Bipolar Membrane With Porous Anion Exchange Layer For Efficient And Long Term Stable Electrochemical Reduction Of Co2 To Co

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Bipolar Membrane with Porous Anion Exchange Layer for Efficient and Long-term Stable Electrochemical Reduction of CO2 to CO

Author : Joey Disch
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Bipolar Membrane with Porous Anion Exchange Layer for Efficient and Long-term Stable Electrochemical Reduction of CO2 to CO by : Joey Disch

Download or read book Bipolar Membrane with Porous Anion Exchange Layer for Efficient and Long-term Stable Electrochemical Reduction of CO2 to CO written by Joey Disch and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Bipolar membranes in forward bias have the potential to address several challenges of alkaline zero-gap CO2 electrolyzers. However, the inevitable gas evolution of CO2 at the membrane junction typically leads to delamination and failure of the membrane after a few hours, limiting its applicability in electrolyzers so far. In this work, a bipolar membrane with a perforated anion exchange layer is presented that allows the CO2 gas to flow back to the cathode and thus preventing accumulation of gas at the junction. This configuration for the first time enables stable operation of a forward bias bipolar membrane showing a degradation rate of 0.5 mV h−1 in a 200 h constant current hold at 100 mA cm−2 and 3.1 V. Highest reported energy efficiency of EECO = 39% and Faradaic efficiency of FECO = 96% at 200 mA cm−2 among forward bipolar membranes prove that the perforated membrane does not compromise efficiency. A maximum CO2 single-pass conversion of 52% at 0.75 mLCO2 min−1 cm−2 and a low specific energy consumption of 665 kJ mol−1 CO2 shows that this concept is superior not only to other bipolar membranes in the literature, but potentially also to conventional anion exchange membrane-based electrolyzers

PEM Water Electrolysis

Author : Dmitri Bessarabov
Publisher : Academic Press
ISBN 13 : 0128111461
Total Pages : 178 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis PEM Water Electrolysis by : Dmitri Bessarabov

Download or read book PEM Water Electrolysis written by Dmitri Bessarabov and published by Academic Press. This book was released on 2018-07-23 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen Energy and Fuel Cell Primers is a series of concise books that present those coming into this broad and multidisciplinary field the most recent advances in each of its particular topics. Its volumes bring together information that has thus far been scattered in many different sources under one single title, which makes them a useful reference for industry professionals, researchers and graduate students, especially those starting in a new topic of research. These volumes, PEM Water Electrolysis vol 1 and 2, allows these readers to identify the technology gaps for the development of commercially viable PEM electrolysis systems for energy applications. This primer examines the fundamentals of PEM electrolysis and selected research topics that are currently subject of attention by academic and industry community, such as gas cross-over and AST protocols. This lays the foundation for the exploration of the current industrial trends for PEM electrolysis, such as power to gas application, are discussed, with strong focus on the current trends in the application of PEM electrolysis associated with energy storage. These include durability aspects of PEM electrolysis systems and components, accelerated stress test protocols, manufacturing aspects of large-scale electrolyzers and components, gas crossover problems in PEM electrolyzer safety, and challenges associated with high-current density operation of PEM electrolyzers. A technology development matrix for systems and components requirements will also be covered, as well as unconventional PEM water electrolysis systems, such as ozone generators Presents the fundamentals and most current knowledge in proton exchange membrane water electrolyzers Explores the technology gaps and challenges for commercial deployment of PEM water electrolysis technologies Includes unconventional systems, such as ozone generators Brings together information from many different sources under one single title, making it a useful reference for industry professionals, researchers and graduate students alike

Flow Chemistry – Fundamentals

Author : Ferenc Darvas
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110388758
Total Pages : 307 pages
Book Rating : 4.1/5 (13 download)

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Book Synopsis Flow Chemistry – Fundamentals by : Ferenc Darvas

Download or read book Flow Chemistry – Fundamentals written by Ferenc Darvas and published by Walter de Gruyter GmbH & Co KG. This book was released on 2014-08-25 with total page 307 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Flow Chemistry fills the gap in graduate education by covering chemistry and reaction principles along with current practice, including examples of relevant commercial reaction, separation, automation, and analytical equipment. The Editors of Flow Chemistry are commended for having taken the initiative to bring together experts from the field to provide a comprehensive treatment of fundamental and practical considerations underlying flow chemistry. It promises to become a useful study text and as well as reference for the graduate students and practitioners of flow chemistry." Professor Klavs Jensen Massachusetts Institute of Technology, USA Broader theoretical insight in driving a chemical reaction automatically opens the window towards new technologies particularly to flow chemistry. This emerging concept promotes the transformation of present day's organic processes into a more rapid continuous set of synthesis operations, more compatible with the envisioned sustainable world. These two volumes Fundamentals and Applications provide both the theoretical foundation as well as the practical aspects.

Electrochemical Cell Design

Author : R.E. White
Publisher : Springer Science & Business Media
ISBN 13 : 1461327954
Total Pages : 397 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Electrochemical Cell Design by : R.E. White

Download or read book Electrochemical Cell Design written by R.E. White and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Photo- and Electro-Catalytic Processes

Author : Jianmin Ma
Publisher : John Wiley & Sons
ISBN 13 : 352734859X
Total Pages : 596 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Photo- and Electro-Catalytic Processes by : Jianmin Ma

Download or read book Photo- and Electro-Catalytic Processes written by Jianmin Ma and published by John Wiley & Sons. This book was released on 2022-01-25 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explore green catalytic reactions with this reference from a renowned leader in the field Green reactions—like photo-, photoelectro-, and electro-catalytic reactions—offer viable technologies to solve difficult problems without significant damage to the environment. In particular, some gas-involved reactions are especially useful in the creation of liquid fuels and cost-effective products. In Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction, award-winning researcher Jianmin Ma delivers a comprehensive overview of photo-, electro-, and photoelectron-catalysts in a variety of processes, including O2 reduction, CO2 reduction, N2 reduction, H2 production, water oxidation, oxygen evolution, and hydrogen evolution. The book offers detailed information on the underlying mechanisms, costs, and synthetic methods of catalysts. Filled with authoritative and critical information on green catalytic processes that promise to answer many of our most pressing energy and environmental questions, this book also includes: Thorough introductions to electrocatalytic oxygen reduction and evolution reactions, as well as electrocatalytic hydrogen evolution reactions Comprehensive explorations of electrocatalytic water splitting, CO2 reduction, and N2 reduction Practical discussions of photoelectrocatalytic H2 production, water splitting, and CO2 reduction In-depth examinations of photoelectrochemical oxygen evolution and nitrogen reduction Perfect for catalytic chemists and photochemists, Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction also belongs in the libraries of materials scientists and inorganic chemists seeking a one-stop resource on the novel aspects of photo-, electro-, and photoelectro-catalytic reactions.

Electrochemical Water and Wastewater Treatment

Author : Carlos Alberto Martínez-Huitle
Publisher : Butterworth-Heinemann
ISBN 13 : 0128131616
Total Pages : 574 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Electrochemical Water and Wastewater Treatment by : Carlos Alberto Martínez-Huitle

Download or read book Electrochemical Water and Wastewater Treatment written by Carlos Alberto Martínez-Huitle and published by Butterworth-Heinemann. This book was released on 2018-05-29 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Water Treatment Methods provides the fundamentals and applications of electrochemical water treatment methods to treat industrial effluents. Sections provide an overview of the technology, its current state of development, and how it is making its way into industry applications. Other sections deal with historical developments and the fundamentals of 18 methods, including coupled methods, such as Electrocoagulation, Peroxi-Coagulation and Electro-Fenton treatments. In addition, users will find discussions that relate to industries such as Pulp and Paper, Pharmaceuticals, Textiles, and Urban/Domestic wastewater, amongst others. Final sections present advantages, disadvantages and ways to combine renewable energy sources and electrochemical methods to design sustainable facilities. Environmental and Chemical Engineers will benefit from the extensive collection of methods and industry focused application cases, but researchers in environmental chemistry will also find interesting examples on how methods can be transitioned from lab environments to practical applications. Offers an excellent overview of the research advances and current applications of electrochemical technologies for water treatment Explains, in a comprehensive way, the fundamentals of different electrochemical uses and applications of different technologies Provides a large number of examples as evidence of practical applications of electrochemistry to environmental protection Explores the combination possibilities with other treatment technologies or emerging technologies for destroying water pollutants

