separation and Column Cascade Design by :
Download or read book The Role of Sidestream Recycle in Hydrogen Isotope Separation and Column Cascade Design written by and published by . This book was released on 1994 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sidestream recycle combined with sidestream equilibration is important in hydrogen isotopic distillation processes because it offers a means to reduce the number of columns required for the extraction of pure homonuclear species. This directly implies simpler systems, reduced control problems, and reduce material inventories. Measurements were recently completed for a single distillation column using feed compositions ((approximately)50--50 D-T) and product flows similar to those expected in an ITER type device wit recycle of an equilibrated sidestream withdrawn from the column. Dynamic studies were conducted with flowrates changing as might be expected for typical Tokamak operations. These experimental results are compared with computer simulations of the dynamic process. The impact of these sidestream recycle studies on the design of isotope separation systems is discussed, especially with respect to column design, tritium inventory, dynamic performance, stability, and system control.
Book Synopsis The Electrolytic Separation of Hydrogen Isotopes by Migration Through a Palladium Membrane by : O. N. Salmon
Download or read book The Electrolytic Separation of Hydrogen Isotopes by Migration Through a Palladium Membrane written by O. N. Salmon and published by . This book was released on 1956 with total page 30 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1985 with total page 888 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book ERDA Energy Research Abstracts written by and published by . This book was released on 1983 with total page 1048 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1992 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Gas Chromatographic Separation of Hydrogen Isotopes Using Metal Hydrides by :
Download or read book Gas Chromatographic Separation of Hydrogen Isotopes Using Metal Hydrides written by and published by . This book was released on 1984 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A study was made of the properties of metal hydrides which may be suitable for use in chromatographic separation of hydrogen isotopes. Sixty-five alloys were measured, with the best having a hydrogen-deuterium separation factor of 1.35 at 60°C. Chromatographic columns using these alloys produced deuterium enrichments of up to 3.6 in a single pass, using natural abundance hydrogen as starting material. 25 references, 16 figures, 4 tables.
Book Synopsis Electrolytic Separation Factors for Hydrogen Isotopes by : Richard R. Foster
Download or read book Electrolytic Separation Factors for Hydrogen Isotopes written by Richard R. Foster and published by . This book was released on 1961 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book INIS Atomindex written by and published by . This book was released on 1983 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process by :
Download or read book Studies of Hydrogen Isotope Separation Using Vanadium Hydride in a Temperature Cycling Process written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Separations of gaseous HT-H2 mixtures on vanadium monohydride were carried out using a two-column temperature cycling process similar to parametric pumping. An equilibrium theory of process operation is presented which was in qualitative agreement with experimental results. Failure to achieve complete removal of HT from the cold column effluent as predicted was ascribed to the finite rates of the exchange reaction and to the presence and operation of an isotope effect in the rate of hydrogen absorption.
Book Synopsis Ei Engineering Conference Index: pt. 1. Civil, environmental, and geological engineering by :
Download or read book Ei Engineering Conference Index: pt. 1. Civil, environmental, and geological engineering written by and published by . This book was released on 1985 with total page 1412 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1975 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Gas Flow-Through System for Hydrogen Isotopic Separation with Metal-Organic Frameworks by : Katharine Harp Rigdon
Download or read book A Gas Flow-Through System for Hydrogen Isotopic Separation with Metal-Organic Frameworks written by Katharine Harp Rigdon and published by . This book was released on 2019 with total page 47 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, we designed and built a gas flow-through system to study dynamic adsorption separation of hydrogen isotopes in metal-organic frameworks (MOFs). MOFs are porous, crystalline materials composed of metal complexes connected by organic linkers. They have been proposed as a cheaper, more energy efficient approach to hydrogen isotope separation than current industrial methods. We have previously found evidence of a zero-point energy-based separation mechanism for hydrogen isotopes in two MOFs: Co-MOF-74 and Cu(I)-MFU-4l. This mechanism, chemical affinity quantum sieving (CAQS), has been extensively studied under static equilibrium conditions. The system in this work was developed so that CAQS could be studied under dynamic conditions that more closely resemble those in industrial separation. Breakthrough analysis is an established technique for studying dynamic separation in porous materials. Generally, a breakthrough experiment involves flowing a gas mixture through a fixed bed of adsorbent material and measuring the composition of the effluent flow. In this work, a 1:1 mixture of common hydrogen and its isotope deuterium was flowed through 71 mg of Co-MOF-74 or 22 mg of Cu(I)-MFU-4l. A quadrupole mass spectrometer was used to monitor the composition of the effluent flow. We saw preferential adsorption of deuterium over common hydrogen in Co-MOF-74 at 77K and Cu(I)-MFU-4l at 170K, 140K, and 110K. This behavior was absent in Cu(I)-MFU-4l at 77K, a phenomenon that we would like to investigate further. Minimal adsorption occurred in both MOFs at room temperature, as expected. A selectivity of deuterium over common hydrogen was calculated for each temperature. These selectivities were approximately 30% lower than comparable literature values. Our goal is to make improvements to our system and methods to measure the selectivity more accurately and reproducibly. Notably, all measured selectivities were higher than the selectivity of the Girdler Sulfide method and cryogenic distillation, two industrial hydrogen isotope separation processes we are trying to improve on. This new system gives us the capability to study dynamic adsorption and kinetic separation of hydrogen isotopes in metal-organic frameworks going forward. We hope that our work will inform the development of efficient, environmentally sustainable separation processes.
Download or read book Fusion Energy Update written by and published by . This book was released on 1986 with total page 614 pages. Available in PDF, EPUB and Kindle. Book excerpt: