Carbon-13 NMR Studies of Liquid Crystals

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ISBN 13 :
Total Pages : 124 pages
Book Rating : 4.:/5 (893 download)

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Book Synopsis Carbon-13 NMR Studies of Liquid Crystals by :

Download or read book Carbon-13 NMR Studies of Liquid Crystals written by and published by . This book was released on 1975 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: High resolution, proton decoupled 13C nmr are observed for a series of neat nematic liquid crystals, the p-alkoxyazoxybenzenes, and a smectic-A liquid crystal, diethylazoxydibenzoate in a magnetic field of 23 kG. The (uniaxial) order parameters S = P2(cos[theta]) are found to be about 0.4 and 0.9 for the nematic and smectic-A phase respectively at the clearing points. The order parameter increases with decreasing temperature in the nematic phase but is constant, or nearly so, with temperature in the smectic-A phase. In the nematic series studied, the ordering exhibits an even-odd alternation along the series and qualitative agreement with a recent theory due to Marcelja is found. In both phases, the spectra show that the molecule rotates rapidly about its long axis. Tentative conclusions about molecular conformational motion and 14N spin relaxation are presented for both nematic and smectic-A phases. In the smectic-A phase, the sample is rotated about an axis perpendicular to H0 and the resulting spectra are discussed. The theory of observed chemical shifts in liquid crystals is treated in an appendix. Equations are derived which relate the nmr spectra of liquid-crystals to the order parameters. A model for the smectic-C phase due to Luz and Meiboom and Doane is described and lineshapes are determined on the basis of this model for special cases. Experiments on smectic-C liquid crystals are currently underway for comparison with the theory. Also treated in an appendix is the dependence of the order parameters on the molecular potential which give rise to the various degrees of order in the different liquid crystalline phases. To a good approximation the functional dependence of the order parameters on the molecular potential is shown to be a simple one in the limit of small tilt angle in the smectic-C phase.

Carbon-13 NMR Studies of Liquid Crystals

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ISBN 13 :
Total Pages : 270 pages
Book Rating : 4.:/5 (35 download)

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Book Synopsis Carbon-13 NMR Studies of Liquid Crystals by : Stuart Anthony Allison

Download or read book Carbon-13 NMR Studies of Liquid Crystals written by Stuart Anthony Allison and published by . This book was released on 1976 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbon-13 NMR Studies of Liquid Crystals

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Publisher :
ISBN 13 :
Total Pages : 236 pages
Book Rating : 4.:/5 (838 download)

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Book Synopsis Carbon-13 NMR Studies of Liquid Crystals by : Chi-Duen Poon

Download or read book Carbon-13 NMR Studies of Liquid Crystals written by Chi-Duen Poon and published by . This book was released on 1989 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals

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Publisher : World Scientific
ISBN 13 : 9814273678
Total Pages : 462 pages
Book Rating : 4.8/5 (142 download)

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Book Synopsis Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals by : Ronald Y. Dong

Download or read book Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals written by Ronald Y. Dong and published by World Scientific. This book was released on 2010 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited volume provides an extensive overview of how nuclear magnetic resonance can be an indispensable tool to investigate molecular ordering, phase structure, and dynamics in complex anisotropic phases formed by liquid crystalline materials. The chapters, written by prominent scientists in their field of expertise, provide a state-of-the-art scene of developments in liquid crystal research. The fantastic assortment of shape anisotropy in organic molecules leads to the discoveries of interesting new soft materials made at a rapid rate which not only inject impetus to address the fundamental physical and chemical phenomena, but also the potential applications in memory, sensor and display devices. The review volume also covers topics ranging from solute studies of molecules in nematics and biologically ordered fluids to theoretical approaches in treating elastic and viscous properties of liquid crystals. This volume is aimed at graduate students, novices and experts alike, and provides an excellent reference material for readers interested in the liquid crystal research. It is, indeed, a reference book for every science library to have. Sample Chapter(s). Chapter 1: Novel Strategies for Solving Highly Complex NMR Spectra of Solutes in Liquid Crystals (1,464 KB). Contents: Novel Strategies for Solving Highly Complex NMR Spectra of Solutes in Liquid Crystals (E E Burnell et al.); Analytical Potentials of Natural Abundance Deuterium NMR Spectroscopy in Achiral Thermotropics and Polypeptide Chiral Oriented Solvents (P Lesot & C Aroulande); Noble Gas Probes in NMR Studies of Liquid Crystals (J Jokisaari); Bicelles OCo A Much Needed Magic Wand to Study Membrane Proteins by NMR Spectroscopy (R Soong et al.); Advances in Proton NMR Relaxometry in Thermotropic Liquid Crystals (P J Sebastiuo et al.); Deuterium NMR Study of Magnetic Field Distortions in Ferroelectric Mesogens (R Y Dong); Deuteron NMR Study of the Effects of Random Quenched Disorder in 12CB Silica Dispersions (D Finotello & V Pandya); Dynamics of Liquid Crystals by Means of Deuterium NMR Relaxation (C A Veracini & V Domenici); Translational Self-Diffusion Measurements in Thermotropics by Means of Statistic Field Gradients NMR Diffusometry (M Cifelli); Deuterium NMR Studies of Static and Dynamic Director Alignment for Low Molar Mass Nematics (A Sugimura & G R Luckhurst); Viscoelastic Properties of Liquid Crystals: Statistical-Mechanical Approaches and Molecular Dynamics Simulations (A V Zakharov); Carbon-13 NMR Studies of Thermotropic Liquid Crystals (R Y Dong); A Combined DFT and Carbon-13 NMR Study of a Biaxial Bent-Core Mesogen (A Marini et al.). Readership: Chemists, physicists and material scientists. In particular, NMR spectroscopists.

Synthesis and Carbon-13 NMR Studies of Liquid Crystals

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Publisher :
ISBN 13 :
Total Pages : 346 pages
Book Rating : 4.:/5 (464 download)

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Book Synopsis Synthesis and Carbon-13 NMR Studies of Liquid Crystals by : Tat-Hung Tong

Download or read book Synthesis and Carbon-13 NMR Studies of Liquid Crystals written by Tat-Hung Tong and published by . This book was released on 1996 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Carbon-13 NMR Studies of Liquid Crystals

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Publisher :
ISBN 13 :
Total Pages : 372 pages
Book Rating : 4.:/5 (486 download)

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Book Synopsis Synthesis and Carbon-13 NMR Studies of Liquid Crystals by : Hong Sun

Download or read book Synthesis and Carbon-13 NMR Studies of Liquid Crystals written by Hong Sun and published by . This book was released on 2000 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:

13C NMR Studies of Liquid Crystals

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ISBN 13 :
Total Pages : 192 pages
Book Rating : 4.:/5 (464 download)

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Book Synopsis 13C NMR Studies of Liquid Crystals by : Matthew L. Magnuson

Download or read book 13C NMR Studies of Liquid Crystals written by Matthew L. Magnuson and published by . This book was released on 1994 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear Magnetic Resonance of Liquid Crystals

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Publisher : Springer Science & Business Media
ISBN 13 : 146121954X
Total Pages : 320 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis Nuclear Magnetic Resonance of Liquid Crystals by : Ronald Y. Dong

Download or read book Nuclear Magnetic Resonance of Liquid Crystals written by Ronald Y. Dong and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intended for researchers and students in physics, chemistry and materials science, this book provides the necessary background information and sufficient mathematical and physical detail to study the current research literature. The book begins with a survey of liquid crystal phases and field effects, together with an introduction to the basic physics of nuclear magnetic resonance. It then discusses orientational ordering and molecular field theories for various liquid crystal molecules and nmr studies of uniaxial and biaxial phases. Subsequent chapters consider spin relaxation processes and rotational, translational, and internal molecular dynamics of liquid crystals. The final chapter discusses two-dimensional and multiple- quantum nmr spectroscopies and their application in elucidating liquid crystal properties. This second edition, updated throughout, incorporates many new references and includes new mathematical appendices.

Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals

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Publisher : World Scientific
ISBN 13 : 981427366X
Total Pages : 462 pages
Book Rating : 4.8/5 (142 download)

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Book Synopsis Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals by : Ronald Y. Dong

Download or read book Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals written by Ronald Y. Dong and published by World Scientific. This book was released on 2010 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: This edited volume provides an extensive overview of how nuclear magnetic resonance can be an indispensable tool to investigate molecular ordering, phase structure, and dynamics in complex anisotropic phases formed by liquid crystalline materials. The chapters, written by prominent scientists in their field of expertise, provide a state-of-the-art scene of developments in liquid crystal research. The fantastic assortment of shape anisotropy in organic molecules leads to The discoveries of interesting new soft materials made at a rapid rate which not only inject impetus to address the fundamental physical and chemical phenomena, but also the potential applications in memory, sensor and display devices. The review volume also covers topics ranging from solute studies of molecules in nematics and biologically ordered fluids to theoretical approaches in treating elastic and viscous properties of liquid crystals. This volume is aimed at graduate students, novices and experts alike, and provides an excellent reference material for readers interested in the liquid crystal research. it is, indeed, a reference book for every science library to have.

Nuclear Magnetic Resonance of Liquid Crystals

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Publisher : Springer
ISBN 13 : 9789400965195
Total Pages : 592 pages
Book Rating : 4.9/5 (651 download)

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Book Synopsis Nuclear Magnetic Resonance of Liquid Crystals by : J.W. Emsley

Download or read book Nuclear Magnetic Resonance of Liquid Crystals written by J.W. Emsley and published by Springer. This book was released on 2011-10-12 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: The liquid crystalline state has been known for about a century and has been studied by many techniques. Nuclear magnetic resonance has been used to study mesophases for thirty years, but it has been in very recent years that advances in this form of spectroscopy have led to a rapid growth in its applications to the study both of liquid crystals and of solutes dissolved in them. It has become apparent that no other method of studying liquid crystals can yield such a wealth of data and it is unrivalled as a means of probing the behaviour of the molecules in mesophases. There has also been a steady increase in the study of the shape of small molecules dissolved in liquid crystals via the analysis of their NMR spectrum. In fact, the study of solutes was until recently regarded as a separate activity to the study of liquid crystals themselves, but this artificial division arose only from the gap between the large amount of information that could be derived from the spectrum of a small molecule and the rather meagre data set obtainable from the spectra of liquid crystals. This gap has, however, narrowed and it is now possible to derive a very detailed picture of the structure and orientational ordering of the large molecules typical of those which form liquid crystals. There has also been a rapid growth of interest in the liquid crystalline state.

Ionic Liquid Crystals

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Publisher : MDPI
ISBN 13 : 3039210866
Total Pages : 108 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis Ionic Liquid Crystals by : Giacomo Saielli

Download or read book Ionic Liquid Crystals written by Giacomo Saielli and published by MDPI. This book was released on 2019-06-24 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book we have collected a series of state-of-the art papers written by specialists in the field of ionic liquid crystals (ILCs) to address key questions concerning the synthesis, properties, and applications of ILCs. New compounds exhibiting ionic liquid crystalline phases are presented, both of calamitic as well as discotic type. Their dynamic and structural properties have been investigated with a series of experimental techniques including differential scanning calorimetry, polarized optical spectroscopy, X-ray scattering, and nuclear magnetic resonance, impedance spectroscopy to mention but a few. Moreover, computer simulations using both fully atomistic and highly coarse-grained force fields have been presented, offering an invaluable microscopic view of the structure and dynamics of these fascinating materials.