Gaseous Carbon Waste Streams Utilization

Author : National Academies of Sciences, Engineering, and Medicine
Publisher : National Academies Press
ISBN 13 : 0309483360
Total Pages : 257 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis Gaseous Carbon Waste Streams Utilization by : National Academies of Sciences, Engineering, and Medicine

Download or read book Gaseous Carbon Waste Streams Utilization written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2019-02-22 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the quest to mitigate the buildup of greenhouse gases in Earth's atmosphere, researchers and policymakers have increasingly turned their attention to techniques for capturing greenhouse gases such as carbon dioxide and methane, either from the locations where they are emitted or directly from the atmosphere. Once captured, these gases can be stored or put to use. While both carbon storage and carbon utilization have costs, utilization offers the opportunity to recover some of the cost and even generate economic value. While current carbon utilization projects operate at a relatively small scale, some estimates suggest the market for waste carbon-derived products could grow to hundreds of billions of dollars within a few decades, utilizing several thousand teragrams of waste carbon gases per year. Gaseous Carbon Waste Streams Utilization: Status and Research Needs assesses research and development needs relevant to understanding and improving the commercial viability of waste carbon utilization technologies and defines a research agenda to address key challenges. The report is intended to help inform decision making surrounding the development and deployment of waste carbon utilization technologies under a variety of circumstances, whether motivated by a goal to improve processes for making carbon-based products, to generate revenue, or to achieve environmental goals.

Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells

Author : M. I. Ismail
Publisher : Elsevier Publishing Company
ISBN 13 :
Total Pages : 574 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells by : M. I. Ismail

Download or read book Electrochemical Reactors: Fundamentals, electrolysers, batteries, and fuel cells written by M. I. Ismail and published by Elsevier Publishing Company. This book was released on 1989 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a guide for professionals interested in energy transfer and electrochemical technology systems. It covers the state-of-the-art of materials, electrochemistry and electrochemical engineering as related to electrochemical reactors, batteries and fuel cells. The fifteen chapters, written by experts in fields related to every aspect affecting reactor performance, are grouped into three parts. The first is devoted to fundamentals of reactors, batteries and fuel cells and covers various aspects of design, parts, construction, materials operation and control systems. The second group is devoted to specific reactors such as aqueous electro-organic and inorganic synthesis, electrochemical polymerization, molten salt electrolysis, electrochemical machining, metal finishing, reactor performance, failure mechanisms, corrosion control, materials selection and techniques. The third group deals with manufacturing techniques and surface treatment of materials for commercial reactors, commercial parts/materials, fastening, assembly and production of reactor parts and mathematical modelling of various reactor processes.

Solar Hydrogen Generation

Author : Krishnan Rajeshwar
Publisher : Springer Science & Business Media
ISBN 13 : 0387728104
Total Pages : 329 pages
Book Rating : 4.3/5 (877 download)

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Book Synopsis Solar Hydrogen Generation by : Krishnan Rajeshwar

Download or read book Solar Hydrogen Generation written by Krishnan Rajeshwar and published by Springer Science & Business Media. This book was released on 2008-02-21 with total page 329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Given the backdrop of intense interest and widespread discussion on the prospects of a hydrogen energy economy, this book aims to provide an authoritative and up-to-date scientific account of hydrogen generation using solar energy and renewable sources such as water. While the technological and economic aspects of solar hydrogen generation are evolving, the scientific principles underlying various solar-assisted water splitting schemes already have a firm footing. This book aims to expose a broad-based audience to these principles. This book spans the disciplines of solar energy conversion, electrochemistry, photochemistry, photoelectrochemistry, materials chemistry, device physics/engineering, and biology.

Solar to Chemical Energy Conversion

Author : Masakazu Sugiyama
Publisher : Springer
ISBN 13 : 3319254006
Total Pages : 472 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Solar to Chemical Energy Conversion by : Masakazu Sugiyama

Download or read book Solar to Chemical Energy Conversion written by Masakazu Sugiyama and published by Springer. This book was released on 2016-01-25 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book explains the conversion of solar energy to chemical energy and its storage. It covers the basic background; interface modeling at the reacting surface; energy conversion with chemical, electrochemical and photoelectrochemical approaches and energy conversion using applied photosynthesis. The important concepts for converting solar to chemical energy are based on an understanding of the reactions’ equilibrium and non-equilibrium conditions. Since the energy conversion is essentially the transfer of free energy, the process are explained in the context of thermodynamics.

Modern Aspects of Electrochemistry 42

Author : Constantinos G. Vayenas
Publisher : Springer Science & Business Media
ISBN 13 : 0387494898
Total Pages : 434 pages
Book Rating : 4.3/5 (874 download)

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Book Synopsis Modern Aspects of Electrochemistry 42 by : Constantinos G. Vayenas

Download or read book Modern Aspects of Electrochemistry 42 written by Constantinos G. Vayenas and published by Springer Science & Business Media. This book was released on 2008-03-08 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

Electro-Fenton Process

Author : Minghua Zhou
Publisher : Springer
ISBN 13 : 9811064067
Total Pages : 437 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Electro-Fenton Process by : Minghua Zhou

Download or read book Electro-Fenton Process written by Minghua Zhou and published by Springer. This book was released on 2017-11-25 with total page 437 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.

New Promising Electrochemical Systems for Rechargeable Batteries

Author : V. Barsukov
Publisher : Springer Science & Business Media
ISBN 13 : 9780792339489
Total Pages : 564 pages
Book Rating : 4.3/5 (394 download)

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Book Synopsis New Promising Electrochemical Systems for Rechargeable Batteries by : V. Barsukov

Download or read book New Promising Electrochemical Systems for Rechargeable Batteries written by V. Barsukov and published by Springer Science & Business Media. This book was released on 1996-02-29 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electricity is the most important secondary energy source, the present production rate, mainly from thermal electric power stations, being of the order of 1.3 TW. However, the total capacity of primary and rechargeable batteries currently in use is the same as the output of the world's power stations. But present battery systems will not meet future needs for the economical storage of large amounts of electrical energy for vehicles, public transport, road levelling, solar energy utilisation, civil video and audio, terrestrial and space communications, etc. Current accumulators based on aqueous acid or alkali systems do not have sufficient output and, moreover, the materials employed (Pb, Cd, Ni) are environmental pollutants that require safe recycling. Further, stocks of these strategic metals are being rapidly depleted. This book discusses actual field results with novel systems, such as rechargeable lithium batteries, zinc/air cells, metal-free accumulators, graphite/carbon devices and others, including fuel cells. The book stresses that a universal electrochemical system is not feasible: the choice of any system must depend on the concrete field of application and must be taken in consideration of a large number of technical, economic and environmental circumstances.

Applications of Ion Exchange Materials in Biomedical Industries

Author : Inamuddin
Publisher : Springer
ISBN 13 : 3030060829
Total Pages : 225 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Applications of Ion Exchange Materials in Biomedical Industries by : Inamuddin

Download or read book Applications of Ion Exchange Materials in Biomedical Industries written by Inamuddin and published by Springer. This book was released on 2019-01-30 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the applications of ion-exchange materials in the biomedical industries. It includes topics related to the application of ion exchange chromatography in determination, extraction and separation of various compounds such as amino acids, morphine, antibiotics, nucleotides, penicillin and many more. This title is a highly valuable source of knowledge on ion-exchange materials and their applications suitable for postgraduate students and researchers but also to industrial R&D specialists in chemistry, chemical, and biochemical technology. Additionally, this book will provide an in-depth knowledge of ion-exchange column and operations suitable for engineers and industrialists.

Ion Exchange Membranes

Author : Yoshinobu Tanaka
Publisher : Elsevier Science
ISBN 13 : 9780444633194
Total Pages : 0 pages
Book Rating : 4.6/5 (331 download)

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Book Synopsis Ion Exchange Membranes by : Yoshinobu Tanaka

Download or read book Ion Exchange Membranes written by Yoshinobu Tanaka and published by Elsevier Science. This book was released on 2015-01-20 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamental study and industrial application of ion exchange membranes started over half a century ago. Through ongoing research and development, ion exchange membrane technology is now applied to many fields and contributes to the improvement of our standard of living. Ion Exchange Membranes, 2nd edition states the ion exchange membrane technology from the standpoint of fundamentals and applications. It discusses not only various phenomena exhibited by membranes but also their applications in many fields with economical evaluations. This second edition is updated and revised, featuring ten expanded chapters. New to this edition is a computer simulation program of ion-exchange membrane electrodialysis for water desalination that provides a guideline for designing, manufacturing and operating a practical-scale electrodialyzer. Meant to replace experiments, this program will be an important asset to those with time and monetary budgets.

Anion Exchange Membranes in Electrochemical Energy Systems

Author : Yunzhu Zhang
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)

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Book Synopsis Anion Exchange Membranes in Electrochemical Energy Systems by : Yunzhu Zhang

Download or read book Anion Exchange Membranes in Electrochemical Energy Systems written by Yunzhu Zhang and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-CO2-emitting sources of renewable energy, such as solar and wind, have become quite popular in recent years, and their electricity generation cost at scale has become comparable with that of gas- and coal-fired power plants. However, their intermittent output makes the resultant electricity hard to dispatch in a reliable manner in the absence of grid-scale electrical energy storage (EES) technologies. Redox-flow batteries (RFBs) are promising devices for medium- to large-scale electric energy storage. They are safe, reliable, and portable, and are designed with decoupled power and energy modules, which makes it easy and cost-effective to scale their output to meet user demands. However, a significant challenge in RFBs is low RFB efficiency, one key reason for which is short-circuiting due to active ion species crossover through the membrane between the electrolyte solutions.This dissertation focuses on resolving this obstacle and addresses the aforementioned issues in two parts. The first part focuses on the use of the boundary element method to model ion transfer and Donnan exclusion phenomena in both anion and cation exchange membranes. The results guided the membrane fabrication for homogeneous, heterogeneous, and asymmetric membranes. The second part of the dissertation focuses on studying the mechanism of ion selectivity in AEMs, especially the Donnan exclusion effect. Once the mechanism of the ion selectivity of membranes was well understood, modified AEMs with high ion selectivity were developed and applied in the V-Ce ED-RFB and Ti-Ce ED-RFB. 79% energy efficiency (EE) was obtained after 100 charge/discharge cycles at 50 mA/cm2 in V-Ce ED-RFB. The highly selective AEMs mentioned above exhibited 0.4 % cation crossover over 1000 hours of operation. The ED-RFB showed 100% capacity retention over 1300 hours of charge/discharge cycles with 70% energy efficiency.

Innovative Wastewater Treatment & Resource Recovery Technologies: Impacts on Energy, Economy and Environment

Author : Juan M. Lema
Publisher : IWA Publishing
ISBN 13 : 1780407866
Total Pages : 690 pages
Book Rating : 4.7/5 (84 download)

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Book Synopsis Innovative Wastewater Treatment & Resource Recovery Technologies: Impacts on Energy, Economy and Environment by : Juan M. Lema

Download or read book Innovative Wastewater Treatment & Resource Recovery Technologies: Impacts on Energy, Economy and Environment written by Juan M. Lema and published by IWA Publishing. This book was released on 2017-06-15 with total page 690 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the 3R concept applied to wastewater treatment and resource recovery under a double perspective. Firstly, it deals with innovative technologies leading to: Reducing energy requirements, space and impacts; Reusing water and sludge of sufficient quality; and Recovering resources such as energy, nutrients, metals and chemicals, including biopolymers. Besides targeting effective C,N&P removal, other issues such as organic micropollutants, gases and odours emissions are considered. Most of the technologies analysed have been tested at pilot- or at full-scale. Tools and methods for their Economic, Environmental, Legal and Social impact assessment are described. The 3R concept is also applied to Innovative Processes design, considering different levels of innovation: Retrofitting, where novel units are included in more conventional processes; Re-Thinking, which implies a substantial flowsheet modification; and Re-Imagining, with completely new conceptions. Tools are presented for Modelling, Optimising and Selecting the most suitable plant layout for each particular scenario from a holistic technical, economic and environmental point of view.