Cubic Liquid Crystals

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ISBN 13 : 9789171742438
Total Pages : 29 pages
Book Rating : 4.7/5 (424 download)

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Book Synopsis Cubic Liquid Crystals by : Per-Olof Eriksson

Download or read book Cubic Liquid Crystals written by Per-Olof Eriksson and published by . This book was released on 1986 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Thermotropic Liquid Crystals

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Publisher : Springer Science & Business Media
ISBN 13 : 1402053541
Total Pages : 331 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Thermotropic Liquid Crystals by : Ayyalusamy Ramamoorthy

Download or read book Thermotropic Liquid Crystals written by Ayyalusamy Ramamoorthy and published by Springer Science & Business Media. This book was released on 2007-05-06 with total page 331 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers developments in the field of thermotropic liquid crystals and their functional importance. It also presents advances related to different sub-areas pertinent to this interdisciplinary area of research. This text brings together research from synthetic scientists and spectroscopists and attempts to bridge the gaps between these areas. New physical techniques that are powerful in characterizing these materials are discussed.

Annual Reports on NMR Spectroscopy

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Publisher : Academic Press
ISBN 13 : 0128047577
Total Pages : 391 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Annual Reports on NMR Spectroscopy by :

Download or read book Annual Reports on NMR Spectroscopy written by and published by Academic Press. This book was released on 2016-01-09 with total page 391 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annual Reports on NMR Spectroscopy provides a thorough and in-depth accounting of the progress made in nuclear magnetic resonance (NMR) spectroscopy and its many applications. Nuclear magnetic resonance (NMR) is an analytical tool used by chemists and physicists to study the structure and dynamics of molecules. In recent years, no other technique has gained as much significance as NMR spectroscopy. It is used in all branches of science in which precise structural determination is required, and in which the nature of interactions and reactions in solution is being studied. Annual Reports on NMR Spectroscopy has established itself as a premier resource for both specialists and non-specialists alike who want to become familiar with the new techniques and applications of NMR spectroscopy. - Serves as the premier resource for learning the new techniques and applications of NMR spectroscopy - Provides a key reference for chemists and physicists using NMR spectroscopy to study the structure and dynamics of molecules

Modern Methods in Solid-state NMR

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788014197
Total Pages : 452 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Modern Methods in Solid-state NMR by : Paul Hodgkinson

Download or read book Modern Methods in Solid-state NMR written by Paul Hodgkinson and published by Royal Society of Chemistry. This book was released on 2018-04-05 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid-state NMR covers an enormous range of material types and experimental techniques. Although the basic instrumentation and techniques of solids NMR are readily accessible, there can be significant barriers, even for existing experts, to exploring the bewildering array of more sophisticated techniques. In this unique volume, a range of experts in different areas of modern solid-state NMR explain about their area of expertise, emphasising the “practical aspects” of implementing different techniques, and illustrating what questions can and cannot be addressed. Later chapters address complex materials, showing how different NMR techniques discussed in earlier chapters can be brought together to characterise important materials types. The volume as a whole focusses on topics relevant to the developing field of “NMR crystallography” – the use of solids NMR as a complement to diffraction crystallography. This book is an ideal complement to existing introductory texts and reviews on solid-state NMR. New researchers wanting to understand new areas of solid-state NMR will find each chapter to be the equivalent to spending time in the laboratory of an internationally leading expert, learning the hints and tips that make the difference between knowing about a technique and being ready to put it into action. With no equivalent on the market, it will be of interest to every solid-state NMR researcher (academic and postgraduate) working in the chemical sciences.

Solid-State Nmr of Polymers

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Publisher : iSmithers Rapra Publishing
ISBN 13 : 9781859572726
Total Pages : 160 pages
Book Rating : 4.5/5 (727 download)

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Book Synopsis Solid-State Nmr of Polymers by : P. Mirau

Download or read book Solid-State Nmr of Polymers written by P. Mirau and published by iSmithers Rapra Publishing. This book was released on 2001 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: NMR spectroscopy has emerged as one of the most important methods for the solid-state characterisation of polymers. This report gives an overview of the methods and applications of NMR to relevant polymer problems with an emphasis on how NMR can be used for materials characterisation and to understand structure-property relationships in polymers. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database gives useful references for further reading.

Research Awards Index

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ISBN 13 :
Total Pages : 1170 pages
Book Rating : 4.3/5 ( download)

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Book Synopsis Research Awards Index by :

Download or read book Research Awards Index written by and published by . This book was released on 1982 with total page 1170 pages. Available in PDF, EPUB and Kindle. Book excerpt: